• Resources Recycling
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• v.27 no.2
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• pp.68-76
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• 2018

EAF (Electric arc furnace) dust is an important secondary resource such as zinc, lead, and iron. Recycling of EAF dust is benefit to solving disposal and environmental problems caused by the heavy metals entrained in the dust. In this study, pyrometallurgical treatment technology of EAF dust reviewed for the improvement of conventional process and development of new process. The existing technologies categorized into four groups: those by rotary kiln process, rotary hearth furnace (RHF) process, shaft type process, and reduction smelting process. The product of these processes are ZnO and Fe or slag as a waste. Their mechanisms for the production of ZnO from EAF dust were carbothermic reduction and oxidation of zinc gas with air.

• Journal of the Korean Recycled Construction Resources Institute
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• v.11 no.4
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• pp.373-380
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• 2023

This study investigated the carbonation of concrete brick cured in a CO₂ environment for the utilization of CO₂ captured in power plants. Concrete brick specimens were produced with electric arc furnace reducing slag (ERS) and electric arc furnace oxidizing slag (EOS), and cured for 3 days in a CO₂ chamber with a concentration of 20 % or in a constant temperature and humidity chamber. The weight change, compressive strength, flexural strength and carbonation depth of concrete bricks were measured. From the results, it was found that when subjected to CO₂ curing, CO₂ was absorbed at the level of 2.4 % of the weight of the specimen. The specimen incorporating ERS showed the highest carbonation depth, and satisfied KS F4004 standards for the concrete brick. Therefore, it is expected that the captured CO₂ can be utilized in the CO₂ curing process of concrete brick.

• Journal of the Korea institute for structural maintenance and inspection
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• v.23 no.4
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• pp.113-119
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• 2019

Many researches on alternative materials as construction materials is continuing by recycling industrial byproducts due to shortage of sitereclamation and natural aggregates. In this paper, engineering properties in early-aged OPC (Ordinary Portland Cement) and GGBFS (Ground Granulated Blast Furnace Slag) concrete are evaluated with EOS aggregate replacement. The related experiments were carried out with 0.6 of water to binder ratio, three levels of EOS replacement ratios (0%, 30% and 50%) for fine aggregate, and two levels of cement replacement with GGBFS (0% and 40%). Several tests such as slump air content, and unit mass measurement are performed for fresh concrete, and compressive strength and diffusion coefficient referred to NT BUILD 492 method are measured for hardened concrete. Through the tests, it was evaluated that the compressive strength in concrete with EOS aggregate increased to 3 days and 7 days but slightly decreased at the age of 28 days. In the accelerated chloride penetration test, GGBFS concrete showed reduced diffusion coefficients by 60 - 67% compared with OPC concrete. The lowest chloride diffusion coefficient was evaluated in the 50% replacement with EOS aggregate, which showed an applicability of EOS aggregate to concrete production.

• Clean Technology
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• v.16 no.4
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• pp.258-264
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• 2010

This study estimated the possibility of phosphate removal characteristics to utilize EAF(electric arc furnace) slag as submarine cover material. The major phosphate removal mechanism was a certain formation of HAP precipitation occurred by the ionization reaction between $Ca^{2+}$ and $OH^-$, which were leached from the EAF Slag. Another phosphate removal mechanism was the adsortion of EAF slag surface. As a result of $PO_4{^-}-P$ removal characteristics using continuous column reactor, $PO_4{^-}-P$ concentration decreased rapidly after 3 days and 10 days later, it show under 0.5 ppm. The result as applied in real sea water, shows that the phosphate removal effects were 93~98% by the subaqueous sediment removal using the EAF slag. In conclusion, EAF slag is useful in $PO_4{^-}-P$ removal and control and it is possible to use without additional process like crush and selection.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2015.05a
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• pp.71-72
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• 2015

As this study is the one related to the ultra high strength concrete essentially used for high rise buildings, it has analyzed on the flowability of ultra high strength concrete according to the variation of coarse aggregate and fine aggregate. The coarse aggregate was planned as two types including Granite Aggregate (GA) and crushed coarse Limestone Aggregate (LA) while fine aggregate was planned as four types including Sea Sand (SS), Limestone Crushed Fine Aggregates (LFA), Electric Arc Furnace Oxidizing Slag Aggregates (EFA) and Crushed Sand (CS) to perform experiment with a total of eight variables. As a result of analyzing slump flow, 500mm concentration time, U-Box and L-Flow, etc. among the characteristics of fresh concrete, a mix using LA+LFA is determined to show high flowability in case of applying ultra high strength concrete.

• Applied Chemistry for Engineering
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• v.26 no.1
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• pp.104-110
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• 2015

It is known that polymer concretes are 8~10 times more expensive than ordinary Portland cement concretes; therefore, in the production of polymer concrete products, it is very important to reduce the amount of polymer binders used because this occupies the most of the production cost of polymer concretes. In order to develop a technology for the reduction of polymer binders, smooth and spherical aggregates were prepared by the atomizing technology using the oxidation process steel slag (electric arc furnace slag, EAFS) and the reduction process steel slag (ladle furnace slag, LFS) generated by steel industries. A reduction in the amount of polymer binders used was expected because of an improvement in the workability of polymer concretes as a result of the ball-bearing effect and maximum filling effect in case the polymer concrete was prepared using the smooth and spherical atomized steel slag instead of the calcium carbonate (filler) and river sand (fine aggregate) that were generally used in polymer concretes. To investigate physical properties of the polymer concrete, specimens of the polymer concrete were prepared with various proportions of polymer binder and replacement ratios of the atomized reduction process steel slag. The results showed that the compressive strengths of the specimens increased gradually along with the higher replacement ratios of the atomized steel slag, but the flexural strength showed a different maximum strength depending on the addition ratio of polymer binders. In the hot water resistance test, the compressive strength, flexural strength, bulk density, and average pore diameter decreased; but the total pore volume and porosity increased. It was found that the polymer concrete developed in this study was able to have a 19% reduction in the amount of polymer binders compared with that of the conventional product because of the remarkable improvement in the workability of polymer concretes using the spherical atomized oxidation steel slag and atomized reduction steel slag instead of the calcium carbonate and river sand.

• Resources Recycling
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• v.28 no.4
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• pp.44-50
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• 2019

In the electric arc furnace process, the chemical energy such as the heat of oxidation reaction and the heat of carbon combustion etc. is consumed as 30% of the total input energy. In order to reduce $CO_2$ emission in EAF, it is necessary to decrease the use of electric power energy during scrap melting stage and increase the use of chemical energy. In general, when the carbon materials is individually charged into the molten steel, the carbon materials floated to the slag layer due to low density before it is dissolved in molten steel. When the concentration of carbon in the molten steel is high, the combustion energy of carbon by oxygen injection can lower the electric power energy and improve the chemical energy consumption. Therefore, an efficient charging methods of carbon material is required to increase the efficiency of carbon combustion heat. On the other hand, Al-dross, which is known as a by-product after Al smelting, includes over 25 mass% of metallic Al, and the oxidation heats of Al is lager than that of carbon. However, the recycling ratio fo Al-dross was very low and is almost landfilled. In order to effectively utilize the heats of oxidation of Al in Al-dross, it is necessary to study the application of Al-dross in the steel process. In this study, the dissolution efficiency of carbon and aluminum in molten steel was investigated by varying the reaction temperature and the mixing ratios of coke and Al-dross.

• Journal of Korean Society of Environmental Engineers
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• v.28 no.3
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• pp.329-336
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• 2006

Iron manufacturing process involves production of various by-product including slag, sludge, sintering and EAF(Electric Arc furnace dust). Some of the by-products such as EAF and sintering dust are disposed of as waste due to their high heavy metal contents. It has been notice for many years that the EAF dust also contain about 65% of Fe(0) and Fe(II) and then the possible utilization of the iron. One possibility is to apply the EAF as a lining material in conjunction with clay or HDPE liners, in waste landfill. The probable reaction between the leachate containing toxic elements such as TCE, PCE dioxine and $Cr^{6+}$ is reduction of the toxic materials in corresponding to the oxidation of the reduced iron and therefore diminishing the toxicity of the leachate. It is, however, prerequisite to evaluate the leaching characteristics of the EAF dust before application. Amelioration of the leachate would be archived only when the level of toxic elements in the treated leachate is less than that of in the untreated leachate. Several leaching techniques were selected to cover different conditions and variable environments including time, pH and contact method. The testing methods include availability test, pH-stat test and continuous column test. Cr and Zn are potentially leachable elements among the trace metals. The pH of the EAF dust is highly alkaline, recording around 12 and Zn is unlikely to be leached under the condition. On the contrary Cr is more leachable under alkaline environment. However, the released Cr should be reduced to $Cr^{3+}$ and then removed as $Cr(OH)_3$. Removal of the Cr is observed in the column test and further study on the specific reaction of Cr and EAF dust is underway.