• Title/Summary/Keyword: Effects of Mo

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Numerical Study on Structure and Pollutant Formation for Syngas Turbulent Nonpremixed Swirling Flames (석탄가스 선회난류 비예혼합 화염장의 화염구조 및 NOx 배출특성 해석)

  • Lee, Jeong-Won;Kang, Sung-Mo;Kim, Yong-Mo;Joo, Yong-Jin
    • Journal of the Korean Society of Combustion
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    • v.14 no.2
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    • pp.10-17
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    • 2009
  • The present study numerically investigate the effects of the Syngas chemical kinetics on the basic flame properties and the structure of the Syngas nonpremixed flames. In order to realistically represent the turbulencechemistry interaction and the spatial inhomogeneity of scalar dissipation rate, the Eulerian Particle Flamelet Model (EPFM) with multiple flamelets has been applied to simulate the combustion processes and NOx formation in the syngas turbulent nonpremixed flames. Validation cases include the Syngas turbulent nonpremixed jet and swirling flames. Based on numerical results, the detailed discussion has been made for the effects of the chemical kinetics, the flame structure, and NOx formation characteristics in the turbulent Syngas nonpremixed flames.

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Investigation of Friction and Wear Characteristics of Automotive friction Materials containing different relative amounts of solid lubricants(Graphite, MoS$_2$, and Sb$_2$S$_3$) (자동차용 마찰재에 사용되는 고체윤활제의 성분비에 따른 마찰 밀 마모 특성에 관한 연구)

  • Choi, Nak-Cheon;Jang, Ho
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 1999.06a
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    • pp.265-271
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    • 1999
  • The effects of solid lubricants on wear and friction characteristics of friction materials were studied using a pad-on-disk type friction tester. Friction materials with four different formulations containing different relative amounts of solid lubricants(graphite, MoS$_2$, and Sb$_2$S$_3$) were investigated. Results of this work showed that each formulation with different lubricants had unique friction characteristics. Friction material containing rich MoS$_2$ showed excellent friction stability at different friction conditions. However friction material containing rich Sb$_2$S$_3$revealed high wear of friction materials.

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Effects on Properties of $V_2O_5$-added $TiO_2$ Ceramics ($V_2O_5$ 첨가가 $TiO_2$ 세라믹스의 물성에 미치는 효과)

  • You, Do-Hyun
    • Proceedings of the KIEE Conference
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    • 2007.11c
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    • pp.138-140
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    • 2007
  • $TiO_2-V_2O_5$ sol was fabricated using sol-gel method and $TiO_2-V_2O_5$ thin films were fabricated using dip-coating method. $V_2O_5$ sol was added 0.01mo1e, 0.03mo1e, 0.05mo1e into $TiO_2$ sol. Viscosity of sol increased fast from about 1,000 minutes and sol began gelation from about 10,000 minutes. As a results of crystalline properties, $V_2O_5$ peaks were not found despite of $V_2O_5$ addition. Endothermic reaction occurred due to evaporation of solvent and dissociation of OH at $80^{\circ}C$. Exothermic reaction occurred due to combustion and oxidation of solvent at $230^{\circ}C$, occurred to combustion and oxidation of alkyl group at $350^{\circ}C$. Thickness of thin films increased $0.1{\sim}0.25{\mu}m$ every a dipping.

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Effect of Carbide Forming Elements on Hardness and Linear Thermal Expansion Coefficient of Low Thermal Expansive Cast Irons (저 열팽창 주철의 경도향상 및 선팽창계수에 미치는 탄화물 형성원소의 영향)

  • Moon, Byung-Moon;Hong, Chun-Pyo
    • Journal of Korea Foundry Society
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    • v.17 no.1
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    • pp.36-50
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    • 1997
  • Invar-type austenitic cast irons are being used as low thermal expansive materials because of its good low thermal expansion characteristics and castability despite its low hardness. The effects of alloying elements such as Cr, Ti, V, and Mo on hardness and linear thermal expansion coefficient of the invar-type austenitic cast irons were investigated. A combined use of V and Mo addition was found to be the most effective for the improvement of hardness without causing an increase in the thermal expansion coefficient. With a combined addition of 4.6wt%V and 3.8wt%Mo, the hardness increased up to 180HB and the thermal expansion coefficient was kept at a relatively low value of $4.6{\times}10^{-6}/^{\circ}C$ in the temperature range from room to $250^{\circ}C$.

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The Effect of Paste Composition and Particle Size on the Alumina Ceramics Metallizing (Paste의 조성과 입도 변화가 알루미나 세라믹스의 Metallizing에 미치는 영향에 관한 연구)

  • 김태송;김성태;김종희
    • Journal of the Korean Ceramic Society
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    • v.30 no.5
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    • pp.347-356
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    • 1993
  • In joining alumina ceramics to metal by using Mo-Mn metallizing process the effects of metallizing thickness, temperature, and the composition of paste on the bond strength and the microstructure of joining interface were investigated. The bond strength variation in the range of metallizing temperature, 1350~155$0^{\circ}C$ was more than 150MPa above 145$0^{\circ}C$ and the optimum metallizing thickness was 30${\mu}{\textrm}{m}$. The optimum contents of Mn in Mo-Mn paste was 5% due to the bond strength decrease with the increase of addition. The effect of SiO2 addition in paste on bond strength was saturated around 200MPa. It was also observed that as the particle size of Mo decreased, the joinning with higher bond strength was shown in spite of low metallizing temperature.

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A Study on CO Substitution of Group 6 Metal Carbonyls by Using Phase Transfer Catalyst(2) (상이동촉매에 의한 GROUP 6 금속카르보닐의 CO 치환에 관한 연구(2) : 반응시간과 촉매량에 의한 영향)

  • Yang, Hyun-Soo;Park, Ha-Seon
    • Applied Chemistry for Engineering
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    • v.3 no.3
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    • pp.407-411
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    • 1992
  • The effects of phase transfer catalyst was studied on the substitution of CO ligand of $Mo(CO)_6$ [M=Cr, Mo, W] with two electron-pairs donating ligands, 2, 2'-bipyridine and 2, 2'-biquinoline. The change of product yield, $M(CO)_4(L)_2$, was discussed according to reaction time, mole composition of $M(CO)_6$, and type of ligand.

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Effects of Mechanical Properties on Wear Resistance of 0.27C-0.70Ni-1.42Cr-0.20Mo Steel (0.27C-0.70Ni-1.42Cr-0.20Mo 내마모강의 기계적 성질에 따른 마모특성)

  • Lee Y. H.;Han C. H.;Shin J. H.;Jang B. L.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2001.10a
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    • pp.260-263
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    • 2001
  • Mechanical properties have been accepted to be major factor to improve wear resistance. The effect of mechanical properties on wear resistance of 0.27C-0.70Ni-1.42Cr-0.20Mo steel was studied under various test conditions. It is clear that yield strength, tensile strength, impact value, and hardness are strongly related each other. Wear resistance tests as pin on plate type and dry sand / rubber wheel type proved to be that wear depends on mechanical properties. Microstructures were also observed to make clear the wear properties. At quenching and low temperature tempering, the specimen has a good wear resistance.

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Effect of Interlayers on the Bending Strength of Silicon Nitride/Staineless Steel Joints (중간재가 질화규소/스테인레스 스틸 접합체의 굽힘강도에 미치는 영향)

  • 박상환;최영화;김태우
    • Journal of the Korean Ceramic Society
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    • v.33 no.3
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    • pp.251-258
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    • 1996
  • The reactions between an active metal brazing alloy and interlayers together with the effects of interlayer type on the interfacial microstructure change were investiaged for silicon nitride/stainless steel joint. The bending strengths were measured for joints with Mo, Cu, Ni interlayer type of different thicknesses. It was found that the interlayer with a low yield strength value is effective to improve the bending strength of the Si3N4/stainless steel joint. The maximum joint strength obtained at room temperature for a laminated Cu/Mo interlayer was about 460 MPa. The combined use of Mo and thin Cu layer was found to be effective in enhancing the bending strength for the Si3N4/S.S.316 joint.

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Verification and validation of ShipMo3D ship motion predictions in the time and frequency domains

  • Mctaggart, Kevin A.
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.3 no.1
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    • pp.86-94
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    • 2011
  • This paper compares frequency domain and time domain predictions from the ShipMo3D ship motion library with observed motions from model tests and sea trials. ShipMo3D evaluates hull radiation and diffraction forces using the frequency domain Green function for zero forward speed, which is a suitable approach for ships travelling at moderate speed (e.g., Froude numbers up to 0.4). Numerical predictions give generally good agreement with experiments. Frequency domain and linear time domain predictions are almost identical. Evaluation of nonlinear buoyancy and incident wave forces using the instantaneous wetted hull surface gives no improvement in numerical predictions. Consistent prediction of roll motions remains a challenge for seakeeping codes due to the associated viscous effects.

The Effects of Environmental Adaptation Patterns in the Railway Public Enterprises on Marketing Capabilities and Organizational Performance: Focused on the Market Orientation of Korail and Subway Firms (철도공기업의 환경적응패턴이 마케팅역량과 조직성과에 미치는 영향: 코레일과 지하철 조직의 시장지향성을 중심으로)

  • Shin, Tack-Hyun;Kim, Sung-Ho
    • Journal of the Korean Society for Railway
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    • v.15 no.1
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    • pp.71-79
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    • 2012
  • The main purpose of this study is to depict the causal relationship among Market Orientation(MO), Marketing Capabilities(MC), and Organizational Performance(OP) with the moderating effect of Environmental Turbulence(ET), especially comparatively highlighting the differences between Korail and Subway firms. Findings show that there partly existed significant interactions effects between ET and MO in case of subway firms, whereas Korail did not reveal any significant results. When considering the strong relationship between MO and MC shown in the subway firms' case, it can be inferred that subway firms continuously have attempted to adapt to the external environment facing them more flexibly and actively over their counterpart, by which the degree of their MC became positively enhanced over Korail. These results give us some implication that MO should be internalized and also MC should get a higher consideration than ever throughout the railway public enterprises in order to strengthen their performance.