• Clean Technology
• /
• v.17 no.4
• /
• pp.346-352
• /
• 2011

The adsorption characteristics of propineb pesticide onto activated carbon has been investigated for the adsorption in aqueous solution with respect to initial concentration, contact time and temperature in batch experiment. The Langmuir and Freundlich adsorption models were applied to described the equilibrium isotherms and isotherm constants were also determined. The Freundlich model agrees with experimental data well. slope of isotherm line indicate that activated carbon could be employed as effective treatment for removal of propineb. The pseudo first order, pseudo second order kinetic models were use to describe the kinetic data and rate constants were evaluated. The adsorption process followed a pseudo second order model, and the adsorption rate constant($k_2$) decreased with increasing initial concentration of propineb. The activation energy, change of free energy, enthalpy, and entropy were also calculated to predict the nature adsorption. The estimated values for change of free energy were -7.28, -8.27 and -11.66 kJ/mol over activated carbon at 298, 308 and 318 K, respectively. The results indicated toward a spontaneous process. The positive value for change of enthalpy, 54.46 kJ/mol, found that the adsorption of propineb on activated carbon is an endothermic process.

• Horticultural Science & Technology
• /
• v.33 no.5
• /
• pp.751-762
• /
• 2015

This study was performed to investigate the stability of soil moisture in controlling air ventilation rate within a horizontal biofilter, and to compare removal efficiency (RE) of indoor air pollutants including fine dust, volatile organic compounds (VOCs), and formaldehyde (HCHO), depending on whether dieffenbachias (Diffenbachia amoena) were planted in the biofilter. The relative humidity, air temperature, and soil moisture contents showed stable values, regardless of the presence of D. amoena, and the plants grew normally in the biofilter. REs for number of fine dust particles (PM10 and PM2.5) within the biofilter filled with only soil were at least 30% and 2%, respectively. REs for number of fine dust particles (PM10 and PM2.5) within the biofilter including the plants were above 40% and 4%, respectively. RE for fine dust (PM10) weight was above 4% and 20%, respectively, in the biofilter containing only soil or soil together with plants. In the case of the biofilter filled with only soil, REs for xylene, ethylbenzene, toluene or total VOC (T-VOC) were each more than 63%; however, REs for benzene and formaldehyde (HCHO) were above 22% and 38%, respectively. In the biofilter with the plants, REs for xylene, ethylbenzene, toluene, and T-VOC were each above 72%, and REs for benzene and HCHO were above 39%. Thus, RE of the biofilter integrated with plants was found to be higher for volatile organic compounds than for fine dust. Hence, the biofilter was very effective for indoor air quality improvement and the effect was higher when integrated with plants.

• Clean Technology
• /
• v.25 no.1
• /
• pp.63-73
• /
• 2019

Numerical analysis was done to evaluate the chemical reaction and the reduction rate inside of selective non-catalytic reduction to denitrification in combustion process. The $NO_X$ reduction in selective non-catalytic reduction is converted to not only nitrogen but also nitrous oxide. Simultaneous $NO_X$ reduction and nitrous oxide generation suppressing is required in selective non-catalytic reduction because nitrous oxide influences the global warming as a greenhouse gas. The current study was performed compare the computational analysis in the same temperature and amount of NaOH, and in comparison with the previous research experiments and confirmed the reliability of the computational fluid dynamics. Additionally, controlling the addition amount of NaOH to predict the $NO_X$ reduction efficiency and nitrous oxide production. Numerical analysis was done to check the mass fraction of each material in the measurement point at the end of selective non-catalytic reduction. Experimental Value and simulation value by numerical analysis showed an error of up to 18.9% was confirmed that a generally well predicted. and it was confirmed that the widened temperature range of more than 70% $NO_X$ removal rate is increased when the addition amount of NaOH. So, large and frequent changes of the reaction temperature waste incineration facilities are expected to be effective.

• Horticultural Science & Technology
• /
• v.28 no.5
• /
• pp.864-870
• /
• 2010

This study was conducted to determine the effects of foliage plants on reducing indoor carbon dioxide ($CO_2$). Five foliage plants such as $Hedera$ $helix$ L., $Ficus$ $benjamina$ L., $Pachira$ $aquatica$, $Chamaedorea$ $elegans$, and $Ficus$ $elastica$ were selected and cultivated in two different growth medium (peatmoss and hydroball). Each plant was placed in an airtight chamber and then treated with the combinations of two different $CO_2$ concentrations (500 or 1,000 ppm) and two different light intensities (50 or $200{\mu}mol{\cdot}m^{-2}{\cdot}s^{-1}$). The change of $CO_2$ concentration (ppm) in the airtight chamber during day and night was measured and then converted into the photosynthetic rate (${\mu}mol\;CO_2{\cdot}m^{-2}{\cdot}s^{-1}$). As the results, each foliage plant reduced $CO_2$ level in the airtight chamber for one hour by photosynthesis. $Pachira$ $aquatica$ and $Ficus$ $elastica$ absorbed $CO_2$ more effectively compared to the other plants. The plants exposed to higher $CO_2$ concentration (1,000 ppm) and higher light intensity ($200{\mu}mol{\cdot}m^{-2}{\cdot}s^{-1}$) showed more effective $CO_2$ elimination rate and photosynthetic rate. The plants that have wide leaves and big leaf areas such as $Pachira$ $aquatica$, $Hedera$ $helix$ L.,and $Ficus$ $elastica$ showed higher photosynthetic rate than the other plants that have smaller leaves. Released $CO_2$ concentration by respiration of the plants during the night was very low compared to the absorbed $CO_2$ concentration by photosynthesis during the day. There was no significant difference between peatmoss and hydroball medium on reducing $CO_2$ concentration and increasing photosynthetic rate. In conclusion, this study suggested that foliage plants can effectively eliminate indoor $CO_2$. Optimum environmental control in relation to photosyntheis and usage of right indoor foliage plants having lots of leaves and showing active photosynthesis even under low light intensity like indoor light condition would be required to increase the elimination capacity of indoor $CO_2$.

• KOREAN JOURNAL OF CROP SCIENCE
• /
• v.54 no.4
• /
• pp.366-374
• /
• 2009

To determine the optimum operating conditions of the indented cylinder length grader based on varietal characteristics, broken rice removal capabilities were measured on the milled rice of 41 varieties at different conditions consisted of 3 types of indented cylinders with different indent-opening diameters and 3 different collecting-angles of broken rice. The broken rice removal capabilities were swayed by the indent's opening diameter and depth as well as the angle of the collecting trough of broken rice on the point of instrument, and by the kernel length and width as well as 1000 grain weight of milled rice on the point of rice variety. When the angle of broken rice collecting-trough reached to near the horizontal center line of the indented cylinder on the direction of upward turning side, which was referred $0^{\circ}$ in this paper, the amount of rice collected in trough increased, whereas the loss of head rice also increased. Considering the removal rate of broken rice as well as loss of head rice, it was thought that the suitable angle of trough for broken rice collecting was located $5^{\circ}$ to $15^{\circ}$ depending on varietal characteristic and indent opening diameter. It was thought that 4.2 mm or more of indent opening diameter was recommendable for the rice varieties having heavier 1000 grain weight than 22.3g, as well as larger sizes than 2.9 and 5.2 mm in width and length of rice kernel, respectively; 3.8 mm for the small-sized thin kernels, and a proper diameter between 3.8 and 4.2 mm for short to middle kernels. The varieties with relatively shorter length compared to width of kernel were more difficult to separate the broken rice than the opposite ones. For effective separation of that, it seems that some specific indent shapes such as wider opening and shallow depth etc. are required. When the broken rice content were excessively high, wider diameters of indent openings than specified sizes were thought to be the better.

• Journal of Soil and Groundwater Environment
• /
• v.11 no.1
• /
• pp.14-22
• /
• 2006

Laboratory column experiment for simultaneous removal of Cd and Cr(VI) were conducted using newly developed material of Fe-loaded zeolite having both reduction ability and sorption capacity. The solution containing Cd and Cr(VI) was injected into the column and the breakthrough curves (BTCs) for the contaminants were observed at the effluent port. Cd breakthrough was not initialized until Cr(VI) breakthrough was completed. Therefore it could be concluded that overall efficiency of Fe-loaded zeolite should be determined by the reactivity for Cr(VI). The relative concentration of Cr(VI) BTC increased to the unit value while initial breakthrough was delayed and the propagation of breakthrough was slowed. In order to quantitatively describe the shape of Cr(VI) BTC, new parameters of ${\alpha}\;and\;{\beta}$ designated to be shape parameters, were defined and applied in contaminant transport concentration. These parameters were employed to represent the degree of initial breakthrough delay and the degree of breakthrough propagation, respectively. As initial contaminant concentration increased, ${\alpha}$ decreased, which indicated the delay of BTC's initiation. And as initial contaminant flow rate increased, ${\beta}$ decreased, which represented the faster propagation of the BTC. From these results, Fe-loaded zeolite was found to be an effective reactive material for PRBs against heavy metals having different ionic forms in groundwater. And it could be expected that as groundwater flows faster, the propagation of breakthrough would be faster and as contaminant concentration is higher, the initial point of breakthrough would appear earlier.

• Korean Journal of Soil Science and Fertilizer
• /
• v.45 no.6
• /
• pp.1230-1236
• /
• 2012

To verify that the electrokinetic remediation is effective for decreasing salinity of fields of the plastic-film house, field tests for physical property, chemical property, and crop productivity of soils have been conducted. The abridged result of those tests is as follows. In the EK treatment, the electrokinetic remediation has been treated at the constant voltage (about 0.8 V $cm^{-1}$) for fields of the farm household. At this time, an alternating current (AC) 220 V of the farm household was transformed a direct current. The HSCI (High Silicon Cast Iron) that the length of the stick for a cation is 20cm, and the Fe Plate for an anion have been spread out on the ground. As the PVC pipe that is 10 cm in diameter was laid in the bottom of soils, cations descend on the cathode were discharged together. For soil physical properties according to the EK treatment, the destruction effect of soil aggregate was large, and the infiltration rate of water was increased. However, variations of bulk density and porosity were not considerable. Meanwhile, in chemical properties of soils, principal ions of such as EC, $NO_3{^-}$-N, $K^+$, and $Na^+$ were better rapidly reduced in the EK treated control plot than in the untreated control plot. And properties such as pH, $P_2O_5$ and $Ca^{2+}$ had a small impact on the EK. For cropping season of crop cultivation according to the EK treatment, decreasing rates of chemical properties of soils were as follows; $NO_3{^-}$-N 78.3% > $K^+$ 72.3% > EC 71.6% $$\geq_-$$ $Na^+$ 71.5% > $Mg^{2+}$ 36.8%. As results of comparing the experimental plot that EK was treated before crop cultivation with it that EK was treated during crop cultivation, the decreasing effect of chemical properties was higher in the case that EK was treated during crop cultivation. After the EK treatment, treatment effects were distinct for $NO_3{^-}$-N and EC that a decrease of nutrients is clear. However, because the lasting effect of decreasing salinity were not distinct for the single EK treatment, fertilization for soil testing was desirable carrying on testing for chemical properties of soils after EK treatments more than two times. In the growth of cabbages according to the EK treatment, the rate of yield increase was 225.5% for the primary treatment, 181.0% for the secondary treatment, and 124.2% for third treatment compared with the untreated control plot. The yield was increased by a factor of 130.0% for the hot pepper at the primary treatment (Apr. 2011), 248.1% for the lettuce at the secondary treatment (Nov.2011), and 125.4% for the young radish at the third treatment (Jul. 2012). In conclusion, the effect of yield increase was accepted officially for all announced crops.

• Journal of the Korea Organic Resources Recycling Association
• /
• v.14 no.1
• /
• pp.151-159
• /
• 2006

In these days, the importance of sludge treatment is emerging due to the London Convention, so this study was conducted to propose the alternatives for the improved sludge treatment on the organic wastewater and sewage sludge with JAR test and settling column equipped with stirrer. The minimum coagulant dosage to earn the optimum sludge settling efficiency resulted from 200mg/l and each critical sludge settling interface showed no distinct difference when PAC was dosed over 200mg/l. Accordingly, Clarification Rate(CR) with 200mg/l dosage was calculated to CR=(Ho-Ht) / Ho=1-0.4=0.6 because the critical sludge settling height stopped at 0.4. The settling velocity of sludge interface was decreased with the increase of MLSS concentration but rather increased with MLSS concentration over 1,000mg/l. This resulted from positive effect of interacted coagulation for floc formation by transfer to the zone of compressed settling when MLSS concentration increased over 1,000mg/l. The settling velocity of sludge interface showed $28.66{\times}10^{-3}/min$ for average settling velocity of sewage sludge which is 6.7 times higher than $4.25{\times}10^{-3}/min$ for average settling velocity of organic wastewater sludge. The increasing rate of CR for organic wastewater activated sludge was higher than that of settling velocity under 200mg/l of PAC dosage but settling velocity was higher than CR over 200mg/l of PAC dosage. However, in case of sewage sludge, the differential rate of CR was low when PAC dosage was increased but the settling velocity was suddenly increased with over 200mg/l dosage. Therefore coagulation effect was more efficient to MLSS settling velocity rather than SS removal effect in the supernatant.

• The Korean Journal of Pesticide Science
• /
• v.17 no.4
• /
• pp.237-243
• /
• 2013

Pesticides were sprayed on perilla leaf and leafy lettuce in a greenhouse and the reduction rate of pesticide residues on each vegetable by washing were tested. The reduction rate of pesticide residues by washing for 30 sec~3 min on perilla leaf were 3~63% in tap water, 2~58% in salt water, 6~74% in green tea water, and 8~86% in detergent solution. The detergent solution only showed significant difference in reduction rates compared to the tab water washing. Considering reduction effects of the washing duration, it was showed that the reduction rates were a pattern of inclining as the duration of washing process increased, but there was no significant difference in the reduction rates except the reduction rates between washing in the detergent solution for 1 min and 3 min. Comparing washing in flowing tab water and in stagnant tab water with leafy lettuce, the reduction rate by one time washing were 8~68% in flowing tab water and 7~64% in stagnant tab water. The water and the time used in this experiment were 17.5 L, 2.9 min with flowing tab water and 4 L, 1 min with stagnant tab water. The reduction rate by 3 times washing in stagnant tab water were 16.5~76.6%, and the water and the time used were 12 L, 3 min. Therefore, when the water and the time used to wash vegetables were considered, washing two or three times in stagnant tab water could be more effective than washing one time in flowing tab water.

• KSCE Journal of Civil and Environmental Engineering Research
• /
• v.3 no.2
• /
• pp.1-15
• /
• 1983

This paper has concentrated on estimating the possibility and mathematical analysis for the application of BFB to the treatment of nightsoil with low dilution rate. The experiment for the study of this purpose was conducted by continuous type reactor at $20^{\circ}C$, varying F/M ratio from 0.12 to 0.37 and dilution ratio from 2 to 10, and in it provided matted reticulated polypropylene sheets for the solid supports. The obtained results showed that the application of BFB to the treatment of nightsoil would be more effective than any other biological treatment process. Also, it has observed that the optimum dilution ratio was about 5 times and the optimum HRT was about 17 hours, and then it was estimated that the reactor volume and the quantity of weak water could be reduced to the extent of 70 percent and 80 percent. The experimental results of BFB could be analysed by the mathematical models applied to complete mixing activated sludge process. The substrate removal rates which were obtained by McKinney's($K_m$) and EcKenfelder's($K_e$) equation was 1.784/hr and $2.0{\times}10l/mg{\cdot}day$, and substrate was removed very rapidly compared to those of conventional type biological treatment processes. The biomass yield coefficient($a_5$), the endogeneous respiration rate(b), the synthesis oxygen demand rate($a{_5}^{\prime}$), and the endogeneous respiration oxygen demand rate(b') were 0.349, 0.0237/day, 0.495 and 0.0336, respectively.