• Journal of the Mineralogical Society of Korea
• /
• v.22 no.4
• /
• pp.313-324
• /
• 2009

We explore the effect of particle shape and size on 3-dimensional (3D) network and pore structure of porous earth materials composed of glass beads and silica gel using NMR micro-imaging in order to gain better insights into relationship between structure and the corresponding hydrologic and seismological properties. The 3D micro-imaging data for the model porous networks show that the specific surface area, porosity, and permeability range from 2.5 to $9.6\;mm^2/mm^3$, from 0.21 to 0.38, and from 11.6 to 892.3 D (Darcy), respectively, which are typical values for unconsolidated sands. The relationships among specific surface area, porosity, and permeability of the porous media are relatively well explained with the Kozeny equation. Cube counting fractal dimension analysis shows that fractal dimension increases from ~2.5－2.6 to 3.0 with increasing specific surface area from 2.5 to $9.6\;mm^2/mm^3$, with the data also suggesting the effect of porosity. Specific surface area, porosity, permeability, and cube counting fractal dimension for the natural mongolian sandstone are $0.33\;mm^2/mm^3$, 0.017, 30.9 mD, and 1.59, respectively. The current results highlight that NMR micro-imaging, together with detailed statistical analyses can be useful to characterize 3D pore structures of various porous earth materials and be potentially effective in accounting for transport properties and seismic wave velocity and attenuation of diverse porous media in earth crust and interiors.

• Proceedings of the KSME Conference
• /
• 2007.05b
• /
• pp.2142-2147
• /
• 2007

Experimental study was conducted to evaluate the performance of a miniature loop heat pipe (MLHP) with non-inverted meniscus type capillary structure. All parts of MLHP in this study were made of copper including the capillary structure and the distilled water was used as a working fluid of MLHP. The outer diameter of evaporator was 9 mm and its length was 119 mm. The effective pore size of the capillary structure was 30 micron and its porosity was 60%. The vapor transport line, the liquid transport line and the condenser were consisted of single 4.0 mm copper tube. The distance between the evaporator and the condenser region was 200 mm and the length of the loop was 969 mm. This MLHP was operated successfully at any orientation but the gravity highly influenced the thermal performance of the MLHP. The maximum thermal load was 130 watts at the bottom heat mode and the 20 watts at the top heat mode.

• Journal of the Korean Society of Industry Convergence
• /
• v.21 no.1
• /
• pp.29-36
• /
• 2018

Low pressure casting process for unidirectional carbon fiber reinforced aluminum (UD-CF/Al) composites which is an infiltration route of molten Al into porous UD-CF preform has been a cost-effective way to obtain metal matrix composites (MMCs) but, easy to cause non-uniform fiber distribution as CF clustering. Such clustered CFs have been a problem to decrease the density and thermal conductivity (TC) of composites, due to the existence of pores in the clustered area. To obtain high thermal performance composites for heat-sink application, the relationship between fiber distribution and porosity has to be clearly investigated. In this study, the CF distribution was evaluated with quantification approach by using two-dimensional spatial distribution method as local number 2-dimension (LN2D) analysis. Note that the CFs distribution in composites sensitively changed by sizes of Cu bridging particles between the CFs added in the UD-CF preform fabrication stage, and influenced on only $LN2D_{var}$ values.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2015.08a
• /
• pp.190.1-190.1
• /
• 2015

Graphite has excellent mechanical and physical properties. It is known to advanced materials and is used to materials for molds, thermal treatment of furnace, sinter of diamond and cemented carbide tool etc. SiC materials are coated on the surface and holes of graphite to protect particles emitted from porous graphite with 5%~20% porosity and make graphite hard surface. SiC materials have high durability and thermal stability. Thermal CVD method is widely used to manufacture SiC thin films but high cost of machine investment and production are required. SiC thin films manufactured by Si reaction liquid and vapore with carbon are effective because of low cost of machine and production. SiC thin films made by vapor silicon infiltration into porous graphite can be obtained for shorter time than liquid silicon. Si materials are evaporated to the graphite surface in about $10^{-2}$ torr and high temperature. Si materials are melted in $1410^{\circ}C$. Si vapor is infiltrated into the surface hole of porous graphite and $Si_xC_y$ compound is made. $Si_x$ component is proportional to the Si vapor concentration. Si diffusion coefficient is estimated from quadratic equation obtained by Fick's second law. The steady stae is assumed. Si concentration variation for the depth from graphite surface is fitted to quadratic equation. Diffusion coefficient of Si vapor is estimated at about $10^{-8}cm^2s^{-1}$.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2015.08a
• /
• pp.59.1-59.1
• /
• 2015

In the Linford group at Brigham Young University we have recently developed three new sets of materials for three different areas of separations science: thin layer chromatography (TLC), high performance liquid chromatography (HPLC), and solid phase microextraction (SPME). First, via microfabrication we have grown patterned carbon nanotube (CNT) forests on planar substrates that we have infiltrated with inorganic materials such as silicon nitride. The coatings on the CNTs are conformal and typically deposited in a process like low pressure chemical vapor deposition. The resulting materials have high surface areas, are porous, and function as effective separation devices, where separations on our new TLC plates are typically significantly faster than on conventional devices. Second, we used the layer-by-layer (electrostatically driven) deposition of poly (allylamine) and nanodiamond onto carbonized poly (divinylbenzene) microspheres to create superficially porous particles for HPLC. Many interesting classes of molecules have been separated with these particles, including various cannabinoids, pesticides, tricyclic antidepressants, etc. Third, we have developed new materials for SPME by sputtering silicon onto cylindrical fiber substrates in a way that creates shadowing of the incoming flux so that materials with high porosity are obtained. These materials are currently outperforming their commercial counterparts. Throughout this work, the new materials we have made have been characterized by X-ray photoelectron spectroscopy, time-of-flight secondary ion mass spectrometry, scanning electron microscopy, transmission electron microscopy, etc.

• Journal of the Korea Concrete Institute
• /
• v.18 no.1 s.91
• /
• pp.65-71
• /
• 2006

Concrete has a void, which exists as one of defect in concrete. If the porosity of concrete increases, durability of concrete decreases. In this paper, to improve surface void of concrete, surface penetration sealers are applied to specimen. And, it were investigated that the resistances of chloride penetration and freezing and thawing for concrete with surface penetration sealer of two types. According to the results, surface penetration sealer has not show a harmful influence on strength and resistance of freezing and thawing. Surface penetration sealers were effective in the resistance of chloride penetration.

• Journal of Environmental Science International
• /
• v.17 no.1
• /
• pp.119-128
• /
• 2008

Laboratory analytical results of 22 sets of hydrophobic adsorbent coils containing surface soil-vapor and two soil samples collected by conventional intrusive method from each boring location at two active dry cleaning facilities in the State of Illinois, U.S.A, were presented to evaluate the performance of soil-vapor survey. The most critical factor to determine the effectiveness of soil-vapor survey is the distance from the soil-vapor sampling device to the actual contamination, which is a function of soil porosity, permeability, primary lithology, and other geological and hydrogeological site-specific parameters. Also this factor can be affected by the history of contaminant-generating operations. The laboratory analytical results in this study showed longer dry cleaning operation history (i.e., 50 years) and presence of fine sand at the beneath Site B allow the contaminants to migrate farther and deeper over a fixed time compared to Site A(i.e., 35 years and silty clay) so that the soil-vapor survey is not likely the most effective environmental site investigation method alone for Site B. However, for Site A, the soil-vapor survey successfully screened the site to identify the location reporting the highest soil concentration of chlorinated solvents.

• Carbon letters
• /
• v.19
• /
• pp.23-31
• /
• 2016

Carbon rich fly ash was recently reported to have compositions that are ideal for use as a precursor and catalyst for carbon nanotube growth. This fly ash powder is mostly composed of pure carbon, predominantly present as sp². In this work, the effect of sonication time on the morphology and structural properties of carbon rich fly ash particles is reported. The obtained results show that ultrasound treatment is an effective tool for producing ultrafine particles/fragments with higher porosity, which might be suitable for the adsorption of gasses. Moreover, carbon nanoparticles (CNPs) of this fly ash were produced in parallel using the ball milling technique, and were evaluated as reinforcements for epoxy based composites. These CNPs have almost spherical shapes with particle sizes of around 30 nm. They were found to have strong C=O carbonyl group bonds, which might be generated during the ball milling process. The tensile testing results of a fly ash CNP reinforced epoxy composite showed significant improvements in the mechanical properties, mainly in the stiffness of the polymer. The stiffness value was increased by around 23% of that of neat epoxy. These CNPs with chemically active groups might also be useful for other applications.

• Journal of Welding and Joining
• /
• v.14 no.6
• /
• pp.58-67
• /
• 1996

The horizontal filet welding is prevalently used in heavy and ship building industries to join the parts. The phenomena occurring in the horizonal fillet welding process are very complex and highly non-linear, so that its analysis is relatively difficult. Furthermore, various kinds of weld defect such as undercut, overlap, porosity. excess weld metal and incomplete penetration can be induced due to improper welding conditions. Among these defects, undercut, overlap and excess weld metal appear frequently in horizontal filet welding. To achieve a satisfactory weld bead geometry without weld defects, it is necessary to study the effect of welding conditions in the weld bead geometry. For analyzing the weld bead geometry with and without weld defects in horizontal fillet welding, a mathematical model was proposed in conjunction with a two-dimensional heat flow analysis adopted for computing the melting tone in . base metal. The reliability of the proposed model was evaluated through experiments. which showed that the proposed model was very effective for predicting the weld bead shape with or without weld defects in horizontal fillet welding.

• Tunnel and Underground Space
• /
• v.7 no.3
• /
• pp.238-245
• /
• 1997

A transient pulse methos has been used to measure the permeability of Pocheon granite pre-heated from $25^{\circ}C$ to $600^{\circ}C$ at effective pressure up to 32MPa. The permeability of whole rock ranged from 0.72 $\mu$d at 10MPa to 0.20 $\mu$d at 32MPa. The permeability of rock heated to $600^{\circ}C$ ranged from 18.07$\mu$d at 10MPa to 6.39$\mu$d at 32MPa. Confining pressure has greater effects on the rocks thermally treated to lower thermal-cycle temperatures than on the higher thermally treated rocks. The increase of permeability is most pronounced between 40$0^{\circ}C$ and $600^{\circ}C$. Below 40$0^{\circ}C$, permeability increase is expected to be associated with the formation of new cracks and widening of preexisting cracks, whereas above 40$0^{\circ}C$, permeability increase is expected to reflect widening of cracks. Using the equivalent channel model, author shows that the exponent n in the relationship relating the permebility(k) to porosity($\phi$) by k∝$$\phi$^n$ falls in the range 2.7$\leq$n$\leq$3.0.