• Journal of Korean Society of Environmental Engineers
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• v.22 no.2
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• pp.193-201
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• 2000

Partitioning of hydrophobic organic compounds (HOCs) to a biosurfactant, hydroxypropyl-${\beta}$-cyclodextrin (HPCD), was conducted to evaluate the feasibility of using HPCD to remove HOCs from soil/groundwater. HOC partitioning to HPCD was very fast, with over 95% of the complexation occurring within 10 min. Some influence of solution chemistry and HOC concentration on HOC-HPCD complex formation coefficients was observed. HPCD sorption on soil as quantified by both a fluorescence technique and total organic carbon measurements was negligible, indicating no significant affinity of HPCD for the solid phase. Although the HOC solubilization capability of HPCD was lower than that of synthetic surfactants such as SDS and Tween 80, HPCD can be effective in removing sorbed HOCs from a model subsurface environment, primarily because of its negligible sorption to the solid phase (i.e., all the HPCD added facilitates HOC elution). However, in contrast with conventional surfactants, HPCD becomes relatively less effective for HOC partitioning with increasing HOC size and hydrophobicity. Therefore, comparisons between HPCD and synthetic surfactants for enhanced remediation applications must consider the specific HOC(s) present and the potential for surfactant material losses to the solid phase, as well as other more generally recognized considerations such as material costs and potential toxicological effects.

• Korean Journal of Agricultural and Forest Meteorology
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• v.16 no.4
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• pp.359-367
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• 2014

Drought index can be used to implement an early warning system for drought and to operate a drought monitoring service. In this study, an approach was examined to determine agricultural drought index (ADI) at high spatial resolution, e.g., 270 m. The value of ADI was calculated based on soil water balance between supply and demand of water. Water supply is calculated by the cumulative effective precipitation with the application of the weight to the precipitation from two months ago. Water demand is derived from the actual evapotranspiration, which was calculated applying a crop coefficient to the reference evapotranspiration. The amount of surface runoff on a given soil type was also used to calculate soil residual moisture. Presence of drought was determined based on the probability distribution in the given area. In order to assess the reliability of this index, the amount of residual moisture, which represents severity of drought, was compared with measurements of soil moisture at three experimental between July 2012 and December 2013. As a result, the ADI had greater correlation with measured soil moisture compared with the standardized precipitation index, which suggested that the ADI would be useful for drought warning services.

• 전기의세계
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• v.28 no.4
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• pp.53-63
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• 1979

Interface recombination velocity in $Al_{x}$G $a_{1-x}$ As-GaAs and $Al_{0.85}$, G $a_{0.15}$ As-GaA $s_{1-y}$S $b_{y}$ heterojunction systems is studied as a function of lattice mismatch. The results are applied to the design of highly efficient III-V heterojunction solar cells. A horizontal liquid-phase epitaxial growth system was used to prepare p-p-p and p-p-n $Al_{x}$G $a_{1-x}$ As-GaA $s_{1-y}$S $b_{y}$-A $l_{x}$G $a_{1-x}$ As double heterojunction test samples with specified values of x and y. Samples were grown at each composition, with different GaAs and GaAs Sb layer thicknesses. A method was developed to obtain the lattice mismatch and lattice constants in mixed single crystals grown on (100) and (111)B oriented GaAs substrates. In the AlGaAs system, elastic lattice deformation with effective Poisson ratios .mu.$_{eff}$ (100=0.312 and .mu.$_{eff}$ (111B) =0.190 was observed. The lattice constant $a_{0}$ (A $l_{x}$G $a_{1-x}$ As)=5.6532+0.0084x.angs. was obtained at 300K which is in good Agreement with Vegard's law. In the GaAsSb system, although elastic lattice deformation was observed in (111) B-oriented crystals, misfit dislocations reduced the Poisson ratio to zero in (100)-oriented samples. When $a_{0}$ (GaSb)=6.0959 .angs. was assumed at 300K, both (100) and (111)B oriented GaAsSb layers deviated only slightly from Vegard's law. Both (100) and (111)B zero-mismatch $Al_{0.85}$ G $a_{0.15}$As-GaA $s_{1-y}$S $b_{y}$ layers were grown from melts with a weight ratio of $W_{sb}$ / $W_{Ga}$ =0.13 and a growth temperature of 840 to 820 .deg.C. The corresponding Sb compositions were y=0.015 and 0.024 on (100) and (111)B orientations, respectively. This occurs because of a fortuitous in the Sb distribution coefficient with orientation. Interface recombination velocity was estimated from the dependence of the effective minority carrier lifetime on double-heterojunction spacing, using either optical phase-shift or electroluminescence timedecay techniques. The recombination velocity at a (100) interface was reduced from (2 to 3)*10$^{4}$ for y=0 to (6 to 7)*10$^{3}$ cm/sec for lattice-matched $Al_{0.85}$G $a_{0.15}$As-GaA $s_{0.985}$S $b_{0.015}$ Although this reduction is slightly less than that expected from the exponential relationship between interface recombination velocity and lattice mismatch as found in the AlGaAs-GaAs system, solar cells constructed from such a combination of materials should have an excellent spectral response to photons with energies over the full range from 1.4 to 2.6 eV. Similar measurements on a (111) B oriented lattice-matched heterojunction produced some-what larger interface recombination velocities.ities.ities.s.

• Journal of Environmental Science International
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• v.4 no.2
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• pp.223-232
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• 1995

New two macrocyclic compounds using as carriers of liquid emulsion menbrame, have been synthesized. These reuslts provide evidance for the usefulness of the theory in designing the systems. The efficiency of selective transport for heavy metal ions have been discussed from the membrane systems that make use of $SCN^-$,<>,$I^-$,CN- and $Cl^-$ ion as co-anions in source phase and make use of $S_2O_3^{2-}$ and $P_2O_7^{4-}$ ion as receiving phase, respectively. The transport rate of M(II) was highest when a maximum amount of the M(II) in the source phase was present as$Cd(SCN)_2$$(P[SCN^-]= 0.40M)$, $Hg(SCN)_2([SCN^-]=0.40M)$ and Pd(CN)$([CN^-]= 0.40M)$. The Cd(II) and Pb(II) over each competitive cations were well transprted with 0.3M-S2032- and 0.3M-P2O74-, respectively in the receiving phase. Results of this study indicate that two criteria must be met in order to have effective macrocycle-mediated transport in these emulsion system. First one must effective extraction of the $M^{n+}$ into the toluene systems. The effectiveness of this extraction is the greatest if locK for $M^{n+}$macrocycle interaction is large and if the macrocycle is very insoluble in the aqueous phase. Second, the ratio of the locK values (or Mn+-receiving phase ($S_2O_3^{2-}$- or $P_2O_7^{4-}$) to $M^{n+}$-macrocycle (($L_1$이나 $L_2$) interaction must be large enough to ensure quantitative stripping of Mn+(($Cd^{2+}$,$Pb^{2+}$)at the toluene receiving Phase interface. $L_1$(3.5-benzo-10,13,18,21-tetraoxa-1,7,diazabicyclo(8,5,5) eicosan) forms a stable ($Cd^{2+}$ and >,$Pb^{2+}$ complexes and $L_1$ is very insoluble in water and its $Cd^{2+}$ and >,$Pb^{2+}$ complex is considerably less stable than $Cd^{2+}$-(S2O3)22- and $Pd^{2+}-P_2O_7^{4-}$ complexes. On the other hand, the stability of the $Hg^{2+}$)+-$L_1$( complex exceed that of the $Hg^{2+}$- (S2O3)22- and Hg2+-P2O74-, and the distribution coefficient of $L_2$(5,8,15,18,23,26-hexaoxa-1,12- diazabicyclo-(10,8,8) octacosane) is much smaller than that of $L_1$. Therefore, the partitioning of Lr is favored by the aqueous receiving Phase, and little heavy metal ions transport is seen despite the large logK for $Hg^{2+}$+-$L_1$ and $Mn^+$($Cd^{2+}$+, $Pb^{2+}$+ and $Hg^{2+}$)-$L_2$ interactions. Key Words : macrocycles, transport, heavy metal, co-anion, source phase, receiveing, complex separation, interaction, destribution coefficient.

• Korean Journal of Agricultural Science
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• v.12 no.2
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• pp.282-291
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• 1985

In order to investigate the settlement characteristics of fill dam with decomposed granite is used as a embankment material instead of conventional clay collected behavoir of Andong dam and analyzed. Andong dam is the use of decomposed granite in the embankment material, and various type of gauges were installed in dam to measure a pore pressure, interval vertical settlement, dam crest settlement, relative settlement, surface settlement and internal horizontal movement. The results were summerized as follows; 1. With the increase of embankment loading, the settlement of core zone during construction increased with linear and under the effective stress $7kg/cm^2$ vertical settlement ratio ranged between 0.1 and 0.8% approximately and showed smaller value than that of fill dam with clay were used as a embankment material. 2. Though embankment loading was increased with about over central part of embankment height, the settlement of core zone in the lower part of the embankment was influenced slightly. 3. Pore pressure responsed sensitively with the increase of coefficient of permeability in core zone and settlement increased with pore pressure were dispersed. 4. During construction relative settlement in the lower part of the embankment has the largest influence on magnitude of the relative density and after construction settlement showed larger value in the core zone which has the largest compression height. 5. Settlement distribution of dam crest showed larger value in the central part, maximum section of dam, but smaller value in near the abutment.

• Journal of Pharmaceutical Investigation
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• v.27 no.4
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• pp.287-293
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• 1997

To make a stable o/w emulsion, the effects of egg lecithin as an emulsifier and polyvinylpyrrolidone (PVP) as an auxiliary emulsifier on the physical stability of emulsion were investigated. The oil-in-water emulsion system was manufactured by microfluidizer and evaluated the physical stability. Average particle size and size distribution of emulsion was measured by dynamic light scattering analyzer and interfacial tension was measured. From the interfacial tension tested, critical micelle concentration of the egg lecithin was 0.1 %w/v and optimal concentration for the preparation of emulsion was 1.0 %w/v. The mean particle size was about $0.2\;{\mu}m$ which was suitable for injections. The short-term accelerated stability studies were conducted by centrifugation, freeze-thaw method and shaking of the emulsion samples. The addition of PVP was caused the reduction in the particle size and improved the physical stability of emulsion. These results suggested that a mixed interfacial film comprising the egg lecithin and PVP was formed at the o/w interface and it was effective in preventing phase separation under thermic or mechanical stress. We used antineoplaston A10 (A10) as a model drug which is peptide and amino acid derivative having a action to the living organism against the development of neoplastic growth by a nonimmunological progress. It has a poor solubility in water and there may be a difficulty in formulation of A10. Emulsion formulation study about A10 was performed. Solubility of A10 in emulsion was about five times as high as that in water. From the results of solubility and partition coefficient, almost A10 molecules in o/w emulsion exist in the interface between oil and water.

• Journal of the Korea institute for structural maintenance and inspection
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• v.20 no.5
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• pp.85-92
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• 2016

The eight mixes and artificial soil aggregates were prepared for evaluating the practical application of lightweight foamed concrete as soil aggregates. The main parameter was unit binder content ranged between from 100 to $800kg/m^3$. In lightweight foamed concrete, flow, slurry and dried density, and compressive strength at different ages were measured. In Artificial soil aggregates crushed from lightweight foamed concrete, particle size distribution, pH, coefficient of permeability, cation exchange capacity(CEC), and ratio of carbon to nitrogen(ratio of C/N), were measured. The test results showed that flow, slurry and dried density, and compressive strength at different ages of lightweight foamed concrete increased with the increasing of unit binder content. Compressive strength at age of 28, of lightweight foamed concrete with unit binder of more than $500kg/m^3$, was more than 4 MPa. The ammonium phosphate immersion time of more than age of 3, was effective to decrease pH of artificial soil aggregates. In addition, artificial soil aggregates was evaluated as high class in terms of cation exchange capacity(CEC), while satisfied with value of ratio of carbon to nitrogen(ratio of C/N) recommended by landscape specification.

• Journal of Korean Society of Forest Science
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• v.103 no.1
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• pp.51-58
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• 2014

Genetic diversity and genetic structures were estimated in seven natural populations of Phellodendron amurense Rupr in South Korea using ISSR markers. The average of polymorphic loci per primer and the proportion of polymorphic loci per population were 4.5 and 78.8% respectively with total 27 polymorphic loci from 6 ISSR primers. The Shannon's diversity index(I) was 0.421 and the expected heterozygosity($H_e$) was 0.285, which was similar to the heterozygosity (hs =0.287) inferred by Bayesian method. In AMOVA, 7.6% of total genetic variation in the populations was resulted from the genetic difference among populations and the other 92.4% was resulted from the difference among individuals within populations. Genetic differentiation(${\theta}^{II}$) and inbreeding coefficient(f) for total population were estimated to be 0.066 and 0.479 by Bayesian method respectively. In Bayesian clustering analysis, seven populations were assigned into three groups. This result was similar to the results of genetic relationships by UPGMA and PCA. The first group included Hwachoen, Gapyeong, Bongpyeong and Yongpyeong population, and the second included two populations in Sancheong region. Muju population was discretely assigned into the third group in spite of the geographically short distance from the Sancheong region. There was no significant correlation between genetic relationship and geographic distribution among populations in Mantel's test. For conservation of the phellodendron trees, it would be effective to consider the findings resulted from this study with ecological traits and life histories of this species.

• Korean Journal of Soil Science and Fertilizer
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• v.43 no.6
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• pp.793-797
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• 2010

The investigations were conducted to improve the physical properties by analyzing physico-chemical properties on the different soil families of textures at 20 upland fields located in the parts of Gyengsangbuk-do area. Soil physico-chemical properties were analyzed for bulk density, hardness, porosity, moisture, pH, EC and organic mater by soil depth on the different soil families of textures. Bulk density distributions were higher than 1.2 Mg $m^{-3}$ in the optimum range. Hardness distributions were lower than 20 mm in the optimum range. Therefore, the physical properties of upland soil was deteriorated. Correlation coefficient of bulk density with hardness and organic mater were higher significantly, that was positive and negative, respectively. The soil hardness had the greatest distribution degree to the crop yield and bulk density and organic matter followed. Conclusively, To improve the physical properties of upland soil was more effective to fertilizing organic matter than other ways.

• Journal of Korea Water Resources Association
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• v.52 no.7
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• pp.463-473
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• 2019

This study compared the characteristics of the optimization technique and the water supply and demand forecast using K-WEAP (Korea-Water Evaluation and Planning System) model and MODSIM (Modified SIMYLD) model considering wtaer supply priority. Currently, The national water resources plan applied same priority for municipal, industrial and agricultural demand. the K-WEAP model performs the ratio allocation to satisfy the maximum satisfaction rate, whereas the MODSIM model should be applied to the water supply priority of demands. As a result of applying the priority, water shortage decreased by an average of $1,035,000m^3$ than same prioritized results. It is due to the increase of the return flow rate as the distribution of Municipal and industrial water increases. Comparing the analysis results of K-WEAP and MODSIM applying the priorities, the relative error was within 5.3% and the coefficient of determination ($R^2$) was 0.9999. In addition, if both models provide reasonable water balance analysis results, K-WEAP is superior to GUI convenience for model construction and data processing. However, MODSIM is more effective in simulation time efficiency. It is expected that it will be able to carry out analysis according to various scenarios using the model.