• Proceedings of the Korean Society For Composite Materials Conference
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• 2005.04a
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• pp.90-93
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• 2005

A thermal model of carbon spun yarn and its composite is presented. Based on voxelization method, the unit cells of spun carbon yam and its composite are divided into a number of volume elements and the local material properties have been given to each element. By using Finite Difference Method, temperature distribution in the unit cell can be obtained. Effective thermal conductivity of unit cell is calculated using the temperature distribution and thermal conductivities of local elements.

• Proceedings of the Korea Concrete Institute Conference
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• 1997.10a
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• pp.450-455
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• 1997

In recent years the research and development about the new material proceeds rapidly and actively in building industry. We are concerned with high-strength concrete as a new material. As the building structure becomes bigger, higher and more specialized, so does the demand of material and member with high strength for building expands greatly. In the future, we will quite need to research repair and rehabilitation to make high strength concrete structural building for our safe. So, I did an study on carbon fiber sheet rehabilitation(CFSR) of reinforced high strength concrete beams. The carbon fiber reinforced plastic(CFRP) bonding method is widely used for reinforcing the existing concrete structure among the various methods. The test results indicate that CFS is very effective for strengthening the damaged beams and controlling deflections of the repaired beams. When carbon fiber sheet rehabilitation of reinforced high strength concrete beams happened diagonal crack, the increase in the number of CFS layer didn't effect the increase in strength of beams. Also, by changing the CFS stick position gave diversified ultimate load in CFSR beams.

• Journal of Electrochemical Science and Technology
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• v.8 no.4
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• pp.338-343
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• 2017

Activated carbon has lower electrical conductivity and reliability than other carbonaceous materials because of the oxygen functional groups that form during the activation process. This problem can be overcome by doping the material with heteroatoms to reduce the number of oxygen functional groups. In the present study, N, F co-doped activated carbon (AC-NF) was successfully prepared by a microwave-assisted hydrothermal method, utilizing commercial activated carbon (AC-R) as the precursor and ammonium tetrafluoroborate as the single source for the co-doping of N and F. AC-NF showed improved electrical conductivity ($3.8\;S\;cm^{-1}$) with N and F contents of 0.6 and 0.1 at%, respectively. The introduction of N and F improved the performance of the pertinent supercapacitor: AC-NF exhibited an improved rate capability at current densities of $0.5-50mA\;cm^{-2}$. The rate capability was higher compared to that of raw activated carbon because N and F codoping increased the electrical conductivity of AC-NF. The developed method for the co-doping of N and F using a single source is cost-effective and yields AC-NF with excellent electrochemical properties; thus, it has promising applications in the commercialization of energy storage devices.

• Journal of the Korean Chemical Society
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• v.6 no.1
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• pp.88-93
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• 1962

The telomerization of vinyl acetate with carbon tetrachloride, chloroform and monochlorobenzene were investigated with respect to the synthesis of those telomers, properties and molecular weights of the formed telomers, and reaction mechanisms. Vinyl acetate reacted with carbon tetrachloride and chloroform to form telomers at 70-90$^{\circ}C$ and 60-70$^{\circ}C$, respectively and it formed polymer with monochlorobenzene. As a chain transfer agent, carbon tetrachloride was more effective than chloroform. In the telomerization of vinyl acetate and carbon tetrachloride: 1) The average molecular weight of the telomer decreased as the mole ratio of carbon tetrachloride to vinyl acetate increased. The optimum conditions for the highest yield of the telomer were as follows: Mole ratio of carbon tetrachloride to vinyl acetate : 2.5 Reaction time : 20 hours. 2) As the reaction proceeded, the refractive index and average molecular weight of the telomer increased rapidly in the first 10 hours but the increase was slow through the next 10 hours, so that, the average recurring number(n) of taxogen in the final product reached an almost definite value, i.e., 3. The telomer formed in the telomerization of vinyl acetate with carbon tetrachloride and chloroform turned to brown color in the air due to decomposition or polymerization. The suggested telomerization mechanism was supported by the hexachloroethane detected in the course of reaction.

• Composites Research
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• v.33 no.4
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• pp.198-204
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• 2020

In this study, we employ the full atomistic molecular dynamics simulation and finite element homogenization method to predict the thermo-mechanical properties of nanocomposites including carbon nanotube bundle. As the number of carbon nanotubes within the single bundle increases, the effective in-plane Young's modulus and in-plane shear modulus decrease, and in-plane thermal expansion coefficient increases, despite the same volume fraction of carbon nanotubes. To investigate the thickness of interphase zone, we employ the radial density distribution. It is investigated that the interphase thickness is almost independent on the number of carbon nanotubes within the single bundle. It is assumed that the matrix and interphase are isotropic materials. According to the predicted thermo-mechanical properties of interphase zone, the Young's modulus and shear modulus of interphase zone clearly decrease, and the thermal expansion coefficient increases. Based on the thermo-mechanical interphase behavior, we developed the multiscale homogenization model to predict the thermo-mechanical properties of PLA nanocomposites that include the carbon nanotube bundle.

• Korean Journal of Plant Tissue Culture
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• v.25 no.2
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• pp.99-102
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• 1998

The most effective medium for shoot initiation in vitro of peach cv. Baekmijosaeng, Yumyeong and nectarine cv. Cheonhong was Quoirin and Lepoivre medium(LP). 20 g/L and 30 g/L sorbitol as carbon source were effective for shoot proliferation of cv. Baekmijosaeng. Addition of 500 mg/L lacto albumin enzymatic hydrolysate(LH) increased shoot number per explant of cv. Baekmijosaeng peach. Removing the apical meristem and horizontal placing of explants on the medium increased cv. Baekmijosaeng shoot.

• Proceedings of the Korea Concrete Institute Conference
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• 2002.05a
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• pp.965-970
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• 2002

The strengthening of concrete structures in situ with externally bonded carbon fiber is increasingly being used for repair and rehabilitation of existing structures. Carbon fiber is attractive for this application due to its good tensile strength, resistances to corrosion, and low weight. Generally bond strength and behavior between concrete and carbon fiber mesh(CFM) is very important, because of the enhanced bond of CFM. Therefore if bond strength is sufficient, it will be expected to enhance reinforcement effect. If insufficient, reinforcement effect can not be enhanced because of bond failure between concrete and CFM. This study is to investigate the bond strength of CFM to the concrete using direct pull-out test and tensile-shear test. The key variables of the experiment are the location of clip, number of clips and thickness of cover mortar. The general results indicate that the clip anchorage technique for increasing bond strength with CFM appear to be effective to maintain the good post-failure behavior.

• Proceedings of the Korea Concrete Institute Conference
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• 2002.05a
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• pp.393-398
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• 2002

This study shows the fatigue test results of experiment on the strengthened slabs, the probability analysis of the fatigue behavior is also presented. Static und fatigue tests were performed on bridge decks strengthened with fiber plastics(Carbon Fiber Sheet, Glass Fiber Sheet, Grid Type Carbon Fiber). In this study, to analyze the probabilistic distribution of the fatigue life, the Weibull distribution was adopted. The Weibull distribution coefficient is inferred from the S-N diagram and the number of repeated load. As the result analysis, as the stress level is higher, the fatigue limit of the strengthened bridge deck are similarly discovered but in the range of the fatigue limit, CG specimen that was strengthened with Grid Type Carbon was proved most effective of reinforcement.

• Nuclear Engineering and Technology
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• v.52 no.10
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• pp.2394-2401
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• 2020

Octadecylamine is an effective film-forming amine that protects carbon steel from corrosion. In the present study, the effect of octadecylamine concentration on adsorption on a carbon steel surface was investigated in anaerobic alkaline solution by using SEM/EDS, TEM and the Materials Studio simulation techniques. TEM morphology observation and EDS elemental detection determine the thicknesses of octadecylamine film on a carbon steel surface, which are confirmed by the in-situ electrochemical impedance spectroscopy measurement and resistance calculation. The Materials Studio simulation reveals the number of octadecylamine film layers at different concentrations. Results obtained in this study indicate that adsorption of octadecylamine film on carbon steel proceeds with the multi-layer adsorption mechanism.

• Journal of the Korea institute for structural maintenance and inspection
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• v.5 no.3
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• pp.181-189
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• 2001

Recently, the need for strengthening reinforced concrete(R.C.) structure has been increased, particularly when there is an increase in load requirements, a change in use, a degradation problem, or design/construction defects. The use of composite materials for structural repair presents several advantages and has been investigated all over the world. It is well known that the incorporation of carbon fiber sheet(CFS) with concrete is one of the most effective ways to strengthen the R.C. structure. In this papers, experimentally investigated the ductile behavior of the R.C. beams strengthened with CFS, and provided the basic data for design of R.C. beams strengthened with CFS. Tests were carried out with 15 beams ($20cm{\times}30cm{\times}240cm$) reinforced with CFS, and with parameters including and the ratio of tensile reinforcement to that of balanced condition and number of CFS. The results show that strengthened and non-strengthened beams exhibit different ductile behovior. Non-strengthened beams showed increase of ductility as amount of the tensile reinforcement decreased. However, bearing capacity of the CFS-strengthened beams are dictated by the strength of the CFS layers that a very high ductility is indicated for the beams with large number of CFS.