• Korean Journal of Materials Research
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• v.26 no.12
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• pp.733-740
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• 2016

$Al_2O_3$ nanosol dispersed under ethanol or N-Methyl-2-pyrrolidone(NMP) was studied and optimized with various dispersion factors and by utilizing the silane modification method. The two kinds of $Al_2O_3$ powders used were prepared by thermal decomposition method from aluminum ammonium sulfate$(AlNH_4(SO_4)_2)$ while controlling the calcination temperature. $Al_2O_3$ sol was prepared under ethanol solvent by using a batch-type bead mill. The dispersion properties of the $Al_2O_3$ sol have a close relationship to the dispersion factors such as the pH, the amount of acid additive(nitric acid, acetic acid), the milling time, and the size and combination of zirconia beads. Especially, $Al_2O_3$ sol added 4 wt% acetic acid was found to maintain the dispersion stability while its solid concentration increased to 15 wt%, this stability maintenance was the result of the electrostatic and steric repulsion of acetic acid molecules adsorbed on the surface of the $Al_2O_3$ particles. In order to observe the dispersion property of $Al_2O_3$ sol under NMP solvent, $Al_2O_3$ sol dispersed under ethanol solvent was modified and solvent-exchanged with N-Phenyl-(3-aminopropyl)trimethoxy silane(APTMS) through a binary solvent system. Characterization of the $Al_2O_3$ powder and the nanosol was observed by XRD, SEM, ICP, FT-IR, TGA, Particles size analysis, etc.

• Bulletin of the Korean Chemical Society
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• v.24 no.1
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• pp.86-90
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• 2003

Reverse-Water-Gas-Shift reaction (RWGSR) was carried out over the ZnO, $Al_2O_3,\;and\;ZnO/Al_2O_3$ catalysts at the temperature range from 400 to 700 ℃. The ZnO showed good specific reaction activity but this catalyst was deactivated. All the catalysts except the $ZnO/Al_2O_3$ catalyst (850 ℃) showed low stability for the RWGSR and was deactivated at the reaction temperature of 600 ℃. The $ZnO/Al_2O_3$ catalyst calcined at 850 ℃ was stable during 210 hrs under the reaction conditions of 600 ℃ and 150,000 GHSV, showing CO selectivity of 100% even at the pressure of 5 atm. The high stability of the $ZnO/Al_2O_3$ catalyst (850 ℃) was attributed to the prevention of ZnO reduction by the formation of $ZnAl_2O_4$ spinel structure. The spinel structure of $ZnAl_2O_4$ phase in the $ZnO/Al_2O_3$ catalyst calcined at 850 ℃ was confirmed by XRD and electron diffraction.

• Proceedings of the SAREK Conference
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• 2008.06a
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• pp.395-401
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• 2008

Since metallic foam will increase the performance of heat exchanger, it have caused many researcher's attention recently. Our research base on the model that metallic foams applied to heat exchanger. In this case, there is three kind of heat transfer mechanisms, heat conduction in fibers, heat transfer by conduction in fluid phase, and internal heat change between solid and fluid phases. In this paper we study both the hydraulic and thermal aspect performance. Pressure drop along air flow direction will be presented. As thermal aspect, we first discuss the acceptance of applying thermal equilibrium among the two phases. then to calculate the dimensionless temperature profile, the heat transfer coefficient and Nu number in 14 metallic foams(7 Aluminium foams, 7 FeCrAlY foams). All these discussion is based on the same velocity u=2 m/s.

• Advances in concrete construction
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• v.10 no.3
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• pp.237-245
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• 2020

Past research efforts already established geopolymer as an environment-friendly alternative binder system for ordinary Portland cement (OPC) and recycled aggregate is also one of the promising alternative for natural aggregates. In this study, an effort was made to produce eco-friendly mortar mixes using geopolymer as binder and recycled fine aggregate (RFA) partially and study the resistance ability of these mortar mixes against the aggressive environments. To form the geopolymer binder, 70% fly ash, 30% ground granulated blast furnace slag (GGBS) and alkaline solution comprising of sodium silicate solution and 14M sodium hydroxide solution with a ratio of 1.5 were used. The ratio of alkaline liquid to binder (AL/B) was also considered as 0.4 and 0.6. In order to determine the resistance ability against aggressive environmental conditions, acid attack test, sulphate attack test and rapid chloride permeability test were conducted. Change in mass, change in compressive strength of the specimens after the immersion in acid/sulphate solution for a period of 28, 56, 90 and 120 days has been presented and discussed in this study. Results indicated that the incorporation of RFA leads to the reduction in compressive strength. Even though strength reduction was observed, eco-friendly mortar mixes containing geopolymer as binder and RFA as fine aggregate performed better when it was produced with AL/B ratio of 0.6.

• Journal of Korea Foundry Society
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• v.30 no.6
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• pp.224-230
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• 2010

To prevent oxidation of Mg melt, $SF_6$ gas has been generally used for Mg alloys during melting and casting as a cover gas. The use of $SF_6$ gas, however, will be restricted owing to its crucial impact on global warming. Non-$SF_6$ process during melting and casting in diecasting industry has been proved with Eco-Mg alloys by a simple addition of small amount of CaO into Mg alloys. This paper shows non-$SF_6$ diecasting procedures for 0.7wt% CaO added AZ91D Eco-Mg alloys. Cold-chamber diecasting was performed under $CO_2$ atmosphere without $SF_6$ gas. An increment of mechanical properties, especially strength and ductility of Eco-Mg alloys is, in part, due to high-quality melt, refined grain size and $Al_2Ca$ second phase strengthening. Microstructures and mechanical properties of 0.7wt% CaO added AZ91D Eco-Mg alloys are evaluated in comparison with those of conventional AZ91D Mg alloy.

• Journal of the Korean Society of Propulsion Engineers
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• v.24 no.4
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• pp.41-47
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• 2020

This study aims to develop eco-friendly propellant that reduce the generation of harmful gases such as HCl gas and increase the emmision of nitrogen gas emissions. For this purpose, GUDN(N-Guanylurea dinitramide) and BTATz(3,6-bis(1H-1,2,3,4-tetrazol-5-ylamino)-1,2,4,5-tetrazine), which are low carbon high nitrogen materials, were used instead of AP(Ammonium Perchlorate) and Al(Aluminium), which are gernerally used in solid propellant. The prepared propellants were analyzed for mechanical properties and combustion characteristics, performance and AGARD smoke classification. Compared with AP/Al propellant, GUDN/BTATz propellant tended to decrease mechanical and combustion rate. Also, as a result of the static test after the production of the 4-inch motor, the performance of combustion of the GUDN/BTATz propellant decreased, but it was confirmed that the secondary smoke was improved by reducing harmful gases such as HCl gas.

• Journal of Korea Foundry Society
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• v.31 no.1
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• pp.11-17
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• 2011

The effect of CaO addition to AM60B Mg alloy on tensile properties has been investigated, with focus on strength and ductility at room and elevated temperatures. The 0.25-0.65wt% CaO added AM60B Eco-Mg diecastings were prepared by high pressure die casting using Buhler 1,450-ton cold chamber machine without $SF_6$ and $SO_2$ gases. The microstructures and tensile properties of each alloy were tested. The results show that the grains of AM60B are refined and the mechanical properties increase with CaO addition at room temperature. The improvement of strength and ductility is prominent at 0.45-0.55wt% CaO addition. Also, improved mechanical properties are maintained at elevated temperature of $150^{\circ}C$. CaO addition results in $Al_2Ca$ phase formation mostly on the grain boundaries. This phase leads to the refinement of grain structures and improvement of ductility as well as strength. The suppression of ${\beta}-Mg_{17}Al_{12}$ phase as well as the decrease of fracture surface porosity and other casting defects caused by melt cleanliness also contribute to the enhancement of mechanical properties of AM60B Eco-Mg at room and elevated temperature.

• Journal of the Korean Society for Heat Treatment
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• v.24 no.4
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• pp.193-198
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• 2011

Effect of CaO addition on age hardening response has been studied by using optical microscopy, scanning electron microscopy and differential thermal analysis in AZ91 and CaO-containing ECO-AZ91 alloys. After solution treatment, the ${\beta}$($Mg_{17}Al_{12}$) phase formed during solidification mostly disappeared in the microstructure in the AZ91 alloy, whereas numerous ${\beta}$ precipitates containing Ca were still observed in the ECO-AZ91 alloy due to its enhanced thermal stability. The ECO-AZ91 alloy showed the delayed peak aging time and higher peak hardness compared with those of the AZ91 alloy. The activation energies for ${\beta}$ precipitation calculated by means of Kissinger method increased from 71.4 to 85.6 kJ/mole by the addition of CaO, which implies that CaO plays a role in reducing ${\beta}$ precipitation rate in the AZ91 alloy.

• Bulletin of the Korean Chemical Society
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• v.24 no.11
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• pp.1623-1626
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• 2003

The dependency of the rate of $CO_2$ reforming of methane on the catalyst loading and the reactor size was examined at a fixed temperature of $750\;^{\circ}C$ and a fixed GHSV of 18000 mL(STP)/$g_{cat}.h$. The conversion of methane in $CO_2$reforming decreased with increase in the reactor size. The catalyst was severely deactivated with increase in the catalyst amount. The amount of carbonaceous species combustible below $550\;^{\circ}C$, determined by TPO experiments with the used catalyst samples increased with increase in the catalyst amount, which was again confirmed by XRD and TEM experiments. The increase of the carbonaceous species combustible below $550\;^{\circ}C$ may be due to the suppression of the reverse Boudouard reaction, since the $CO_2$ reforming of methane, a highly endothermic reaction, resulted in lowering the reaction temperature.

• Journal of Advanced Marine Engineering and Technology
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• v.38 no.10
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• pp.1190-1199
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• 2014

As a considerable, experimental approach, an autocarriage type of $CO_2$ welding machine and a MIG(metal inert gas) welding robot in the inert gas atmosphere were utilized in order to realize Al 5083 welding to hull and relevant components of green leisure ships. This study aims at investigating the effect of welding conditions(current, voltage, welding speed, etc.) on thermal deformation that occurs as welding operation and tensile characteristics after welding, by using Al 5083, nonferrous material, applied to manufacturing of eco-environmental leisure ships. With respect to welding condition to minimize the thermal deformation, 150 A and 16 V at the wire-feed rate of 6 mm/sec were acquired in the process of welding Al 5083 through an auto carriage type of $CO_2$ welding feeder. As to tensile characteristics of Al 5083 welding through a MIG welding robot, most of tensile specimens showed the fracture behavior on HAZ(heat affected zone) located at the area joined with weld metal, except for some cases. Especially, for the case of the Al specimen with 5 mm thickness, 284.62 MPa of tensile strength and 11.41 % of elongation were obtained as an actual allowable tensile stress-strain value. Mostly, after acquiring the optimum welding condition, the relevant welding data and technical requirements might be provided for actual welding operation site and welding procedure specification (WPS).