• 제목/요약/키워드: EVAPORATION

검색결과 3,553건 처리시간 0.031초

용매 증발법에 의한 $YGdO_3:Eu^{3+}$ 형광체의 제조와 발광 특성 (Synthesis and Luminescence Properties of $YGdO_3:Eu^{3+}$ Phosphor by Solvent Evaporation Method)

  • 이동규;전상배;이진화
    • 한국응용과학기술학회지
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    • 제24권3호
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    • pp.238-245
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    • 2007
  • $Eu^{3+}$ doped $YGdO_3$ phosphors particles which have fine size and narrow size distribution with non aggregated uniform morphology were prepared by solvent evaporation method for the improvement of emission efficiency. Several parameters have been investigated in this study such as the influences of composition ratio of host materials, calcination temperature, amount of activator, surfactant, pH and flux on the photoluminescence intensity, particle size and dispersion. $Eu^{3+}$ doped $YGdO_3$ phosphor presented a strong narrow band emission peak at 612nm. The maximum emission intensity of$YGdO_3:Eu^{3+}$ occurred when $Eu^{3+}$ concentration is 3wt% under vacuum ultra violet excitation. Prepared phosphors were found to have small round-shaped particles about 150nm in size. The addition of PVA as a surfactant inhibits the grain growth and the agglomeration of particles efficiently by reducing the oxygen bridge bonds. As the pH reduces, PL intensity increase due to reducing the formation of oxygen bridge bonds. The particles prepared from solvent evaporation method with 5wt% LiCl were found to have 120% PL intensity compare to particles prepared without LiCl flux.

용매증발법에 의한 부피바카인 microsphere의 제조 및 평가 (Preparation and Evaluation of Bupivacaine Microspheres by a Solvent Evaporation Method)

  • 곽손혁;황성주;이병철
    • 약학회지
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    • 제44권6호
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    • pp.511-520
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    • 2000
  • Various bupivacaine-loaded microspheres were prepared from poly (d,l-lactide) (PLA) or poly (d,l-lactic-co-glycolide) (PLGA) by a solvent evaporation method for the sustained release of drug. PLA and PLGA microspheres were prepared by w/o/w and w/o/o multiple emulsion solvent evaporation, respectively. The effects of process conditions such as emulsification speed, emulsifier type, emulsifier concentration and internal/external phase ratio on the characteristics of microspheres were investigated. The prepared microspheres were characterized for their drug loading, size distribution, surface morphology and release kinetics. Drug loading efficiency was higher in the microspheres prepared by w/o/o multiple emulsion than that by w/o/w multiple emulsion method, because the solubility of bupivacaine HCI was decreased in oil phase compared with water phase. The prepared microspheres had an average diameter between 1 and $2\;{\mu}M$ in all conditions of two methods. In morphology studies the PLA microspheres showed an irregular shape and smooth surface, but PLGA microspheres had a spherical shape and smooth surface. The release pattern of the drug from microspheres was evaluated on the basis of the burst effect and the extent of the release after 24h. The in vitro release of bupivacaine HCl from microspheres showed a large initial burst release and $60{\sim}80%$ release within one day in all conditions of two methods. The extents of the burst release against PLA and PLGA microspheres were $30{\sim}50%$ and $50{\sim}80%$ within 20min, respectively. This burst release seems to be due to the smaller size of microspheres and the solubility of drug in water.

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전자빔 패터닝과 double-angle 그림자 증착법을 이용한 sub-micron 크기의 $Al-AlO_x-Al$ 터널접합 제작공정개발 (Fabrication of Sub-Micron Size $Al-AlO_x-Al$ Tunnel Junction using Electron-Beam Lithography and Double-Angle Shadow Evaporation Technique)

  • ;최재원;류시정;박정환;류상완;김정구;송운;정연욱
    • Progress in Superconductivity
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    • 제10권2호
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    • pp.99-102
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    • 2009
  • We report our development of the fabrication process of sub-micron scale $Al-AlO_x-Al$ tunnel junction by using electron-beam lithography and double-angle shadow evaporation technique. We used double-layer resist to construct a suspended bridge structure, and double-angle electron-beam evaporation to form a sub-micron scale overlapped junction. We adopted an e-beam insensitive resist as a bottom sacrificing layer. Tunnel barrier was formed by oxidation of the bottom aluminum layer between the bottom and top electrode deposition, which was done in a separate load-lock chamber. The junction resistance is designed and controlled to be 50 $\Omega$ to match the impedance of the transmission line. The junctions will be used in the broadband shot noise thermometry experiment, which will serve as a link between the electrical unit and the thermodynamic unit.

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Estimation of Potential Water Resources in Mega Cities in Asia

  • Takuya, Komura;Toshitsugu, Moroizumi;Kenji, Okubo;Hiroaki, Furumai;Yoshiro, Ono
    • 한국수자원학회:학술대회논문집
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    • 한국수자원학회 2008년도 학술발표회 논문집
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    • pp.75-81
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    • 2008
  • The water shortage in mega cities in Asia, which face a rapid growth in urban population, is an outstanding problem. It is important, therefore, to accurately estimate the water balance in each city in order to use the limited water resources effectively. In this study, we estimated the potential water resources in し sixteen mega cities in Asia. The target cities were Delhi and Calcutta, India; Colombo, Sri Lanka; Dhaka, Bangladesh; Yangon, Myanmar; Bangkok, Thailand; Kuala Lumpur, Malaysia; Singapore; Jakarta, Indonesia; Hanoi, Vietnam; Beijing and Hong Kong, the People's Republic of China; Seoul, the People's Republic of Korea; Manila, the Philippines, and Sapporo and Tokyo, Japan. The potential water resources were estimated by subtracting the actual evaporation from the amount of rainfall. The actual evaporation was estimated using the potential evaporation obtained by Hamon's equation which requires the air temperature and the possible hours of sunshine. When the results of Hamon's and Penman's evaporation equations were compared, a considerable error appeared in the low latitude region. The estimation using Hamon's equation was corrected with the linear regression line of Hamon's and Penman's equations. A classification of the land cover was carried out based on satellite photographs of the target cities, and the volume of surface runoff for each city was obtained using the runoff ratios which depended on the land cover. As a result, the potential water resources in the above mega cities in Asia were found to be greater than the world average. However, the actual water resources which are available for one person to use are probably very limited.

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하절기 기화냉각장치 설치에 따른 가스터빈 성능변화 (Performance Change of Gas Turbine with a Evaporation Cooling System in Summer Season)

  • 정현조;유호선;문승재
    • 플랜트 저널
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    • 제13권1호
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    • pp.37-43
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    • 2017
  • 본 연구는 하절기 가스터빈 압축기 입구에 설치된 기화냉각장치로 인하여 저하된 공기온도가 가스터빈 성능에 어떠한 변화를 미치는지에 대하여 해석하였다. 연구 대상은 인천화력본부 가스터빈 3호기이며, 기종은 Siemens SGT6-4000F(V 84.3A)이다. 기화냉각장치 설치 전후를 비교하기 위하여 특설계측기를 설치하였으며, 2015년 8월 3일에서 14일까지 11시부터 15시 사이에 대기온도 $29{\pm}1^{\circ}C$ 조건에서 설치 전후 각각 5회씩 총 10회에 걸쳐 정밀성능시험을 시행하고 각각의 평균값을 적용하였다. 시험 결과, 가스터빈 압축기 입구 공기온도 $4.12^{\circ}C$ 저하로 공기 밀도가 증가되어 압축기 압력비는 0.27 증가, 압축기 효율은 0.29 %p 상승, 가스터빈 엔탈피강하 효율은 0.31 %p 증가하였고, 가스터빈 효율은 0.44%p, 출력은 4,489 kW가 증대되는 효과를 얻을 수 있었으며, 습도 및 유동저항 증가에 따른 영향은 미미하였다.

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촉매를 사용하지 않는 열 기화법으로 다양한 형태의 ZnO 3차원 구조체 합성 (Different morphologies of three dimensional ZnO structures synthesized by thermal evaporation method without a catalyst)

  • 방신영;;오동근;;최봉근;함헌;김경훈;심광보
    • 한국결정성장학회지
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    • 제23권1호
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    • pp.8-13
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    • 2013
  • 다른 형태의 ZnO는 형태에 따라 각각의 활용분야에 사용할 수 있다. 다양한 형태의 ZnO 구조체(structures)는 촉매를 사용하지 않는 열 기화법(thermal evaporation process)으로 합성되었다. ZnO 구조체의 형태들은 같은 실험 공정에서 기판과 소스간의 거리에 의존하였으며, 그 결과 합성물의 형태는 hollow, cage, star 이었다. ZnO 구조체의 형상과 결정성을 주사전자현미경(SEM)과 X선 회절분석(XRD)으로 각기 평가했다. 본 연구에서는 어떤 종류의 성장 요소가 최종 구조체의 형태에 관여하는지를 입증한다.

동시진공증발법을 이용한 Cu(In,Ga)Se2 박막 제작에 관한 연구 (A study on Cu(In,Ga)Se2 thin film fabarication using to co-evaporation)

  • 박정철;추순남
    • 한국정보통신학회논문지
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    • 제16권10호
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    • pp.2273-2279
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    • 2012
  • 동시진공증발법(co-evaporation)으로 Cu(In,Ga)$Se_2$ 박막을 제작하는 논문으로서 1단계($1^{st}$-stage)에서 기판온도(substrate temperature)가 $400^{\circ}C$에서 $In_2Se_3$상($In_2Se_3$ phase)이 존재하였으며 2,3단계($2^{nd}$-stage, $3^{rd}$-stage)에서 기판온도 변화에 따른 흡수 스펙트럼(absorbency spectrum)은 차이가 크지 않다. 이것은 박막의 두께가 전부 $1{\mu}m$ 이상이므로 흡수 스펙트럼(absorbency spectrum)은 거의 차이가 없다. 2,3단계에서 기판온도 변화에 따른 SEM과 XRD를 분석한 결과, 기판온도가 증가할수록 결정구조(crystal structure)의 밀도(density)가 증가하고 기공(vacancy)이 감소하며 $480^{\circ}C$, $500^{\circ}C$에서 Cu(In0.7Ga0.3)$Se_2$상(${\mu}m$)이 형성되었다.

열증착법으로 합성된 ZnO 나노 구조체의 구조적 특성 (Structural characteristics of ZnO nanostructures synthesized by the thermal evaporation method)

  • 방신영;김우식;정준호;최봉근;심광보
    • 한국결정성장학회지
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    • 제18권2호
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    • pp.81-86
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    • 2008
  • 열증착법(thermal evaporation method)에 의해 ZnO 나노선을 합성하였다. 나노선 합성조건에 따른 구조적 특성을 분석하여 그 합성 메카니즘을 확인하였다. ZnO 나노선 합성 시 기화 온도가 고온일수록 성장속도가 빠르고 $CO/CO_2$ 분압이 역전되는 1000$^{\circ}C$ 이상에서는 그 형태가 크게 변화하고, 성장온도 700$^{\circ}C$ 이상에서 Au 촉매가 그 기능을 하고 있음을 확인하였다. 성장된 ZnO 나노선은 380 nm에서의 blue emission을 나타냄을 확인하였다.

Effects of Sintering Atmosphere on Piezoelectric Properties of 0.75BF-0.25BT Ceramic

  • Kim, Dae Su;Kim, Jeong Seog;Cheon, Chae Il
    • 한국세라믹학회지
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    • 제53권2호
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    • pp.162-166
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    • 2016
  • 0.75BF-0.25BT ceramics were prepared by sintering at $980-1040^{\circ}C$ in air or under atmosphere powder. A sample with 1 mole %-excess $Bi_2O_3$ was also prepared to compensate for $Bi_2O_3$-evaporation. Physical and piezoelectric properties of these three samples were compared. When the sintering temperature increased from $980^{\circ}C$ to $1040^{\circ}C$, the density of the sample sintered in air decreased continuously due to Bi-evaporation. Due to the suppression of Bi-evaporation, the sample sintered under atmosphere powder had a higher density at sintering temperatures above $1000^{\circ}C$ than did the sample sintered in air. The addition of 1 mole %-excess $Bi_2O_3$ successfully compensated for Bi-evaporation and kept the density at the higher value until $1020^{\circ}C$. Grain size increased continuously when the sintering temperature increased from 980 to $1040^{\circ}C$, irrespective of the sintering atmosphere. When the sintering temperature increased, the piezoelectric constant ($d_{33}$) and the electromechanical coupling factor ($k_p$) increased for all samples. The sample with 1 mole % excess-$Bi_2O_3$ showed the highest density and the best piezoelectric properties at sintering temperature of $1020^{\circ}C$.

R410A를 이용한 브레이징 타입 판형열교환기에서 물 측 유동방향에 따른 응축/증발 성능 평가 (An Experimental Study on Evaporation/Condensation Heat Transfer with Flow Direction in Brazed Plate Heat Exchanger using Refrigerant 410A)

  • 이성우;정영만;이재근;이동혁
    • 대한설비공학회:학술대회논문집
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    • 대한설비공학회 2009년도 하계학술발표대회 논문집
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    • pp.1096-1101
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    • 2009
  • The plate heat exchanger(PHE) in heat pump has two flow streams of the refrigerant and water. The flow direction of the refrigerant, unlike that of water, can be changed by a 4-way valve depending on operating condition. Therefore the flow arrangement is a parallel flow for heating and a counter flow for cooling, respectively. In this study, the effects of the flow direction of the water on the heat transfer rate are investigated experimentally. The experiments are carried out for brazed plate heat exchangers under a parallel and counter flow conditions in evaporation and condensation. The experimental parameters in this study include the mass flux of the refrigerant 410A from 3 to $14\;kg/m^2s$ and the flow patterns for the pressure of PHE fixed at 0.97 and 2.46 MPa. The results show that both the heat transfer rate and frictional pressure drop across the PHE increase with the mass flux. The heat transfer rate of the refrigerant 410A for evaporation show great sensitivity to flow direction of the water. The heat transfer rate for evaporation with a counter flow are 5-30% higher than that with a parallel flow.

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