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An Analysis of Temporal Characteristic Change for Various Hydrologic Weather Parameters (I) - On the Basic Statistic, Trend - (각종 수문기상인자의 경년별 특성변화 분석(I) - 기본통계량, 경향성을 중심으로 -)

  • Lee, Jae-Joon;Jang, Joo-Young;Kwak, Chang-Jae
    • Journal of Korea Water Resources Association
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    • v.43 no.4
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    • pp.409-419
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    • 2010
  • In this study, for the purpose of analyzing the characteristics of Korean hydrologic weather parameters, 9 hydrologic weather parameters data such as annual precipitation, annual rainy days, annual average relative humidity, annual average temperature, annual duration of sunshine, annual evaporation, annual duration of precipitation, annual snowy days and annual new snowy days are collected from 63 domestic meteorological stations that has the hydrologic weather parameters records more than 30 years. And the basic characteristics of hydrologic weather parameters through basic statistics, moving average and linear regression analysis are perceived. Also trend using the statistical methods like Hotelling-Pabst test and Mann-Kendall test about hydrologic weather parameters is analyzed. Through results of basic analysis, moving average and linear regression analysis it is shown that precipitation is concentrated in summer and deviation of precipitation for each season showed significant difference in accordance with Korean climate characteristics, besides the increase in annual precipitation and annual average temperature, annual average relative humidity and annual duration of sunshine reduction and annual rainy days is said to increase or decrease. The results of statistical analysis of trend are summarized as trend commonly appeared in annual average relative humidity and annual average temperature. and annual precipitation, annual rainy days and annual duration of sunshine showed different results according to area.

Effect of Liposome Encapsulation on Intestinal Absorption of Rhodamine 123 (리포솜 봉입이 로다민 123의 소장 흡수에 미치는 영향)

  • Hong, Soon-Sun;Lee, Hae-Ree;Li, Hong;Chung, Suk-Jae;Kim, Dae-Duk;Shim, Chang-Koo
    • YAKHAK HOEJI
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    • v.49 no.2
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    • pp.185-191
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    • 2005
  • The absorption of a P-gp substrate, rhodamine 123, from a liposomal dosage form was investigated across Caco-2 cell monolayers, rat intestines and rat intestinal Peyer's patches in Ussing chamber, Rhodamine 123 was incorporated into liposomes according to the standard evaporation method, which led to a production of liposomes with a mean diameter of 71.3 nm. The permeability (Papp of rhodamine 123 from a water solution across the monolayer was $2.45{\times}10^{-6}$ cm/s for $A{\leftrightarrow}B$ (apical to basal) and $14.0{\times}10^{-6}$ cm/s for $B{\leftrightarrow}A$ (basal to apical) directions, consistent with the fact that rhodamine 123 is one of the P-gp substrates. The transport of rhodamine 123 from the liposomal dosage form was much lower for both directions compared to the solution of rhodamine 123. The transport of rhodamine 123 across the rat intestine was also significantly decreased for both directions, I.e., influx and efflux, by the liposomal incorporation of the compound. The transport of rhodamine 123 across the Peyer's patch was substantially reduced by liposomal incorporation. No difference was found in the transport between the Peyer's patch and non-Peyer's patch. These observations suggest that the contribution of transport via Peyer's patches in the uptake of liposomes may be minimal, especially for rapidly absorbed compounds like rhodamine 123. Therefore, the increased absorption of P-gp substrates does not appear to be feasible by incorporating the compounds in liposomes, due to negligible involvement of Peyer's patches in the uptake of particulate dosage forms like liposomes. Liposomes may rather represent a sustained release dosage form of incorporated compounds.

Effect of Ionizing Radiation of Physiological Characteristics of Fresh Mushrooms (Agaricus bisporus L.) (양송이 버섯의 생리적 특성에 대한 감마선 조사 영향)

  • Byun, Myung-Woo;Kwon, Joong-Ho;Cho, Han-Ok;Cha, Bo-Sook;Kang, Se-Sik;Kim, Joong-Man
    • Korean Journal of Food Science and Technology
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    • v.21 no.5
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    • pp.669-675
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    • 1989
  • Fresh mushroom (Agaricus bisporus L.) was irradiated (0, 1, 2, 3kGy) and kept for 20 days at 9{\pm}1^{\circ}C\;and\;80{\pm}7%$ RH. Parameters of qualities were investigated on the physical and physiological characteristics. The pileus and stipe on nonirradiated mushroom were expanded and elongated from the 3rd day of storage, there by losing the acceptability as edible samples. After 5 days of storage, 2 to 3kGy of gamma irradiation were especially effective for controllong natural maturation and senescence of fresh mushrooms and so irradiated mushrooms were acceptable more than 20days storage. The texture of irradiated samples was superior to that of nonirradiated samples, even though softening of the tissue occurred during storage. Weight loss was greatest in the nonirradiated sample due to evaporation from an increased surface area resulting from expansion and ripending, which were retarded in the 2 to 3kGy irradiated samples after 5days of storage. These results suggest that the irradiation dose of 2 to 3kGy is apparently effective to extend the shelf life of fresh mushrooms stored at the above-mentioned condition.

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Fabrication of the Low Driving Voltage ZnS:Mn EL Device and Investigation of its Electro-optical Properties (저전압구동 ZnS:Mn EL device의 제작 및 전기 광학적 특성조사)

  • Kim, Jae-Beom;Kim, Do-Hyeong;Jang, Gyeong-Dong;Bae, Jong-Gyu;Nam, Gyeong-Yeop;Lee, Sang-Yun;Jo, Gyeong-Je;Jang, Hun-Sik;Lee, Hyeon-Jeong;Lee, Dong-Uk
    • Korean Journal of Materials Research
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    • v.10 no.4
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    • pp.290-294
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    • 2000
  • ZnS:Mn TFEL devices were fabricated by electron-beam evaporation method and then the electro-optical properties were investigated. To investigate the capacitance which was due to oxygen vacancy at the $Ta_2O_5$ thin film, AES(Auger Electron Spectroscopy) and C-F(capacitance-frequency) measurements were used. It was found that the capacitance was decreased by annealing the $Ta_2O_5$ film in oxygen ambience. From EL emission measurement, we observed the EL emission spectrum which had the peak range from 550nm and 650nm. This emission is associated with the transition from $^4T_1(^4G)$ first excited state to $^6A_1(^6S)$ ground state in the $3d^5$ energy level configuration of $Mn^{2+}$ occurs. The threshold voltage of EL device with $Ta_2O_5$ insulator layer was found to be 24V~28V. The CIE color coordinates of these emission are X=0.5151, Y=0.4202 which is yellowish orange emitting. The EL device using $Ta_2O_5$ insulator layer can be driven with a low voltage which is beneficial to the practical application.

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Determination of Convection Heat Transfer Coefficient Considering Curing Condition, Ambient Temperature and Boiling Effect (양생조건·외기온도·비등효과를 고려한 콘크리트 외기대류계수의 결정)

  • Choi Myoung-Sung;Kim Yun-Yong;Woo Sang-Kyun;Kim Jin-Keun
    • Journal of the Korea Concrete Institute
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    • v.17 no.4 s.88
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    • pp.551-558
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    • 2005
  • The setting and hardening of concrete is accompanied with nonlinear temperature distribution caused by development of hydration heat of cement. Especially at early ages, this nonlinear distribution has a large influence on the crack evolution. As a result, in order to predict the exact temperature history in concrete structures it is required to examine thermal properties of concrete. In this study, the convection heat transfer coefficient which presents thermal transfer between surface of concrete and air, was experimentally investigated with variables such as velocity of wind, curing condition and ambient temperature. At initial stage, the convection heat transfer coefficient is overestimated by the evaporation quantity. So it is essential to modify the thermal equilibrium considered with the boiling effect. From experimental results, the convection heat transfer coefficient was calculated using equations of thermal equilibrium. Finally, the prediction model for equivalent convection heat transfer coefficient including effects of velocity of wind, curing condition, ambient temperature and boiling effects was theoretically proposed. The convection heat transfer coefficient in the proposed model increases with velocity of wind, and its dependance on wind velocity is varied with curing condition. This tendency is due to a combined heat transfer system of conduction through form and convection to air. From comparison with experimental results, the convection heat transfer coefficient by this model was well agreed with those by experimental results.

Influence of Curing Methods on Compressive Strength and Shrinkage of High Strength Mortar with High Volume SCMs (양생방법 변화가 혼화재 다량치환 고강도 모르타르의 압축강도 및 수축변화에 미치는 영향)

  • Han, Cheon-Goo;Baek, Cheol
    • Journal of the Korea Institute of Building Construction
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    • v.18 no.1
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    • pp.33-40
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    • 2018
  • Currently, in South Korea, because of reducing the construction period or treating wasted water, there are some cases of missing wet curing for concrete structure even though for high strength concrete. This air curing conditions is considered to cause increased possibility of compressive strength decrease, and increasing drying or autogenous shrinkages. As a solution of shrinkage of concrete, The authors' research team conducted the research on improving durability of concrete with decreasing autogenous shrinkage by adding the oil or fat to induce the saponification. Therefore, in this research, the influence of curing method on compressive strength, shrinkage on evaporation rate of high strength mortar including high volume supplementary cementitious materials (SCMs) was evaluated depending on various curing methods such as air curing, drying after painting emulsified refined cooking oil (ERCO), and drying after 7 and 28 days' wet curing. The experimental result showed the air curing method caused approximately 50% of decreased compressive strength and 1.9 times of increased shrinkage rather than the 28-day-wet curing method, thus it was known that the wet curing significantly influences on performance of high strength mortar using high volume SCMs. However, the ERCO painting curing caused decreased performance of concrete rather than drying after 7 days curing while it caused improved performance of concrete than entire period air curing.

Spectroscopical Analysis of SiO2 Optical Film Fabricated by FHD(Flame Hydrolysis Deposition) (FHD(Flame Hydrolysis Deposition)공정으로 제작된 SiO2 광도파막의 분광학적 분석)

  • Kim, Yun-Je;Shin, Dong-Wook
    • Journal of the Korean Ceramic Society
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    • v.39 no.9
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    • pp.896-901
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    • 2002
  • Since many process parameters of FHD(Flame Hydrolysis Deposition) are involved in forming multi-component amorphous silica film ($SiO_2-B_2O_3-P_2O_5-GeO_2$), it has not been easy to predict the optical, mechanical and thermal properties of deposited film from the simple process parameters, such as source flow rate. Furthermore, the prediction of final composition of film becomes even more difficult after sintering at high temperature due to the evaporation of volatile dopants. The motivation of the study was to clarify the quantitative relationship between simple process parameters such as the flow rate of source gases and resulting chemical composition of sintered film. Hence, the compositional analysis of silica soot by FTIR(Fourier Transformation Infrared Spectroscopy) and ICP-AES(Inductively Coupled Plasma-Atomic Emission Spectrometry) under the control of the amount of dopant was carried out to obtain the quantitative composition. By measuring spectrum of absorbance from FTIR, the compositional change of B-O, Si-O, OH($H_2O$) in silica film was measured. The concentrations of these dopants were also measured by ICP-AES, which were compared with the FTIR result. The final quantitative relationship between simple process parameters and composition was deduced from the comparison between two results.

Studies on the Optical and the Electrical Characterization of Organic Electroluminescence Devices of Europium Complex Fabricated with PVD(Physical Vopor Deposition) Technique (진공 증착법에 의하여 제작한 Europium complex 유기 박막 전기발광소자의 광학적.전기적 특성에 관한 연구.)

  • Lee, Myeong-Ho;Lee, Han-Seong;Kim, Yeong-Gwan;Kim, Jeong-Su
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.48 no.5
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    • pp.285-295
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    • 1999
  • Electroluminescent(EL) devices based on organic materials have been of great interest due to their possible applications for large-area flat-panel displays. They are attractive because of their capability of multi-color emission, and low operation voltage. An approach to realize such device characteristics is to use active layers of lanthanide complexes with their inherent extremely sharp emission bands in stead of commonly known organic dyes. In general, organic molecular compounds show emission due to their $\pi$-$\pi*$ transitions resulting in luminescence bandwidths of about 80 to 100nm. Spin statistic estimations lead to an internal quantum efficiency of dye-based EL devices limited to 25%. On the contrary, the fluorescence of lanthanide complexes is based on an intramolecular energy transfer from the triplet of the organic ligand to the 4f energy states of the ion. Therefore, theoretical internal quantum efficiency is principally not limited. In this study, Powders of TPD, $Eu(TTA)_3(phen) and AlQ_3$ in a boat were subsequently heated to their sublimation temperatures to obtain the growth rates of 0.2~0.3nm/s. Organic electrolumnescent devices(OELD) with a structure of $glass substrate/ITO/Eu(TTA)_3(phen)/AI, glass substrate/ITO/TPD/Eu(TTA)_3(phen)/AI and glass substrate/ITO/TPD/Eu(TTA)_3(phen)/AIQ_3AI$ structures were fabricated by vacuum evaporation method, where aromatic diamine(TPD) was used as a hole transporting material, $Eu(TTA)_3(phen)$ as an emitting material, and Tris(8-hydroxyquinoline)Aluminum$(AlQ_3)$ as an electron transporting layer. Electroluminescent(EL) and current density-voltage(J-V) characteristics of these OELDs with various thickness of $Eu(TTA)_3(phen)$ layer were investigated. The triple-layer structure devices show the red EL spectrum at the wavelength of 613nm, which is almost the same as the photoluminescent(PL) spectrum of $Eu(TTA)_3(phen)$.It was found from the J-V characteristics of these devices that the current density is not dependent on the applied field, but on the electric field.

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Electrical Properties of Al3+ and Y3+ Co-doped SnO2 Transparent Conducting Films (Al3+와 Y3+ 동시치환 SnO2 투명전극 박막의 전기적 특성)

  • Kim, Geun-Woo;Seo, Yong-Jun;Sung, Chang-Hoon;Park, Keun-Young;Cho, Ho-Je;Heo, Si-Nae;Koo, Bon-Heun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.10
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    • pp.805-810
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    • 2012
  • Transparent conducting oxides (TCOs) have wide range of application areas in transparent electrode for display devices, Transparent coating for solar energy heat mirrors, and electromagnetic wave shield. $SnO_2$ is intrinsically an n-type semiconductor due to oxygen deficiencies and has a high energy-band gap more than 3.5 eV. It is known as a transparent conducting oxide because of its low resistivity of $10^{-3}{\Omega}{\cdot}cm$ and high transmittance over 90% in visible region. In this study, co-doping effects of Al and Y on the properties of $SnO_2$ were investigated. The addition of Y in $SnO_2$ was tried to create oxygen vacancies that increase the diffusivity of oxygen ions for the densification of $SnO_2$. The addition of Al was expected to increase the electron concentration. Once, we observed solubility limit of $SnO_2$ single-doped with Al and Y. $\{(x/2)Al_2O_3+(x/2)Y_2O_3\}-SnO_2$ was used for the source of Al and Y to prevent the evaporation of $Al_2O_3$ and for the charge compensation. And we observed the valence changes of aluminium oxide because generally reported of valence changes of aluminium oxide in Tin - Aluminium binary system. The electrical properties, solubility limit, densification and microstructure of $SnO_2$ co-doped with Al and Y will be discussed.

Enhanced Dissolution and Permeation of Biphenyl Dimethyl Dicarboxylate Using Solid Dispersions (고체분산체로부터 비페닐디메칠디카르복실레이트의 용출 및 투과 증전)

  • Moon, Jee-Hyun;Chun, In-Koo
    • Journal of Pharmaceutical Investigation
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    • v.29 no.3
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    • pp.227-234
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    • 1999
  • Solid dispersions were prepared to increase the dissolution rate of biphenyl dimethyl dicarboxylate (DDB) using water-soluble carriers such as povidone, copolyvidone, $2-hydroxypropyl-{\beta}-cyclodextrin (HPCD)$, sodium salicylate or sodium benzoate by solvent evaporation method. Solid dispersions were characterized by infrared spectrometry, differential scanning calorimetry (DSC) and powder X-ray diffractometry, dissolution and permeation studies. DDB tablets (7.5 mg) were prepared by compressing the powder mixtures composed of solid dispersions, lactose, com starch, crospovidone and magnesium stearate using a single-punch press. DDB capsules (7.5 mg) were also prepared by filling the mixtures in empty hard gelatin capsules (size No.1). From the DSC and powder x-ray diffractometric studies, it was found that DDB was amorphous in the HPCD or copolyvidone solid dispersions. Dissolution rates after 10 min of DDB alone and solid dispersions (1 : 10) in sodium benzoate, sodium salicylate and copolyvidone were 11.8, 23.5, 22.8 and 82.5%, respectively. Dissolution rates of DDB after 30 min from 1 : 10 and 1 : 20 copolyvidone solid dispersions were 80.5 and 95.0%, respectively. For the DDB tablets prepared using solid dispersions (1 : 20), the initial dissolution rate was dependent on carrier material, and was ranked in order, $Kollidon\;30\;{\ll}$ copolyvidone < HPCD. For the HPCD solid dispersion tablets, dissolution rate reached 97.4% after 15 min, but thereafter slowly decreased to 80.7% after 2 hr due to the precipitation of DDB. However, in the case of copolyvidone solid dispersion tablets, dissolution increased linearly and reached 93.4% after 2 hr. Reducing the volume of test medium from 900 to 300 ml markedly decreased the dissolution rate of the tablets containing 1 : 20 HPCD solid dispersions and 1 : 10 copolyvidone solid dispersion. For 1 : 20 copolyvidone solid dispersion tablets, there was no significant change in dissolution rate up to 1 hr with different volumes of test medium. Preparation of the copolyvidone solid dispersion (1 : 20) in capsules markedly delayed the dissolution (31.2 % after 2hr) due to the limited diffusion within capsules. The permeation rate $(13.4\;g/cm^2\;after\;8\;hr)$ of DDB through rabbit duodenal mucosa from copolyvidone solid dispersion (1 : 10) was markedly enhanced, when compared with drug alone or physical mixtures. From overall findings, DDB formulations containing copolyvidone solid dispersions (1 : 20) could be used to remarkably improve the dissolution rate in dosage form of powders and tablets.

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