• Title/Summary/Keyword: EVAPORATION

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Evaporation Rate of Lead in Molten Copper Alloy by Gas Injection (가스취입에 의한 용융 동 합금 중 납의 증발속도)

  • Kim, Hang-Su;Jeong, Seong-Yeop;Jeong, U-Gwang;Yun, Ui-Han;Son, Ho-Sang
    • Korean Journal of Materials Research
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    • v.12 no.1
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    • pp.68-74
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    • 2002
  • The lead has to be removed for the recycling of copper alloy. The lead cannot be removed from the copper alloy by oxidation. It can be removed by the evaporation because of its high vapor pressure. However, rare information is found on removal of lead from copper alloy. The purpose of present work is to provide a fundamental knowledges on the removal of lead from the copper alloy by evaporation. Gas injection was made in molten copper alloy, and the evaporation rate of lead was measured. The influence of Ar gas flow rata(2~4 L/min), initial contents of lead(2~4wt%Pb), temperature(1200~140$0^{\circ}C$) was investigated based on the thermodynamic and the kinetics. The rate constant is increased with increasing flow rate of Ar and temperature. Though amount of lead removed is increased with higher initial lead concentration, the rate constant is not changed significantly. The activation energy is estimated from the temperature dependence of the rate constant. Also removal of lead from the copper by adding chloride was made for the comparison.

Deposition of Yttria Stabilized Zirconia by the Thermal CVD Process

  • In Deok Jeon;Latifa Gueroudji;Nong M. Hwang
    • The Korean Journal of Ceramics
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    • v.5 no.2
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    • pp.131-136
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    • 1999
  • Yttria stabilized zirconia(YSZ) films were deposited on porous NiO substrates and quartz plates by the thermal CVD using $ZrCl_4, YCl_3$ as precursors, and $O_2$ as a reactive gas at atmospheric pressure. The evaporation temperature of $ZrCl_4$ was varied from $250^{\circ}C$ to $550^{\circ}C$ while the temperatures of $YCl_3$ and the substrate were varied from $1000^{\circ}C$ to $1030^{\circ}C$. As the evaporation temperature of $ZrCl_4$ increased, the deposition rate of $ZrO_2$ decreased, contrary to our expectation. As a result of the decreased deposition rate of $ZrO_2$, the yttria content increase. The high evaporation temperature of $ZrCl_4$ makes the well-faceted crystal while the low evaporation temperature leads to the cauliflower-shaped structure. The dependence of the evaporation temperature on the growth rate and the morphological evolution was interpreted by the charged cluster model.

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Experimental Study on Evaporation and Combustion Characteristics of Fuel Droplet with Carbon Nano-Particles in RCM (급속압축장치에서 탄소 나노입자가 첨가된 연료 액적의 증발 및 연소 특성에 관한 실험적 연구)

  • Ahn, Hyeongjin;Jyoti, Botchu Vara Siva;Baek, Seung Wook
    • Journal of the Korean Society of Combustion
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    • v.21 no.2
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    • pp.7-14
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    • 2016
  • Evaporation and combustion characteristics of fuel droplet with carbon nanoparticle were investigated in a rapid compression machine(RCM). RCM is an experimental equipment to simulate one compression stroke of reciprocating engine. Nitrogen was charged into reaction chamber for evaporation experiment, while oxygen was charged for combustion experiment. N990 carbon black and n-heptane were used to synthesize the carbon nanofluids. Surfactant, span80, was used to make synthesis easier. The droplet pictures were taken using a high speed camera with 500 frames per second. Thermocouple, of which tip is $50{\mu}m$, was used not only to measure transient bulk temperature, but also to suspend the droplet. Reaction chamber temperature was calculated from pressure data. The evaporation rate of nanofluids was improved compared to pure fuel. The ignition delay was promoted due to the nanoparticle, but the burning rate was decreased.

Characteristics of Thin Films Fabricated by Using the Layer-by-Layer Sputtering and Evaporation Method (순차 스퍼터 법과 증발 법으로 제작한 박막의 특성)

  • Cheon, Min-Woo;Park, Yong-Pil;Kim, Jeong-Ho
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.571-574
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    • 2003
  • The thin films fabricated by using the layer-by-layer sputtering was compared with the thin film fabricated by using the evaporation method. Re-evaporation in the form of Bi atoms or $Bi_2O_3$ molecules easily bring out the deficiency of Bi atoms in thin film due to the long sputtering time of the layer-by-layer deposition. On the other hand, the respective atom numbers corresponding to BiSrCaCuO phase is concurrently supplied on the film surface in the evaporation deposition process and leads to BiSrCaCuO phase formation. Also, it is cofirmed that by optimizing the deposition condition, each single phase of the Bi2201 phase and the Bi2212 phase can be fabricated, the sticking coefficient of Bi element is clearly related to the changing of substrate temperature and the formation of the Bi2212 phase.

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Design and Development of Sputter-evaporation System for Micro-wiring on Medical Catheter (의료용 도뇨관 표면의 도선용 구리 박막 증착을 위한 스퍼터링-열증착 연속공정장비의 설계 및 개발)

  • Chang, Jun-Keun;Chung, Seok
    • Journal of the Korean Society for Precision Engineering
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    • v.16 no.3 s.96
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    • pp.62-71
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    • 1999
  • Integrating micro-machined sensors and actuators on the conventional devices with the copper power lines was incompatible to fabricate the mass produced micro electromechanical system (MEMS) devices. To achieve the compatibility of the wiring method between MEMS parts and devices, we developed the three-dimensional sputter-evaporation system that coats micropatterned thin copper films on the surface of the MEMS element. The system consists of a process chamber, two branch chambers, the substrate holder, and a linear-rotary motion feedthrough. Thin copper film was sputtered and evaporated on the biocompatible polymer, Pellethane$^{circed{R}}$ and silicone, catheter that is 2 mm in diameter and 700 mm in length. The metal film coating technique with three-dimensional thin film sputter-evaporation system was developed to apply the power and signal lines on the micro active endoscope. In this paper, we developed the three-dimensional metal film sputter-evaporation system operated on the low temperature for the biopolymeric substrates used in the medical MEMS devices.

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Comparison of the Ion-exchange Method and Evaporation Method for the Detection of Radioactivity in Water (수중 방사능 측정시 이온교환농축법과 증발건조법의 비교)

  • Ji, Pyung-Gook;Park, Chong-Mook;Ro, Seung-Gy
    • Journal of Radiation Protection and Research
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    • v.13 no.2
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    • pp.52-56
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    • 1988
  • An ion-exchange method for the detection of radioactivity in water using ion-exchange resin in concentrating radioactive nuclides was compared with an evaporation method. The loss of the radioactive materials in the sample treated by the ion-exchange method was less by about 20% than that by the evaporation method. In addition, the evaporation method needed about 20 hours for evaporating one liter of the sample at $70^{\circ}C$, while the ion-exchange method spent 6 hours to adsorb and adsorb the same amount of the sample on the resin. Consequently, the ion-exchange method is more effective than the evaporation method for the treatment of the radioactively contaminated water and is especially suitable for detecting the low-level radioactivity in water.

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Experimental Study on Effects of PAG Oil for $CO_2$ Evaporation Heat Transfer (PAG 오일이 $CO_2$ 증발열전달에 미치는 영향에 관한 실험적 연구)

  • Lee, Sang-Jae;Kim, Dae-Hoon;Choi, Jun-Young;Lee, Jae-Heon;Kwon, Young-Chul
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.20 no.5
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    • pp.357-363
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    • 2008
  • In order to investigate $CO_2$ heat transfer coefficient and pressure drop by PAG oil concentration during $CO_2$ evaporation, the experiment on evaporation heat transfer characteristics in a horizontal micro-fin tube was performed. The experimental apparatus consisted of a test section, a DC power supply, a heater, a chiller, a mass flow meter, a pump and a measurement system. Experiment was conducted for various mass fluxes($400{\sim}1200\;kg/m^2s$), heat fluxes($10{\sim}30\;kW/m^2$) and saturation temperatures ($-5{\sim}5^{\circ}C$), and PAG oil concentration($0{\sim}5\;wt%$). The variation of the heat transfer coefficient was different in accordance with the oil concentration. With the increase of the oil concentration, the evaporation heat transfer coefficient decreased and the delay of dryout by oil addition was found. Pressure drop increased with the increase of the oil concentration and heat flux, and the decrease of saturation temperature.

Establishing the Models for Optimized Design of Water Injection in Boilers with Waste-heat-recovery System (가습연소 폐열회수 보일러의 물분사 설계모델 구축에 관한 연구)

  • Shin, Jaehun;Moon, Seoksu
    • Journal of ILASS-Korea
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    • v.26 no.2
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    • pp.96-103
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    • 2021
  • In order to improve the overall efficiency and meet the emission regulations of boiler systems, the heat exchanging methods between inlet air and exhaust gas have been used in boiler systems, named as the waste-heat-recovery condensing boiler. Recently, to further improve the overall efficiency and to reduce the NOx emission simultaneously, the concept of the water injection into the inlet air is introduced. This study suggests the models for the optimized design parameters of water injection for waste-heat-recovery condensing boilers and performs the analysis regarding the water injection amount and droplet sizes for the optimized water injection. At first, the required amount of the water injection was estimated based on the 1st law of thermodynamics under the assumption of complete evaporation of the injected water. The result showed that the higher the inlet air and exhaust gas temperature into the heat exchanger, the larger the amount of injected water is needed. Then two droplet evaporation models were proposed to analyze the required droplet size of water injection for full evaporation of injected water: one is the evaporation model of droplet in the inlet air and the other is that on the wall of heat exchanger. Based on the results of two models, the maximum allowable droplet sizes of water injection were estimated in various boiler operating conditions with respect to the residence time of the inlet air in the heat exchanger.

Thermal evaporation을 이용해 성장 온도에 따른 ZnO nanorod의 특성

  • Lee, Hye-Ji;Kim, Dong-Yeong;Kim, Ji-Hwan;Kim, Hae-Jin;Son, Seon-Yeong;Kim, Jong-Jae;Kim, Hwa-Min
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.25-25
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    • 2009
  • Zinc Oxide (ZnO) nanorod were grown on Si wafer by a thermal evaporation method at various temperatures. And their structure and optical properties were measured using Photoluminescence(PL), Scanning electron microscopy(SEM), and X-ray diffraction(XRD) analysis.

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