• Title/Summary/Keyword: EPR

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Electron Paramagnetic Resonance of the I2-Doped PBMPV Conducting Polymers

  • Lee, C. H.;Lee, Cheol-Eui;J.-I. Jin;S.-J. Chung
    • Journal of Magnetics
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    • v.2 no.4
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    • pp.123-125
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    • 1997
  • We have studied a series of I2-doped poly [2-buthoxy-5-methoxy-1, 4-phenylenevinylene] (PBMPV) conducting polymers by means of electron paramagnetic resonance (EPR) measurements. In this work, the EPR linewidth and spin density were obtained from the EPR intensity and studied as a function of the degree of doping.

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유럽형 PWR의 개발현황

  • M. 와토우;H. 자이델버거
    • Nuclear industry
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    • v.15 no.8 s.150
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    • pp.74-79
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    • 1995
  • NPI(Nuclear Power International)사와 그 모기업인 지멘즈(Siemens)사와 프라마톰(Framatome)사는 유럽의 주요 전력업체들의 지원을 받아 차세대원자로인 유럽형 가압경수로(European Pressurized Water Reactor : EPR)를 지금까지 개발해 왔다. EPR은 높은 안전성과 경제성, 평이성, 향상된 운전성 등의 차세대원자로의 당면과제를 만족스럽게 해결함으로써 앞으로 세계 원자력산업에 크게 기여할 것으로 본다. EPR의 개발현황을 살펴본다.

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EPR Lineshape and g-Factor of the Single Crystal $Mn_xSi_{1-x}$

  • Son, Phil-Kook;Hwang, Young-Hun;Heo, Kyong-Chan;Kim, Hung-Cheol;Ok, Chi-Il;Um, Young-Ho;Kim, Jang-Whan
    • Journal of the Korean Magnetic Resonance Society
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    • v.8 no.1
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    • pp.47-54
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    • 2004
  • We have measured the linewidth and g-factor of EPR signals of the single crystal Mn$_{x}$Si$_{1-x}$ as a function of Mn-composition (0.4$\leq$x$\leq$0.9). We have investigated the linewidth of Mn$_{0.49}$Si$_{0.51}$ as a function of temperature (100 $\leq$ T $\leq$ 300 K). From these results EPR linewidth equation could be fitted for experimental data of EPR linewidth. This type of equation is similar to the shape of EPR linewidth of DMS (dulite magnetic semiconductor).or).r).

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Structural Analysis and Single-Crystal EPR Study of Dimeric Cu(I) Complex with TTF Derivative

  • Kwon, Sun-Young;Seo, Young-Joo;Lee, Yang-Joo;Noh, Dong-Youn;Lee, Hong-In
    • Journal of the Korean Magnetic Resonance Society
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    • v.8 no.2
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    • pp.86-95
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    • 2004
  • A Cu(I) complex with an asymmetric TTF derivative (CET-EDTTTF) is prepared from the slow-diffusion method using CET-EDTTTF and Cu(I)Br solutions and characterized by X-ray crystallography and EPR spectroscopy. Structural analysis shows Cu(I) ions are tetrahedrally coordinated to two bridging bromides, one terminal bromide, and one S atom from CET-EDTTTF. Detailed geometrical and EPR analysis identified that the dimmer molecule contains [Cu$_2Br_4]^{2-}$ anion between two [CET-EDTTTF]$^+$ radical cations. Single-crystal EPR investigation of the complex reveals that the ganisotropy is unusually big, compared to those of the previously reported TTF+ cation radicals, implying that there is significant contribution of the Cu d-orbital to the HOMO of the complex.

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Effects of Axial Flow Compressor Surge on the Performance in Turbofan Engine (터보팬 엔진의 축류압축기 서지가 엔진성능에 미치는 영향)

  • Oh, Chang-Yong;Koo, Ja-Ye
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2008.05a
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    • pp.236-239
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    • 2008
  • This thesis has analyzed the effect of the surge happening in flight on the engine performance of the PW4000 turbofan engine. EPR is judged to be the most highly sensitive parameter responding when surge occurs. Both N1 rpm and N2 rpm decreases almost simultaneously just like an EPR. During the take-off rolling, the N1 vibration is more sensitive than the N2 vibration. Consequently, the surge can be detected by EGT increase, while the other parameters decrease.

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EPR Investigation on a Quantitative Analysis of Eu(II) and Eu(III) in LiCl/KCl Eutectic Molten Salt

  • Park, Yong-Joon;Kim, Tack-Jin;Cho, Young-Hwan;Jung, Yong-Ju;Im, Hee-Jung;Song, Kyu-Seok;Jee, Kwang-Yong
    • Bulletin of the Korean Chemical Society
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    • v.29 no.1
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    • pp.127-129
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    • 2008
  • EPR spectroscopic technique was applied for a quantitative analysis of Eu(II) for a speciation of europium in a LiCl-KCl eutectic melt. By adopting the first absorption line of each isotopes (151Eu and 153Eu), a calibration plot was obtained. The calibration of the EPR intensity shows a good linearity according to the amount of Eu(II). The EPR intensity was identified to increase proportionally with a decrease of the attenuation parameter for EPR microwave power. The fluorescence technique was used qualitatively to find whether either of Eu(II) or Eu(III) ions exists in a molten salt sample. The ICP-AES technique was also adopted to determine the total concentration of europium in the sample, since EPR is only sensitive for detecting the Eu(II) ion. The extent of the reduction of Eu(III) in the LiCl-KCl eutectic melt at 723 K was determined by using this technique.

Detection of gamma irradiated South Sea cultured pearls (감마선 조사된 남양진주의 검지)

  • Choi, Hyun-Min;Lee, Bo-Hyun;Kim, Young-Chool
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.22 no.1
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    • pp.36-41
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    • 2012
  • We have been performed on $Co^{60}$ ${\gamma}$-ray irradiation of South Sea cultured pearls, with the absorbed dose of 0.1~100 kGy at room temperature. In addition, it was investigated electron paramagnetic resonance (EPR) and amino acid analysis (AAA) for detection of Gamma irradiated South Sea cultured pearls. It was observed that the irradiated South Sea cultured pearls revealed additional free radical peak such as $CO_2^-$, at a g-factor of $2.001{\pm}0.002$ in EPR spectra. From the amino acid analysis (AAA), it was shown that some of amino acid in the protein of the nacre destroyed after ${\gamma}$-ray; glutamic acid residue by 11.43 %, alanine by 3.11 %, and histidine by 43.75 %. It was useful to detect the irradiated South Sea cultured pearls by EPR measurement in our study.

Preliminary Study on Electron Paramagnetic Resonance(EPR) Signal Properties of Mobile Phone Components for Dose Estimation in Radiation Accident (방사선사고시 피폭선량평가를 위한 휴대전화 부품의 전자상자성공명(EPR) 특성에 대한 예비 연구)

  • Park, Byeong Ryong;Ha, Wi-Ho;Park, Sunhoo;Lee, Jin Kyeong;Lee, Seung-Sook
    • Journal of Radiation Protection and Research
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    • v.40 no.4
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    • pp.194-201
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    • 2015
  • We have investigated the EPR signal properties in 12 components of two mobile phones (LCD, OLED) using electron paramagnetic resonance (EPR) spectrometer in this study.EPR measurements were performed at normal atmospheric conditions using Bruker EXEXSYS-II E500 spectrometer with X-band bridge, and samples were irradiated by $^{137}Cs$ gamma-ray source. To identify the presence of radiation-induced signal (RIS), the EPR spectra of each sample were measured unirradiated and irradiated at 50 Gy. Then, dose-response curve and signal intensity variating by time after irradiation were measured. As a result, the signal intensity increased after irradiation in all samples except the USIM plastic and IC chip. Among the samples, cover glass(CG), lens, light guide plate(LGP) and diffusion sheet have shown fine linearity ($R^2$ > 0.99). Especially, the LGP had ideal characteristics for dosimetry because there were no signal in 0 Gy and high rate of increase in RIS. However, this sample showed weakness in fading. Signal intensity of LGP and Diffusion Sheet decreased by 50% within 72 hours after irradiation, while signals of Cover Glass and Lens were stably preserved during the short period of time. In order to apply rapidly EPR dosimetry using mobile phone components in large-scale radiation accidents, further studies on signal differences for same components of the different mobile phone, fading, pretreatment of samples and processing of background signal are needed. However, it will be possible to do dosimetry by dose-additive method or comparative method using unirradiated same product in small-scale accident.