Journal of the Korean Magnetic Resonance Society (한국자기공명학회논문지)
- Volume 8 Issue 2
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- Pages.86-95
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- 2004
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- 1226-6531(pISSN)
Structural Analysis and Single-Crystal EPR Study of Dimeric Cu(I) Complex with TTF Derivative
- Kwon, Sun-Young (Department of Chemistry, Seoul Women’s University) ;
- Seo, Young-Joo (Department of Chemistry Education, Kyungpook National University) ;
- Lee, Yang-Joo (Department of Chemistry Education, Kyungpook National University) ;
- Noh, Dong-Youn (Department of Chemistry, Seoul Women’s University) ;
- Lee, Hong-In (Department of Chemistry Education, Kyungpook National University)
- Published : 2004.12.20
Abstract
A Cu(I) complex with an asymmetric TTF derivative (CET-EDTTTF) is prepared from the slow-diffusion method using CET-EDTTTF and Cu(I)Br solutions and characterized by X-ray crystallography and EPR spectroscopy. Structural analysis shows Cu(I) ions are tetrahedrally coordinated to two bridging bromides, one terminal bromide, and one S atom from CET-EDTTTF. Detailed geometrical and EPR analysis identified that the dimmer molecule contains [Cu