• Title/Summary/Keyword: EPDM 고무

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Fracture Toughness of the Thermoplastic Vulcanizates from EPDM/PP/Ionomer Ternary Blends (EPDM/PP/Ionomer 삼원 블렌드로 된 열가소성 가황체의 파괴 인성)

  • Kim, K.;Cho, W.J.;Ha, C.S.;Go, J.H.
    • Elastomers and Composites
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    • v.31 no.5
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    • pp.341-346
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    • 1996
  • The fracture mechanics investigation of the thermoplastic vulcanizates(TPV) from EPDM and PP/Ionomer ternary blends was performed in terms of the J-integral by measuring fracture energy via the locus method. The TPV from ternary blends consisting of EPDM, PP and ionomer were prepared in a laboratory integral mixer by blending and vulcanizing simultaneously. Vulcanization was performed with dicumyl peroxide (DCP) and the composition of EPDM and PP was fixed at 50/50 by weight. Two kinds of poly(ethylene-co-methacrylic acid) (EMA) lonomers were used. The J-integral values at crack initiation, Jc, of the dynamically vulcanized EPDM and PP/EMA Ionomer ternary blends were affected by the cation types $(Na^+\;or\;Zn^{2+})$ and contents(5-20wt%) of the added EMA Ionomers. The ternary blend containing 20wt% zinc-neutralized EMA Ionomer and 1.0phr DCP showed the highest Jc values of the blends.

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A Study on the Fatigue Property of Magneto-Rheological Elastomers

  • Kim, Tae Woo;Choi, You Jin;Kim, Nam Yoon;Chung, Kyung Ho
    • Elastomers and Composites
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    • v.53 no.3
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    • pp.150-157
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    • 2018
  • Fatigue properties of rubber are one of the most important characteristics in the rubber industry. In this study, the fatigue properties of MREs (magneto-rheological elastomers) based on NR (natural rubber), EPDM (ethylene-propylene diene monomer), and AEM (ethylene/acrylic elastomer) were investigated. For comparison, MREs with a Shore hardness of 60A were prepared. According to the relative results, the fatigue properties of EPDM MRE were the worst. Thus, we investigated methods to improve the fatigue properties of EPDM MRE by varying the carbon black content and curing systems of EPDM as the matrix of the MRE. Dynamic properties were measured using a fatigue tester and an RPA (rubber process analyzer), and the XPS (X-ray photoelectron spectroscopy) was used to analyze the curing system of the EPDM matrix. According to the results, the Payne effect increased and the fatigue resistance decreased as the carbon black content increased. In case of the curing system, the CV (conventional vulcanization) system was superior to the EV (efficient vulcanization) system in terms of the fatigue resistance. This was because the number of flexible bonds in the case of the CV system was higher than that in the case of the EV system. However, the EV system showed excellent mechanical properties because it had many monosulfidic bonds with strong binding energy.

The Ablation Effect of Fabric/EPDM Rubber with Manufacturing process (Fabric/EPDM계 고무의 제작 공정에 따른 삭마 특성)

  • Kim, Jin-Yong;Rho, Tae-Ho;Lee, Won-Bok;Cho, Won-Man;Rhee, Young-Woo
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2012.05a
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    • pp.92-95
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    • 2012
  • The dual pulse rocket motor is a pressure vessel containing two pulse grains separated by a pulse separation device such as a fragile bulkhead. One of the important things in this systems is case insulation design using the excellent materials in the 1st stage pulse motor. We investigated manufacturing process of fabric/EPDM chamber insulations in order to protect the 1st stage pulse motor case with high intensity gas flow. Simulation motor connected with extension tube having FRP disc was designed to study ablation characteristics of insulation.

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Effects of Activator on Rubber Characteristics for Gasket to Lithium Ion Battery (리튬 이온 전지용 개스킷 고무 물성에 미치는 가교조제의 영향)

  • Kang, Dong-gug;Kim, Hye-young;Kang, Young-im;Hur, Byung-ki;Seo, Kwan-ho
    • Applied Chemistry for Engineering
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    • v.22 no.4
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    • pp.395-399
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    • 2011
  • Material of the gasket for lithium ion battery requires the chemical resistance, the electrical insulting property, the compression set, the anti-contamination level and the low temperature resistance. We compounded ethylene propylene diene monomer (EPDM), which showed widely different solubility parameter index, with adjusting the amount of metal oxide as an activator. We did long-term test and compression set against an electrolyte with consideration for operating conditions in lithium-ion battery. In these tests, we checked the physical, chemical characteristics and the effect to lithium ion battery with different kinds of activators. In case of rubber with ZnO as an activator, through 1000 h depositing test in propylene carbonate which is one of representative solvents, we could get the satisfying characteristics and result. However, $Zn^{2+}$ had eluted in the ion elution test. So, ZnO should be limited in EPDM compound for the gasket material in lithium-ion battery.

Effect of Carbon Black on Mechanical and Damping Properties of EPDM/Carbon Black System (EPDM/Carbon Black계에서 Carbon Black에 따른 기계적 성질 및 방진 특성)

  • No, Tae-Kyeong;Kang, Dong-Guk;Seo, Jae-Sik;Yang, Kyung-Mo;Seo, Kwan-Ho
    • Elastomers and Composites
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    • v.47 no.3
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    • pp.231-237
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    • 2012
  • This study measured the mechanical and damping properties of EPDM compounds including fillers. Semi-reinforcing furnace black (SRF), high abrasion furnace black (HAF) and acetylene black were used as fillers. Dicumyl peroxide (DCP) were used as curing agents. The measurements were conducted using a moving die rheometer (MDR), durometer, universal testing machine (UTM), compression set and dynamic mechanical analysis (DMA). The tensile strength and elongation at break increased with increasing SRF contents in EPDM compounds. However, they decreased with increasing the amount of acetylene black. In the inspecting temperature range, EPDM compound filled acetylene black had stable storage modulus. Furthermore, the tan ${\delta}$ of the EPDM compounds obtained was enhanced by compounding with acetylene black.

염무/열 반복열화에 따른 실리콘 고무의 특성 변화에 미치는 ATH 첨가 효과

  • Kim, Kyu-Baek;Lee, Chung;Kim, Ki-Yup;Ryu, Boo-Hyung
    • Proceedings of the Korean Institute of Industrial Safety Conference
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    • 2003.10a
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    • pp.142-147
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    • 2003
  • 고분자 애자용 재료로 EPDM, 폴리에틸렌, 에폭시, 실리론 고무 등이 사용되고 있으며, 이중 실리콘 고무는 내후성, 내트랙킹성, 내아크성, 내환경성, 발수성등이 우수하다는 것이 많은 연구를 통해 밝혀졌다. 그러나, 옥외용 고분자는 다양한 환경에 의한 열화에 의해 낮은 인열강도를 나타내고 반복 열화에 따라 전기적 특성과 기계적 강도가 급격히 저하하는 단점을 가지고 있다.(중략)

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Evaluation of Dynamic Characteristics of Rubber Materials Using a Double Cantilever Sandwich Beam Method (양팔 샌드위치보 시험법에 의한 EPDM고무의 동특성 평가 연구)

  • Kim, Kwang-Woo;Choi, Nak-Sam
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.26 no.7
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    • pp.1393-1400
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    • 2002
  • A double cantilever sandwich-beam method has been applied to the evaluation of the frequency dependence of dynamic elastic modulus and material loss factor of EPDM rubbers. The flexural vibration of a double cantilever sandwich-beam specimen with an inserted rubber layer was studied using a finite element simulation in combination with the sine-sweep test. Effects of the rubber layer length on the dynamic characteristics were also investigated: reliable values were measured when the length of the inserted rubber layer was larger than and equal to 50% of the effective specimen length. The values were compared with those obtained by the dynamic mechanical analysis and the simple resonant test. Relationships of the dynamic characteristics of rubbers with frequency could be determined using the least square error method.

Study on Surface Chemical Structure and Mechanical Properties of EPDM Rubber with Microwave Irradiation Time

  • Eom, SeoBin;Lee, Sun Young;Park, Sung Han;Lee, Seung Goo
    • Elastomers and Composites
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    • v.53 no.3
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    • pp.124-130
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    • 2018
  • Recently, microwaves have been used for desulfurization because they can selectively dissociate C-S and S-S bonds present in vulcanized rubber. In this study, we investigated the changes in structural and physical properties of EPDM (Ethylene propylene diene monomer) rubber by irradiating it with microwaves for different durations. The surface chemical composition of the irradiated EPDM rubber was analyzed by FT-IR, XPS, and EDS analyses. It was confirmed by XPS that C-S and S-S S2p peak heights greatly decreased when microwave irradiation was performed for more than 5 min. In the EPDM sample irradiated with microwaves for 10 min, the number of S-O bonds significantly increased owing to oxidation. As the microwave irradiation time was increased, SEM images showed cracks and voids on the EPDM surface. The 20% decomposition temperature of the EPDM rubber sample was investigated by TGA, and it was found to be about $435.23^{\circ}C$ for the EPDM rubber irradiated for 10 min. The crosslinking density of the EPDM rubber was determined by measuring the degree of swelling, and the highest value was observed for the E5 sample irradiated for 5 min. The degree of swelling of the E10 sample irradiated for 10 min was lower than that of the E5 sample. These results indicate that when irradiated with microwaves for more than a certain time, desulfurization occurs and the side chain of the EPDM rubber dissociates and forms additional crosslinking bonds.

Phase Equilibrium Study on the Ternary System of SBR/EPDM/Solvent (SBR, EPDM 및 Solvent로 이루어진 삼성분계의 상 평형에 관한 연구)

  • Go, Jin-Hwan;Park, Byung-Ho
    • Elastomers and Composites
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    • v.37 no.4
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    • pp.211-216
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    • 2002
  • The polymer-polymer interaction parameter, x 23t, of the styrene-butadiene polymer (SBR) and ethylene-propylene-diene terpolymer (EPDM) was investigated by observing the phase behavior of the ternary system of SBR/EPDM/solvent. The solvent used in this study was benzene acting as a good solvent for SBR but as a poor solvent for EPDM. Ternary solutions with various concentrations and mixing ratios of the two component polymers were separated into two phases by temperature change The cloud point curves (CPC) showed that the differerence of solvent affinities toward each polymer and the repulsive interaction between two polymers considerably affect the shape of CPC near 15℃. In the temperature range of 5℃ ~ 25℃, incompatible behaviours arised from both the difference of mixing ratios and concentration were clearly observed. Also the phase separation temperature greatly influenced on the composition of each separated phase. The calculated x 23t values from Flory-Huggins theory were in the range of 0.6301 ~ 1.0775, which suggest that the SBR/EPDM systems are incompatible.

Morphology of EPDM-based Thermoplastic Vulcanizates (EPDM계 열가소성 가황체의 형태학적 연구)

  • Lee, Sang-Jin;Kim, Young-Kyoo;Park, Seong-Soo;Cho, Won-Jei;Ha, Chang-Sik
    • Elastomers and Composites
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    • v.32 no.3
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    • pp.157-165
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    • 1997
  • The morphology of the thermoplastic vulcanizates prepared from ethylene-propylene-diene terpolymer, polypropylene and high density polyethylene(HDPE) or ethylene based ionomer were studied. Blends were prepared in a laboratory internal mixer where EPDM was cured in the presence of PP and HDPE or ionomer under shear with dicumyl peroxide(DCP). The effects of DCP concentration and rubber/plastics composition were studied. In the morphological analysis by scanning electron microscopy (SEM), a small amount of EPDM acted as a compatibilizer to HDPE and PP. It was also revealed that the dynamic vulcanization process could reduce the domain size of the crosslinked EPDM phase. When ionomer was added to EPDM/PP blend, the thermoplastic vulcanizate showed typical ductile fracture topology and the trend was more clearly observed when DCP contents and ionomer contents are higher.

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