• Title/Summary/Keyword: EN-ratio

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$TiO_2$ Photoanode on Dye-Sensitized and Electrochemical Properties of Solar Cells (염료감응형 태양전지용 $TiO_2$ 광전극의 전기화학적 특성)

  • Jin, En-Mei;Park, Kyung-Hee;Gu, Hal-Bon;Park, Bok-Kee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.253-254
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    • 2008
  • The $TiO_2$ Pastes was prepared with the starting materials of $TiO_2$ (P-25), ethyl cellulose, a-terpineol and bis(2-ethylhexyl) phthalate, and this $TiO_2$ paste application for dye-sensitized solar cells (DSSCs) were investigated. In order to improved transparency of $TiO_2$ photoanode films, $TiO_2$ paste was changed ethyl cellulose and a-terpineol contents. The morphology of prepared $TiO_2$ films were investigated by field emission scanning electron microscopy (FE-SEM). The electrochemical properties of the thin films and the performance of DSSCs were measured by photovoltaic-current density and AC impedance. Energy conversion efficiency was obtained about 5.7% at ethyl cellulose and a-terpineol on best mixed ratio under illumination with AM 1.5 ($100mWcm^{-2}$)simulated sunlight.

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Synthesis LiFePO4- poly(sodium 4-styrenesulfonate) composite cathode material for rechargeable lithium battery by hydrothermal method

  • Hiep, Nguyen Van;Wang, Wan Lin;Jin, En Mei;Gu, Hal-Bon
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.137.2-137.2
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    • 2011
  • Poly (sodium 4-styrenesulfonate) (PSS) is ionomer based on polystyrene that is electrical conductivity and isoviscosity. LiFePO4 has been a promising electrode material however its poor conductivity limits practical application. To enhance the electronic conductivity of LiFePO4, in this study we prepared LiFePO4- PSS composite by the hydrothermal method. LiFePO4 was heated at $170^{\circ}C$ for 12h and then different wt% PSS (0%, 2.91%, 4.75%, 7.36%, 10%) are added to LiFePO4 and milled at 300rpm for 10h. And then the obtained powders were subsequently heated at $500^{\circ}C$ for 1h under argon flow. The cathode electrode were made from mixtures of LiFePO4-PSS: SP-270- PVDF in a weighting ratio 75%: 25%:5%. The electrochemical properties of LiFePO4- PSS/Li batteries were analyzed by cyclic voltammetry and charge/discharge tests. LiFePO4-C/Li battery with 4.75 wt% PSS displays discharge capacity of 128 mAh g-1 at room temperature that is considerably higher than pure LiFePO4/Li battery ( 113.48 mAhg-1).

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A Study on Optimum design of Corrugated web girder using Eurocode (유로코드를 이용한 주름웨브보의 최적설계 연구)

  • Shon, Su-Deok;Yoo, Mi-Na;Lee, Seung-Jae
    • Journal of Korean Association for Spatial Structures
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    • v.12 no.4
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    • pp.47-56
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    • 2012
  • This paper describes the structural design and optimization of sinusoidally corrugated web girder by using EUROCODE (EN 1993-1-5). The optimum design methodology and characteristics of the optimal cross-section are discussed. We investigate a shear buckling and the concerned standards for corrugated web and explain the equations to obtain a critical stress according to buckling type. In order to perform optimization, we consider an objective function as minimum weight of the girder and use the constraint functions as slenderness ratio and stresses of flanges as well as corrugated web and deflection. Genetic Algorithm is adopted to search a global optimum solution for this mathematical model. For numerical example, the clamped girder under the concentrated load is considered, while the optimum cross-sectional area and design variables are analyzed. From the results of the adopted example, the optimum design program of the sinusoidally corrugated web girder is able to find the suitable solution which satisfied a condition subject to constraint functions. The optimum design shows the tendency to decrease the cross-sectional area with the yielding strength increase and increase the areas with load increase. Moreover, the corrugated web thickness shows a stable increase concerning the load.

Method for Measuring Prompt Fission Neutron Energy Spectrum by Means of Threshold Activation Detectors (발단 방사화 검출기를 이용한 핵분열 즉발 중성자 에너지 스펙트럼 측정방법)

  • 노성기;신희성;박종묵
    • Nuclear Engineering and Technology
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    • v.22 no.4
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    • pp.410-415
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    • 1990
  • Prompt fission neutron energy spectrum as a function of energies of neutron inducing fission has been calculated en the basis of the Madland-Nix(MN) model. The resultant spectra have been weighted to excitation functions of $^{27}$ Al(n, $\alpha$), $^{32}$ S(n, p) and $^{115}$ In(n, n') threshold reactions in order to get the average cross sections and then spectral indices which are defined as the average cross section ratio for two selective threshold reactions among the above three. It is appeared that spectral indices together with the neutron spectra are varying with energies of neutron inducing fission. This may indicate that the prompt fission neutron energy spectrum can be determined by measuring experimentally the spectral index.

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The Preparation of Blue CoAl2O4 Powders by the Malonate Method: The Effect of the Amount of Malonic Acid Used, the Formation Pathway of CoAl2O4 Crystallites and the Characteristics of the Prepared Powders

  • Lee, Gong-Yeol;Ryu, Kwang-Hyun;Kim, Hong-Gun;Kim, Yoo-Young
    • Bulletin of the Korean Chemical Society
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    • v.30 no.2
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    • pp.373-377
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    • 2009
  • A pathway for the formation of normal $CoAl_2O_4$ particles is suggested. The optimal amount of malonic acid was determined, and the characteristics of the obtained powders were investigated. Normal $CoAl_2O_4$ powders were prepared using solutions of malonic acid and metal nitrates. X-ray diffraction, Brunauer-Emmett-Teller (BET) and scanning electron microscope (SEM) measurements, as well as Fourier transform infrared (FTIR) and ultraviolet/visible (UV-Vis) spectroscopy were carried out. Normal $CoAl_2O_4$ crystallites were formed by a solid state reaction between $CoAl_2O_4$ and amorphous aluminum oxide. The optimal molar ratio of malonic acid to the nitrate anions present in the initial solution was found to be 0.30~0.35. The particles were composed of agglomerates of primary particles. The primary particles were 40 nm in size. This size was relatively constant regardless of the preparation temperature. However, the size of the agglomerated particles increased to 220 nm with increasing temperature.

Synthesis and Luminescence Characterization of En3+ Doped Gd2O3 Phosphors by Combustion Method

  • Jeong, Young-Ho;Myung, Kwang-Shik;Kim, Jung-Duk;Han, Sang-Do;Park, Jin-Won;Singh, K.C.
    • Transactions on Electrical and Electronic Materials
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    • v.4 no.5
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    • pp.28-32
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    • 2003
  • Europium-doped gadolinium oxide ($Gd_2O_3;Eu^{3+}$) phosphors have been prepared by combustion method using urea[H$_2$NCONH$_2$] or carbohydrazide[H$_2$NNHCONHNH$_2$] as fuel materials in a preheated furnace at 500$^{\circ}C$. The phosphors obtained were fired at 1200$^{\circ}C$ for 3 hours to get better luminescent properties. The combustion method used was found to be a simple and fast method for the preparation of fine-sized particles. The influence of the fuel/oxidant (urea or carbohydrazide/nitrate) mole ratio on the phosphor has been investigated and the optimum values for various parameters have been determined. By this method, phosphor that has better brightness and smaller size particles than that obtained by conventional method has been prepared.d has been prepared.

Enhanced Dispersion of High Performance Dye-sensitized Solar Cells (분산특성이 향상된 고효율 염료감응형 태양전지)

  • Jin, En-Mei;Park, Kyung-Hee;Gu, Hal-Bon;Park, Bok-Kee
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.22 no.6
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    • pp.501-505
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    • 2009
  • $TiO_2$ nano-particle paste was prepared by ethyl cellulose, $\alpha$-terpineol and bis(2-ethylhexyl) phthalate (dioxcyl phthalate) for dye-sensitized solar cells (DSSCs). Dispersion and absorbance of $TiO_2$ photoanode films was controlled by adding different amount of ethyl cellulose and $\alpha$-terpineol. The morphology of prepared $TiO_2$ films was studied by field emission scanning electron microscopy (FE-SEM) and the optical properties of $TiO_2$ films were measured by UV/vis spectra. Photovoltaic-current density was observed to determine the electrochemical response of DSSCs. Energy conversion efficiency was obtained about 7.1% at ethyl cellulose and $\alpha$-terpineol at optimal mixed ratio (as ethyl cellulose: 0.1 g; $\alpha$-terpineol: 1.5 ml) under illumination with AM 1.5($100\;Wcm^{-2}$) simulated sunlight.

Behavior of CFS built-up battened columns: Parametric study and design recommendations

  • Vijayanand, S;Anbarasu, M
    • Structural Engineering and Mechanics
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    • v.74 no.3
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    • pp.381-394
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    • 2020
  • The structural performance of cold-formed steel (CFS) built-up battened columns were numerically investigated in this paper. The built-up column sections were formed by connecting two-lipped channels back-to-back, with a regular spacing of battens plates, and have been investigated in the current study. Finite element models were validated with the test results reported by the authors in the companion paper. Using the validated models, the parametric study was extended, covering a wider range of overall slenderness to assess the accuracy of the current design rules in predicting the design strengths of the CFS built-up battened columns. The parameters viz., overall slenderness, different geometries, plate slenderness (b/t ratio) and yield stress were considered for this study. In total, a total of 228 finite element models were analyzed and the results obtained were compared with current design strength predicted by Effective Width Method of AISI Specifications (AISI S100:2016) and European specifications (EN1993-1-3:2006). The parametric study results indicated that the current design rules are limited in predicting the accuracy of the design strengths of CFS built-up battened columns. Therefore, a design equation was proposed for the AISI and EC3 specifications to predict the reliable design strength of the CFS Built-up battened columns and was also verified by the reliability analysis.

Participation in GVCs and Income Inequality (글로벌 가치사슬에서 전방참여와 후방참여가 소득불평등에 미치는 영향)

  • Li, Jia-En;Choi, Young-Jun
    • Korea Trade Review
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    • v.44 no.2
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    • pp.269-282
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    • 2019
  • This study analyzes the effects of participation in the global production network on the income inequality using panel data from 2005 to 2016 for 63 countries. In this study were used fixed effects model with autocorrelation, random effect model with autocorrelation and the GLS method. Results are as follows: First, the economic development level supports the Kuznets hypothesis. And then, the forward participation in global value chains increased income inequality, and the backward participation decreased income inequality. In order to derive more detailed estimation results, we analyzed OECD countries and non-OECD countries. First, OECD countries featured decreased, but increased beyond a certain level as a U-shaped curve, that did not support the Kuznets hypothesis. In contrast, non-OECD countries followed the Kuznets U-curve. Second, participation in the global production network showed that both OECD and non-OECD countries featured increased income inequality. In contrast, backward participation appears to mitigate income inequality both in OECD and non-OECD countries. Finally, the ratio of labor and capital is significant in mitigating income inequality in non-OECD countries in which they feature backward participation in production networks. This can be interpreted as developing economies participate in the global production network due to increased capital accumulation and increased the labor productivity.

Suggestion of Efficient High Dose Spent Filter Handling and Compaction Equipment

  • Lee, Kyungho;Chung, Sewon;Park, Seonghee;Kim, HuiGyeong
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.20 no.2
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    • pp.243-253
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    • 2022
  • Spent filters with a high radiation dose rate of 2 mSv·hr-1 or more are not easily managed. So far, the Korean policy for spent filter disposal is to store them temporarily at nuclear power plants until the waste filters can be easily managed. Nuclear power plant decommissioning in Korea is starting with Kori unit 1. Volume reduction of waste generated during decommissioning can reduce the cost and optimize the space usage at disposal site. Therefore, efficient volume reduction is a very important factor during the decommissioning process. A conceptual method, based on the experiences of developing 200 and 800 ton compactors at Orion EnC, has been developed considering worker exposure with the followings a crusher (upgrade of compaction efficiency), an automatic dose measuring system with a NaI(Tl) detector, a shield box, an inner drum to prepare for easy handling of drums and packaging, a 30 ton compactor, and an automatic robot system. This system achieves a volume reduction ratio of up to 85.7%; hence, the system can reduce the disposal cost and waste volume. It can be applied to other types of wastes that are not easily managed due to high dose rates and remote control operation necessity.