• 제목/요약/키워드: EMULSION

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유화중합에 의한 전분-아크릴 고분자의 합성에 관한 연구 (A Study on the Synthesis of Starch-Acrylic Polymer by Emulsion Polymerization)

  • 이미숙;류훈;조을륭
    • 폴리머
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    • 제34권1호
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    • pp.58-62
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    • 2010
  • 전분을 매트릭스 고분자로 하여 아크릴 단량체를 유화중합 방법으로 그래프트 중합하였다. 에멀젼의 점도와 입자경은 전분 함량이 증가함에 따라 전분의 히드록시기가 물과 상호작용하고 고분자 입자가 분산매인 물 쪽으로 팽윤함으로 인해 증가하였다. 에멀젼의 화학적 안정성은 전분 함량이 증가할수록 양호하였으나 내수성과 내알칼리성은 전분 함량이 증가할수록 친수성이 증가하면서 감소하였다. 탄산칼슘을 포함한 전분-아크릴 에멀젼 배합물의 불투명도는 전분의 함광이 증가함에 따라 전분 고유의 색깔에 의해 감소하였고 도막의 상태는 전분의 함량이 증가함에 따라 도막의 무정형 상태가 증가하면서 균열이 없는 매끈한 외관을 나타내었다.

도공지 노화에 관한 연구(III) - 도공지 노화방지를 위한 새로운 도공용 바인더 적용 - (Studies on the aging behavior of coated paper(III) - The application of new coating binder for anti-thermal aging -)

  • 신우슬;김선경;조병욱;이용규
    • 한국펄프종이공학회:학술대회논문집
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    • 한국펄프종이공학회 2011년도 춘계학술발표회 논문집
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    • pp.339-347
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    • 2011
  • This study was carried out in order to manufacture the high quality coated paper. High quality coated paper includes not only present state but also the state of the future. So in this study, acrylic-styrene emulsion which polymerized in laboratory was compared with SB(Styrene-butadiene) latex during thermal aging. The coated paper with three different formulations which controlled the dosage of acrylic-styrene emulsion were prepared. The coated paper were thermally aged at $105^{\circ}C$ for 18days and the optical properties were measured. Brightness, whiteness and CIE L value were higher during thermal aging with increasing amount of acrylic-styrene emulsion. CIE $a^*$ value was higher and CIE $b^*$ value decreased with increasing amount of acrylic-styrene emulsion. These results indicate that high quality coated paper which has anti -thermal aging property can be manufactured with acrylic-styrene emulsion.

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디젤기관에 있어서 에멀젼 연료가 연소특성에 미치는 영향 (Effects on the Characteristics of Combustion by using Emulsion Fuel in Diesel Engine)

  • 임재근;조상곤;황상진;유동훈;서장원
    • 한국마린엔지니어링학회:학술대회논문집
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    • 한국마린엔지니어링학회 2006년도 전기학술대회논문집
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    • pp.41-42
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    • 2006
  • A study on the combustion characteristics by using Emulsion Fuel in Diesel Engine is performed experimentally. In this paper, the experiments are performed at engine speed 1800rpm, emulsion fuel ratio is 0%, 10%, 20%, and main measured items are specific fuel consumption, pressure, ratio of pressure rise, rate of heat release etc. The obtained conclusions are as follows. 1) Specific fuel consumption increase maximum 19.8% at low load, but is not effected at full load. 2) Ratio of pressure rise and rate of heat release are about the same in the case of 10% and 20% of emulsion fuel ratio. 3) Cylinder Pressure increase 11.7%, ratio of pressure rise increase 60.4% in case of emulsion fuel ratio 20% at full load. 4) Rate of heat release increase 76.9% in case of emulsion fuel ratio 20% at full load.

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분리 팥 단백질의 유화특성에 관한 연구 (Emulsion Properties of Small Red Bean Protein Isolates)

  • 김현정;손경희;박현경
    • 한국식품조리과학회지
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    • 제6권4호통권13호
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    • pp.9-14
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    • 1990
  • The emlsifying properties of small red bean protein isoates were evaluated through their emulsion capacity and stability of the resulting emulsions. The influence of pH, Sodium Chloride and heat treatment on the efficiency of small red bean protein isolates as emulsifying agents was studied. The surface hydrophobicity (So) of small red bean protein islates also examined. The results were obtained as follows; 1. The emusion capacity of small red bean protein isolates was high at pH 11, low at pH 3 and decreased by heat treament. With addition of NaCl, emulsion capacity decreased steadily and showed lowest value when 0.2M NaCl was added. 2. The emulsion stability at pH 4.5 and heat treatment over $60^{\circ}C$ decreased emulsion stability at pH 4.5. When NaCl was added, emulsion stability was generally increased. 3. The surface hydrophobicity of small red bean protein isolates showed the highest value at pH 3 and lowest at pH 11 and increased as the heating temperature increased When 0.2 M NaCl was added, surface hydrophobicity also increased at pH 4.5.

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금속 코팅용 아크릴 올리고머 에멀젼의 합성에 관한 연구 (In situ synthesis of acrylic emulsion for improvement of anti corrosion property on steel plate)

  • 이수;박근호;진석환;박신규
    • 한국응용과학기술학회지
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    • 제25권4호
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    • pp.485-494
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    • 2008
  • The acrylic coating emulsions were prepared by the emulsion polymerization to protect the surface of steel plate from the corrosion chemicals like acid, base and salt water. MMA(methyl methacrylate), styrene, BA(butyl acrylate), and 2-HEMA(2-hydroxyethyl methacrylate) were used as monomer. KPS(potassium persulfate) and SBS(sodium bisulfite) as redox initiator and SDBS(sodium dodecylbenzene sulfonate) as emulsifier were used on the emulsion polymerization reaction. The most stable in-situ coating was obtained when 10% of MMA was added. Both particle size and quantity in emulsion were decreased as increasing the mount of SDBS. the most stable prepared coating emulsion with polyisocyanate crosslinker showed very high anticorrosion properties on the coated steel layer to salt water, whereas no significant improvement of anticorrosion property to acdic and basic condition it showed.

Utilization of Dried Garlic Powder and α-Tocopherol to Improve the Shelf-life of Emulsion-type Sausage during Refrigerated Storage

  • Kim, Young-Jik;Choi, In-Hag
    • 한국축산식품학회지
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    • 제32권6호
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    • pp.725-731
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    • 2012
  • This study investigated the shelf life of emulsion-type sausages containing garlic powder and/or ${\alpha}$-tocopherol during storage at $4^{\circ}C$ for 0, 10, 20, and 30 d. Six groups of emulsion-type sausages were included: control (no additives), GP1 (1% garlic powder), GP3 (3% garlic powder), AT100 (100 IU of ${\alpha}$-tocopherol/kg of sausage), AT200 (200 IU of ${\alpha}$-tocopherol/kg of sausage), and GP1+AT100 (1% garlic powder+100 IU of ${\alpha}$-tocopherol/kg of sausage). During storage, the pH, thiobarbituric acid reactive substances, and residual nitrite content were reduced by the addition of garlic powder and/or ${\alpha}$-tocopherol relative to the control (p<0.05). In addition, emulsion-type sausages supplemented with garlic powder and/or ${\alpha}$-tocopherol improved color stability (p<0.05). The results suggest that a higher amount of garlic powder and their different combinations could improve the shelf life of emulsion-type sausages and protect against lipid oxidation.

침장용 PLA 섬유에 대한 저온 경화유제에 관한 연구 (Study on Low Temperature Curing Emulsion of PLA Fiber for Bedding)

  • 안영무
    • 패션비즈니스
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    • 제16권1호
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    • pp.41-51
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    • 2012
  • Polyester is mainly used as a bedding filler material. PLA fiber as an eco-friendly material for substituting polyester has a low melting temperature and therefore a hardening process is impossible. This study is to develop the oil for feather touch that can treat at the melting temperature of PLA. The slippery and soft aminosilicone emulsion, and the bulky epoxysilicone emulsion were used. They had proper viscosity and particle size for flexibility and elasticity. When using methoxy aminosilane [$H_2NSi(OCH_3)_3$] as an aminosilane and [$Zn(OCOCH_3)_2$] as a catalyst, the hardening reaction was fast and effective. Feather touch process were treated by 2 steps. At first step, aminosilicone emulsion, epoxysilicone emulsion and methylaminosilane were mixed and homogenized, and at second step, 5% blened solution of the first step, Zn catalyst 1%, distilled water 94% were treated at PLA fiber. After treatment the static friction coefficient and dynamic friction coefficient were reduced to 23.5-60.8% and 30.0-61.3% respectively, and the laundry and sun light fastnesses have not shown any decrease.

Induction of Immunity Against Hepatitis B Virus Surface Antigen by Intranasal DNA Vaccination Using a Cationic Emulsion as a Mucosal Gene Carrier

  • Kim, Tae Woo;Chung, Hesson;Kwon, Ick Chan;Sung, Ha Chin;Kang, Tae Heung;Han, Hee Dong;Jeong, Seo Young
    • Molecules and Cells
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    • 제22권2호
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    • pp.175-181
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    • 2006
  • Delivery of DNA vaccines to airway mucosa would be an ideal method for mucosal immunization. However, there have been few reports of a suitable gene delivery system. In this study we used a cationic emulsion to immunize mice via the intranasal route with pCMV-S coding for Hepatitis B virus surface antigen (HBsAg). Complexing pCMV-S with a cationic emulsion dramatically enhanced HBsAg expression in both nasal tissue and lung, and was associated with increases in the levels of HBs-specific Abs in serum and mucosal fluids, of cytotoxic T lymphocytes (CTL) in the spleen and cervical and iliac lymph nodes, and of delayed-type hypersensitivity (DTH) against HBsAg. In contrast, very weak humoral and cellular immunities were observed following immunization with naked DNA. In support of these observations, a higher proliferative response of spleenocytes was detected in the group immunized with the emulsion/pCMV-S complex than in the group immunized with naked pCMV-S. These findings may facilitate development of an emulsion-mediated gene vaccination technique for use against intracellular pathogens that invade mucosal surfaces.

THE STUDY ON STABLE EMULSION SYSTEM AND SELECTIVE ADDITION OF ACTIVE INGREDIENT IN W/O/W ONE STEP MULTIPLE EMULSION

  • Kim, Se-gie;Park, Hee-nam;Kim, Tae-kyoo
    • 대한화장품학회지
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    • 제24권3호
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    • pp.96-104
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    • 1998
  • It was possible to produce W/O/W one step multiple emulsion on the system which satisfied following conditions. 1. 1-5% of hydrophilic liquid surfactant over HLB20 and lipophilic liquid surfactant which has HLB 3∼5 2. Non wax copolymers as oil thickener 3. More than 0.5% of carbomer as aqueous thickener 4. The manufacturing process which neutralize the dispersed carbomer (2.0% in water), after emulsifying. For the selective addition into inner and outer aqueous phase, we melted the glucose in water before emulsifying. Using an Anthrone analysis method, we analyzed the encapsulation yield of glucose in inner water phase. It was possible to raise the water encapsulation yield of the multiple emulsion through the following conditions. 1. Using of anionic hydrophilic surfactant(HLB 40) and lipophilic surfactant (HLB 3∼5) 2. Controlling the ratio of hydrophilic surfactant and lipophilic surfactant 3. Strengthening interface with increase of non wax oil thickener. When the separated adding process of glucose was adopted, approximately 85% of glucose was added selectively within inner aqueous phase.

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다단계 유화중합을 이용한 마이크론 크기의 PMMA/PDVB 및 PS/PDVB 단분산 입자의 제조 (Preparation of Micron-size Monodispersed PMMA/PDVB and PS/PDVB Particles by Multi-staged Seeded Emulsion Polymerization)

  • 최봉철;엄기범;변자훈;박홍수;우종표;백운필
    • 한국응용과학기술학회지
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    • 제21권4호
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    • pp.370-379
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    • 2004
  • Highly crosslinked micron-size monodispersed PMMA/PDVB and PS/PDVB particles were prepared using seeded multi-stage emulsion polymerization. PMMA and PS seed particles were synthesized by seeded multi-stage emulsion polymerization and soap-free emulsion polymerization. Then PMMA/PDVB and PS/PDVB particles were obtained using semi-batch type emulsion polymerized using divinyl benzene as a cross-linkable monomer in the presence of seed particles. PMMA particles with size of ca. 730 nm and polydispersity of 1.03 were successfully prepared in this experiment. PS particles with size of ca. 1.5 ${\mu}m$ and polydispersity of 1.01 were prepared in this experiment. Highly crosslinked PS/PDVB particles with size of ca. 1.3 ${\mu}m$ and polydispersity of 1.00 were obtained.