• Transactions of the Korean Society for Noise and Vibration Engineering
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• v.19 no.9
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• pp.915-921
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• 2009

Cellulose based electro-active paper(EAPap) is considered as a new smart material which has a potential to be used for biomimetic actuators and sensors. Beside of the natural abundance, cellulose EAPap is fascinating with its biodegradability, lightweight, high mechanical strength and low actuation voltage. When the external stress is applied to EAPap, it can generate the electrical output due to its piezoelectric property. Using piezoelectric behavior of EAPap, we studied the feasibility of EAPap as mechanical strain sensor applications and compared to commercial strain sensor. By measuring the induced output voltage from the thin piezoelectric cellulose EAPap under static and dynamic force, we propose cellulose EAPap film as a potential strain sensor material.

• Macromolecular Research
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• v.14 no.6
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• pp.624-629
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• 2006

The cellulose-based, Electroactive Paper (EAPap) has recently been reported as a smart material with the advantages of lightweight, dry condition, biodegradability, sustainability, large displacement output and low actuation voltage. However, it requires high humidity.. This paper introduces an EAPap made with a cellulose solution and lithium chloride (LiCl), which can be actuated in room humidity condition. The fabrication process, performance test and effect of LiCl content of the EAPap actuator are illustrated. The bending displacement of the EAPap actuators was evaluated with actuation voltage, frequency, humidity and LiCl content changes. At a LiCl/ cellulose content of 3:10, the displacement output was maximized at a room humidity condition. Even though the displacement output was less than that of a high humidity EAPap actuator, the mechanical power output was not reduced due to the increased resonance frequency, which is promising for developing EAPap actuators that are less sensitive to humidity.

• Transactions of the Korean Society for Noise and Vibration Engineering
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• v.15 no.9 s.102
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• pp.1077-1083
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• 2005

Electro-Active Paper (EAPap) is one of attractive electro-active polymer (EAP) materials for artificial muscles due to its many advantages such as light weight, biologically degradable, low cost, large displacement output, low actuation voltage and low power consumption. However, drawbacks of EAPap actuators include low force output and humidity dependence. To enhance the performance of EAPap, conductive polymer (PPy) and SWNT/conductive polymer (PANI) are coated on EAPap PPy as conductive polymer is coated on cellulose EAPap by means of electrochemical deposition. Two different dopants are used in PPy through conducting polymer processing. SWNTS are mixed with PANI in emeraldine base along with different dopants. The compound materials are coated on cellulose EAPap using spin coating system. The performance of PPy/EAPap and SWNT/PANI/EAPap are evaluated in terms of bending displacement, blocked force, and the effects of dopants, humidity, coaling time, voltage and frequency are investigated. Comparing with EAPap actuators, SWNT/PANI/EAPap actuators show $200\%$ improvement of bending displacement and $300\%$ increment of blocked force.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2005.11a
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• pp.735-738
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• 2005

Electro-Active Paper (EAPap) is attractive as an EAP actuator material due to its merits in terms of lightweight, dry condition, large displacement output, low actuation voltage and low power consumption. This paper presents the performance of EAPap actuators with thickness variation. The EAPap is made with cellulose paper, and is shown to bend in response to an external electric field. Up to the present, we have tested displacement, current and force of EAPap with 20 $\mu$m thickness. The thickness of EAPap is important factor that affects the performance of the actuator. Therefere, three different thickness of EAPap, 20, 30, and 40 $\mu$m are investigated that inference the tip displacement, blocked force, the resonance and the actuator efficiency. There is an optimum thickness of EAPap, which is resulted from the stiffness and the mass. The performance of EAPap with thickness is discussed.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2008.11a
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• pp.368-371
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• 2008

Cellulose based Electroactive Paper (EAPap) has been developed as a new smart material due to its advantages of piezoelectricity, large displacement, low power consumption, low cost and flexibility. EAPap can be used fur a surface acoustic wave (SAW) device using the piezoelectric property of EAPap, resulting in the cost effective and flexible SAW device. In this paper, inter digit transducer (IDT) structure using lift-off technique with a finger gap of $10{\mu}m$ was used for micro fabrication of the cellulose EAPap SAW devices. The performance of IDT patterned SAW device was characterized by a Network Analyzer. The feasibility of cellulose EAPap as a potential acoustic device was presented and explained.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2009.04a
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• pp.462-465
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• 2009

Cellulose based electro-active paper (EAPap) is a new smart material that has a potential to be used in biomimetic actuator and sensor. Beside of the natural abundance, cellulose EAPap is fascinating with its biodegradability, lightweight, high mechanical strength and low actuation voltage. An actuating mechanism of EAPap is revealed to be the combination of ion migration effect and piezoelectricity. EAPap can generate the electrical current and voltage when the mechanical stress applied due to its electro-mechanical characteristics. In this paper, we investigated the feasibility of EAPap as a mechanical strain sensor.

• Journal of the Korean Society for Precision Engineering
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• v.31 no.8
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• pp.737-742
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• 2014

This paper reports a customized silver ink and its inkjet printing process on a cellulose electro-active paper (EAPap). To synthesize a silver ink, silver nanoparticle is synthesized from silver nitrate, polyvinylpyrrolidone and ethylene glycol, followed by adding a viscosifier, hydroxyethyl-cellulose solution, and a surfactant, diethylene glycol. The silver ink is used in an inkjet printer (Fujifilm Dimatix DMP-2800 series) to print silver electrodes on cellulose EAPap. After printing, the electrodes are heat treated at $200^{\circ}C$. The sintered electrodes show that the thickness of the electrodes linearly increases as the number of printing layers increases. The electrical resistivity of the printed electrodes is $23.5{\mu}{\Omega}-cm$. This customized ink can be used in inkjet printer to print complex electrode patterns on cellulose EAPap to fabricate flexible smart actuators, flexible electronics and sensors.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2002.05a
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• pp.495-498
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• 2002

Recently, the advent of electro-active papers (EAPap) actuators has been reported. In this paper, the possibility of the actuators is demonstrated. EAPap is a paper that produces large displacement with small force under an electrical excitation. EAPap is made with a chemically treated paper by constructing thin electrodes on both sides of the paper. When electrical voltage is applied on the electrodes the EAPap produces bending displacement. To improve the bending performance of EAPap, different paper fibers-softwood, hardwood, bacteria cellulose, cellophane, carbon mixture paper, electrolyte containing paper and Korean traditional paper, in conjunction with additive chemicals were tested. Two attempts were made to construct the electrodes: the direct use of aluminum foil and the gold sputtering technique. It was found that a cellophane paper exhibits a remarkable bending performance. When 2MV/m of excitation voltage was applied on the paper actuator, more than 3mm of tip displacement was observed out of the 30 mm long paper beam. This is quite low excitation voltage compared to that of other EAPs. The actuation principle of electro-active paper (EAPap) and possible applications are addressed.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2007.05a
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• pp.934-937
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• 2007

This study focused on investigating the effect of aligned cellulose fibers to the performance of EAPap actuator. The performance of EAPap is dependant on the material direction of cellulose film. Electrospinning was used to improve material directionality of EAPap. DMAc cellulose solution which cotton pulp was resolved in DMAc solvent was used for electrospinning cellulose film. To increase directionality of nano fibers, the Electrospun film was stretched by 10 % strain during drying process. Induced in-plane strain of Electrospun EAPap was proportional to the applied voltage and larger than that of spincast EAPap. It is concluded that the performance of EAPap was improved by aligning cellulose fibers.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2007.05a
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• pp.943-946
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• 2007

In-plane piezoelectric charge constant of Electro-Active paper (EAPap) was investigated based on direct and converse piezoelectric effects. EAPap samples were made with cellulose film with very thin gold electrode coated on both sides of the film. To characterize direct piezoelectricity of EAPap, induced charge was measured when mechanical stress was applied to EAPap. In-plane piezoelectric charge constant was extracted from the relation between induced charge and applied in-plane normal stress. To investigate converse piezoelectricity, induced in-plane strain was measured when electric field was applied to EAPap. Piezoelectric charge constant was also extracted from the relation of induced in-plane strain and applied electric field. Piezoelectric charge constants obtained from direct and converse piezoelectricity are 31 pC/N and 178 x 10-12m/V for 45 degree sample, respectively. Measured piezoelectric charge constants of EAPap provide promising potential as a piezoelectric material.