• 제목/요약/키워드: E.A.V.

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폴리(스티렌-설파디아진) 공중합체를 이용한 항균 나노섬유 제조 (Construction of Antibacterial Electrospun Nanofiber from Poly(styrene-co-sulfadiazine) via Electrospinning)

  • 황석호;안경환;차희철;김정열;황홍구;허완수;이상원
    • 공업화학
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    • 제20권4호
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    • pp.386-390
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    • 2009
  • 항균효과가 있는 sulfadiazine을 포함하는 아크릴형 단량체를 축합반응으로 합성하였으며, 합성된 아크릴형 단량체와 스티렌 단량체를 함께 라디칼 공중합으로 poly(styrene-co-sulfadiazine)을 합성하였다. 중합체의 중량평균분자량이 27800이었으며, 화학구조와 sulfadiazine과 스티렌 단량체간의 몰비는 핵자기공명분석을 통하여 확인하였다. 이 중합체를 이용하여 15 kV 하에서 전기방사를 수행하여 나노섬유 멤브레인을 제조하였으며, 멤브레인을 구성하고 있는 섬유의 직경은 약 500~800 nm 크기를 가졌다. 제조된 멤브레인의 항균성을 평가하기 위하여 양성균 S. Aureus와 음성균 E. Coli를 사용하였으며, 균주의 colony의 개수 증감으로 항균성을 평가하였다.

(1-x) [0.5PZT-0.25PNN-0.25PZN]- x [Ni0.9Zn0.1Fe2O4] 세라믹스의 압전/자성 성질 및 자기전기적 효과 (Piezoelectric/magnetic Properties and Magnetoelectric Effects in (1-x) [0.5PZT-0.25PNN-0.25PZN] - x [Ni0.9Zn0.1Fe2O4] Particulate Ceramic Composites)

  • 박영권;손세모;류지구;정수태
    • 한국전기전자재료학회논문지
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    • 제23권11호
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    • pp.869-874
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    • 2010
  • Magnetoelectric composites with compositions (1-x)[0.5PZT-0.25PNN-0.25PZN](ferroelectric) - x[$(Ni_{0.9}Zn_{0.1})Fe_2O_4$](ferrite) in which x varies as 0, 0.1, 0.2, 0.4, 0.6, 0.8, 1.0 were prepared by conventional ceramic process. The presence of two phases (ferroelectric phase with large grain and ferrite phase with small grain) in the particulate ceramic composites was confirmed by XRD, SEM and EDX. The ferroelectric and magnetic properties of the composites were studied by measuring the P-E and M-H hysterisis loop on the composite composition (x=0, 0.1, 0.2, 1), they were strongly affects of the phase content in composite. The magnetoelectric votage was measured as a function of DC magnetic field and the maximum magnetoelectric voltage coefficient of 14 mV/cm Oe was observed in x=0.2(80 mol% ferroelectric and 20 mol% ferrite phase).

산화구리가 피복된 Na0.5Bi4.5Ti4O15 틀입자를 이용한 BNKT 무연 압전 세라믹스의 저온소성 연구 (Low Temperature Sintering of BNKT Lead-Free Piezoelectric Ceramics Using CuO-Coated Na0.5Bi4.5Ti4O15 Templates)

  • 정광휘;이상섭;안창원;한형수;이재신
    • 한국전기전자재료학회논문지
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    • 제33권5호
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    • pp.337-343
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    • 2020
  • This study investigated the low temperature sintering with various templates of Bi-based lead-free piezoelectric ceramics. The effects of using CuO-coated Na0.5Bi4.5Ti4O15 templates on the sintering behavior as well as the dielectric, ferroelectric, and piezoelectric properties of Bi1/2(Na0.78K0.22)1/2TiO3 (BNKT) ceramics have been examined. In comparison with the specimens sintered with the Na0.5Bi4.5Ti4O15 templates without CuO coating, those sintered with the CuO-coated Na0.5Bi4.5Ti4O15 templates showed larger template sizes as well as a larger electric field induced strain (Smax/Emax) of 422 pm/V after sintering at temperatures as low as 975℃. These results are promising for low-cost multilayer ceramic actuator applications.

나노 다공질 FTO 제작 및 광전변환특성 고찰 (Synthesis of Nanoporous F:SnO2 Materials and its Photovoltaic Characteristic)

  • 한덕우;성열문
    • 조명전기설비학회논문지
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    • 제23권1호
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    • pp.176-181
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    • 2009
  • 본 연구에서는 염료 태양전지(Dye-sensitized solar cells; DSCs)에 적용하기 위한 나노-다공질의 FTO(F:$SnO_2$) 재료를 Sol-gel 연소법을 이용하여 다양한 열처리 온도를 변수로 제작하였으며, 각각의 결과물들에 대한 물성적 특성을 고찰하였다. FTO nano-powder는 SnCl4-98.0[%]와 HF-$48{\sim}51$[%]가 교반된 것에 NH4OH를 Sol-gel법의 촉매로 사용하였고, 첨가재로써 Ketjen Black을 사용하였다. 얻어진 결과물에 대한 XRD 측정 결과, 열처리 온도가 상승함에 따라 $SnO_2$의 회절각인 25.6[$^{\circ}$]($2{\Theta}$) 부근에서 강한 peak값이 나타났다. XPS 측정 결과에 의하면, 각각의 F1s, Sn 3d, O 1s의 binding energy는 682, 484, 528[eV]에서 광전자 피크가 확인되었다. 열처리 온도가 증가함에 따라 표면적이 감소하며, pore size는 증가함을 BET측정 결과로 알 수 있었다. 본 실험을 통해 열처리 온도조절에 따른 나노-다공성 FTO powder의 특성제어가 용이함이 확인되었고, Sol-gel 연소법에 의한 간단하고 효과적인 방법으로 나노-다공성 소재의 제작이 가능하여, DSCs의 응용에도 유용할 것으로 기대된다.

Theoretical Investigations on Structure and Function of Human Homologue hABH4 of E.coli ALKB4

  • Shankaracharya, Shankaracharya;Das, Saibal;Prasad, Dinesh;Vidyarthi, Ambarish Sharan
    • Interdisciplinary Bio Central
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    • 제2권3호
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    • pp.8.1-8.5
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    • 2010
  • Introduction: Recently identified human homologues of ALKB protein have shown the activity of DNA damaging drugs, used for cancer therapy. Bioinformatics study of hABH2 and hABH3 had led to the discovery of a novel DNA repair mechanism. Very little is known about structure and function of hABH4, one of the members of this superfamily. Therefore, in present study we are intended to predict its structure and function through various bioinformatics tools. Materials and Methods: Modeling was done with modeler 9v7 to predict the 3D structure of the hABH4 protein. This model was validated with the program Procheck using Ramachandran plot statistics and was submitted to PMDB with ID PM0076284. The 3d2GO server was used to predict the functions. Residues at protein ligand and protein RNA binding sites were predicted with 3dLigandSite and KYG programs respectively. Results and Discussion: 3-D model of hABH4, ALKBH4.B99990003.pdb was predicted and evaluated. Validation result showed that 96.4 % residues lies in favored and additional allowed region of Ramachandran plot. Ligand binding residues prediction showed four Ligand clusters, having 24 ligands in cluster 1. Importantly, conserved pattern of Glu196-X-Pro198- Xn-His254 in the functional domain was detected. DNA and RNA binding sites were also predicted in the model. Conclusion and Prospects: The predicted and validated model of human homologue hABH4 resulted from this study may unveil the mechanism of DNA damage repair in human and accelerate the research on designing of appropriate inhibitors aiding in chemotherapy and cancer related diseases.

Bacillus Subtilis NRLSI IV로 제조한 청국장의 접종포자농도와 발효시간에 따른 품질 특성 (The Quality Characteristics of Chunggujang Prepared by Bacillus Subtilis NRLSI IV on the Different Inoculum Levels and Fermentation Times)

  • 김경미;김행란;박홍주
    • 한국지역사회생활과학회지
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    • 제17권3호
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    • pp.123-131
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    • 2006
  • To compare the quality characteristics, chunggugjang was prepared with Bacillus subtilis NRLSI IV on the different inoculum levels$(10^2,\;10^4,\;10^6,\;and\;10^8 CFU/ml)$ and fermentation times(0, 12, 24, 36, and 48 hours). Although significant change in total nitrogen content was not found, the content of amino type, soluble and ammonia type nitrogen was generally increased according to the increase in fermentation time. Decomposition rate of nitrogen was also increased by fermentation time and nitrogen solubility was the highest value(62-75.9%) at 48 hour fermentation. In results of color changes, it was found that L and a value were decreased but there was no significant changes in b value as fermentation time was increased. In chunggugjang made with long fermentation time, hardness was decreased and relative viscosity of viscous substance was gradually decreased after little increase at initial fermentation time. The effect of inoculum level on hardness and relative viscosity were similar to that of fermentation time, i.e. the decrease of these at high inoculum level. In activity of V-GTP, 36 hour incubation could produce the highest value whereas no effect of inoculum level was found during fermentation except at 48 hour. In chunggugjang made with $10^2CFU/mL$ of Bacillus subtilis NRLSI IV, the content of glucose, sucrose, raffinose and stachyose was dramatically decreased at initial fermentation time and that of phytic acid, oxalic acid, citric acid, tartaric acid and malic acid was also decreased during fermentation, although the increase in acetic acid was found.

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Cd-free 태양전지를 위한 ZnS/CIGS 이종접합 특성 향상 연구 (Study of ZnS/CIGS Hetero-interface for Cd-free CIGS Solar Cells)

  • 신동협;김지혜;고영민;윤재호;안병태
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2011년도 춘계학술대회 초록집
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    • pp.106.1-106.1
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    • 2011
  • The Cu(In,Ga)Se2 (CIGS) thin film solar cells have been achieved until almost 20% efficiency by NREL. These solar cells include chemically deposited CdS as buffer layer between CIGS absorber layer and ZnO window layer. Although CIGS solar cells with CdS buffer layer show excellent performance, the short wavelength response of CIGS solar cell is limited by narrow CdS band gap of about 2.42 eV. Taking into consideration the environmental aspect, the toxic Cd element should be replaced by a different material. Among Cd-free candidate materials, the CIGS thin film solar cells with ZnS buffer layer seem to be promising with 17.2%(module by showa shell K.K.), 18.6%(small area by NREL). However, ZnS/CIGS solar cells still show lower performance than CdS/CIGS solar cells. There are several reported reasons to reduce the efficiency of ZnS/CIGS solar cells. Nakada reported ZnS thin film had many defects such as stacking faults, pin-holes, so that crytallinity of ZnS thin film is poor, compared to CdS thin film. Additionally, it was known that the hetero-interface between ZnS and CIGS layer made unfavorable band alignment. The unfavorable band alignment hinders electron transport at the heteo-interface. In this study, we focused on growing defect-free ZnS thin film and for favorable band alignment of ZnS/CIGS, bandgap of ZnS and CIGS, valece band structure of ZnS/CIGS were modified. Finally, we verified the photovoltaic properties of ZnS/CIGS solar cells.

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이온빔보조 반응법을 이용한 고분자 표면의 친수성처리와 그 응용 (Hydrophilic surface formation of polumer treated by ion assisted reaction and its applications)

  • 조정;최성창;윤기현;고석근
    • 한국진공학회지
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    • 제8권3B호
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    • pp.262-268
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    • 1999
  • Polycarbonate (PC) and Polymethylmethacrylate (PMMA) surface was modified by ion assisted reaction (IAR) technique to obtain the hydrophilic functional groups and improve the wettability. In conditions of ion assisted reaction, ion beam energy was changed from 500 to 1500eV, and ion dose and oxygen gas blown rate were fixed $1\times10^{16}$ ions/$\textrm{cm}^2$ and 4ml/min, respectively. Wetting angle of water on PC and PMMA surface modified by $Ar^+$ ion without blowing oxygen at 4ml/mon showed $5^{\circ}$ and $10^{\circ}$. Changes of wetting angle with oxygen gas and $Ar^+$ ion irradiation were explained by considering formation of hydrophilic group due to a reaction between irradiated polymer chain by energetic ion irradiation and blown oxygen gas. X-ray photoelectron spectroscopy analysis shows that hydrophilic groups such as -C-O, -(C=O)- and -(C=O)-O- are formed on the surface of polymer by chemical interaction. The polymer surface modification using ion assisted reaction only changed the surface physical properties and sept the bulk properties. In comparison with other modification methods, the surface modification by IAR treatment was chemically stable and enhanced the adhesion between metal and polymer surface. The applications of various kinds of polymer surface modification methods, metal and polymer surface. The applications of various kinds of polymer surface modification could be appled to the new materials about hydrophilic surface properties by IAR treatment. The adhesion between metal film and polymer measured by Scotch tape test whether the hydrophilic surfaces could improve the adhesion strength or not.

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플라즈마 디스플레이 패널의 고속 구동을 위한 세폭 펄스 어드레스 방전특성 (Discharge Characteristics of Narrow Width Pulse Addressing for the High-Speed Driving of Plasma Display Panels)

  • 염정덕
    • 조명전기설비학회논문지
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    • 제21권7호
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    • pp.13-19
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    • 2007
  • 본 연구는 1,080개의 주사선수를 가지는 full-HD PDP를 위한 새로운 고속구동방식에 관한 것으로 고속 어드레스에 의한 표시방전의 방전특성을 고찰하여 새로운 구동방식의 특성을 평가하였다. 이 구동방식에서 어드레스 펄스의 폭이 좁아지면 최초 표시방전의 상대적 방전강도와 방전지연시간은 그 영향을 받는다. 어드레스 펄스의 인가위치의 변화는 방전강도와 무관하나 방전지연시간에는 영향을 미친다. 그러나 어드레스 펄스의 인가위치가 [$6{\mu}s$]이내이고 펄스의 폭이 [$0.7{\mu}s$]이내라면, 어드레스 펄스의 인가위치나 폭에 무관하게 안정된 표시방전을 유도할 수 있다. 실험결과로부터 폭이 좁은 어드레스 펄스를 사용하는 고속구동기술은 축적되는 벽전하의 부족으로 인해 공간전하의 영향에 매우 민감하다는 것을 알았다.

토끼 동방결절에서 완만내향전류의 Slow Component에 관한 연구 (The Slow Component of the Second Inward Current in the Rabbit Sino-Atrial Node)

  • 엄융의;김기환;황상익
    • The Korean Journal of Physiology
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    • 제18권1호
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    • pp.9-17
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    • 1984
  • The second inward current $(i_{si})$ was studied by the two microelectrode voltage clamp technique in the sino-atrial node of the rabbit. The slow component $(i_{si,2})$ of the second inward current was sometimes identified and $i_{si}$ behaved as if it were a mixture of two currents. We analysed the $(i_{si,2})$ in relation to membrane potential and frequency of voltage clamp pulses. 1) Membrane was held at -40mV which was usually found to be zero current level. When depolarizing pulses were applied, the slow inward current $(i_{si})$ was activated. 2) It was shown that there are three categories of the $i_{si}$ activation by the low level of depolarizing clamp pulses. Moderately fast inward current with single component was developed in most cases in the presence of tetrodotoxin(TTX). But sometimes there was two separate components of $i_{si}$ activation in the peak level and the time course. Thirdly the only slow component of $i_{si}$ was found in rare cases. 3) The activation of $(i_{si,2})$ was dependent upon membrane potential. The $i_{si}$ shows two separate peaks during clamp depolarizations and higher clamp pulses lead to fusion of the peaks. 4) The $i_{si,2}$ activation showed that it decreased with repetitive clamp pulses and it was more evident in higher frequencies(2Hz)(negative staircase).

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