• Title/Summary/Keyword: Dynamic viscosity

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Physicochemical Properties of Gelatin from Jellyfish Rhopilema hispidum

  • Cho, Suengmok;Ahn, Ju-Ryun;Koo, Ja-Sung;Kim, Seon-Bong
    • Fisheries and Aquatic Sciences
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    • v.17 no.3
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    • pp.299-304
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    • 2014
  • The objective of this study was to elucidate the physicochemical characteristics of gelatin extracted from jellyfish Rhopilema hispidum. We investigated the proximate composition, amino acids, gel strength, gelling/melting points, dynamic viscoelastic properties, and viscosity of jellyfish gelatin. Jellyfish gelatin contained 12.2% moisture, 1.5% lipid, 2.1% ash, and 84.8% protein. Glycine, hydroxyproline, proline, and alanine were the predominant amino acids. The gelatin showed a gel strength of 31.2 kPa, a gelling point of $18.0^{\circ}C$, and melting point of $22.3^{\circ}C$. The gelatin was composed of ${\alpha}_1$-chain, ${\alpha}_2$-chain, ${\beta}$-chain, and ${\gamma}$-chain. During cooling and heating process, jellyfish gelatin showed lower elastic modulus (G') and loss modulus (G") values than mammalian gelatin. Jellyfish gelatin did not show superior rheological properties to mammalian gelatin, like other fish gelatin; however, it can be used in various food and cosmetic products not requiring high gel strength.

A Study on the MR Cylinder with Built-in alves (밸브 내장형 MR 실린더에 관한 연구)

  • Song Joo-Young;Ahn Kyoung-Kwan
    • Journal of the Korean Society for Precision Engineering
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    • v.22 no.7 s.172
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    • pp.130-136
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    • 2005
  • A new MR cylinder with built-in valves using MR fluid (MR valve) is suggested and fabricated fur fluid control systems. The MR fluid is a newly developed functional fluid whose obvious viscosity is controlled by the applied magnetic field intensity. The MR cylinder is composed of cylinder with small clearance and piston with electromagnet. The differential pressure is controlled by the applied magnetic field intensity. It has the characteristics of simple, compact and reliable structure. The size of MR cylinder and piston has $\varphi30mm\times300mm$ and $\varphi28.5mm\times120mm$ in face size, respectively and 0.8mm in gap length. Through experiments, it was found that the differential pressure is controlled by the applied magnetic field intensity under little influence of the flow rate, which corresponds to a pressure control valve. The differential pressure of 0.47MPa was obtained with the input current of 1.5A. The rising time was 2.3s in step response of a manipulator using the MR cylinder. The effectiveness of the MR cylinder was also demonstrated through the position control.

Rotordynamic Analysis of Automotive Turbochargers Supported on Ball Bearings and Squeeze Film Dampers in Series: Effect of Squeeze Film Damper Design Parameters and Rotor Imbalances (볼 베어링과 스퀴즈 필름 댐퍼로 지지되는 차량용 터보차저의 회전체동역학 해석: 스퀴즈 필름 댐퍼 설계 인자와 회전체 불균형 질량의 영향)

  • Kim, Kyuman;Ryu, Keun
    • Tribology and Lubricants
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    • v.34 no.1
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    • pp.9-15
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    • 2018
  • Modern high-performance automotive turbochargers (TCs) implement ceramic hybrid angular contact ball bearings in series with squeeze film dampers (SFDs) to enhance transient responses, thereby reducing the overall emission levels. The current study predicts the rotordynamic responses of the commercial automotive TCs (compressor wheel diameter = ~53 mm, turbine wheel diameter = ~43 mm, and shaft diameter at the bearing locations = ~7 mm) supported on ball bearings and SFDs for various design parameters of SFDs, including radial clearance, axial length, lubricant viscosity, and rotor imbalance conditions (i.e., amplitudes and phase angles) while increasing rotor speed up to 150 krpm. This study validates the predictive rotor finite element model against measurements of mass, polar and transverse moments of inertia, and free-free mode natural frequencies and mode shapes. A nonlinear rotordynamic model integrates nonlinear force coefficients of SFDs to calculate the transient responses of the TC rotor-bearing system. The predicted results show that SFD radial clearances, as well as phase angles of rotor imbalances, have the paramount effect on the dynamic responses of TC shaft motions.

Performance Evaluation of 6WD Military Vehicle Featuring MR Damper (MR댐퍼를 적용한 6WD 군용차량의 성능평가)

  • Ha, Sung-Hoon;Choi, Seung-Bok;Rhee, Eun-Jun;Kang, Pil-Soon
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.19 no.1
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    • pp.17-23
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    • 2009
  • This paper proposes a new type of MR(magnetorheological) fluid based suspension system and applies it to military vehicle for vibration control. The suspension system consists of gas spring and MR damper. The nonlinear behavior of spring characteristics is evaluated with respect to the wheel travel and damping force model due to viscosity and yield stress of MR fluid is derived. Subsequently, a military vehicle of 6WD is adopted for the integration of the MR suspension system and its nonlinear dynamic model is established by considering vertical, pitch and roll motion. Then, a sky-hook controller associated with semi-active actuating condition is designed to reduce the imposed vibration. In order to demonstrate the effectiveness of the proposed MR suspension system, computer simulation is undertaken showing vibration control performance such as roll angle and pitch angle evaluated under bump and random road profiles.

Study on Low Temperature Curing Emulsion of PLA Fiber for Bedding (침장용 PLA 섬유에 대한 저온 경화유제에 관한 연구)

  • Ahn, Young-Moo
    • Journal of Fashion Business
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    • v.16 no.1
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    • pp.41-51
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    • 2012
  • Polyester is mainly used as a bedding filler material. PLA fiber as an eco-friendly material for substituting polyester has a low melting temperature and therefore a hardening process is impossible. This study is to develop the oil for feather touch that can treat at the melting temperature of PLA. The slippery and soft aminosilicone emulsion, and the bulky epoxysilicone emulsion were used. They had proper viscosity and particle size for flexibility and elasticity. When using methoxy aminosilane [$H_2NSi(OCH_3)_3$] as an aminosilane and [$Zn(OCOCH_3)_2$] as a catalyst, the hardening reaction was fast and effective. Feather touch process were treated by 2 steps. At first step, aminosilicone emulsion, epoxysilicone emulsion and methylaminosilane were mixed and homogenized, and at second step, 5% blened solution of the first step, Zn catalyst 1%, distilled water 94% were treated at PLA fiber. After treatment the static friction coefficient and dynamic friction coefficient were reduced to 23.5-60.8% and 30.0-61.3% respectively, and the laundry and sun light fastnesses have not shown any decrease.

Sulfonated Poly(ethylene glycol) Containing Methacrylate Copolymer Surfaces; Preparation, Characterization and In Vitro Biocompatibility

  • Park, Ki-Dong;Park, Hyung-Dal;Lee, Hee-Jung;Kim, Young-Ha;Tooru Ooya;Nobuhiko Yui
    • Macromolecular Research
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    • v.12 no.4
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    • pp.342-351
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    • 2004
  • Poly(ethylene glycol) (PEG1K) and sulfonated PEG (PEG1K-SO$_3$) methacrylate (MA) copolymers have been prepared and characterized. The structures of the synthesized copolymers were confirmed by $^1$H and $^{13}$ C NMR spectroscopy and elemental analysis. The bulk characteristics of the copolymers were evaluated by viscosity and thermal analysis. The surface properties of the copolymers were investigated using dynamic contact angle measurements and electron spectroscopy for chemical analysis. The hydrophilicity of the surfaces modified with PEG1KMA or PEG1K-SO$_3$MA increased, possibly as a result of the orientation of the hydrophilic PEG1KMA/PEG1K-SO$_3$MA chains into the water phase. Platelets adhered less to the surfaces of the copolymers than they did to a polyurethane control. In addition, adhesion of platelets to the copolymer surfaces decreased upon increasing the chain density of PEG1KMA and sulfonated PEG1KMA in the copolymers. Both bacterial adhesion and protein adsorption were significantly reduced on the copolymer surfaces and their levels differ depending on the kind of surface or media.

Poly(ethylene terephthalate)(PET) Nanocomposites Filled with Fumed Silicas by Melt Compounding

  • Chung, Su-Chul;Hahm, Wan-Gyu;Im, Seung-Soon;Oh, Seong-Geun
    • Macromolecular Research
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    • v.10 no.4
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    • pp.221-229
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    • 2002
  • PET nanocomposites filled with fumed silicas were prepared via direct melt compounding method at various mixing conditions such as filler type and filler content. Some fumed silicas were pre-treated to improve the wettability and dispersibility, and principal characterizations were performed to investigate the effects of nano fumed silicas on polymer matrix. Hydrophobic fumed silica (M-FS), which has the similar contact angles of water with neat PET, acted as the best reinforcement for the thermal stability and mechanical properties of PET nanocomposite, and FE-SEM images also showed that M-FS was uniformly dispersed into matrix and had good wettability. But, some filler (O-FS) had low dispersibility and caused the deterioration of mechanical properties. Besides, the results of DSC revealed the nucleation effect of all fillers in polymer matrix, and PET nanocomposite filled with hydroptilic fumed silica (FS) showed markedly the characteristic dynamic rheological properties such as shear thinning behavior at very low frequencies and the decrease of viscosity.

Preparation and Properties of Waterborne-Polyurethane Coating Materials Containing Conductive Polyaniline

  • Kim, Han-Do;Kwon, Ji-Yun;Kim, Eun-Young
    • Macromolecular Research
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    • v.12 no.3
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    • pp.303-310
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    • 2004
  • We have prepared an aqueous dispersion of poly(aniline-dodecyl benzene sulfonic acid complex) (PANI-DC) that has an intrinsic viscosity (〔η〕) near 1.3 dL/g using aniline as a monomer, dodecyl benzene sulfonic acid(DBSA) as a dopant/emulsifier, and ammonium peroxodisulfate(APS) as an oxidant. We found that the electrical conductivity of a PANI-DC pellet was 0.7 S/cm. A waterborne-polyurethane (WBPU) dispersion, obtained from isophorone diisocyanate/polytetramethylene oxide glycol/dimethylol propionic acid/ethylene diamine/triethylene amine, was used as a matrix polymer. We prepared blend films of WBPU/PANI-DC with variable weight ratios (from 99/1 to 66/34) by solution blending/casting and investigated the effects that the PANI-DC content has on the mechanical and dynamic mechanical properties, hardness, electrical conductivity, and antistaticity of these films. The tensile strength, percentage of elongation, and hardness of WBPU/PANI-DC blend films all decreased markedly upon increasing the PANI-DC content. The antistatic half-life time ($\tau$$\sub$$\frac{1}{2}$/) of pure WBPU film was about 110 s, but we found that those of WBPU/ultrasound-treated PANI-DC blend films decreased exponentially from 1.2 s to 0.1 s to almost 0 s upon increasing the PANI-DC content from 1 wt% to 15 wt% to > 15 wt%, respectively.

The Effect of Glass Fiber and Coupling Agents in the Blends of Silicone Rubber and Liquid Crystalline Polymers

  • Das T.;Banthia A.K.;Adhikari B.;Jeong Hye-Won;Ha Chang-Sik;Alam S.
    • Macromolecular Research
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    • v.14 no.3
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    • pp.261-266
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    • 2006
  • Blends of silicone rubber (VMQ) and liquid crystalline polymer (LCP) were prepared using a melt blending technique in the presence and absence of glass fiber and coupling agents. The effect of glass fiber and coupling agents on the thermal, dynamic mechanical, morphological pro-perties and cure characteristics of VMQ/LCP blends were studied. The vinyl silane coupling agent showed a significant effect on the above mentioned properties of VMQ/LCP blends by reacting at the interface between VMQ and LCP. The viscosity of the VMQ/LCP blends decreased with the addition of a coupling agent. A substantial improvement in storage modulus of VMQ/LCP blends was observed in the presence of glass fiber and coupling agents. However, as a coupling agent vinyl silane proved to be better than amine for the VMQ/LCP-glass-containing blends. The thermal stability of the pure silicone rubber was higher than those of the blends. This high thermal stability of silicone rubber was attributed to the Si-O-Si bonds. However, the thermal stability of the blends decreased further in the presence of a coupling agent, possibly due to a decrease in blend crystallinity.

Effect of Coagulant Type on the Silica Dispersion and Properties of Functionalized RAFT ESBR Silica Wet Masterbatch

  • Kim, Woong;Ryu, Gyeongchan;Hwang, Kiwon;Song, Sanghoon;Kim, Wonho
    • Elastomers and Composites
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    • v.55 no.3
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    • pp.167-175
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    • 2020
  • Various studies have been conducted to improve silica dispersion of silica filled tire tread compounds; among them, silica wet masterbatch (WMB) technology is known to be suitable for manufacturing silica filled compounds that have high silica content and high dispersibility. Till now, the WMB study is focused on the natural rubber (NR) or emulsion styrene-butadiene rubber (ESBR) that does not have a silica-affinity functional group, and a study of NR or ESBR having a silica-affinity functional group is still not well known. Unlike the dry masterbatch technology, the WMB technology can solve the problems associated with the high Mooney viscosity when applied to silica-friendly rubber. However, a coagulant suitable for each functional group has not yet been determined. Therefore, in this study, different coagulant applied silica WMB was prepared by applying calcium chloride, sulfuric acid, acetic acid, and propionic acid by using a carboxyl group functionalized reversible addition fragmentation chain transfer ESBR. The evaluation of the WMB compounds revealed that the calcium chloride added WMB compound showed excellent silica dispersion, abrasion resistance, and rolling resistance.