• Journal of the Korean Applied Science and Technology
• /
• v.18 no.4
• /
• pp.261-272
• /
• 2001

An ACR/HMMM film was prepared by blending high-solid ACR with curing agent, hexamethoxymethyl melamine (HMMM). An active curing reaction was observed at $170^{\circ}C$. The dynamic viscoelastic $T_{g}$ of the final film increased with the static viscoelastic $T_{g}$ of the film. The log damp value, which means a viscoelastic ratio, decreased with the increase in the curing temperature of the film. Physical properties of the films were within a suitable range for films, and by an accelerated weathering resistance test the films were proved weather resistible ones.

• Advances in nano research
• /
• v.14 no.6
• /
• pp.541-555
• /
• 2023

The extensive use of polymeric matrix composites in the athletic sector may be attributed to its high strength-to-weight ratio, production economy, and a longer lifespan than conventional materials. This study explored the impact of carbon nanotubes on the properties of different composite field sports equipment components. The test specimens were fabricated using the compression molding technique. The insertion of carbon nanotubes increases mechanical properties related to the process parameters to account for an improvement in the stick sections' overall performance. The dynamic response of functionally graded reinforced nanocomposite wire structure is examined in this paper on the bases of high-order hyperbolic beam theory lined to the size-dependent nonclassical nonlocal theory under the external mechanical load due to the physical activities. Finally, the impact of different parameters on the stability of nanocomposite structures is discussed in detail.

• Structural Engineering and Mechanics
• /
• v.64 no.1
• /
• pp.121-133
• /
• 2017

This paper proposes an analytical solution method for free vibration of curved functionally graded (FG) nonlocal beam supposed to different thermal loadings, by considering porosity distribution via nonlocal elasticity theory for the first time. Material properties of curved FG beam are assumed to be temperature-dependent. Thermo-mechanical properties of porous FG curved beam are supposed to vary through the thickness direction of beam and are assumed to be temperature-dependent. Since variation of pores along the thickness direction influences the mechanical and physical properties, porosity play a key role in the mechanical response of curved FG structures. The rule of power-law is modified to consider influence of porosity according to even distribution. The governing equations of curved FG porous nanobeam under temperature field are derived via the energy method based on Timoshenko beam theory. An analytical Navier solution procedure is used to achieve the natural frequencies of porous FG curved nanobeam supposed to thermal loadings with simply supported boundary condition. The results for simpler states are confirmed with known data in the literature. The effects of various parameters such as nonlocality, porosity volume fractions, type of temperature rising, gradient index, opening angle and aspect ratio of curved FG porous nanobeam on the natural frequency are successfully discussed. It is concluded that these parameters play key roles on the dynamic behavior of porous FG curved nanobeam. Presented numerical results can serve as benchmarks for future analyses of curve FG nanobeam with porosity phases.

• Elastomers and Composites
• /
• v.30 no.1
• /
• pp.20-31
• /
• 1995

The purpose of this study is to investigate the reinforcement of inorganic filler silica, treated by MDI about SBR vulcanizate. The characteristics of vulcanization, physical properties, surface properties and dynamic properties were investigated after mixing those silica with SBR and unmodified silica with SBR. In this experiment only the quantity of silica was variable. In the vulcanization characteristics tested by rheometer, S-series showed the fastest scorch $time(t_{10})$ and optimum cure $time(t_{90})$. And in test or tensile characteristics hardness, tensile strength, 100%, 300% modulus and elongation were all appeared in the order of M>S-series. The characteristic bonding of urea between unmodified silica and MDI could be confirmed in IR spectrum. The shapes of silicas treated chemically were observed by SEM. And the dispersion of the filler in the SBR composite was uniform. In the dynamic characteristics by the RDS, the order of elastic modulus G' values was as follows : M>S-series, and also the order of damping values was as follows : M>S-series.

• Macromolecular Research
• /
• v.11 no.3
• /
• pp.198-201
• /
• 2003

Aqueous emulsion of polyurethane (PU) ionomers were reinforced with hydrophobic nanosilica to give composites. The aqueous emulsion was stable and the particle size increased as the content of hydrophobic nanosilica was increased. The reinforcing effect of nanosilica in mechanical properties of these composites were examined by dynamic mechanical and tensile tests, and the Shore A hardness was measured. Enhanced thermal and water resistance and marginal reduction in transparency of these composites were observed compared with pristine polymer. These results were similar with those of our previous studies on waterborne PU/organoclay nanocomposites.

• Elastomers and Composites
• /
• v.33 no.2
• /
• pp.75-82
• /
• 1998

The purpose of this experimental study was to investigate the effects of vulcanization condition on the properties of reinforced rubbers. Rubber reinforcing ability of carbon black was more efficient than other fillers, but tensile properties were not affected by vulcanization condition while vulcanization condition affected the physical properties of rubber compounds with silica and silane treated slica. It was found that silica and silane treated silica filled rubber compounds showed good dynamic properties, rebound, heat build-up, 0 and $60^{\circ}C$ tan $\delta$ compared with carbon black filled rubber compounds. Carbon black filled rubber compounds were higher than silica and silane treated silica filled rubber compounds in total crosslinking density by vulcanization condition. By analysis of crosslinking type, polysulfide crosslinking was the highest in the carbon black filled rubber compounds with decreasing the ratio of sulfur to accelerator, monosulfide crosslinking was the highest in the silane treated silica filled compounds with in-creasing the ratio of sulfur to accelerator.

• Macromolecular Research
• /
• v.15 no.7
• /
• pp.610-616
• /
• 2007

We developed a coarse-grained force field and have extended it to polystyrene with longer chain length. A systematic method was introduced and was utilized to explain how the coarse-grained force field for polystyrene could be developed from the atomistic simulation in the paper. We elected to use polystyrene with different chain lengths of 20, 40 and 80 monomers in this study. In three cases, we utilized the same new mapping scheme. The coarse-grained force field does reproduce the bond, angle, and radial distribution of the atomistic model. The coarse-grained model proved successful, as shown by analyses of the static and dynamic properties of different chain lengths.

• Fibers and Polymers
• /
• v.7 no.4
• /
• pp.333-338
• /
• 2006

Silk fibroin (SF) fiber from the Antheraea pernyi silkworm was treated with a 1.23 N iodine-potassium iodide ($I_2-KI$) aqueous solution, and the structure and physical properties were investigated to clarify the effects of the iodine treatment. The noticeably high weight gain value of SF fiber, about 25 wt% was attributed to the absorption of polyiodide ions in the form of $I_3{^-}\;and\;I_5{^-}$. Fourier transform infrared spectroscopy and X-ray diffraction measurements suggested that polyiodide ions mainly entered the amorphous region. In addition, a new sharp reflection on the meridional direction, corresponding to a period of $7.0{\AA}$, was observed and indicated the possibility of the formation of mesophase structure of ${\beta}$-conformation chains. Dynamic viscoelastic measurements showed that the damping tan ${\delta}$ peak at $270^{\circ}C$ gradually shifted to lower temperature in the iodinated SF fibers, suggesting an enhancement of the molecular motion of the fibroin chains induced by the presence of polyiodide ions. With heating above $254^{\circ}C$, the iodine component introduced intermolecular cross-linking of SF, and the melt flow of the sample was inhibited. The thermal decomposition stability of fibroin molecules was greatly enhanced by iodine treatment.

• Elastomers and Composites
• /
• v.48 no.2
• /
• pp.103-113
• /
• 2013

The properties of the rubber composites containing a silane and silica were evaluated by changing the mixing time and temperature, in order to find the optimum mixing conditions. Characteristics of the compounds were evaluated after mixing at $120^{\circ}C$, $140^{\circ}C$, and $160^{\circ}C$ with various mixing time. With increasing of mixing time, mooney viscosity decreased while the bound rubber contents of the compounds increased. Viscosity rise by increased mixing time was bigger at low temperature and the higher the mixing temperature the faster in the formation of bound rubber. With lower mixing temperature of $120^{\circ}C$, cross-linking rate was almost constant. Dynamic viscoelastic properties and dispersity of the compound showed that dispersion of ingredients and reaction was not sufficient with the mixing time of less than 10min. On the contrary, with high temperature, it was obvious that good dynamic and physical properties could be obtained due to sufficient coupling reaction, however it was thought this high temperature is not optimum because of sensitive cross-linking rate and physical properties and excessive formation of bound rubber. Consequently, it was confirmed that the mixing condition of 10min at $140^{\circ}C$ was optimum for the silane coupling reaction and dispersion of functionalized S-SBR containing silica and silane.

• Earthquakes and Structures
• /
• v.18 no.1
• /
• pp.1-14
• /
• 2020

The vehicle-bridge interaction (VBI) analysis might be cumbersome and computationally expensive in bridge engineering due to the necessity of solving large number of coupled system of equations. However, VBI analysis can provide valuable insights into the dynamic behavior of highway bridges under specific loading conditions. Hence, this paper presents a numerical study on the dynamic behavior of a conventional highway bridge under strong near-field and far-field earthquake motions considering the VBI effects. A recursive substructuring method, which enables solving bridge and vehicle equations of motion separately and suitable to be adapted to general purpose finite element softwares, was used. A thorough analysis that provides valuable information about the effect of various traffic conditions, vehicle velocity, road roughness and effect of soil conditions under far-field and near-field strong earthquake motions has been presented. A real-life concrete highway bridge was chosen for numerical demonstrations. In addition, sprung mass models of vehicles consist of conventional truck and car models were created using physical and dynamic properties adopted from literature. Various scenarios, of which the results may help to highlight the different aspects of the dynamic response of concrete highway bridges under strong earthquakes, have been considered.