• 제목/요약/키워드: Dynamic mechanical analyzer

검색결과 89건 처리시간 0.023초

폴리아미드6/반응성 포리프로필렌 블렌드계에서 SEBS-g-MA의 충격개선효과 (Impact Modification Effects of SEBS-g-MA on Polyamide 6/Maleated Polypropylene Blends)

  • 고재송;윤태성;정인권;최형기;장윤호
    • 공업화학
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    • 제10권8호
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    • pp.1141-1146
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    • 1999
  • PA6/PP-g-MA 블렌드계에 상용성 충격개선제로서 SEBS-g-MA를 첨가하여 용융혼합하였고 기계적 물성과 모폴로지 변화를 조사하였다. SEBS-g-MA의 첨가에 의해 인장강도는 약간 감소하지만 파단신율은 증가하였다. 충격강도는 PP-g-MA와 SEBS-g-MA 함량이 증가할수록 증가하였다. 이는 무수말레산의 카르복시기와 아마이드의 반응에 의해 계면접착력과 상용성의 개선이 이루어졌기 때문이다. Dynamic mechanical thermal analyzer(DMTA)를 이용한 tan ${\delta}$의 변화에서도 전형적인 고분자 블렌드의 상용화거동을 보였다. 최종적으로 이 블렌드물의 상구조를 관찰한 결과에서도 SEBS-g-MA의 첨가에 따라 분산상의 크기가 감소하는 것으로 보아 상용성과 계면접착력이 개선됨을 확인하였다.

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Synthesis and Properties of Bio-Thermoplastic Polyurethanes with Different Isocyanate Contents

  • Li, Xiang Xu;Sohn, Mi Hyun;Cho, Ur Ryong
    • Elastomers and Composites
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    • 제54권3호
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    • pp.225-231
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    • 2019
  • Bio-based polyester polyol was synthesized via esterification between azelaic acid and isosorbide. After esterification, bio-based polyurethanes were synthesized using polyester polyol, 1,3-propanediol as the chain extender, and 4,4'-diphenylmethane diisocyanate, in mixing ratios of 1:1:1.5, 1:1:1.8, 1:1:2, and 1:1:2.3. The bio TPU (Thermoplastic Polyurethane) samples were characterized by using FT-IR (Fourier Transform Infrared Spectroscopy), TGA (Thermal Gravimetric Analysis), DSC (Differential Scanning Calorimetry), and GPC (Gel Permeation Chromatography). The mechanical properties (tensile stress and hardness) were obtained by using UTM, a Shore A tester, and a Taber abrasion tester. The viscoelastic properties were tested by an Rubber Processing Analyzer in dynamic strain sweep and dynamic frequency test modes. The chemical resistance was tested with methanol by using the swelling test method. Based on these results, the bio TPU synthesized with the ratio of 1:1:2.3, referred to as TPU 4, showed the highest thermal decomposition temperature, the largest molecular weight, and most compact matrix structure due to the highest ratio of the hard segment in the molecular structure. It also presented the highest tensile strength, the largest elongation, and the best viscoelastic properties among the different bio TPUs synthesized herein.

자동차용 CD/DVD 데크의 진동 저감 및 성능 향상에 관한 연구 (A Study on the Vibration Reduction and Performance Improvement of the CD/DVD is used from the Vehicle)

  • 박영필;정두한;정진태
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2004년도 추계학술대회
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    • pp.799-804
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    • 2004
  • Dynamic characteristic of CD/DVD deck for vehicle is analyzed in this paper. Generally CD/DVD deck for vehicle is used from inferior environment with the vibration of the vehicle and shock of outside and so on. Therefore it must have the structure which is stabilized from the vibration to prevent read error. For this purpose, vibration characteristic of the deck for vehicle should be identified. To analyze characteristic of the deck system, we perform the signal analysis and modal testing using the FFT analyzer. Also we change the design factor degrading the performance of the deck system and verify the efficiency improvement using the acceleration measurement occurring to the sound discontinuation.

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고분자 전해질 연료전지용 복합수지 분리판 개발 (Development of Composite Bipolar Plate for PEMFC)

  • 강현민;한인수;임찬
    • 신재생에너지
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    • 제3권4호
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    • pp.3-7
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    • 2007
  • Graphite/polymer composite bipolar plates for PEMFC are successfully developed, and their typical properties are superior to commercially available ones. Thermal property of the developed bipolar plate was evaluated by dynamic mechanical analyzer, and the results were compared to commercial ones. The specimens were immersed into the deionized water bath at $80^{\circ}$... for 1500hrs to evaluate dimensional stability and durability. Dimension, weight of the specimens as well as extraction conductivity was measured as each 500hrs. Fully molded bipolar plates without any machining or milling were also prepared using a specially developed mold, and they were applied to the fuel cell performance test. Results were compared to the machined commercial bipolar plate.

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고분자 전해질 연료전지용 복합수지 분리판 개발 (Development of Composite Bipolar Plate for PEMFC)

  • 강현민;한인수;임찬
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2007년도 추계학술대회 논문집
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    • pp.5-7
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    • 2007
  • Graphite/polymer composite bipolar plates for PEMFC are successfully developed, and their typical properties are superior to commercially available ones. Thermal property of the developed bipolar plate was evaluated by dynamic mechanical analyzer, and the results were compared to commercial ones. The specimens were immersed into the deionized water bath at $80^{\circ}C$ for 1500hrs to evaluate dimensional stability and durability. Dimension, weight of the specimens as well as extraction conductivity was measured as each 500hrs. Fully molded bipolar plates without any machining or milling were also prepared using a specially developed mold, and they were applied to the fuel cell performance test. Results were compared to the machined commercial bipolar plate.

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인공의족의 외반 특성이 하퇴절단자의 무릎과 발목에 미치는 영향 (Effect of Foot Eversion on Knee and Ankle of Trans-tibial Amputees)

  • 배태수;장윤희;김신기;문무성
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2008년도 추계학술대회A
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    • pp.1505-1508
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    • 2008
  • One of the important functions of prosthetic foot is the foot inversion-eversion which is so important when walking on uneven surfaces. The aim of our study was to evaluate the effect of foot eversion angle especially on knee and ankle joint for transtibial amputees by motion analysis. The experimental data were collected from three transtibial amputees and then ten healthy individuals. To simulate walking on side sloping ground, we used custom-made slope (5, 10, 15 degrees). Motion analysis was performed by 3-dimensional motion analyzer for 6 dynamic prosthetic feet. The results showed that knee abduction moments of amputated leg were decreased but those of sound leg were mainly increased as foot eversion angle increased. And ankle abduction moments of sound leg were inconsistent in magnitude and tendency between control and experimental group. Therefore foot eversioncharacteristics should be considered to develop advanced prosthetic foot.

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Physical and chemical Cross-Linking Effects in Thermoplastic Polyurethane Elastomers with Different Macroglycol

  • Heo, Jae-Ho;Jeong, Du-Gam;Kim, Eun-Young;Kim, Han-Do
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 1997년도 추계총회 및 학술발표회 논문집
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    • pp.126-130
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    • 1997
  • A series of Thermoplastic polyurethane elastomers was prepared via a two-step polymerization process. The NCO/OH feed ratio of polyurethane synthesized in this study was varied from 1 to 1.3. Studies have been made on the effects of chemical and physical cross-linkina, and the properties of thermoplastic polyurethane elastomers based on isophorone diisocyanate (IPDI)/1,4-butanediol (BD)/poly(propylene glycol) (PPG, MW:2000), isophorone diisocyanate (IPDI)/BD /poly(oxytetramethylene) glycol (PTMG, MW:2000) was compared. These materials were characterized using FTIR spectrometer, dynamic mechanical thermal analyzer, and tensile retraction tester. PTMG based polyurethane elastomers showed higher elasomeric behavior than PPG based polyurethane elastomers at the same NCO/OH ratio. This feature has been connected with the specific nature of the polyols. The permanent set(%) was decreased with increasing maximum elongation from 50% to 300%.

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산업용 압전 잉크젯 헤드의 구동신호에 따른 특성 (The Effects of Driving Waveform for Piezoelectric Drop On Demand Industrial Inkjet Head)

  • 김영재;유영석;심원철;박창성;정재우;오용수
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제55권8호
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    • pp.417-422
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    • 2006
  • This paper presents the effect of driving waveform for piezoelectric bend mode inkjet printhead with optimized mechanical design. Experimental and theoretical studies on the applied driving waveform versus jetting characteristics were performed. The inkjet head has been designed to maximize the droplet velocity, minimize voltage response of the actuator and optimize the firing frequency to eject ink droplet. The head design was carried out by using mechanical simulation. The printhead has been fabricated with Si(100) and SOI wafers by MEMS process and silicon direct bonding method. To investigate how performance of the piezoelectric ceramic actuator influences on droplet diameter and droplet velocity, the method of stroboscopy was used. Also we observed the movement characteristics of PZT actuator with LDV(Laser Doppler Vibrometer) system, oscilloscope and dynamic signal analyzer. Missing nozzles caused by bubbles in chamber were monitored by their resonance frequency. Using the water based ink of viscosity of 4.8 cps and surface tension of 0.025 N/m, it is possible to eject stable droplets up to 20 kHz, 4.4 m/s and above 8 pl at the different applied driving waveforms.

인공의족의 외반 특성이 하퇴절단자의 무릎과 발목에 미치는 영향 (Effect of Eversion Characteristics on Knee and Ankle Joint of Trans-tibial Amputees)

  • 배태수;장윤희;김신기;문무성
    • 대한기계학회논문집A
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    • 제33권9호
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    • pp.886-891
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    • 2009
  • One of the important functions of prosthetic foot is the foot inversion-eversion which is so important when walking on uneven surfaces. The aim of our study was to evaluate the effect of foot eversion angle especially on knee and ankle joint for transtibial amputees by motion analysis. The experimental data were collected from three transtibial amputees and then ten healthy individuals. To simulate walking on side sloping ground, we used custom-made slope (5, 10, 15 degrees). Motion analysis was performed by 3-dimensional motion analyzer for 6 dynamic prosthetic feet. The results showed that knee abduction moments of amputated leg were decreased but those of sound leg were mainly increased as foot eversion angle increased. And ankle abduction moments of sound leg were inconsistent in magnitude and tendency between control and experimental group. Therefore foot eversioncharacteristics should be considered to develop advanced prosthetic foot.

카오스 이론을 적용한 보행분석 연구 (Application of the Chaos Theory to Gait Analysis)

  • 박기봉;고재훈;문병영;서정탁;손권
    • 대한기계학회논문집A
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    • 제30권2호
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    • pp.194-201
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    • 2006
  • Gait analysis is essential to identify accurate cause and knee condition from patients who display abnormal walking. Traditional linear tools can, however, mask the true structure of motor variability, since biomechanical data from a few strides during the gait have limitation to understanding the system. Therefore, it is necessary to propose a more precise dynamic method. The chaos analysis, a nonlinear technique, focuses on understand how variations in the gait pattern change over time. Eight healthy eight subjects walked on a treadmill for 100 seconds at 60 Hz. Three dimensional walking kinematic data were obtained using two cameras and KWON3D motion analyzer. The largest Lyapunov exponent from the measured knee angular displacement time series was calculated to quantify local stability. This study quantified the variability present in time series generated from gait parameter via chaos analysis. Knee flexion-extension patterns were found to be chaotic. The proposed Lyapunov exponent can be used in rehabilitation and diagnosis of recoverable patients.