• Journal of Korean Society of Environmental Engineers
• /
• v.27 no.6
• /
• pp.590-598
• /
• 2005

An adequate method to identify chromium separation, Cr(III) and Cr(VI), in water samples were studied by using High Performance Liquid Chromatography(HPLC) coupled with Inductively Coupled Plasma Mass Spectometer(ICP-MS) equipped with Dynamic Reaction Cell(DRC). The characteristic distribution of Cr(III) and Cr(VI) in the raw water taken at the six water intake stations in Seoul, was analyzed by the method developed by the authors. The chromium species separated by HPLC was isocratically conducted by using tetrabutylammonium phosphate monobasic(1.0 mM TBAP), ethylenediaminetetraacetic acid(0.6 mM EDTA) and 2% v/v methanol as the mobile phase. 5% v/v methanol was used as flushing solvent. A reactive ammonia($NH_3$) gas was used to eliminate the potential interference of $ArC^+$. Several Parameters such as solvent ratio, pH, flow rate and sample injection volume were optimized for the successful separation and reproducibility. Although it has been reported thai the separation sensitivity of Cr(III) is superior to that of Cr(VI), the authors observed Cr(VI) was more sensitive than Cr(III) when ammonia($NH_3$) gas was used as the reaction gas. It took less than 3 minutes to analyze chromium species with this method and the estimated detection limits were $0.061\;{\mu}g/L$ for Cr(III) and $0.052\;{\mu}g/L$, for Cr(VI). According to the results from the analysis on chromium species in the raw water of the six intake stations, the concentrations of Cr(III) ranged from 0.048 to $0.064\;{\mu}g/L$(ave. $0.054\;{\mu}g/L$) while that of Cr(VI) ranged from 0.014 to $0.023\;{\mu}g/L$(ave. $0.019\;{\mu}g/L$). Recovery ratio was very high($90.1{\sim}94.1%$). There were two or three times more Cr(III) than Cr(VI) in the raw water.

• Journal of Navigation and Port Research
• /
• v.36 no.1
• /
• pp.21-26
• /
• 2012

Recently, vessel hijacking by pirates has been a big issue around the world. For example, the hostages of VLCC "SAMHO Dream" were released for a large sum of ransom. On January 20, 2011 "SAMHO Jewelry" succeeded releasing all of the 21 crews on the vessel by attacking the pirates in international waters for the first time since the founding of the Naval Force. Furthermore, the "HANJIN Tianjin" crews evacuated to the Citadel promptly and were rescued by the navy. As hijacking of Korean vessels by pirates is increasing, various safety measures must be implemented. As a matter of fact, the standard for ship's facilities has been partially revised and setting up an evacuation shelter on all vessels sailing dangerous zone has been reinforced. This research aims to discuss crew Citadel installation on vessels intended for long haul. In addition, it will look at measures against potential gas flow in the event of pirate armed attacks and fire outbreak onboard a vessel. It will also assess the optimal number of crew Citadels theoretically. Lastly, the optimal number of shelters in the event of fire outbreak will be discussed based on an FDS simulation.

• Journal of the Korean association of regional geographers
• /
• v.12 no.4
• /
• pp.475-495
• /
• 2006

This paper is to analyse a changing space of energy flows in Northeast Asia from geopolitical and geoeconomic perspectives that have been recently promoted for energy security of countries in this region. The research is based on an analytical framework in an integration of political ecology and political economy. Because of an ever-increasing input of energy resources for economic growth and of dramatically increasing price of crude oil and recent instability of oil market, South Korea, China and Japan have been deeply concerned with energy security and conducted very actively geopolitical strategies. And hence the space of energy flows in the region is now in a process of dynamic reconfiguration, in which the project for development of oil and natural gas fields in East Siberia and construction of pipelines to transport them can be seen as one of competitive issues among these countries. In spite of worrying about stagflation due to rapid increase of oil price, such geo-strategies for energy security and reconfiguration of space of energy flows seem to keep the accumulation of capital in this region continue with generation of huge privatized oil companies.

• Korean Chemical Engineering Research
• /
• v.59 no.3
• /
• pp.417-428
• /
• 2021

The combustion characteristics of anthracite, which follow a complex process with low reactivity, must be considered through the dynamic behavior of circulating fluidized bed (CFB) boilers. In this study, computational fluid dynamics (CFD) simulation was performed to analyze the combustion characteristics of anthracite in a pilot scale 0.1 MW_th Oxy-fuel circulating fluidized bed (Oxy-CFB) boiler. The 0.1MW_th Oxy-CFB boiler is composed of combustor (0.15 m l.D., 10 m High), cyclone, return leg, and so on. To perform CFD analysis, a 3D simulation model reactor was designed and used. The anthracite used in the experiment has an average particle size of 1,070 ㎛ and a density of 2,326 kg/m³. The flow pattern of gas-solids inside the reactor according to the change of combustion environment from air combustion to oxygen combustion was investigated. At this time, it was found that the temperature distribution in air combustion and oxygen combustion showed a similar pattern, but the pressure distribution was lower in oxygen combustion. addition, since it has a higher CO₂ concentration in oxygen combustion than in air combustion, it can be expected that carbon dioxide capture will take place actively. As a result, it was confirmed that this study can contribute to the optimized design and operation of a circulating fluidized bed reactor using anthracite.

• Journal of Korean Society of Forest Science
• /
• v.111 no.4
• /
• pp.490-501
• /
• 2022

In this study, the isoprene and terpene emissions from 32 major urban tree species were investigated. We conducted sampling using a dynamic enclosure system between June and July 2021. Seedlings aged < three years were enclosed in a chamber consisting of a 400 L transparent Tedlar bag. The air flow from the outlet of the chamber was sampled using Tenax-filled sorbent tubes under standard conditions (temperature: 30°C; PAR: 1,000 μmol/m²/sec). A thermal desorption gas chromatography/mass spectrometry system was used to analyze the following 38 biogenic volatile organic compounds: isoprene, monoterpenes, sesquiterpenes, oxygenated monoterpenes, and oxygenated sesquiterpenes. Isoprene emitters included Quercus mongolica, Salix koreensis, Robinia pseudoacacia, and Salix chaenomeloides. Monoterpene emitters included Pinus strobus, Cedrela sinensis, and Cercis chinensis. The monoterpene emission profiles were dominated by á-pinene, myrcene, camphene, and limonene. The predominant oxygenated monoterpene and oxygenated sesquiterpene were eucalyptol and caryophyllene oxide, respectively. For all species, the contributions of sesquiterpenes and oxygenated sesquiterpenes were relatively low.