• Title/Summary/Keyword: Dynamic Range

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Determination of Tributyl Phosphate Degradation Products by Ion Chromatography (이온크로마토그래피에 의한 Tributyl Phosphate(TBP) 분해산물의 정량)

  • Han, Sun Ho;Lee, Hyo Jin;Yang, Han Beom;Park, Yang Soon;Joe, Kih Soo
    • Analytical Science and Technology
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    • v.15 no.4
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    • pp.329-334
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    • 2002
  • Tributyl phosphate(TBP) is used in solvent extraction process for radioactive waste. This compound may be degraded to dibutyl phosphate($DBP^-$), monobutyl phosphate($MBP^{2-}$) and ${PO_4}^{3-}$ by radioactive material. Amount of $DBP^-$ and $MBP^{2-}$ in TBP must be monitored because they production of these compounds means degradation of which leads to a decrease in the extraction yield. Retention behavior for $DBP^-$, $MBP^{2-}$, $F^-$, $Cl^-$, ${NO_2}^-$, ${NO_3}^-$, ${SO_4}^{2-}$ and ${PO_4}^{3-}$ are studied with AS4A-SC(Dionex) analytical column and $Na_2CO_3$/NaOH eluent by Ion chromatography. Optimum condition for these anions is 2 mM $Na_2CO_3$/1 mM NaOH eluent. All anions by this condition is well separated within 15min. Dynamic range is $10{\mu}g/mL$ - $100{\mu}g/mL$ for DBP and $5{\mu}g/mL$ - $50{\mu}g/mL$ for $MBP^{2-}$, respectively. The Detection limit for AS4A-SC are $1{\mu}g/mL$ for $DBP^-$ and $0.5{\mu}g/mL$ for $MBP^{2-}$ in this system with a $25{\mu}L$ sample loop.

Study on the Visual Characteristics and Subjectivity in the Live Action Based Virtual Reality (실사기반 가상현실 영상의 특징과 주체 구성에 대한 연구)

  • Jeon, Gyongran
    • Cartoon and Animation Studies
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    • s.48
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    • pp.117-139
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    • 2017
  • The possibility of interactivity of digital media environment is adopted in human expression system and integrates the dynamic aspect of digital technology with expressive structure, thereby transforming the paradigm of image acceptance as well as image expression range. Virtual reality images have an important meaning in that they are changing the one-way mechanism of production and acceptance of images that lead to producers-video-audiences beyond the problem of verisimilitude such as how vividly they simulate reality. First of all, the virtual reality image is not one-sided but interactive image composed by the user. Viewing a virtual reality image does not just see the camera shine, but it gets the same view as in the real world. Therefore, the image that was controlled through framing changes to be configured positively by the user. This implies a change in the paradigm of image acceptance as well as a change in the existing form of the image itself. In addition, the narrative structure of the image and the subjects that are formed in the process are also required to be discussed. In the virtual reality image, the user 's gaze is a fusion of the gaze inside the image and the gaze outside the image. This is because the position of the user as the subject of the gaze in the virtual reality image is continuously restricted by the device of the discourse such as the editing and the narration of the shot. The significance of the virtual reality image is not aesthetically perfect but it is reconstructed according to the user to reflect the existence of the user positively and engage the user in the image.

A Study on the Air Foil Journal Bearing Analysis with Perturbed Rarefaction Coefficients

  • Lee, Yong-Bok;Park, Dong-Jin;Kim, Chang-Ho;Jang, Gun-Hee
    • KSTLE International Journal
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    • v.7 no.2
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    • pp.27-34
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    • 2006
  • Knudsen number is the ratio of molecular mean free path versus mm thickness and the criterion to determine the flow form. When its value is lower than 0.01, the flow can be assumed to has no slip boundary condition. And in the case that the value is between 0.01 and 10, then the flow has slip boundary condition at both the adjacent walls. The condition of the air flow between the rotating journal and top foil in the air foil bearing is determined by the rotating speed and load, and the Knudsen number is also varied by those values. Because the molecular mean free path is variable to the pressure and temperature, more exact formulation is necessary to understand and analyze the flow regime. In this study, the analysis considering Knudsen number formulated with those variables (pressure, temperature and mm thickness) was executed. The approximate value was examined using the equation to confirm whether the flow has the slip or no-slip boundary condition. From the analytic investigation, it was decided to range approximately 0.01 to 1.0 and the flow can be supposed to have the slip boundary condition. Under the condition of the slip flow, the static characteristics of the air foil bearing were examined using modified Reynolds equations. The results were compared with those considering no slip condition. It shows that the slip condition makes the flow decelerates and the load carrying capacity decreases compared with no slip condition. And as the bearing number and eccentricity ratio increase, the load carrying capacity also increased at both the cases. From this result, it can be supposed that the bearing torque also increases. In the analysis of the dynamic characteristics, the perturbed Knudsen number was taken into consideration. Because the Knudsen number is expressed as the terms of each variable, the perturbed equation can be simply derived. The results of both cases considering and not considering Knudsen number were compared each other. In the case of the direct terms of the stiffness and damping coefficients, the difference between both cases was little and increased as the bearing number and eccentricity ratio increased. And the cross terms have less or more differences.

Novel Graphene Volatile Memory Using Hysteresis Controlled by Gate Bias

  • Lee, Dae-Yeong;Zang, Gang;Ra, Chang-Ho;Shen, Tian-Zi;Lee, Seung-Hwan;Lim, Yeong-Dae;Li, Hua-Min;Yoo, Won-Jong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.120-120
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    • 2011
  • Graphene is a carbon based material and it has great potential of being utilized in various fields such as electronics, optics, and mechanics. In order to develop graphene-based logic systems, graphene field-effect transistor (GFET) has been extensively explored. GFET requires supporting devices, such as volatile memory, to function in an embedded logic system. As far as we understand, graphene has not been studied for volatile memory application, although several graphene non-volatile memories (GNVMs) have been reported. However, we think that these GNVM are unable to serve the logic system properly due to the very slow program/read speed. In this study, a GVM based on the GFET structure and using an engineered graphene channel is proposed. By manipulating the deposition condition, charge traps are introduced to graphene channel, which store charges temporarily, so as to enable volatile data storage for GFET. The proposed GVM shows satisfying performance in fast program/erase (P/E) and read speed. Moreover, this GVM has good compatibility with GFET in device fabrication process. This GVM can be designed to be dynamic random access memory (DRAM) in serving the logic systems application. We demonstrated GVM with the structure of FET. By manipulating the graphene synthesis process, we could engineer the charge trap density of graphene layer. In the range that our measurement system can support, we achieved a high performance of GVM in refresh (>10 ${\mu}s$) and retention time (~100 s). Because of high speed, when compared with other graphene based memory devices, GVM proposed in this study can be a strong contender for future electrical system applications.

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Climate Change Impacts on Forest Ecosystems: Research Status and Challenges in Korea (기후변화에 따른 산림생태계 영향: 우리나라 연구현황과 과제)

  • Lim Jong-Hwan;Shin Joon-Hwan;Lee Don-Koo;Suh Seung-Jin
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.8 no.3
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    • pp.199-207
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    • 2006
  • Recent global warming seems to be dramatic and has influenced forest ecosystems. Changes in phonology of biota, species distribution range shift and catastrophic climatic disasters due to recent global warming have been observed during the last century. Korean forests located mainly in the temperate zone also have been experienced climatic change impacts including shifting of leafing and flowering phonology, changes in natural disasters and forest productivity, However, little research has been conducted on the impact of climate change on forest ecosystems in Korea which is essential to assess the impact and extent of adaptation. Also there is a shortage in basic long-term data of forest ecosystem processes. Careful data collection and ecological process modeling should be focused on characteristic Korean forest ecosystems which are largely complex terrain that might have hindered research activities. An integrative ecosystem study which covers forest dynamics, biological diversity, water and carbon flux and cycles in a forest ecosystem and spatial and temporal dynamics modeling is introduced. Global warming effects on Korean forest ecosystems are reviewed. Forestry activity and the importance of forest ecosystems as a dynamic carbon reservoir are discussed. Forest management options and challenges for future research, impact assessment, and preparation of mitigating measures in Korea are proposed.

A Multistage Authentication Strategy for Reliable N-to-N Communication in CGSR based Mobile Ad Hoc Networks (CGSR 기반의 이동 애드 흑 네트워크에서 신뢰성 있는 통신을 위한 노드간 인증 기법)

  • Lee Hyewon K.;Mun Youngsong
    • Journal of KIISE:Information Networking
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    • v.32 no.6
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    • pp.659-667
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    • 2005
  • A Mobile Ad Hoc Network(MANET) is a multi hop wireless network with no prepared base stations or centralized administrations, where flocks of peer systems gather and compose a network. Each node operates as a normal end system in public networks. In addition to it, a MANET node is required to work as a router to forward traffic from a source or intermediate node to others. Each node operates as a normal end system in public networks, and further a MANET node work as a router to forward traffic from a source or intermediate node to the next node via routing path. Applications of MANET are extensively wide, such as battle field or any unwired place; however, these are exposed to critical problems related to network management, node's capability, and security because of frequent and dynamic changes in network topology, absence of centralized controls, restricted usage on network resources, and vulnerability oi mobile nodes which results from the special MANET's character, shared wireless media. These problems induce MANET to be weak from security attacks from eavesdropping to DoS. To guarantee secure authentication is the main part of security service In MANET because networks without secure authentication are exposed to exterior attacks. In this paper, a multistage authentication strategy based on CGSR is proposed to guarantee that only genuine and veritable nodes participate in communications. The proposed authentication model is composed of key manager, cluster head and common nodes. The cluster head is elected from secure nodes, and key manager is elected from cluster heads. The cluster head will verify other common nodes within its cluster range in MANET. Especially, ID of each node is used on communication, which allows digital signature and blocks non repudiation. For performance evaluation, attacks against node authentication are analyzed. Based on security parameters, strategies to resolve these attacks are drawn up.

The Motion Response of an Oil Boom with Flexible Skirt (유연한 스커트를 가진 오일붐의 운동응답해석)

  • 성홍근;조일형;최항순
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.7 no.2
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    • pp.156-162
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    • 1995
  • A numerical method for a 2-D oil boom model considering the flexibility of skirt has been developed The neater is assumed rigid and the skirt is tensioned membrane having a point mass at its end The fluid motion is potential. The kinematic condition which demands the continuity of the displacement is imposed at the joint between the floater and the skirt. The dynamic condition for the point mass is imposed at the bottom end of the skirt. The numerical method is based on the Green's function method in the frame of linear potential theory. It finds it's solution simultaneously from the total system of three equations, integral equation, the equation of motion of the floater and the equilibrium equation of the deformation of the skirt. Integral equation is derived by applying the Green's theorem to radiation potential and Green's function. Proper descretization of those three equations leads to the system of a linear algebraic equation. Due to the flexibility of skirt the motion of floater can be diminished in some range of wave frequency and furthermore the mechanism of resonance of the oil boom can be changed. The motion responses of various oil booms have been compared varying the length of the skirt and the point mass. The numerical method has been validated indirectly from the good correspondence between the motion responses of the flexible skirt model and the rigid skirt model in low frequency limit.

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A Review on Soil Respiration Measurement and Its Application in Korea (토양호흡의 측정과 국내 연구 현황에 대한 고찰)

  • Lee, Eun-Hye;Lim, Jong-Hwan;Lee, Jae-Seok
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.12 no.4
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    • pp.264-276
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    • 2010
  • The objectives of this study were to introduce the methods of soil respiration measurement, to review soil respiration studies conducted in Korea, and to suggest potential issues generated from using various methods for soil respiration measurement. According to the measurement principles, the methods of soil respiration measurements are classified as: alkali absorption method (AA), closed chamber method (CC), closed dynamic chamber method (CDC), and open flow method (OF). Based on the litereaure review on soil respiration studies in Korea, the CDC method was mostly used by the researchers (62%), followed by the AA (17%), OF (13%) and CC (8%) methods. Along with these methods, various instruments were used such as LI-6400-09, EGM-3, EGM-4, and automatic soil respiration chamber. Most of the soil respiration measurements were carried out in forest ecosystems and the reported soil respiration showed a wide range of variations from 130 to 900 mg $CO_2\;m^{-2}h^{-1}$. Continuous monitoring of soil respiration with minimal disturbance and the potential inconsistency in measurements are still the challenges facing the researchers, causing a paucity in quality datasets of sufficient quantity. Few attempts of intercomparison among different methods hinder the data users from synthetic analysis and assessment of the collected datasets. In order to better estimate soil carbon budget and understand their exchange mechanisms in key ecosystems of Korea, it is necessary to measure soil respiration at various plant functional types, soils, and climate conditions over a decadal time scale along with the study on the partitioning of soil respiration into autotrophic and heteorotrophic components.

Determination of radiolysis products in Tri-Octyl Amine by high performance liquid chromatography-mass spectrometer (HPLC-MS에 의한 Tri-Octyl Amine(TOA)의 방사선 분해산물 정량)

  • Yang, Han-Beom;Lee, Eil-Hee;Moon, Hyung-Sil
    • Analytical Science and Technology
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    • v.18 no.3
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    • pp.201-205
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    • 2005
  • Tri-octyl amine (TOA) is used in solvent extraction process for radioactive waste. This compound may be degraded to di-octyl amine (DOA), mono-octyl amine (MOA) by radioactive materials. Amount of TOA, DOA and MOA in TOA must be monitored because they production of these compounds means degradation of which leads to a decrease in the extraction yield. Retention behavior for TOA, DOA and MOA are studied with Phenomenex LUNA-$C_{18}$ ($4.6mm{\times}25cm$) analytical column and $CH_3OH:H_2O$ (50 mmol $CH_3COONH_4$) eluent by liquid chromatography. Optimum condition for these compounds is $CH_3OH:H_2O$ (50 mmol $CH_3COONH_4$) = 85 : 15 ratio. TOA, DOA and MOA compounds is well separated within 20 minute. Dynamic range is $30{\sim}160{\mu}g/mL$ for TOA, $5{\sim}100{\mu}g/mL$ for DOA and $0.1{\sim}5{\mu}g/mL$ for MOA, respectively. The detection limit are $0.1{\mu}g/mL$ for TOA, $1{\mu}g/mL$ for DOA (in SCAN mode) and $0.1{\mu}g/mL$ for MOA (in SIM mode) in this system with $20{\mu}L$ sample loop.

Bioanalytical method validation for determination of arsenic speciation in dog plasma using HPLC-ICP/MS (Dog 혈장 중 HPLC-ICP/MS를 이용한 비소 화학종 분석법 검증)

  • Kim, Jong-Hwan;Kwon, Young Sang;Shin, Min-Chul;Kim, Su Jong;Seo, Jong-Su
    • Analytical Science and Technology
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    • v.29 no.5
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    • pp.234-241
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    • 2016
  • The approach presented in this article refers to the bioanalytical method validation for the detection and quantitative determination of arsenic species including arsenite (As(III)), arsenate (As(V)), dimethylarsinic acid (DMA) and monomethylarsonic acid (MMA) in dog plasma by high-performance liquid chromatography inductively coupled plasma mass spectrometry (HPLC-ICP/MS). The arsenic species were separated using an agilent As speciation column by a mobile phase of 2 mM sodium phosphate monobasic, 0.2 mM ethylenediaminetetraacetic acid disodium salt dehydrate, 10 mM sodium acetate, 3 mM sodium nitrate and 1 % ethyl alcohol at pH 11 (adjusted with 1M NaOH). The method validation experiment was obtained selectivity, linearity, accuracy, precision, matrix effect, recovery, system suitability, dilution integrity and various stabilities. All calibration curves showed good linearity (R2>0.999) within test ranges. The lower limit of quantitation (LLOQ) was 5 ng/mL for As(III), As(V) and DMA, and 20 ng/mL for MMA. The system suitability and dilution values were within 6.5 % and 7.7 %. Subsequently, the developed and validated HPLC-ICP/MS method was also successfully applied to determine the arsenic speciation in dog plasma samples, and the recoveries for the spiked samples were in the range of 91.5–102.2 %. Therefore, this method could be applied to the evaluation of arsenic exposure, health effect assessment and other bio-monitoring studies in biological samples.