• Textile Coloration and Finishing
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• v.9 no.5
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• pp.10-18
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• 1997

In order to study the properties of safflower yellow colors, thermodynamic parameters and dyeing properties on the silk in several dyeing conditions were investigated. The uv-visible spectra of safflower yellow colors in several solvents show hypsochromic shift with the polarity of solvent but bathochromic shift with increasing acidity of solution. The apparent diffusion coefficients and standard affinities of dyeing increased with the increase of dyeing temperature. The standard heat of dyeing(${\Delta}H^0$), entropy change(${\Delta}S^0$) and activation energy($E_{act}$) were calculated to be - 1.144kcal/mol, -7.498(5$0^{\circ}C$)~-3.804(9$0^{\circ}C$)cal/molㆍdeg and 0.123kcal/mol, respectively. The concentration of safflower yellow colors in the silk fiber increased with dyeing temperature, time, concentration of colors and acidity of initial dyebath. Silk fabrics were dyed bright yellow by pre-mordanting with tin chloride. Lightfastness of silk fabrics pre-mordanted by tin chloride was not excellent.

• Textile Coloration and Finishing
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• v.11 no.4
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• pp.39-49
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• 1999

In order to study the properties of cochineal colors, uv-visible spectra of cochineal colors solution, dyeing properties on the wool in several dyeing conditions and thermodynamic parameters were investigated. UV-visible spectra of cochineal colors solution showed hypochromic effect with the lapse of irradiation time but bathochromic shift with decreasing acidity of solution and addition of metallic ions. The concentration of cochineal colors in wool fiber increased with the increase of dyeing temperature, time, and acidity of initial dyebath. The value of apparent diffusion coefficients and standard affinities of dyeing decreased with the increase of dyeing temperature. The standard heats of dyeing$(\Delta{H}^\circ)$ and variation of entropy$(\Delta{S}^\circ)$ increased with the increase of concentration of initial dyebath. The activation energy$(E_a)$ were calculated to be 1.399~2.595kcal/mol in condition of 6~1%(o.w.f) dyebath. Wool fabrics were dyed reddish blue by iron sulfate, copper sulfate, aluminum acetate and tannic acid, and red by tin chloride, respectively. Lightfastness of wool fabrics dyed by cochineal colors were increased by mordant treatment, especially copper sulfate and iron sulfate treatment.

• Textile Coloration and Finishing
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• v.12 no.5
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• pp.280-287
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• 2000

For thousands of years, dyes were obtained from natural sources, such as plants and animals. Although synthetic dyes have replaced many natural dyes for commercial use but natural dyes with their fascinating color are still used extensively by some people. To investigate the dyeing properties of chestnut bur, which is most widely found in our country, some experiments were performed under the several dyeing conditions with silk and cotton fabrics. It was found that $\lambda_{max}$ of chestnut but extract was 410nm and the color of the fabric dyed is Yellow Red. The K/S value of silk and cotton fabrics increased when the dyeing temperature was higher than $60^\circ{C}$ and the dyeing time was more than 30 minutes. Optimal dyeing pH was between 5 and 6, and repetition of dyeing increased K/S value of the sample fabrics. K/S value of silk fabric dyed with chestnut bur extract was higher than that of cotton. Post-mordanting method showed higher color yield compared with pre-mordanting, and higher temperature and increased time in mordanting increased the dye-uptake.

• Textile Coloration and Finishing
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• v.16 no.6
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• pp.10-15
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• 2004

The colorants were extracted from the flower leaf of rose using a buffer solution. Dyeing properties and the fastness of silk fabrics dyed with rose flower extracts were investigated. K/S values of dyed fabrics were increased as the concentration of rose flower extracts was increased. Optimum dyeing temperature of rose flower extracts was $30^{\circ}C$. Fastness were generally good except light fastness which was extremely poor.

• Journal of the Korean Professional Engineers Association
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• v.15 no.2
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• pp.24-31
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• 1982

This study concerns with the reduction of the COD and deceleration of dyeing wastewater from DAEGU city area by ozonation. The COD reduction by ozonation follows near linear relationships versus ozonation time, temperature and concentration. The color in dyeing wastewater and of dyes can he strikingly reduced as the water is quasi colorless after ozone treatment. COD reduction rate of wastewater was found not to be dependented on pH, however, high temperature gave better results, although economically not feasible. The ozonation of dyeing wastewater can give good results when dyes, scouring agent and sticking agents were pre-separated.

• Textile Coloration and Finishing
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• v.11 no.3
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• pp.9-14
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• 1999

To investigate the effect of dyeing conditions, such as pick-up rate, dye concentration, time and temperature in thermosol dyeing on the dyeability of industrial polyester belt, dye uptake and rubbing fastness were measured. The dye uptake was increased with the increase of pick-up rate, dye concentration, dyeing time and temperature. The high rubbing fastness(class 5) for polyester belt dyed with Cibacet Blue F3R at the various conditions was obtained.

• Fibers and Polymers
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• v.7 no.4
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• pp.352-357
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• 2006

The cotton fabrics were pretreated by sodium 2-(2,3-dibromopropionylamino)-5-(4,6-dichloro-1,3,5-triazinylamino) benzenesulfonate (DBDCBS) at alkaline condition ofroom temperature and then dyed with four disperse dyes having amino groups (C.I. Disperse Yellow 9, C.I. Disperse Red 11, C.I. Disperse Blue 56 and C.I. Disperse Violet 1) at acidic condition of high temperature. A novel hetero-bifunctional bridge compound, DBDCBS, has two reactive groups such as dichloro-striazinyl group and ${\alpha},\;{\beta}$-dibromopropionylamido group. The first has reactivity towards hydroxy group of cellulosic fiber and the second shows reactivity towards amino groups of disperse dye containing amino groups. The results indicate that it is possible to dye polyester/cotton blend at one-bath dyeing using one kind of disperse dye containing amino groups. Therefore, two kinds of dyeing methods such as two-bath process one-bath dyeing and one-bath process one-bath dyeing were investigated and their dyeabilities were compared. The differences between these two methods were negligibly small so that perfect one-bath one-step dyeing of polyester/cotton blend by one kind of disperse dye was achieved.

• Textile Coloration and Finishing
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• v.21 no.6
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• pp.12-21
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• 2009

The dyeing property of direct-spinning type and seaisland type 0.2D micro polyester nonwoven fabrics was characterized by three disperse dyes (Dorosperse Red KFFB, Blue KGBR, Yellow KRL) at $120^{\circ}C$ and $130^{\circ}C$. Before and after reduction cleaning, dyeing fastness was evaluated and the thermomigaration after heat setting at $180^{\circ}C$ for 60 min were also evaluated. Direct-spinning type fabric showed better dyeing property, wash fastness, and light fastness, but worse rub fastness than seaisland type fabric. The dyeing property and fastness of direct-spinning type fabric increased at higher dyeing temperature, whereas seaisland type fabric exhibited lower dyeing fastness and the increase of thermomigration at higher dyeing temperature. Non-fixed dye in fiber surface was removed by reduction cleaning process, then dyeing fastness was improved and thermomigration decreased. The higher dye uptake of direct-spinning type non-woven fabric caused the increase of dye molecule migration from fiber internal to fiber surface, so this fabric showed larger thermomigration than seaisland type non-woven fabric.

• Journal of the Korean Society of Costume
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• v.36
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• pp.109-119
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• 1998

For the purpose of standardization and practicability of natural dyeing, the mordanting and dyeing properties of Caseaslpinia Sappan, L. and Brazilin were studied. Appropriate extraction, dyeing and mordanting condition of Caeaslpinia Sappan, L. were determined, and the effect of mordanting method on dye up-take adn color fastness of dyed fabric was investigated. The most absorbance of Caeaslpinia Sappan, L. solution was 445nm, Brazilin was 448nm. The color of bazilin solution was affected by pH 7~9. The optimum temperature to extract Caesalpinia Sappan, L. was 10$0^{\circ}C$ adn dyeing solution for 1 hour. In case mordants concentration, the most absorbance was 0.3%. In case mordanting test, the best and proper temperature to quantities of absorbed mordants in silk was 8$0^{\circ}C$ and the most quantities of absorbed mordants in silk was mordant treatment by Cu. Effective dyeing time to silk was 60min. Effective mordanting temperature was 8$0^{\circ}C$, and its time was 30min. K/S value of dyeing fabrics was recoginazed by mordanting treat-ment, specially Fe, Sn, Al, Cu. K/S value of pre-mordanting was higher than post-mordanting. After soaping treatment K/S value of pre- and post-mordanting silk was decreased and 0.1%(W/V) quantity of mordant was sufficient for treatment. In the case of Caeaslpinia Sappan, L. fastness was increased by mordanting treatment. Mordants and mordanting treatment method affected the amount of absorption and color change of dyed silk.

• Journal of the Korean Society of Clothing and Textiles
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• v.25 no.8
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• pp.1484-1492
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• 2001

For the purpose of standardization and practicability of dyeing by natural dye, the mordanting and dyeing properties of Lithodpermum officinale were studied. Appropriate extraction, dveing and mordanting conditions of Lithodpermum officinale were determined, and the effect of mordanting no dye uptake and color fastness of dyed fabric was investigated. The maximum absorbances of Lithopermum officinale solution were at 521 and 561 mn, shikonin solution were 517 and 556 mn. According to the UV-VIS spectroscopy of shikonin solution showed batho chromic shift with the increase of temperature and the absorbance of shikonin solution increased with the increase of temperature. The color of Lithodpermum officinale solution was affected by pH 8∼9, they became dark, reduced reddish and bluish. The optimum conditions for extraction from Lithodpermum officinale were at 80$\^{C}$ and for 1 hour and at 25$\^{C}$ for 24 hours. And effective dyeing conditions with silk fabric were temperature at 80∼100$\^{C}$ and period for 60min. K/S value and color fastness of dyed fabrics were increased by mordanting treatment. In the case of Lithodpermum officinale light fastness was better than Sophora japonica, Gaesalpinia Sappan, Rhusjara,. Cochineal dyeing fabrics. Perspiration fastness of Lithodpermum officinale were good. Fastness of abrasion and dry-cleaning were good these fastness improvement were generatlly effected by post-mordanting treatment.