• Title/Summary/Keyword: Dyeing, Fastness

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A study on Improving the Dyeability of BTCA treated Cotton Fabrics Containing Nitrogenous Cationic Additives (BTCA처리 면직물의 질소계양이온화제 첨가에 의한 염색성 향상에 관한 연구)

  • 박은경;유효선
    • Journal of the Korean Society of Clothing and Textiles
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    • v.24 no.6
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    • pp.819-827
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    • 2000
  • The purpose of this study is to produce cotton fabric having improved dyeability and colorfastness as well as retaining the desirable durable press property. When cotton fabric was treated with additives, nitrogen content was increased as the additive concentration was increased. DP ratings and wrinkle recovery properties of BTCA treated cotton fabrics were greatly increased. But DP rating was lowered slightly by adding additives and wrinkle recovery property was decreased with the increase of additive concentration. Tensile strength was decreased by BTCA treatment but increased as additive concentration was increased. Various BTCA/additive treatments produced great affinity for reactive and acid dyes when dyebaths were adjusted at pH 3. It was showed that dyeability was increased as additive concentration was increased. The most effective additive for improving the dyeing properties of the crosslinked cotton was TEAㆍHCl. In case of reactive dye, there was almost no improvement on the dyeability of finished cotton by adding salt. Color fastness to washing and light of finished and dyed cotton were low except for the washfastness of reactive dye. Dyeing the BTCA/additive treated cotton fabrics with reactive dye had no effect on the physical properties.

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A Study on Natural Dyeing (3) - Change of physical structure and Chinese gallotannin treatment on silk fabric - (천연염색에 관한 연구 (3) - 견에 대한 Chinese gallotannin 처리 및 구조변화 -)

  • Kim, Hye In;Eom, Seong Il;Park, Su Min
    • Textile Coloration and Finishing
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    • v.13 no.5
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    • pp.1-1
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    • 2001
  • As the basic study to investigate the mechanism of improvement in the dyeing fastness of natural dyes on silk fabrics the optical behavior of tannin solution, the optimal condition of tannin treatment and the changes of the physical structure of silk fabrics were studied in the treatment of tannin. Results obtained were as follows ; 1.The K/S values of tannin-treated silk fabrics were not changed by tannin content on silk fabrics but yellowing of tannin in treatment condition. 2. As the concentration of tannin was increased in its treating condition, the tannin content and K/S vague of tannin-treated silk fabrics were increased. 3. Because tannin gave rise to yellowing by hydrolysis and oxidation at high temperature, the higher tannin-treating temperature was, the lower the tannin content and K/S values of silk fabrics 4. The tannin content of silk fabric was higher in acidic treating condition and the highest K/S value was showed at pH 5. 5. As the tannin content of silk fabric was increased, the value of ζ -potential of it became negative. 6. As the tannin content of silk fabric was increased, the crystallinity and crystallite size of it were decreased. This meant that the fraction of amorphous region in the fibers increased. And the degree of orientation of it was decreased with the tannin treatment.

A Study on Natural Dyeing (3) - Change of physical structure and Chinese gallotannin treatment on silk fabric - (천연염색에 관한 연구 (3) -견에 대한 Chinese gallotannin 처리 및 구조변화-)

  • 김혜인;엄성일;박수민
    • Textile Coloration and Finishing
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    • v.13 no.5
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    • pp.289-297
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    • 2001
  • As the basic study to investigate the mechanism of improvement in the dyeing fastness of natural dyes on silk fabrics the optical behavior of tannin solution, the optimal condition of tannin treatment and the changes of the physical structure of silk fabrics were studied in the treatment of tannin. Results obtained were as follows ; 1 The K/S values of tannin-treated silk fabrics were not changed by tannin content on silk fabrics but yellowing of tannin in treatment condition. 2. As the concentration of tannin was increased in its treating condition, the tannin content and K/S vague of tannin-treated silk fabrics were increased. 3. Because tannin gave rise to yellowing by hydrolysis and oxidation at high temperature, the higher tannin-treating temperature was, the lower the tannin content and K/S values of silk fabrics 4. The tannin content of silk fabric was higher in acidic treating condition and the highest K/S value was showed at pH 5. 5. As the tannin content of silk fabric was increased, the value of $\xi$ -potential of it became negative. 6. As the tannin content of silk fabric was increased, the crystallinity and crystallite size of it were decreased. This meant that the fraction of amorphous region in the fibers increased. And the degree of orientation of it was decreased with the tannin treatment.

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Reactive Dyeing of Photografted para-Aramid Fabrics

  • Kim, Eun-Min;Jang, Jin-Ho
    • Textile Coloration and Finishing
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    • v.23 no.3
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    • pp.155-162
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    • 2011
  • para-Aramid has limited dyeability because of its highly crystalline structure and compactness. To improve the dyeability of the para-aramid to reactive dyes of bright color in deep shade, the fabrics were photografted under continuous UV irradiation with dimethylaminopropyl methacrylamide and 4-benzoyl benzoic acid as a monomer and a hydrogen -abstractable photoinitiator respectively. A UV energy of 35J/$cm^2$ and a photoinitiator concentration of ten percent or more with respect to the monomer in the formulation was required for optimal photografting. Grafting yield increased with higher monomer application level. Surface analysis indicated significant alterations in the atomic composition of the photografted fabric surface and the fabric surface was covered with the grafted polymers. While the pristine para-aramid fabrics showed no appreciable dyeability to the ${\alpha}$-bromoacrylamide reactive dyes, the grafted para-aramid fabrics enhanced the dyeability to the reactive dyes substantially. In case of C.I. Reactive Blue 50, a K/S value of 8.7 can be obtained with the grafted para-aramid fabrics with a grafting yield of 2.3 %. Also the color fastness properties of the dyed fabrics was excellent in the conditions of washing, rubbing and light irradiation.

Dyeing of High Strength and High Molecular Weight Polyethylene Fiber Using Super Hydrophobic Fluorescence Dyes (초소수성 형광염료에 의한 고강도/고분자량폴리에틸렌섬유의 염색)

  • Kim, Taekyeong;Park, Jihoon;Lee, Junheon;Kim, Taegun
    • Textile Coloration and Finishing
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    • v.29 no.4
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    • pp.223-230
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    • 2017
  • Three super hydrophobic fluorescence dyes were selected to dye high molecular weight polyethylene fiber and their molar absorptivity, emission spectrum, and quantum yield were measured. From the results of color strength on the fiber, all the three dyes exhibited linear increase according to the dye concentration and Fluoro3 dye showed the highest color strength among them. Emission strength of the fluorescence dyes on the fiber was investigated according to the dye concentrations. The emission was increased with the increase of the dye concentration at relatively low dye concentration and then after showing the maximum emission strength the emission was decreased at higher dye concentrations. The highest emission was obtained in Fluoro2 dye. Color fastness to washing and rubbing was generally good enough, however, especially to light, only Fluoro3 dye exhibited rating 3 acceptable practically and Fluoro1 and 2 was ratings 1 which is unacceptable level.

Properties of PMMA Dyed with Reactive Azo Dye (반응성 아조염료로 착색한 PMMA의 성질)

  • Geum, Neri;Heo, Ji-Won
    • Applied Chemistry for Engineering
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    • v.17 no.4
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    • pp.426-431
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    • 2006
  • Acryl and vinyl sulfone functionalized blue and orange azo dyes were prepared by the coupling reaction of 6-bromo-2-cyano-4-nitroaniline and 2,5-dimethoxy-4-(vinylsulfonyl)benzenamine with 3-acrylamido-(N,N-diethylamino)benzene and 3-methyl-(N,N-diethylamino)benzene, respectively, for the coloring of poly(methyl methacrylate) (PMMA). Allyl functionalized dye was also prepared by reacting vinyl sulfone-containing dye with allylamine. Three types of dyeing method were used: the copolymerization of reactive dye with methyl methacrylate (MMA) and dyeing by polymerization of MMA in the presence of polymeric dye and dye 2 without reactive function. The color fastness for the three PMMAs were evaluated by comparing the solubility of dye under various conditions.

Coloration of Cotton Fabrics with Tannins of Persimmon Extracts by Heating Process (감 탄닌 추출물의 열 발색공정에 의한 면직물 염색)

  • Jung, Jong-Suc;Park, Ji-Sun;Kim, Tae-Kyeong
    • Textile Coloration and Finishing
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    • v.20 no.3
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    • pp.25-30
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    • 2008
  • In order to examine the availability of a heating process for persimmon dyeing, the cotton fabrics treated with various concentrations of persimmon extracts were heated at various temperatures and times. The raw and fermented persimmon extracts were used for the coloration. For both extracts, the color strength of fabrics was. increased with the increase of coloration temperature, time, and concentration of the extracts. Considering the practical aspects. and color strength, the temperature around $200^{\curc}C$ and the time longer than 60 minutes can be determined as the. optimum coloration conditions of persimmon extracts onto cotton fabrics. However, somewhat loss of strength by the hearing process seems to be inevitable. The color fastness to washing was excellent for both color change and staining showing a rating of 5.

Effect of Chitosan Pretreatment on the Dyeing of Cotton and Silk Fabrics using Caesalpinia sappan - Effect of the Change in Chitosan Molecular Weight - (키토산 사전 처리가 면과 견직물의 소목 염색에 미치는 영향 - 키토산의 분자량 변화에 따른 효과 -)

  • Choi In-Ryu;Kim Jong-Jun;Jeon Dong-Won
    • The Research Journal of the Costume Culture
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    • v.13 no.4 s.57
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    • pp.576-588
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    • 2005
  • The effect of chitosan pretreatment on the dyeing of cotton fiber and silk fiber was investigated. However, it has been difficult to evaluate the effect of the chitosan precisely, since the characterization of the molecular weight and effect of the degree of deacetylation were not elucidated for the application. The treatment effect may change diversely since the chitosan solution viscosity differs a lot based on the chitosan molecular weight. In this study, three chitosan specimens, varying in molecular weight, were applied for the fabric pretreatment in order to investigate the effect of chitosan molecular weight. Also, in order to maximize the efficacy of the chitosan, highly deacetylated chitosan specimens, meeting the deacetylation degree of $100\%$, were selected far the application. The air-permeability change according to the chitosan molecular weight change, influence on the mordanting, color change, and wash fastness change were investigated.

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Dyeing Properties of Ultra-fine Nylon Suede Non-woven Fabric with Sulphur Black Dye by Pad-steam Process (흑색 황화염료와 초극세사 나일론 스웨이드 부직포 직물의 Pad-steam 염색 및 염색성 평가)

  • Kim, Min Seok;Jung, Dae-Ho;Lee, Mikyung;Ko, Jae Wang;Lee, Jeong Hoon;Lee, Seung Geol
    • Textile Coloration and Finishing
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    • v.29 no.4
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    • pp.211-222
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    • 2017
  • In this study, we investigated the dyeing properties of the ultra-fine nylon suede non-woven fabric with Sulphur black dye regarding to the effect of dye concentrations, reducing agent contents, sodium carbonate contents, antioxidant contents, immersion temperature and exposure time in air by pad-steam process. The optimal conditions of dyeing for the ultra-fine nylon suede non-woven fabric were determined with dye concentration of 30% o.w.f., reducing agent content of $9{\sim}13g/{\ell}$, sodium carbonate content of $1{\sim}4g/{\ell}$, antioxidant content of $1{\sim}5g/{\ell}$, immersion temperature of $70^{\circ}C$, exposure time of 20 minutes in air and immersion time of 1 minute, respectively. Meanwhile, the colorfastness to washing, the colorfastness to light, and the colorfastness to perspiration for dyed ultra-fine nylon suede non-woven fabric were achieved in the range of 4-5 grades. The formaldehyde and arylamine were not detected on the ultra-fine nylon suede non-woven fabric by KC tests.

Study on the Mechanical Properties of Polyketone Fiber according to Coating Process for Technical Textile (산업용 폴리케톤 섬유의 코팅 가공에 따른 기계적 물성에 관한 연구)

  • Kim, Sang Yong;Jeon, Jae Woo;Kwak, Dong Sub;Lee, Won;Lee, Deuk Jin;Whang, Sun Dong;Do, Sung Jun
    • Textile Coloration and Finishing
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    • v.27 no.4
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    • pp.334-339
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    • 2015
  • Polyketone fiber, a newly developed high strength fiber, has a tenacity and modulus similar to the paramid fiber, and can be used for reinforcing mechanical rubber goods(MRG), such as tires, hoses, and technical textiles. In addition, aliphatic polyketone, which has excellent strength, modulus, chemical stability and reasonable price, is being developed only in South Korea. It will be expected for replacement of super fiber such as aramids and increasing the technical textile market share. This paper surveys the mechanical properties of polyketone fiber yarn for technical textiles. For this purpose, two kinds of yarns are prepared, mechanical properties of coated and uncoated polyketone yarns such as tensile strength, elongation and modulus were examined before and after weather resistance test(temperature $60^{\circ}C$, humidity 60%, amount of power $0.67w/m^2$). The differences of mechanical properties between uncoated and coated yarns for high functional technical textiles and composite materials are estimated through this study.