• Title/Summary/Keyword: Dyeing, Fastness

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The development of dyeing process by ultrasonics wave for clean technology (초음파를 이용한 피혁의 친환경 염색공정 기술 개발)

  • Kim, W.J.;Kim, H.H.;Kim, S.C.;Park, K.S.
    • Clean Technology
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    • v.10 no.1
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    • pp.19-25
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    • 2004
  • The leather was fixed with various colors through the dyeing process in leather manufacturing. During the dyeing process, the amount of 30~50% dyestuff which were not bonded with leather drained with waste water. These dyestuff raise lots of environmental problems, so technology for improving the fixing effect, levelling effect and penentration effect with the use of small amount of dyestuff has been required. Also, insufficient color fastness level 2~3 grade for common natural leather needs to be improved at the same time. Accordingly, the use of ultrasound(us) in dyeing process has decreased the amount of dyestuff and obtained the smooth permeability effect. So, we could find that the reduction of amount of dyestuff in wastewater led to decrease in environmental trouble caused by leather waste water with severe contamination degree and improved fastness up to 0.5 grades.

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Hair-dyeing by using Pomegranate Hull Extract (석류 과피 추출물을 이용한 모발염색)

  • Cho, A-Rang;Shin, Youn-Sook;Yoo, Dong-Il
    • Textile Coloration and Finishing
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    • v.20 no.6
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    • pp.42-50
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    • 2008
  • The objective of this study is to investigate the efficacy of pomegranate hull colorant as a natural hair coloring dye. The extract of pomegranate hull was concentrated and freeze-dried to get colorant powder. Effect of dyeing condition and mordanting on the dye uptake of hair by using Al, Fe, Cu, Cr, Sn compounds, color change and colorfastness were explored. In addition, tensile strength was measured and the surface of the hair was observed. Dye uptake of hair measured by K/S value (400 nm) indicated that ionic bonding seems to be involved in the sorption of pomegranate colorant to hair. Maximum sorption was obtained at pH 3.5 and the concentration of 50% (on the weight of hair, o.w.h.). Acidic dyeing condition (pH $3.5{\sim}5.0$) showed yellow color however alkaline dyeing condition (pH $7{\sim}11$) gave reddish yellow color. Pomegranate hull colorant produced greyish brown color on hair and the hair mordanted with Fe showed dark brown color. Mordants except Fe did not increase dye uptake significantly. Mordants except Cu increased light fastness and mordants except Cr increased washing fastness level slightly. According to SEM observation and the tensile strength retention measurement, the mordant dyed hair gave more damage to hair by ultraviolet light and washing than the hair dyed without mordanting. Experimental results of K/S value and colorfastness(light and washing) supported that pomegranate hull colorant without mordanting can be used as a semi-permanent natural hair coloring dye.

Dyeing Properties of Sea-Island Type PET nanofilament (해도형 폴리에스테르 나노필라멘트 섬유의 염색특성)

  • Jeong, Cheon-Hee;Min, Mun-Hong;Nam, Sung-Wook;Choe, Jong-Deok;Yi, Jong-Woo
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2012.03a
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    • pp.117-117
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    • 2012
  • Dyeing and fastness properties of 800nm sea-Island type PET nanofilament fabrics have been investigated. The dye uptake of nanofilament commended at lower temperatures and showed faster rate of dye uptake. The build up and wet fastness propertied of disperse dye on nanofilament were relatively poor since the more dye was needed to achieve a given depth of shade due to the large surface area.

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Preparation of Waterborne Polyurethanes Containing Polycarbonate Component and Their Applications to the Impregnation Finishing for Artificial Leathers (폴리카보네이트 성분을 포함하는 수분산 폴리우레탄의 제조와 인공피혁 함침가공에의 응용)

  • Lee, Kyoung-Woo;Ko, Jae-Hoon;Shim, Jae-Yun;Kim, Young-Ho
    • Polymer(Korea)
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    • v.33 no.2
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    • pp.175-182
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    • 2009
  • Waterborne polyurethanes (WPUs) based on isophorone diisocyanate and mixed polyols of poly(tetramethylene glycol) (PTMG)/polycarbonate diol (PCD) were synthesized. The variation of mechanical and dyeing properties and alkali resistance of the WPU films were analyzed according to the polycarbonate (PC) content. The tensile strength of the films increased and the elongation at break decreased with the PC content in the WPU film. The incorporation of PC component in the WPU film did not affect the alkaline hydrolysis behavior. The synthesized WPU solutions were used as impregnating resins for the production of PET artificial leathers. The prepared WPU resins showed the good color fastness to washing, rubbing, and light of the artificial leather fabrics. The improvement of the properties became greater with the PC content in the WPU resin.

Synthesis of Azo Based Disperse Dyes for Dyeing Polyester Fiber in Supercritical Carbon Dioxide (초임계 유체 염색용 아조계 분산염료 합성 및 PET 섬유에 대한 염색 특성 연구)

  • Shin, Seung-Rim;An, Kyoung-Lyong;Lee, Sunhye;Ko, Eunhee;Lee, In-Yeol;Kim, Changil;Jun, Kun
    • Textile Coloration and Finishing
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    • v.33 no.1
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    • pp.10-23
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    • 2021
  • In order to synthesize the dye suitable for supercritical carbon dioxide(ScCO2) dyeing, a series of azo based disperse dyes were prepared using various aniline derivatives as diazo components and indol derivatives as coupling components. Dyeing process in ScCO2 of the synthesized dyes was performed on PET fiber at 120℃ for 2 hrs under 250bar pressure with 0.5% o.w.f. of dye concentration. The absorption maxima varied from 400 to 580nm depending on the substituted groups in aniline derivatives and the indol derivatives. The dyes showed high molar extinction coefficients(ε) of 27,000~61,000M-1cm-1. Dyed PET fiber exhibited excellent brightness and good light, washing and perspiration(acid/alkali) fastness properties.

Photo-grafting Dyeing of Wool Fabrics with ${\alpha}$-bromoacrylamide reactive dye (반응성 염료를 이용한 양모직물의 광그라프트 염색)

  • Dong, Yuanyuan;Jang, Jin-Ho
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2011.03a
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    • pp.31-31
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    • 2011
  • Lanasol dyes containing ${\alpha}$-bromoacrylamide or ${\alpha},{\beta}$-dibromopropionylamide group are used for wool dyeing. They are normally applied to wool under pH 4.5 to 6.5 at $100^{\circ}C$. Although wool fabric can be dyed to obtain deep colour, high light and wet fastness, the dyeing processes need long dyeing time at high temperature, with salt addition, which inevitably causes environmental problems. Grafting is a modification method for textile where monomers are covalently bonded onto the polymer chain. It can be initiated by ozone, ${\gamma}$ rays, electron beams, plasma, corona discharge and UV irradiation. Coloration by UV-induced photografting exhibits several advantages such as fast reaction rate, energy saving, simple equipment, easy exploitation and environmentally friendliness. Also it requires much lower energy compared to the conventional dyeing and less damage to the substrate. In this study, a direct sequential UV-induced photografting onto wool fabrics was discussed. To understand the graft polymerization mechanism further, several characterization methods were used. Moreover, the effects of several principal factors on the graft photopolymerization were investigated. Furthermore, the colorfastness results were compared with conventional dyeing methods.

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A Study on Dyeability of Cotton Fabrics -Effects of Dyeing on Water Repellent Finished Cotton- (면직물의 염색성에 관한 연구 -발수가공포의 염색효과-)

  • 장지혜
    • Journal of the Korean Home Economics Association
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    • v.35 no.3
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    • pp.115-124
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    • 1997
  • In this study, Water Repellent Finish was carried out before dyeing on cotton fabrics. It was aimed to improve on dyeing properties of cotton fabrics with direct dye. The results obtained were summerized as follows: 1. The K/S value of water repellent finished cotton fabrics increased. This phenomena in water repellent finished cotton fabrics were much more noticiable than unfinished cotton fabrics. 2. The color fastness(light, washing, and rubbing) of water repellent finished cotton-dyed were worse than those of unfinished cotton-dyed with direct dye. △E of water repellent finished cotton fabrics wasn't showed significant difference as compared with that of unfinished cotton fabrics. 3. The water repellency of finished cotton after dyeing got down from 100 to 70. That of finished-cotton before dyeing was 100. 4. Moisture regain, stiffness and weight of finished cotton fabrics were not almost differenciated with unfinished cotton fabrics. Moreover, the tensile strength of finished cotton fabrics was increased compared to that of unfinished cotton fabrics. As conclusion, according to the above results when the cotton fabrics were dyed with direct dye, it was much more effective that water repellent finished cotton fabrics were dyed rather than trational process, that is pre-dyeing after-finishing even if, by low liquor ratio. The physical properties of fabrics were maintained or increased.

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Dyeing Characteristics of Herb Dyed Fabrics Treated with Mordants - Focused on Sage and Rosemary Extract - (매염제 처리에 의한 허브 염색직물의 염착 특성 - 세이지와 로즈마리 추출물 중심으로 -)

  • Goo, Sin Ae;Bae, Hyun Sook
    • Fashion & Textile Research Journal
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    • v.22 no.1
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    • pp.119-129
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    • 2020
  • Unlike synthetic dyes, natural dyes do not affect the human body or create atmosphere pollution that are also mothproof, antibiotic and sterilized. This study examined the changes in dye adsorption properties according to mordant types and mordanting method to qualify trends using sage and rosemary extracts. Dyeability of sage extract is often similar to rosemary extract regardless of dyeing conditions. Dyeing properties of herb colorants on cotton, silk and wool fiber and effect of dyeing conditions on dye uptake were also compared. Dyed fabric showed a yellowish color and the dyeing affinity was somewhat good with rosemary extract. The surface color of the dyed fabrics was darkened by mordant treatment. The K/S value of herb colorants of protein fiber was higher than cellulose fiber. The concentration of mordant having the highest dyeing affinity was different from the mordant type. Regardless of the type of fiber, the K/S value of premordanting was the highest in mordanting method, and the K/S value of simultaneous mordanting indicated no noticeable mordant effect. The fastness of washing of silk fabric was reduced the most by mordant treatment. The lightfastness was reduced in Al mordant treatment regardless of the type of fiber. The lightfastness of wool increased somewhat by mordant treatment.

Dyeability of Low-melting Hybrid Polyester at Low Temperature (저융점 폴리에스테르 복합사의 저온 염색성)

  • Hwang, Ji-Hyun;Kim, Chang-Nam;Ma, Jin-Suk;Oh, Hae-Sun;Yoon, Nam-Sik
    • Textile Coloration and Finishing
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    • v.24 no.2
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    • pp.113-120
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    • 2012
  • Jacquard floor covering could be prepared from low-melting/regular sheath-core hybrid polyester, where the fiber is dyed in yarn state. With regard that the expected high shrinkage of the hybrid polyester in water makes problems in yarn dyeing, low-temperature dyeing properties of the hybrid polyester were studied. The rate of shrinkage of low-melting hybrid polyester exceeds 9% in hot water above $90^{\circ}C$, at such condition, cheese yarn dyeing is very difficult. Although disperse dyes exhaust in a relatively high speed on low-melting hybrid polyester, diffusion of these dyes to the core regular polyester was extremely slow under $90^{\circ}C$. Foron Blue E-BL 150, an anthraquinone E-type disperse dye, showed appreciable diffusion after 48hrs dyeing at $90^{\circ}C$. The fastness to rubbing and drycleaning were improved by one grade after reduction cleaning.

Study on Dying with Yellow Flowers - From Wild Flowers - (황화(黃花) 식물의 염색연구 - 들꽃을 중심으로 -)

  • Woo, Hyun-Ri;Kim, Sun-Mee
    • Journal of the Korea Fashion and Costume Design Association
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    • v.10 no.2
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    • pp.1-10
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    • 2008
  • Yellow, one of the five direction colors, is a prevailing color in artificial dyeing. The color has implied and symbolized wealth and power since ancient times. Yellow has been extracted mainly from flowers. Shapes, colors and scents of flowers not only have enriched emotional mentality, but have also been used for medicinal herbs, and dyestuff since the very old days. Coloring matter from flowers is very beautiful, and it has been used for dyeing textiles. Textile dyeing have formed a color culture and developed a dyeing culture since ancient times. Flowers include a variety of color matters, and can be easily obtained around us. Therefore, flowers have been a widespread natural dyestuff. It is well known that beautiful colors can be extracted from flowers, which are eco-friendly and non-polluting. In addition, flowers are easily provided. In this study, yellow wild flowers were selected as subjects. Seven flowers with color matters distiguishable through the naked eye were used: Korean forsythia, golden-wave, Mongolian dandelion, sunflower, conflower, chelidonium and chrysanthemum. Coloring matters were extracted from the seven flowers, which have been used to create a variety of colors through various dyestuffs; and the colors have been analyzed and presented. Dyeing and coloring matters were tested and analyzed, and several types of dyestuff had also been scientifically measured after treatment.

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