• Bulletin of the Korean Chemical Society
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• 제31권4호
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• pp.989-998
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• 2010

The titled dye of DBPI gives amplified spontaneous emission (ASE) with maximum at 580 nm upon pumping by nitrogen laser (${\lambda}_{ex}\;=\;337.1\;nm$). The ground state absorption cross section (${\sigma}_A$) and emission cross section (${\sigma}_E$) as well as effective emission cross section(${\sigma}^*_E$) have been determined. The electronic absorption spectra of DBPI were measured in ethanol and tetrahydrofuran at room and low temperature. DBPI displays molecular aggregation in water. The photochemical reactivity of DBPI was also studied in carbon tetrachloride upon irradiation with 525 nm light. The electrochemical investigation of DBPI dye has been carried out using cyclic voltammetry and convolution deconvolution voltammetry combined with digital simulation technique at a platinum electrode in 0.1 mol/L tetrabutyl ammonium perchlorate (TBAP) in two different solvents acetonitrile ($CH_3CN$) and dimethylformamide (DMF). The species were reduced via consumption of two sequential electrons to form radical anion and dianion (EE mechanism). In switching the potential to positive direction, the compound was oxidized by loss of two sequential electrons, which were followed by a fast dimerization and/or aggregation process i.e $EC_{dim1}EC_{dim2}$ mechanism. The electrode reaction pathway and the chemical and electrochemical parameters of the investigated compound were determined using cyclic and convolutive voltammetry. The extracted electrochemical parameters were verified and confirmed via digital simulation method.

• 방사성폐기물학회지
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• 제19권4호
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• pp.517-532
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• 2021

Safe geological disposal of spent nuclear fuel (SNF) requires knowledge of the deep hydrochemical characteristics of the repository site. Here, we conducted a set of deep hydrochemical investigations using a 750-m borehole drilled in a model granite system in Wonju, South Korea. A closed investigation system consisting of a double-packer, Waterra pump, flow cell, and water-quality measurement unit was used for in situ water quality measurements and subsequent groundwater sampling. We managed the drilling water labeled with a fluorescein dye using a recycling system that reuses the water discharged from the borehole. We selected the test depths based on the dye concentrations, outflow water quality parameters, borehole logging, and visual inspection of the rock cores. The groundwater pumped up to the surface flowed into the flow cell, where the in situ water quality parameters were measured, and it was then collected for further laboratory measurements. Atmospheric contact was minimized during the entire process. Before hydrochemical measurements and sample collection, pumping was performed to purge the remnant drilling water. This study on a model borehole can serve as a reference for the future development of deep hydrochemical investigation procedures and techniques for siting processes of SNF repositories.

• 한국광학회지
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• 제10권2호
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• pp.162-168
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• 1999

본 연구에서는 개념적으로 기생 발진을 비롯한 증폭기의 오동작 가능성을 최소화하고 좁은 선폭의 연속파 레이저를 펄스 증폭하기 위한 목적으로 새로운 구조를 갖는 사중경로 색소 레이저 증폭기를 제안하고 실험적으로 구현하였다. 펌핑 레이저의 펄스 에너지가 5.6 mJ이고 연속파 레이저의 입력 강도 100 mW일 때, 사중경로 증폭기는 약 130 MHz(FWHM)의 선폭과 1.5 mJ의 에너지를 갖는 레이저 펄스를 출력하였으며, 이는 약 2$\times$106 이상의 높은 증폭 이득과 27%의 에너지 효율에 해당하는 것이다. 사중경로 증폭기 내에 회절격자를 사용하면, 파장 선택 소자가 없는 보통의 증폭기와 비교할 때 총 출력 에너지가 4% 정도 증가됨과 동시에 ASE가 차지하는 비율이 10배 이상 감소하여, 총 출력 빔에 대해 ASE 에너지가 1.5% 이하로 억제된다.

• Journal of Mechanical Science and Technology
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• 제15권12호
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• pp.1853-1859
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• 2001

An experimental study is presented for a flow field in a two dimensional wavy channels by PIV. This flow has two major applications such as a blood flow simulation and the enhancement of heat transfer in a heat exchanger. While the numerical flow visualization results have been limited to the fully developed cases, existing experimental results of this flow were simple qualitative ones by smoke or dye streak test. Therefore, the main purpose of this study is to produce quantitative flow data for fully developed and developing flow regimes by the Correlation Based Correction PIV (CBC PIV) and to conjecture the analogy between flow characteristics and heat transfer enhancement with low pumping power. Another purpose of this paper is to examine the onset position of the transition and the global mixing, which results in transfer enhancement. PIV results on the Fully developed and developing flow in a wavy channel at Re=500, 1000 and 2000 are obtained. for the case Reynolds Number equals 500, the PIV results are compared with the finite difference numerical solution.

• 설비공학논문집
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• 제16권4호
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• pp.368-373
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• 2004

A flow field in a passage with periodically converging-diverging cross-section is investigated experimentally by PIV measurement. A tube with a sinusoidally wavy cross section is one of several devices employed for enhancing the heat and mass transfer efficiency due to turbulence promotion and unsteady vortical motion. While the numerical flow visualization results have been limited to the fully developed cases, existing experimental results of this flow were simple qualitative ones by smoke or dye streak test. Therefore, the main purpose of this study is to produce quantitative flow data for fully developed and transient flow regime by the Correlation Based Correction PIV (CBC PIV) and to conjecture the analogy between flow characteristics and heat transfer enhancement with low pumping power. Another purpose of this paper is to examine the onset position of the transition and the global mixing, which results in transfer enhancement. At Re=2000, evidences of the global mixing are captured at 2.5 wavy module through the variation of RMS values and instantaneous velocity plot.

• 한국가시화정보학회지
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• 제22권1호
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• pp.79-84
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• 2024

As microchips' degree of integration is getting higher, its cooling problem becomes important more than ever. One of the promising methods is using fractal microchannel heat sink by mimicking nature's Murray networks. However, most of the related works have been progressed only by numerical analysis. Perhaps such lack of direct experimental studies is due to the technical difficulty of the temperature and heat flux measurement in complex geometric channels. Here, we demonstrate the direct visualization of in situ temperature profile in a fractal microchannel heat sink. By using the temperature-sensitive fluorescent dye and a transparent Polydimethylsiloxane window, we can map temperature profiles in silicon-based fractal heat sinks with various fractal scale factors (a=1.5-3.5). Then, heat transfer rates and pressure drops under a fixed flow rate were estimated to optimize hydrodynamic and thermal characteristics. Through this experiment, we found out that the optimal factor is a=1.75, given that the differences in heat transfer among the devices are marginal when compared to the variances in pumping power. This work is expected to contribute to the development of high-performance, high-efficiency thermal management systems required in various industrial fields.