• Title/Summary/Keyword: Dye dopant

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Interrelation on the Electronic Structure and Spectroscopic-Photoeletric Characteristics in the Cyanine and Merocyanine Dye(II) (Cyanine 및 Merocyanine색소의 분광특성 및 광전특성에 대한 전자구조의 상관관계(II))

  • 손세모
    • Journal of the Korean Graphic Arts Communication Society
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    • v.13 no.2
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    • pp.1-17
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    • 1995
  • Organic thin film electroluminescene devices were fabricated using by molecularly doped method with N,N`-diphenyl-N,N`-bis(3-methylphenyl)-1,1`-biphenyl-4,4`-diamine(TPD) as a hole transport material, tris(8-quinolinolate) aluminium(III)(Alq3) as an emitting and electron transport agent, fluorescent squarylium(SQ) dye as a dopant, and poly(methylmethacrylate) as polymer materials. A cell structure of ITO/TPD-PMMA/Alq3-dopant/Mg was employed. The EL spectrum covers a wide range of the visible region and orange emission os observed. Two peaks at 520 and 660nm correspond to the emissions 620nm Alq3 and SQ dye, respectively.

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Thermo-Recording for The Composite System of (Disk-Like Molecules and Liquid Crystals)

  • Jeong, Hwan-Kyeong
    • Journal of the Korean Applied Science and Technology
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    • v.19 no.3
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    • pp.245-249
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    • 2002
  • A (disk-like liquid crystal (DLC) monomer/liquid crystals(LCs)/chiral dopant/dichroic dye) composite was irradiated with ultraviolet (UV) light. The (DLC network/LCs/chiral dopant/dichroic dye) was formed in the homeotropically oriented smectic A(SA) phase by the surface orientation treatment and the electric field. A focal-conic texture exhibiting strong light scattering appeared in the heat-induced chiral nematic phase(N${\ast}$) of the composite upon heating. Thermo-recording in the composite system has been realized by using a He-Ne laser. The laser irradiation was induced the phase transitions from SA phase to chiral nematic(N${\ast}$) phase in the composite system.

Light Emitting Characteristics of Multi-layer OLEO Fabricated with DCM (DCM 계열을 이용한 OLED의 전기적인 발광 특성에 관한 연구)

  • Chun, Min-Ho;Yun, Suk-Won;Lim, Sung-Tack;Shin, Dong-Myung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.04b
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    • pp.57-60
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    • 2002
  • In generally, the guest-emitter doped system has been reported to give a bright electroluminescence(EL). The purpose of using doped system is to improve for increasing lifetime and efficiency, and tuning multicolor light. This indicates an enhanced electron-hole recombination rate in emitting layer. The purpose of this study is to obtain the high performance EL devices for flat panel display with red emission. We fabricated EL devices using the guest-host system. where DCM derivatives were taken as a dopant. The devices are fabricated in multilayer system with various concentration of the dopant (red light emitting dye). We measured the I-V characteristics and EL spectra from these devices. and we compared with photoluminescence(PL) quantum yield among the DCM derivatives. The emission mechanism of devices is participated in energy transfer. The energy transfer from these hosts to DCM generates luminescence spectra that vary from yellow red to red, depending on DCM derivatives. Absorption and emission spectra of organic materials composing the devices depend on the emission materials doped with the DCM derivatives. We demonstrated that the high EL efficiency can be achieved by doping host material with DCM derivatives and molecular steric structures

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Study of White Light Emission with Three or Two color in Multi Organic Emitting Layers with DCJTB, DPVBi and Coumarin6

  • Yoo, Seok-Jun;Lee, Chan-Jae;Kim, Dong-Won;Han, Jeong-In
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08b
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    • pp.1433-1436
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    • 2007
  • Using a blue emitting DPVBi material and red dopant DCJTB, WOLEDs with and without green emitter C6 added in ETL or HTL have been fabricated. The chromaticity color index of WOLEDs without C6 depends strongly on the doping concentration. In addition, manipulating thickness of emitting layer is similar effect such as controlling weight concentration of dopant. While the white color of WOLEDs with C6 added in ETL or HTL depend on position of C6. WOLED of three colors added green dye have been shown turn-on voltage of 3.25V, and EL efficiency 3.05cd/A @9V, $8102\;cd/m^2$, CIE coordinates (0.30, 0.32).

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Effects of Li Dopant on Electrical Properties and Microstructure of ZnO Ceramics (Li Dopant가 ZnO 세라믹스의 전기적 특성과 미세 구조에 미치는 영향)

  • Jun, Min-Chul;Koh, Jung-Hyuk
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.4
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    • pp.282-285
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    • 2012
  • It is well known that Zinc Oxide (ZnO) is an attractive material for its various applications. ZnO has been mostly used as a transparent conducting oxide in liquid crystal displays, solar cells due to its advantages of low cost, high productivity, and excellent electrical conductivity. Notably, flexible-dye-sensitized solar cells (DSSCs) based on polyethylene terephthalate (PET) substrates require low temperature sintering processing conditions. Therefore, low temperature processing conditions have been strongly required for transparent conducting film applications. In this paper, we prepared low temperature-sintered ZnO ceramics employing Li as a sintering aid.

Luminance Characteristics of a Novel Red-Light-Emitting Device Based on Znq2 and Dye

  • Cho, min-Jeong;Park, Wan-Ji;Lee, Jeong-Gu;Lim, In-Su;Lim, Kee-Joe;Kim, Hyun-Hoo
    • Transactions on Electrical and Electronic Materials
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    • v.3 no.2
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    • pp.16-19
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    • 2002
  • In this study, a novel red emitting organic electroluminescent (EL) device was fabricated with the bis(8-oxyquinolino)zinc II (Znq2) doped dye as an emitting layer. The Znq2 was synthesized successfully from zinc chloride (ZnC1$_2$) as an initial material. Then, we fabricated the red organic EL device with a dye (DCJTB) doped and inserted Znq2 between emission layer and cathode for increasing EL efficiency. The hole transporting layer is a N,N'-diphenyl-N,N'-bis-(3-methylphenyl)-1,1'-diphenyl-4,4-diamine (TPD), and the host material of emission layer is Znq2. And the electrical and luminance characteristics of the device were measured. We found that the EL device with Znq2 inserting layer results in the increasing luminance efficiency.

A Study on Electrical and Optical Properties of Dye Doped Organic Electroluminescent Devices (색소 Dopant에 의한 청색 발광 소자의 전기적, 광학적 특성 연구)

  • 이무상;최상건;노병규;오환술
    • Proceedings of the IEEK Conference
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    • 2000.11b
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    • pp.269-272
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    • 2000
  • In this paper, we was fabricated and analyzed a blue organic electroluminescent devices with the organic dye, such as 1,1,4,4-Tetraphenyl-1,3-butadi-ene(TPB). The device was made by simultaneously co-depositing two materials. The device structure was composed of the ITO glass, TPD, Alq$_3$doped TPB, and aluminum(A1) electrode. Carrier injection from the two electrodes was significant]y observed and the blue light in EL spectrum, with an emission maximum at 462nm, was triggered at a driving voltage of 11V.

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Investigation on Femtosecond Laser Processing of Polymeric Thin Films (펨토초 레이저를 이용한 폴리머 박막 재료 초미세 공정에 관한 연구)

  • Jeoung S.C.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2006.05a
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    • pp.669-670
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    • 2006
  • Two-photon absorption coefficient of a series of dyes in polymer thin films was determined by measuring the femtosecond laser ablation threshold. The threshold value of polymeric thin films decreased gradually when the dopant increased. The two-photon absorption coefficient of the dye molecules dispersed in the polymer film was estimated by using the theoretical relationship between the ablation threshold of the blended polymeric thin films and the dye concentration. The relative values of two-photon absorption cross-section are in good agreement with those measured in solution. On the other hand, the absolute values are smaller than the latter.

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Effects of Doping in Organic Electroluminescent Devices Doped with a Fluorescent Dye

  • Kang, Gi-Wook;Ahn, Young-Joo;Lee, Chang-Hee
    • Journal of Information Display
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    • v.2 no.3
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    • pp.1-5
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    • 2001
  • The effect of doping on the energy transfer and charge carrier trapping processes has been studied in organic light-emitting diodes (OLEDs) doped with a fluorescent laser dye. The devices consisted of N,N'-diphenyl-N,N'-bis(3-methylphenyl)-1,1-biphenyl-4,4'-diamine (TPD) as a hole transporting layer, tris(8-hydroxyquinoline) aluminum ($Alq_3$) as the host, and a fluorescent dye, 4-dicyanomethylene-2-methyl-6-[2-(2,3,6,7-tetrahydro-1 H,5H-benzo[i,j]quinolizin-8-yl) vinyl]-4H-pyran) (DCM2) as the dopant. Temperature dependence of the current-voltage-luminescence (I-V-L) characteristics, the electroluminescence (EL) and photoluminescence (PL) spectra are studied in the temperature ranging between 15 K and 300 K. The emission from DCM2 was seen to be much stronger compared with the emission from $Alq_3$, indicative of efficient energy transfer from $Alq_3$ to DCM2. In addition, the EL emission from DCM2 increasd with increasing temperature while the emission from the host $Alq_3$ decreased. The result indicates that direct charge carrier trapping becomes efficient with increasing temperature. The EL emission from DCM2 shows a slightly sublinear dependence on the current density, implying the enhanced quenching of excitons at high current densities due to the exciton-exciton annihilation.

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Red OLEDs containing the dotted-line doped layer structure in its emitting region.

  • Lee, Chang-Min;Han, Jeong-Whan
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.612-615
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    • 2004
  • We present an extremely high efficient red organic light-emitting diodes (OLEDs) using a fluorescent dye 4-(dicyanomethylene)-2-tert-butyl-6-(1,1,7,7-tetramethyljulolidyl-9-enyl)-4H-pyran (DCJTB) doped into an emitting region which consists of multiple pairs of a doped and an undoped layer. An emitting region of OLEDs composes of a tris-(8-hydroxyquinolinato) aluminum (Alq3) codoped with rubrene of 5% wt. or a mixture of Alq3 and rubrene (1:1). The luminance yield of the codoped device and the mixed device are 6.5 cd/A and 9.2 cd/A at 10 mA/$cm^2$, respectively. We have considerably improved the luminance yields of red OLEDs as much as ${\sim}$90% at 10 mA/$cm^2$ compared with that of the device doped with only DCJTB. We attribute it to both the emitting assist dopant (rubrene) and the dotted-line doping structure in an emitting region of OLED.

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