• 제목/요약/키워드: Dye analysis

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A New Ionic Liquid for a Redox Electrolyte of Dye-Sensitized Solar Cells

  • Kang, Man-Gu;Ryu, Kwang-Sun;Chang, Soon-Ho;Park, Nam-Gyu
    • ETRI Journal
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    • v.26 no.6
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    • pp.647-652
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    • 2004
  • A new ionic liquid, 1-vinyl-3-heptylimidazolium iodide (VHpII), was synthesized and applied as a redox electrolyte for dye-sensitized solar cells. The chemical structure of the synthesized VHpII was confirmed using $^1H$ NMR. Thermogravimetric analysis showed that the VHpII was stable for thermal stress of up to $250^{\circ}C$. The energy conversion efficiencies of the VHpII-based dye-sensitized solar cells were investigated in terms of the effect of a lithium iodide addition. A solar cell containing the redox couple of VHpII and iodine showed a conversion efficiency of 2.63% under 1 sun light intensity at AM 1.5. Adding 0.4 M LiI results in a conversion efficiency of 3.63%, which was an improvement of about 40%. The increased conversion efficiency was ascribed to an increase in external quantum efficiency.

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A Study on the Functional Improvement of Natural Dyed Fabrics (천연염색 직물의 기능성 향상에 관한 연구)

  • Seo, Myoung-Hee
    • The Korean Journal of Community Living Science
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    • v.19 no.2
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    • pp.213-221
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    • 2008
  • In this study, a dye bath was made using a mixture of distilled water, pine needle extract and bamboo vinegar. Analysis and comparison of various functions of cotton fabrics dyed using bamboo charcoal and gardenia seeds in distilled water and in the dye bath mixture were done. The summary of the results is as follows. Comparing bamboo vinegar and the pine needle extracts, the bamboo vinegar had a higher antibacterial function. In the case of natural dyeing cotton fabrics using bamboo charcoal and gardenia seeds, the additional amount of dyestuff for optimization is 10 g and 20 g respectively per 1 liter of distilled water. The suitable dye bath mixture ratio of distilled water, pine needle extract, and bamboo vinegar considering functionality and economical efficiency of dyed fabrics is 4:3:3. By using the mixture made in this study as a dye bath, improved antibacterial function, deodorization, and colorfastness can be obtained more than distilled water alone.

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Analysis Thermal Performance of PV/Thermal Collector with Dye-sensitized Solar Cell Module (염료감응형태양전지 모듈 적용 PVT 집열기의 열적 성능 분석)

  • Jang, Han-Bin;Mun, Jong-Hyeok;Gang, Jun-Gu;Kim, Jin-Hui;Kim, Jun-Tae
    • Proceedings of the Korean Society for Emotion and Sensibility Conference
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    • 2009.11a
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    • pp.273-276
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    • 2009
  • Photovoltaic-thermal(PVT) collectors are a combination of photovoltaic modules with solar thermal collectors, forming one device that receives solar radiation and produces electricity and heat simultaneously. Of various PV modules, dye-sensitized solar cell(DSC) is a relatively new type of solar cell technology that can transmit light while they can generate electricity. With this aspect, DSC can be applied into solar thermal collectors. The object of this study is to evaluate the thermal performance of PVT collector with DSC. The thermal performance of the DSC PVT combind collector was measured in outdoor conditions with the solar radiation of over $700W/m^2$. In this study, the PVT collector with the 30% light transmittance of DSC achieved its thermal efficiency of about 36%.

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Biological Decolorization Characteristics of Dyeing Wastewater (염색폐수의 생물학적 색도제거 연구)

  • Kim, Mee-Kyung;Seo, Sang-Jun;Shin, Eung-Bai
    • Journal of Korean Society on Water Environment
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    • v.22 no.2
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    • pp.333-341
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    • 2006
  • The concept for the decolorization in biological dye wastewater treatment systems is based on anaerobic treatment, for the reductive cleavage of the dyes' azo linkages, in combination with aerobic treatment, for the degradation of the products from azo dye cleavage, aromatic amines. Batch tests were conducted to examine the conditions and the factors affecting biological treatment of dye wastewater. From the tests, the removal efficiencies of organics and colors of dyeing wastewater were improved to $COD_{Cr}$ 27% and color 9% by injecting 10% of the domestic wastewater as a cosubstrate, and $COD_{Cr}$ 30%, color 22% with 30% injection of domestic wastewater. Therefore it was proved that decolorization efficiency is demonstrated with domestic wastewater as a cosubstrate. The analysis of aromatic amines in wastewater showed that decolorization was achieved by cometabolism while aromatic amines were produced by cleavage of azo bonds under anaerobic conditions and these products were removed in an aerobic tank subsequently.

Analysis of Panax ginseng Polysaccharide by Alcian Blue Dye (알시안블루 색소를 이용한 인삼다당체의 함량 분석)

  • 한용남;김선영
    • Journal of Ginseng Research
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    • v.16 no.2
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    • pp.105-110
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    • 1992
  • Polysaccharide contents in Panax ginseng roots were evaluated by a spectrophotometry, utilizing the complex formation of ginseng polysaccharide with alcian blue dye in 50 mM ammonium biphos-phate, pH 4.2. The polysaccharide content in red ginseng was about three times higher than that in fresh ginseng when both were extracted with water, and increased about two times when red ginseng was extracted with an alkaline solution. The determination of polysaccharide in various parts of ginseng revealed that main roots contained the component more than fine roots. Fresh ginseng sections stained by the dye showed polysaccharide mainly was found in cortex and combium but not in epidermis.

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The Surface Analysis of the Merocyanine Dye LB film using Optical system (광학시스템을 이용한 메로시아닌 색소 LB막의 표면 모폴로지 해석)

  • Kang, Ki-Ho;Shin, Hoon-Kyu;Chang, Jung-Soo;Kwon, Young-Soo
    • Proceedings of the KIEE Conference
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    • 2000.07c
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    • pp.1714-1716
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    • 2000
  • We fabricated the optical system of merocyanine dye using Langmuir-Blodgett(LB) technique because quite uniform orientation could be obtained, which is one of the most important factors to affect to its optical characteristics. The resonance frequency and other electrical parameters at the parallel resonance state were measured using the impedance analyser(HP 4294 A). Also the morphological changes of dye molecules after UV irradiation were observed using AFM. The parallel resonance frequency and resistance by electrical equivalent circuit were decreased with the UV irradiation and these aspects are different from general mass adsorption process. Therefore the structural changes of dye molecules are being considered, that is, the aggregated molecules become dissociated. It indicates that the shifts of the resonance frequency and the others occurred without mass absorption.

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Physical-based Dye-sensitized Solar Cell Equivalent Circuit Modeling and Performance Analysis (물리 기반의 염료 감응형 태양전지 등가회로 모델링 및 성능 분석)

  • Wonbok Lee;Junhyeok Song;Hwijun Choi;Bonyong Gu;Jonghwan Lee
    • Journal of the Semiconductor & Display Technology
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    • v.22 no.3
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    • pp.67-72
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    • 2023
  • In this paper, a dye-sensitized solar cell (DSSC), one of the representative third-generation solar cells with eco-friendly materials and processes compared to other solar cells, was modeled using MATLAB/Simulink. The simulation was conducted by designating values of series resistance, parallel resistance, light absorption coefficient, and thin film electrode thickness, which are directly related to the efficiency of dye-sensitized solar cells, as arbitrary experimental values. In order to analyze the performance of dye-sensitized solar cells, the optimal value among each parameter experimental value related to efficiency was found using formulas for fill factor (FF) and conversion efficiency.

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Application of response surface methodology in pes/speek blend NF membrane for dyeing solution treatment

  • Lau, W.J.;Ismail, A.F.
    • Membrane and Water Treatment
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    • v.1 no.1
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    • pp.49-60
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    • 2010
  • In this study, response surface methodology (RSM) was performed in NF membrane process to evaluate the separation efficiency of membrane in the removal of salt and reactive dye by varying different variables such as pressure, temperature, pH, dye concentration and salt concentration. The significant level of both the main effects and the interaction were observed by analysis of variance (ANOVA) approach. Based on the statistical analysis, the results have provided valuable information on the relationship between these variables and the performances of membrane. The rejection of salt was found to be greatly influenced by pressure, pH and salt concentration whereas the dye rejection was relatively constant in between 96.22 and 99.43% regardless of the changes in the variables. The water flux on the other hand was found to be affected by the pressure and salt concentration. It is also found that the model predictions were in good agreement with the experimental data, indicating the validity of these models in predicting membrane performances prior to the real filtration process.

Analysis of Optical Properties of Merocyanine Dye LB Films by Using Q.C.M. (Q.C.M.을 이용한 메로시아닌 색소 LB막의 광학적 특성 분석)

  • Kang, Ki-Ho;Kim, Jung-Myoung;Shin, Hoon-Kyu;Chang, Jeong-Soo;Kwon, Young-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.04b
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    • pp.130-133
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    • 2000
  • The optical characteristics of merocyanine dyes have been investigated widely due to their possible application to the high efficiency photo-electric devices. The optical systems are mostly fabricated using vacuum evaporation. casting and Langmuir-Blodgett method and the arrangement and orientation of dye molecules is one of the most important factors in the study on the optical characteristics. In this study. we fabricated the molecular systems through the LB techniques and investigated the optical characteristics of merocyanine dye LB film using the oscillation characteristics of quartz crystal. It was quite interesting behavior that the resistance and frequency shift at the parallel resonance under the UV irradiation.

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Studies on the Oxidative Structural Change of Azo Dye Acid Red 27 by Ozone (O3에 의한 아조염료 Acid Red 27의 산화분해시 구조 변화에 관한 연구)

  • Baek, Mi-Hwa;Kim, Dong-Su
    • Journal of Korean Society on Water Environment
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    • v.21 no.6
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    • pp.564-568
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    • 2005
  • The structural change of azo dye (Acid Red 27) by oxidation with ozone has been investigated using FT-IR and $^1H$ NMR. The solution pH was observed to decrease during oxidation reaction, which was considered to be due to the generation of several organic and inorganic acids as the result of the decomposition of azo compound. The FT-IR analysis showed that changes of specific absorption bands of Acid Red 27 were observed after ozonation. When azo dye was oxidized by ozone, several new peaks were shown to appear by $^1H$ NMR analysis and the peaks were generally shifted to the direction of up field. This was presumably due to the breakage of benzene ring contained in the molecular structure of Acid Red 27 by the oxidation and the shape of peaks was shown to change according to the reaction time.