• Title/Summary/Keyword: Durability of electrodes

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A Study on RF High Power Durability of Al-Cu Alloy Electrodes Used in Ladder-type SAW(surface acoustic wave) Filters (Al-Cu 합금 전극막 구조를 갖는 사다리형 SAW filter의 RF-고전력 내구성 특성 고찰)

  • 김남철;이기선;서수정;김지수;김윤동
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.5
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    • pp.435-443
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    • 2001
  • As power durable RF SAW filters, AL-(0∼2wt%)Cu alloy multi-layered thin electrodes were deposited on 42° LiTaO$_3$ piezoelectric substrates by magnetron sputtering process, and then ladder-type RF SAW filters, satisfying the electrical specification of CDMA transmission band, were fabricated through optimizing SAW resonator structures. The temperature of film electrodes in SAW filter was increased with RF power, and reached the maxima to cause a failure of SAW filters at the cut-off frequencies of the RF filter band. As RF power increases, the electrodes of Al-Cu alloy showed higher power durability than that of pure Al. The multi-layer laminated film of Al-1wt.% Cu/Cu/Al-1wt%Cu resulted in the best power durability up to 4W of RF power. Every film electrode, however, was destroyed within seconds whenever applying a critical RF power to SAW filters, regardless of the composition and structure of film electrodes. The breakdown of film electrodes under FR power seems to believe due to the fatigue of electrodes caused by repetitive cyclic stress of surface acoustic wave, which is amplified as RF power increases.

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Durability Evaluation of ER Fluids in Hydraulic Control Systems (유압제어시스템 적용을 위한 ER 밸브의 내구성 평가)

  • Kim, Do-Tae;Jang, Sung-Cheol
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.16 no.2
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    • pp.100-105
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    • 2007
  • Electro-rheological(ER) fluid and valve are fabricated and evaluated experimentally in its durability to utilize the hydraulic control systems for long term operation. The two-ports ER valve used in the experiment consist of twelve parallel multi-layer electrodes and provide a restriction to the passage of ER fluid because of the viscous pressure drop and a component induced by the electric field. The durability test of ER valve are performed by measuring the surface roughness of electrodes with variation of an electric field strength and test time(1000 or 1800min.). Also, the shear stress and shear rate are measured to evaluate the durability of ER fluid as function of time. After durability test, ER shear stress increases approximately proportional to the shear rate with applied electric field intensity, In the ER valve, the center line average height roughness(Ra) of copper electrode increases about 1.56 times and ten-point median height roughness(Rz) increases about 2.2 times after the durability test. An understanding of these durability is essential to predicting the service life of ER fluid and valves.

Development of photo-sensitive aluminum electrode materials in PDPs

  • Kim, Chul-Hong;Chae, So-Ra;Hwang, Yun-Tae;Kim, Min-Jae;Heo, Eun-Gi;Lee, Byung-Hak;Park, Yung-Jun;Chung, Chong-In;Kim, Dong-Jun;Cho, Jae-Hwi;Kim, Hyun-Don;Okamoto, Kuninori;Kweon, Tae-Jong
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.269-271
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    • 2009
  • We investigated on the sintering behaviors and electrical properties of photo-sensitive aluminum (Al) electrode materials in plasma display panels. General characteristics of Al electrodes was totally different to that of conventional Ag materials; resistivity was decreased with the increasing of metal particle sizes and the amount of frit content and there is almost no width difference between developed and fired electrodes layers. Microstructures of fired electrodes revealed that Al electrodes had different mechanism on necking between metal particles and making electrical conducting path. Chemical durability (especially, antialkalinity) and adhesion of Al electrodes must be carefully controlled. Nevertheless there are difficulties of processing Al electrodes, we developed and optimized photo-sensitive Al materials as address electrodes without any changes of existing patterning equipment and sintering conditions.

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Effect of Adhesion Strength Between Flexible Substrates and Electrodes on the Durability of Electrodes (유연 기판과 전극 사이의 접합력이 전극의 내구성에 미치는 영향)

  • Doyeon Im;Byoung-Joon Kim;Geon Hwee Kim;Taechang An
    • Journal of Sensor Science and Technology
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    • v.33 no.2
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    • pp.86-92
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    • 2024
  • Flexible electronic devices are exposed to repeated mechanical deformation; therefore, electrode performance is an important element. Recently, a new technology has been developed to improve the adhesion strength between polymer substrates and metal thin films through the cross-linking reaction of bovine serum albumin (BSA) bioconjugation proteins; however, additional performance evaluation as an electrode is necessary. Therefore, in this study, we investigated the effect of adhesive strength between a flexible substrate and a metal thin film on the performance of a flexible electrode. Cracks and changes in the electrical resistance of the electrode surface were observed through outer bending fatigue tests and tensile tests. As a result of a bending fatigue test of 50,000 cycles and a tensile test at 10% strain, the change in the electrical resistance of the flexible electrode with a high adhesion strength was less than 40%, and only a few microcracks were formed on the surface; thus, the electrical performance did not significantly deteriorate. Through this study, the relationship between the adhesion strength and electrical performance was identified. This study will provide useful information for analyzing the performance of flexible electrodes in the commercialization of flexible electronic devices in the future.

The Effect of F-treatment on the Degradation Behavior of the $CaNi_{5}$ and MG-$CaNi_{5}$ Electrodes ($CaNi_{5}$ 및 MG-$CaNi_{5}$ 전극의 퇴화거동에 미치는 불화처리의 영향)

  • Lee, C.R.;Oh, S.J.;Kang, S.G.
    • Korean Journal of Materials Research
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    • v.9 no.6
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    • pp.622-629
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    • 1999
  • Effects of the fluorination in the $K_2$TiF\ulcorner solution and in-situ KF+ KOH electrolyte on the electrochemical charge-discharge properties of CaNi\ulcorner and the Mg-CaNi\ulcorner electrodes were investigated. In-situ fluorination in the KF+ KOH electrolyte compared with pre-fluorination in the$ K_2$TiF\ulcorner solution could improve the electrochemical cycling durability of CaNi\ulcorner and MG-CaN\ulcorner electrodes. The fluorinated layer on the alloy surface by pre-fluorination to improve the activity and anti-corrosion of the electrodes was dissolved in the pure KOH electrolyte during the cycling. The fluorinated layer was formed continuously on the surface of the electrode by thee2N KF addition in the 6N KOH electrolyte. The excess F\ulcorner ion addition in KOH electrolyte could improve the electrochemical cycling durability of CaNi\ulcorner and Mg-CaNi\ulcorner electrode. But, in case of MG-CaNi\ulcorner electrode, the discharge capacity of the electrode was reduced and the poor cycling property was shown with increasing of the MG process times.

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Effect of Thermally Grown TiO2 Interlayer on Chlorine Evolution Efficiency and Durability of Ti/RuO2-PdO-TiO2 Electrodes (열산화법으로 생성된 TiO2 중간보호층이 Ti/RuO2-PdO-TiO2전극의 염소발생 효율 및 내구성에 미치는 영향)

  • Park, Da Jung;Choi, Sung Mook;Lee, Kyu Hwan
    • Journal of the Korean institute of surface engineering
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    • v.51 no.4
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    • pp.207-213
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    • 2018
  • Not only efficiency of chlorine evolution reaction (CER) but also durability namely service life is very important property in dimensional stable anode for Ballast Water Management System (BWMS) for marine ships. Many researchers have been focused on improving efficiency of CER by controlling composition, phase and surface area for a long time, but the efforts to increase durability was relatively small. In this study, we have investigated the effect of $TiO_2$ protective interlayers on efficiency and durability of DSA electrodes. $TiO_2$ protective interlayers were prepared by thermal oxidation at 500, 600 and $700^{\circ}C$ on Ti substrate. And then the DSA electrodes consisting of $Ti/RuO_2-PdO-TiO_2$ were prepared by thermal decomposition method on $TiO_2$ interlayers. The efficiencies of CER of DSA electrodes without $TiO_2$ interlayer and with $TiO_2$ interlayer grown at 500, 600 and $700^{\circ}C$ were 94.19, 94.45, 84.60 and 76.75% respectively. On the otherhand, durabilities were 30, 55, 90 and 65 hours respectively. In terms of industrial aspect, the performance of DSA is considered high efficiency and durability which can correspond to total production of chlorine. If we considered the performance index of DSA as the product of efficiency and durability, performance indices could be recalculated as 28.26, 50.85, 76.14 and 49.89 respectively. As the thermal oxidation temperature increasing, life time were increased remarkerbly, while efficiency of CER was decreased slightly. As a result, DSA electrode with $TiO_2$ interlayer grown at $600^{\circ}C$ has shown about 2.7 times performace of original DSA electrode without $TiO_2$ interlayer.

Fabrication of Ti/IrO2/Ta2O5 Electrode with High Electrochemical Activity and Long Lifetime (전기화학적 활성과 내구성이 높은 Ti/IrO2/Ta2O5 전극 제조)

  • Kim, Da-eun;Yoo, Jaemin;Lee, Yongho;Pak, Daewon
    • Journal of Korean Society on Water Environment
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    • v.33 no.1
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    • pp.34-39
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    • 2017
  • Under a corrosive environment, electrodes that are applied in the water-treatment system need not only very high electrochemical activity for fast reactions, but also high durability for cost saving. Therefore, the fabrication condition of iridium electrodes was examined to produce a more durable iridium electrode in this study. Tantalum was selected as a binder to enhance the durability of the iridium electrode. Investigation of the weight ratio between the catalyst and the binder to improve electrochemical activity was performed. Also, to compare the effect of the different coating amounts of the catalyst, the results of CV (Cyclic Voltammetry) and EIS (Electrochemical Impedance Spectroscopy) were discussed. Furthermore, an ALT(Accelerated Lifetime Test) was designed and applied to the electrodes to determine the conditions for highly durable electrode fabrication.

Durability and Driving Characteristics of Flexible Electronic Paper Display Using CNT Electrode (CNT 전극을 적용한 플렉시블 전자종이 디스플레이의 내구성 및 구동특성)

  • Kim, Young-Cho
    • Journal of Convergence for Information Technology
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    • v.12 no.2
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    • pp.127-133
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    • 2022
  • Two types of charged particle-type electronic paper display panels with electrodes using ITO and CNT are fabricated to compare durability and electro-optical characteristics. The sheet resistance of the ITO electrode is 10 (ohm/sq.), and the sheet resistance of the CNT electrode is 300, 600, 1000 (ohm/sq.), and durability is carried out by impact and flexibility measurements. Variation in case of the ITO electrode begins at shocks of 40 times and curvature radius of 10 mm, and no change is observed in the CNT electrode. The driving voltage, electric field required for particle movement, reflectivity, and response time measurements show similar results for all ITO and CNT electrodes.

Surface control and durability evaluation of CNT and ITO coated PET transparent electrode with different dry conditions (건조 상태에 따른 CNT 및 ITO로 코팅된 PET 투명전극의 표면 조절 및 내구성 평가)

  • Kwon, Dong-Jun;Wang, Zuo-Jia;Gu, Ga-Young;Park, Joung-Man
    • Composites Research
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    • v.24 no.5
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    • pp.17-22
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    • 2011
  • Recently transparent electrodes using carbon nanotube (CNT) have been studied actively to replace conventional ITO. In this work, CNT or ITO coated poly(ethylene terephthalate) (PET) were prepared by controlling the surfaces since the cohesion degree depends upon drying conditions. As transparent electrode application, 3 drying temperatures were set as 20, 80, and $120^{\circ}C$ to produce the change of surface properties. Interfacial durability and electrical properties of prepared transparent electrodes were evaluated by electrical resistance measurement. Surface change with changing drying temperature was observed by FE-SEM, whereas the transparency change was measured by UV-spectroscopy. The electronic properties of nanoparticle coated surface were evaluated using cyclic voltametry method upon the surface change with controlled drying temperature. Durability of CNT coated surfaces was better than ITO coated ease. As drying temperature increased, better coated surface was prepared due to improved cohesion among nanoparticles, which resulted in increased electrical properties.

Electrochemical Properties of Graphite-based Electrodes for Redox Flow Batteries

  • Kim, Hyung-Sun
    • Bulletin of the Korean Chemical Society
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    • v.32 no.2
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    • pp.571-575
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    • 2011
  • Graphite-based electrodes were prepared using synthetic graphite (MCMB 1028) or natural graphite (NG) powder using a dimensionally stable anode (DSA) as a substrate. Their electrochemical properties were investigated in vanadiumbased electrolytes to determine how to increase the durability and improve the energy efficiency of redox flow batteries. Cyclic voltammetry (CV) was performed in the voltage range of -0.7 V to 1.6 V vs. SCE at various scan rates to analyze the vanadium redox reaction. The graphite-based electrodes showed a fast redox reaction and good reversibility in a highly concentrated acidic electrolyte. The increased electrochemical activity of the NG-based electrode for the $V^{4+}/V^{5+}$ redox reaction can be attributed to the increased surface concentration of functional groups from the addition of conductive material that served as a catalyst. Therefore, it is expected that this electrode can be used to increase the power density and energy density of redox flow batteries.