• Title/Summary/Keyword: Dual Flocculation

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A SINGLE FLOCCULANT/DUAL FLOCCULATION SYSTEM FOR DEWATERING USING A BRANCHED SELF INVERSING EMULSION FLOCCULANT

  • Bae, Young-Han;Lee, Sung-Sik
    • Environmental Engineering Research
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    • v.11 no.4
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    • pp.208-216
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    • 2006
  • In order to create a single flocculant/dual flocculation system, polyacrylamide-co-trimethyl ammonium ethyl acrylate chloride (TAEAC) polymers with varying molecular weights and structures were prepared for use of flocculants. The higher the cationic density of the polymer is higher, the higher was the conversion rate and the ratio of monomer. An acrylamide as nonionic monomer was less reactive than a TAEAC as cationic monomer. The branched polymer which was polymerized with a cross-linking agent, N, N-methylene bis-acrylamide had a higher stability and higher viscosity than a linear polymer but its dewatering efficiency was poor in a single flocculation system. In the case of single flocculant/dual flocculation, the branched polymer has better flocculation efficiency and the water content of the dewatered cakes was lower than the others, as the result of a re-flocculation effect. The optimum conditions for dual flocculation are a sequence in which the $1^{st}$ and $2^{nd}$ dosage are 75% and 25%/total dosage of a single flocculation system. The dewatering efficiency of a dual flocculation system is improved considerably from 10 to 25% under the experimental conditions used herein.

Reduction of Dehydrated Cake by the Optimization of Flocculation Factors and the Single Flocculant/Dual Flocculation System (응집인자 최적화 및 다단응집 시스템을 이용한 탈수 케이크 감량)

  • Kim, Hyung-Jun;Bae, Young-Han;Lee, Sang-Hee
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.8
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    • pp.839-846
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    • 2008
  • The flocculation characteristics of polyacrylamide base flocculants were estimated to reduce the moisture content of the dehydrated cakes. The dewaterability for sewage sludge was found to have a marked effect depending on the flocculant type, agitating speed and time, kind of dissolution water, etc. The optimal agitating speed and time were 700 rpm and 3 sec, respectively, in this experimental condition. and the dewaterability was proportion to the agitating speed upto 700rpm. When recycle water as the dissolution water was used, the solution viscosity of all kind of flocculants was decreased. However, the change of its viscosity are not proportioned to the dewaterabilities for each flocculant. Flocculation system of combinations of the first and sencond flocculation using single flocculant was investigated. Effects of the ratio of first and second dosage for dual flocculation on the dewaterability were also investigated. The optimum conditions of dual flocculation system are 75% and 50% as first dosages for low and high viscous flocculant for total dosage of common flocculation, respectively. Based on the results, an overall mechanism of dual flocculation system is proposed and it is envisaged that optimization of flocculation processes in this way can result in considerable savings in cost.

Behavior of PCC During Loading at High Consistency Pulp Slurry (고농도 펄프 슬러리 충전에서 PCC의 거동)

  • Cho, Byoung-Uk;Won, Jong-Myoung
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.43 no.5
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    • pp.43-48
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    • 2011
  • Filler loading at thick stock was carried out in order to verify if the dual addition of filler can be used as a means to reduce the detrimental effects of filler on the strength properties of paper. PCC was added to 3.5% pulp slurry blended with HwBKP, BCTMP and SwBKP. Cationic starch was used as a fixing agent. The mixture of PCC and pulp was stirred for 5, 10 and 20min. at 1,000 rpm. The remaining PCC was washed out before handsheet making. PCC particles were flocculated and fixed on the pulp fiber and/or space between fibers. It is expected that the flocculation and inclusion of PCC can be helpful to improve the strength properties of paper due to the reduction of detrimental effect in fiber bonding. The distinct tendency in PCC flocculation and fixing on pulp fiber was not observed by the change of cationic starch dosage and treatment time.

Examining the Equality of Multi-Outlet Flow Rates within a Dual Open Channel (이중 수로 구조의 분배수로 내 다지점 유출 유량의 균등성 평가에 관한 연구)

  • Kim, Seong-Su;Park, No-Suk;Jeong, Woo-Chang;Wang, Chang-Keun
    • Journal of Korean Society of Water and Wastewater
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    • v.26 no.3
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    • pp.423-430
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    • 2012
  • This study was conducted to qualify the equality of the flow distribution from open channel between rapid mixing basin and flocculation basins in a domestic S_ water treatment plant, and to suggest a remedy for improving the equality. In order to evaluate the feasibility of the suggested remedy, computational fluid dynamics (CFD) technique are used, and for verifying the CFD simulation results tracer tests were carried out. From the results of CFD simulation and tracer tests, it was investigated that the modification of hydraulic structure in the distribution channel, which is to install the longitudinal orifice baffle in flow direction, could improve the equality of the flow distribution over 75%.

Synthesis of Microaglae-Capturing Magnetic Microcapsule Using CaCO3 Microparticles and Layer-by-Layer Coating

  • Lee, Young-Hee;Seo, Jung-Cheol;Oh, You-Kwan;Lee, Kyubock
    • Korean Journal of Materials Research
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    • v.28 no.7
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    • pp.376-380
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    • 2018
  • Microalgae produce not only lipids for biodiesel production but also valuable biochemicals which are often accumulated under cellular stress mediated by certain chemicals. While the microcarriers for the application of drug delivery systems for animal cells are widely studied, their applications into microalgal research or biorefinery are rarely investigated. Here we develope dual-functional magnetic microcapsules which work not only as flocculants for microalgal harvesting but also potentially as microcarriers for the controlled release of target chemicals stimulating microalgae to enhance the accumulation of valuable chemicals. Magnetic microcapsules are synthesized by layer-by-layer(LbL) coating of PSS-PDDA on $Fe_3O_4$ nanoparticle-embedded $CaCO_3$ microparticles followed by removing $CaCO_3$ sacrificial templates. The positively charged magnetic microcapsules flocculate microalgae by electrostatic interaction which are sequentially collected by the magnetophoretic separation. The microcapsules with a polycationic outer layer provide efficient binding sites for negatively charged microalgae and by that means are further utilized as a chemical-delivery and flocculation system for microalgal research and biorefineries.

A Study on the Behavior of Residual Fluoride in Water Treatment Process (정수처리과정(淨水處理過程)에서의 잔류불소(殘留弗素)이온 거동(擧動)에 관한 연구(硏究))

  • Lee, Taek-Soon;Moon, Byung-Hyun;Seo, Gyu-Tae;Jin, Hong-Sik
    • Journal of Korean Society of Water and Wastewater
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    • v.14 no.2
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    • pp.164-173
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    • 2000
  • Fluoridation of drinking water to a level of about 0.8mg/l (below 1.5mg/l) for reducing the incidence of tooth decay is recommended. However, concerns about potential problems of unknown effects and overdosing hinders the fluoridation. This study describes the work performed to obtain information on the behavior of fluoride under various conditions in the process of water fluoridation. Effects of water treatment chemicals, water treatment unit, and water distribution on water fluoridation were investigated at both lab and an actual water treatment plant. Residual fluoride concentration was not affected by lime and chlorine dosage up to 20mg/l. Flocculation with PAC slightly decreased the residual fluoride concentration as PAC dosage increased. Average fluoride concentration of 0.87mg/l at an intake basin was decreased to 0.83mg/l by sedimentation, 0.81mg/l by dual media(sand+anthracite) filtration, and 0.79mg/l by granular activated carbon filtration in the water treatment plant.

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Effect of Mixing Shear on Flocculation of Anionic PAM and Cationic Starch Adsorbed PCC and Its Effect on Paper Properties (교반 속도가 음이온성 PAM과 양이온성 전분으로 도포된 경질탄산칼슘의 응집과 종이 물성에 미치는 영향)

  • Choi, Do-Chim;Won, Jong Myoung;Cho, Byoung-Uk
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.2
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    • pp.53-60
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    • 2015
  • The effects of stirring speed during filler modification by dual polymers on flocculation and reflocculation of PCC (precipitated calcium carbonate) particles and its effect on handsheet properties were elucidated. PCC surface was modified by adsorbing A-PAM (anionic polyacrylamide) and C-starch (cationic starch) in series at various stirring speeds. It was found that increasing stirring speed during filler modification decreased the initial floc size of PCC. Continuous stirring with the same speed for filler modification resulted in the decrease of a floc size, eventually reached a steady state. The variations in a floc size was influenced by the stirring speed during filler modification: the lower the stirring speed during filler modification, the larger the floc size variations. Conclusively, the stability of PCC floc could be improved by increasing the stirring speed. In addition, the stirring speed influenced the handsheet properties. The smaller the PCC floc, the lower the strength of handseet. However, too much larger floc size also deteriorated paper strength. There exists an optimum floc size in term of paper strength which shall be controlled by stirring speed during filler modification.

A Study on Efficient Simple Water Supply System in Rural Areas (농촌지역의 효율적인 간이 상수처리에 관한 연구)

  • 이홍근;백남원;백도현
    • Journal of Environmental Health Sciences
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    • v.22 no.3
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    • pp.103-115
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    • 1996
  • The purpose of this study was to establish acceptable criteria for the design of simple water treatment plant in rural areas. To develop efficient simple water treatment methods for rural areas, water quality in the study areas was investigated and rapid and slow filtrations in pilot-scale were tested under various conditions. The main results of this study are as follows. It was found that the water qualities of the study areas exceed the drinking water standards, which implies that some treatments are required in rural areas. Treatment efficiencies of both rapid sand and dual-media (sand and anthracite) filtration without pre-treatment such as flocculation and sedimentation are very low, which were turned out to be unadequate for the rural areas. Treatment efficiencies of both vertical and horizontal slow filtration without chlorination are very high for consumed $KMnO_4, NH_3-N, NO_3-N$, turbidity, and very low for coliform and bacteria. Treatment efficiencies of both vertical and horizontal slow filtration with chlorination are very high over the most pollutants. A slow filtration with chlorination is efficient for the rural areas. An adequate depth of sand layer is over 60 cm. A horizontal filtration is more economical than a vertical filtration. A horizontal filtration can be operated for a relatively long periods of time without sand washing or replacement because clogging is removed by simple back-washing.

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Application of PEO/Cofactor System on Papermaking Process for Recycled Fibers (재생 지료 공정에서의 PEO/cofactor 보류 시스템의 적용)

  • Jung, Chul-Hun;Lee, Jin-Ho;Kil, Jung-Ha;Park, Jong-Moon
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.44 no.4
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    • pp.25-31
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    • 2012
  • Ionic trash in furnish decreases retention and drainage performance of the microparticle retention system using recycled fibers in closed papermaking system. Two retention systems, such as the microparticle system and the PEO/cofactor system, were compared and analyzed to improve retention. The PEO/cofactor system achieved similar retention performance at low addition level as the microparticle system. Optimum ratio of PEO/cofactor dual polymer system was 1:10. Ash retention was increased when using the fixing agent. As the TMP ratio increased, the PEO/cofactor system was more efficient in retention and drainage than the other system. The high molecular weight and non-ionic polymer retention system had less effect on flocculation hindrance than the traditional electrostatic retention system.

Retention, Drainage, Formation, and Fracture Toughness Depending on Retention System, Molecular Weights of Polyelectrolytes and Dosage Sequences (보류시스템, 고분자 전해질 분자량과 약품투입순서에 따른 보류, 탈수, 지합, 파괴인성의 변화)

  • Chae, Hee-Jae;Kim, Mun-Sung;Park, Chang-Soon;Park, Jong-Moon
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.41 no.2
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    • pp.13-19
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    • 2009
  • In order to produce high quality paper at the lowest cost in high speed, typically various polyelectrolytes as retention aids were used. Retention systems such as single polymer system, dual polymer system, and microparticle system were used. The objective of this study was to analyze the changes of retention, drainage, formation and fracture toughness depending on types of retention system, molecular weight of C-PAM and dosage sequences of agents. When single polymer system was applied, retention was increased with poor formation and drainage. When common microparticle system(C-PAM/bentonite) was used, high molecular weight PAM gave high retention and fast drainage, but poor formation. When the microparticle system with reverse dosage sequence(bentonite/C-PAM) was used, low molecular weight PAM gave high retention, fast drainage and good formation. When various retention agents were applied, fracture toughness was increased than that of blank. When using high molecular weight PAM and consequently causing excessive flocculation, fracture toughness was decreased.