• Proceedings of the Korean Society of Propulsion Engineers Conference
• /
• 2006.05a
• /
• pp.347-350
• /
• 2006

The rocket grade hydrogen peroxide has been widely used as a monopropellant in propulsion systems. In the present paper, we described an experimental study of a catalytic reactor that employs two stage catalyst beds to enhance the low temperature performance of the reactor. $K_2MnO_4$ was chosen as the catalyst for the initial stage of the reactor bed for its superior behavior in the low temperature regime. LSC was used for the catalyst of the second stage of the reactor. The gas generator with combined catalyst beds was built and tested to exhibit high decomposition efficiency over 90% and successful cold-start characteristics.

• Journal of the Korean Society for Aeronautical & Space Sciences
• /
• v.34 no.3
• /
• pp.87-92
• /
• 2006

The rocket grade hydrogen peroxide has been widely used as a monopropellant in propulsion systems. In the present paper, we described an experimental study of a catalytic reactor that employs two stage catalyst beds to enhance the low temperature performance of the reactor inlet. $K_2MnO_4$ was chosen as the catalyst for the initial stage of the reactor bed for its superior behavior in the low temperature regime. Alumina sol-gel method was successfully applied for coating $K_2MnO_4$ on a reactor bed of cordierite monolith. LSC was used for the catalyst of the second stage of the reactor. The reactor with combined catalyst beds was built and tested to exhibit superior performance in low temperature regime and high decomposition efficiency.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.27 no.10
• /
• pp.1377-1384
• /
• 2003

An analysis has been performed for active thermal control of the KOMPSAT monopropellant rocket engine assembly, i.e., dual thruster module(DTM). The main efforts of this work have been directed at determining proper heater sizes for propellant valves and catalyst beds necessary to maintain their temperatures within specified temperature ranges under KOMPSAT environment and operational conditions. The TAS incorporated with TRASYS thermal radiation analyzer was used to establish a complete heat transfer model which allows to predict the DTM temperature as a function of time. The thermal analysis has been performed in transient mode to verify the appropriate power for catalyst bed heaters necessary to increase catalyst bed temperature to the required value within a specified period of time. Similar analysis has been executed to validate the heater power for the thermostatically controlled primary and redundant heater circuits used to prevent hydrazine freezing, i.e., single fault. Moreover the effect of the radiative property of thermal control coating of heat shield was examined. Thruster firing condition was also simulated for the heat soakback condition. As a consequence, all thermal analysis results for DTM satisfactorily met the thermal requirements for the KOMPSAT DTM under the worst case average voltage, i.e. 25 volt.

• Journal of information and communication convergence engineering
• /
• v.6 no.3
• /
• pp.305-309
• /
• 2008

This paper presents an innovative prototype of a new conceptual electromagnetic induction eddy current based fluid heating appliance using voltage-fed quasi resonant zero voltage soft switching PWM high-frequency inverter using IGBTs, which can operate at a constant frequency variable power regulation scheme. The promising simple high efficient low noise inverter type electromagnetic induction eddy current based pipeline fluid heating appliance is proposed for saturated steam generator, superheated steam generator, hot water and hot air producer, metal catalyst heating for exhaust gas cleaning in engine. Under these technological backgrounds, a novel electromagnetic induction eddy current Dual Packs Heater(DPH) based pipeline fluid heating incorporates thin metal layer type package for continuous fluid heating appliances applying two types of voltage-fed quasi load resonant ZVS-PWM high frequency inverter. The unique features of a novel electromagnetic induction eddy current DPH based continuous pipeline fluid heating appliance is illustrated on the basis of simulation and discussed for the steady state operating characteristics and experimental results.

• Journal of Korean Society for Atmospheric Environment
• /
• v.33 no.6
• /
• pp.605-615
• /
• 2017

Efficient simultaneous reduction conditions for $NO_x$ and $NH_3$-slip was investigated in SCR (Selective Catalytic Reduction) process with load variation by applying dual catalysts (SCR catalyst, $NH_3$ decomposition catalyst) system. $N_2O$ formation characteristics were analyzed to look into possible undesirable reaction pathways. In the experiments of catalyst characteristics, various operational variables were tested for the combined catalytic system, such as $NH_3/NO_x$ ratio, temperature, oxygen concentration and $H_2O$. The reaction characteristics of $NO_x$, $NH_3$ and $N_2O$ were analyzed and optimal conditions could be evaluated for the combustion facility with varied load. In terms of $NO_x/NH_3$ simultaneous reduction and $N_2O$ formation suppression, optimal condition was considered NSR 1.2 and temperature $300^{\circ}C$. At this operational condition, $NO_x$ conversion was 98%, $NH_3$ reduction efficiency was 95%, generated $N_2O$ concentration 9.5 ppm with inlet $NO_x$ concentration of 100 ppm. In $NH_3-SCR$ process with $NH_3$ decomposition catalyst, $NO_x$ and $NH_3$ can be considered to be reduced simultaneously at limited conditions. The results of this study may be utilized as basic data at facilities requiring simultaneous $NO_x$ and $NH_3$ reduction for facilities with load variation.

• Resources Recycling
• /
• v.11 no.6
• /
• pp.3-11
• /
• 2002

Recently, waste printed circuit board (PCB) has significantly increased in its amount due to the rapid development of electronic industries. Since several kinds of noxious materials and also valuable metals are contained in it, the waste PCB is in an urgent need of recycling for the dual purposes for the prevention of environmental pollution and recovery of valuable resources. Also, the catalyst which equipped in the exhaust pipes of automobiles to reduce emission of air pollutants contains precious met-als so that their recovery from the waste auto-catalysts is required. In this study, the recovery of valuable metals from waste PCB and auto-catalyst by arc furnace melting process has been investigated, which is known to be very stable and suitable f3r less production of pollutants due to its high operating temperature. The effect of the kind of flux on the recovery of precious metals was examined by using quicklime, converter slag, and copper slag as the flux. In addition, the influence of direct and alternating current and the applying direction of direct current has been investigated. It was observed that using converter or copper slag as a flux was more desirable for a higher efficiency in the precious metal recovery compared with quicklime. For the effect of current, application of direct current taking the bottom as a negative pole generally showed a better efficiency for the extraction of valuable metals from waste PCB, which was also observed for the case of waste auto-catalyst. The average recovery of precious metals from both wastes by arc furnace melting process was very high, which was up to in the range of 95～97%.

• International Journal of Automotive Technology
• /
• v.3 no.1
• /
• pp.33-40
• /
• 2002

Increasingly stringent emission regulations of EU and CARB (California Air resource Board) require mandatory OBD (On Board Diagnostics) far the catalytic converters of a vehicle. It demands that MIL(Malfunction Indication Light) should be tuned on to inform the driver of catalytic converter failures. Currently dual oxygen sensor method Is widely used for the converter OBD. However, since it works only alter converter light-off, it has a serious limitation when applied to TLEV or more stringent emission regulations where more than 85% of total emission is coming out before converter light-off. In addition, a recent development in catalyst material. coating technology and additive catalysts leads to a much improved OSC (Oxygen Storage Capacity) after converter light-off, current methods are very difficult to determine levels of converter aging. Therefore, it is desired to develop an OSC detecting method before converter light-off to diagnose converter failures with higher reliability. In this study, OSCs of converters are measured by an absolute measuring method and a dynamic measuring method, and some of fundamental ideas are suggested about converter OBD before converter light-off. The converters are aged with two different aging methods; those are a furnace aging and an engine bench aging: to represent aging conditions in actual field applications. Dual oxygen sensor method at the lower temperature than light-off is also studied at a model gas bench with the converters. It is fecund that there is a certain point in temperature lower than light-off where difference due to aging level becomes maximum, thus a proper dynamic method to effectively monitor catalytic converters could be implemented fur the range lower than light-off temperatures. With this result, the aging level of converters is examined at an engine bench.

• Bulletin of the Korean Chemical Society
• /
• v.32 no.spc8
• /
• pp.2970-2972
• /
• 2011

One-pot homo- and cross-coupling reactions of arenediazonium tosylate salts bearing a halogen group have been exploited for the synthesis of biaryls and polyaryls under mild conditions. $Pd(OAc)_2$ has proven to be an efficient catalyst for the successful dual transformation of diazonium salts into p-quaterphenyl (3).

• Corrosion Science and Technology
• /
• v.8 no.6
• /
• pp.223-226
• /
• 2009

Polymer coatings are commonly applied to metal substrates to prevent corrosion in aggressive environments such as high humidity and under salt water. Once the polymer coating has been breached, for example due to cracking or scratches, it loses its effectiveness, and corrosion can rapidly propagate across the substrate. The self-healing system we will describe prevents corrosion by healing the damage through a healing reaction triggered by the actual damage event. This self-healing coating solution can be easily applied to most substrate materials, and our dual-capsule healing system provides a general approach to be compatible with most common polymer matrices. Specifically, we expect an excellent anti-corrosion property of the self-healing coatings in damaged parts coated on galvanized metal substrates.

• Microbiology and Biotechnology Letters
• /
• v.39 no.4
• /
• pp.382-386
• /
• 2011

Microbial fuel cells (MFC), devices that use bacteria as a catalyst to generate electricity, can utilize a variety of organic wastes as electron donors. The current generated may differ depending on the organic matter concentrations used, when other conditions, such as oxidant supply, proton transfer, internal resistance and so on, are not limiting factors. In these studies, a single-cathode type MFC (SCMFC) and dual-cathode type MFC (DCMFC) were used to ascertain the current's improvement through an increase in the contact area between the anode and the cathode compartments, because the cathode reaction is one of the most serious limiting factors in an MFC. Also an MFC was conducted to explore whether an improvement in electricity generation resulted from oxidizing the carbon sources and nitrates. About 250 mg $L^{-1}$ sodium acetate was fed to an anode compartment with a flow rate of 0.326 mL $min^{-1}$ by continuous mode. The current generated from the DCMFC was higher than the value produced from MFC with a single cathode. COD removal of dual-cathode MFC was also higher than that of single-cathode MFC. The nitrate didn't affect current generation at 2 mM, but when 4 and 8 mM nitrate was supplied, the current in the single-cathode and dual-cathode MFC was decreased by 98% from $5.97{\pm}0.13$ to $0.23{\pm}0.03$ mA and $8.40{\pm}0.23$ to $0.20{\pm}0.01$ mA, respectively. These results demonstrate that increasing of contact area of the anode and cathode can raise current generation by an improvement in the cathode reaction.