• Title/Summary/Keyword: Drying resistance

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Physical Properties of High-Solid Coatings with 80% Solid Contents Acrylic Resins Containing Caprolactone Group and HMDI-Trimer (카프로락톤기 함유 80% 고형분인 아크릴수지와 HMDI-Trimer에 의한 하이솔리드 도료의 도막물성)

  • Park, Hong-Soo;Jung, Choong-Ho;Jo, Hye-Jin;Shim, Il-Woo;Kim, Seung-Jin;Kim, Seong-Kil
    • Journal of the Korean Applied Science and Technology
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    • v.23 no.2
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    • pp.110-114
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    • 2006
  • The high-solid coatings were prepared by blending the synthesized acrylic resin in the previous paper, and hexamethylene diisocyanate-trimer and curing it at room temperature. The characterization of the films of the prepared coatings was performed. The $60^{\circ}$ specular gloss, impact resistance, cross-hatch adhesion, and heat resistance of the films proved to be good, and the pencil hardness, drying time, and pot-life proved to be slightly poor. From a viscoelastic measurement using a rigid-body pendulum, curing was accelerated with the Tg value.

Separating and purifying polysaccharide, polypeptide from sea cucumber and their functions (해삼으로부터 다당류와 폴리펩타이드의 분리, 정제 및 기능성)

  • Jin, Hai-zhu;Fu, Xue-jun;Shen, Jing-yu;Sun, Bo;Wang, Hong-tao
    • Proceedings of the Korean Society of Postharvest Science and Technology of Agricultural Products Conference
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    • 2005.09a
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    • pp.112-123
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    • 2005
  • For thestudying and utilizing the thorn sea cucumber synthetically, the method preparing polysaccharide and polypeptide from sea cucumber was studied. The comparatively rational craft for preparing crude polysaccharide is fresh raw materials deal with oar form, $60\%$ of the ethanol precipitate after hydrolyzed by pretense and vibrated with ultrasonic wave auxiliary. The purification of polysaccharide and removal of protein fromcrude polysaccharide were made through precipitation method using the acetate. The polypeptide is obtained by concentrating in vacuum, freeze-drying after mixing precipitations of two times. Polysaccharide acute poisoning experiment indicate there is no bad reaction when LD50>5000g/kg, there strain rate of liver tumor H11 approach present generally acknowledged tumor treat medicine cyclophosphamide, and there is no side effect. The fatigue resistance function of polypeptide experiment also indicates that the fatigue resistance ability of mouse which fed on added sea cucumber polypeptide has a great improvement.

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Corrosion Behavior of Zn and Zn-AI Alloy Coated Steels under Cyclic Wet-dry Environments

  • Nishikata, Atsushi;Yadav, Amar Prasad;Tsutsumi, Yusuke;Tsuru, Tooru
    • Corrosion Science and Technology
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    • v.2 no.4
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    • pp.165-170
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    • 2003
  • Atmospheric corrosion behaviors of Zn, Zn-5%Al and Zn-55%A l coated steels have been investigated under cyclic wet-dry environments containing chloride ions. The wet-dry cycle was carried out by alternate exposure to immersion in 0.5 M (or 0.05 M) NaCl solutions and drying at $25^{\circ}C$ and 60 %RH. The polarization resistance $R_p$ and solution resistance $R_s$ were monitored by AC impedance technique. From the obtained $1/R_p$ and $1/R_s$ values, the corrosion rate of the coatings and the Time of Wetness (TOW) were estimated, respectively. Effects of chloride ions and TOW on the corrosion rates of Zn, Zn-5%Al, Zn-55%Al coatings and appearance of red rust (onset of underlying steel corrosion) under wet-dry cycles are discussed on the basis of the corrosion monitoring data.

Effect of MoS$_2$ and $Fe_2O_3$ Additives on the Tribological Behavior of the Plasma Sprayed Zirconia Based Coatings (MoS$_2$$Fe_2O_3$ 첨가제가 지르코니아계 용사코팅층의 마모마찰 특성에 미치는 영향)

  • 신종한;임대순;안효석
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 1997.10a
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    • pp.93-99
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    • 1997
  • High Temperature wear behavior of plasma sprayed ZrO$_2$ and MoS$_2$, $Fe_2O_3$ coatings were investigated for high temperature wear resistance applications. The MoS$_2$, $Fe_2O_3$ added powders containing 2.5, 5.0, 7.5, 10.0 mol% of $MoS_2$, $Fe_2O_3$ for plasma spray were made by spray drying method. Wear test were performed at temperature ranges from room temperature to 600$\circ$C. The microstructural change of coatings and the worn. surface were examined by SEM and XRD. In ZrO$_2$ coating, the coefficient of friction and wear amount of room temperature to 400$\circ$C was increased with temperature and decreased with temperature over 400$\circ$C. The coefficient of friction and wear amount of MoS$_2$ added coatings were increased with temperature, but those of $Fe_2O_3$ added coatings had lower coefficient of friction and higher wear resistance than ZrO$_2$ coating.

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An Analytic Study on the Creep Properties for Fibers Mixed of High Strength Concrete (고강도 콘크리트의 섬유 혼입에 따른 크리프 특성 분석에 관한 연구)

  • Park, Hee-Gon;Kwon, Hae-Won;Lee, Bo-Hyeong;Bae, Yeoun-Ki;Lee, Jae-Sam;Jung, Sang-Jin
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2009.11a
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    • pp.81-85
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    • 2009
  • In the recent years, the high strength concrete has increasingly been used according to extending market of tall buildings. However, Ministry of Land, transport and Maritime Affairs was established by law with an alternative plan after June 2008 because of the weakness of high strength concrete accompanied spalling phenomena in fire. The mix design of concrete has to properly meet standards which are the spalling resistance of concrete and limited temperature of steel reinforcement. The fire proof concrete mixed fiber has widely been used to meet spalling safety on the many construction sites, the most researches about the fire proof concrete mixed fiber had being carried out focused on fire resistance, compressive strength and cast in place of concrete. But the most important thing is column shortening used the fire proof concrete within the vertical members. In this paper, the fire proof concrete filled spalling safety standards was experimented by required material when the column shortening is revised between normal concrete and fire proof concrete mixed fiber and then the results have done a comparative analysis. Also, The paper aimed to indicate a basic data for revision of column shortening of fire proof concrete.

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Evaluation of Corrosion Characteristics of Underwater Hardening Paint (수중 경화형도료의 부식특성에 관한 전기화학적 고찰)

  • Moon, Kyung-Man;Oh, Min-Seok;Lee, Myung-Hoon;Lee, Syung-Yul;Kim, Yun-Hae
    • Journal of Ocean Engineering and Technology
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    • v.25 no.2
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    • pp.85-91
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    • 2011
  • Many protection methods such as surface coating, electric protection, or other methods have been applied to the numerous steel structures widely used in continental and marine areas to control their corrosion, which is done from an economic point of view. Most of these steel structures are primarily protected by coating methods. However, some steel piles under seawater are protected by the electric protection method, that is, either using an impressed current or a sacrificial anode method. Furthermore, environmental contamination may cause a severely corrosive environment, which, in turn, causes the accelerated corrosion of steel structures. Subsequently, coated steel structures could deteriorate more rapidly than the designed lifetime because of the acid rain caused by air pollution, etc. Therefore, a coating of marine paint exposed to seawater, that is, underwater hardening painting, is increasingly required to be fast drying as well as highly corrosion resistant. In this study, five types of underwater hardening paints were prepared with different resin series and additives. Their corrosion and water resistances were investigated using electrochemical methods such as corrosion potential, polarization curves, impedance and cyclic voltammogram measurements, etc. Even though it is generally accepted that the corrosion resistance of bare steel tends to increase with a shift of the corrosion potential in the noble direction, the corrosion resistance of a sample with a coating exhibited a relatively better tendency when it had a lower corrosion potential in this study. The corrosion current density was also decreased with a decrease in the diffusion limiting current density, which may mean that there is some relationship between corrosion and water resistance. The S sample of the ceramic resin series showed the relatively best corrosion and water resistance among those of samples, while the worst corrosion and water resistance were observed for the R sample of the epoxy resin series. The corrosion and water resistance of those samples tended to deteriorate with an increase in the immersion days, and their corrosion and water resistances were considered to be apparently improved by the types of resin and additives.

Evaluation of Erosion Resistance Capability with Adhesive Soil Seeding Media (접착성 식생기반재의 침식저항능력 평가)

  • Seong, Si-Yung;Shin, Eun-Cheol
    • Journal of the Korean Geosynthetics Society
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    • v.14 no.2
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    • pp.71-79
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    • 2015
  • This paper describes vegetation based soil-media hydroseeding measures that have been previously applied as slope revegetation methods show problems such as insufficient binding force, drying, and insufficient organic matter. In particular, in the case of slope faces in regions where scattering is severe, a vicious circle exists in which remarkably low vegetation cover rates and increases in withering rates over time lead to further decreases in vegetation cover rates, which lead to further increases in erosion and scattering. Therefore, in the present study, environment friendly soil stabilizers were applied for resistance against erosion or scattering and engineering evaluations such as long-term immersion tests and flow resistance tests were conducted to determine appropriate mixing ratios. According to the results of long-term immersion tests utilizing environment friendly soil stabilizers and existing greening soil based materials, 100% collapse occurred at 30 hours and 40 days in the case of soil stabilizer mixing ratios of 0% and 2%, respectively. While the original form of the samples remained intact until the experiment was completed in the case of mixing ratios exceeding 4% indicating that 2% or higher soil stabilizer mixing ratios could affect the maintenance of forms even under extreme conditions. In addition, artificial rainfall tests were conducted on 40, 45, and 55 degree slope faces to evaluate the structural stability of vegetation based materials. Flow resistance tests were conducted on soil stabilizer mixing ratios of 0, 4, 8% to evaluate erosion resistance capability. Based on the results of the tests, environment friendly soil stabilizers applied for prevention of scattering or resistance against erosion by rainwater are considered to provide large effects to reduce losses and loss rates showed a tendency of decreasing rapidly when soil stabilizers were mixed.

Application of Acrylic Resins Containing Caprolactone Group and 90% Solid Contents to High-Solid Coatings (카프로락톤기 함유 90% 고형분인 아크릴수지의 하이솔리드 도료에의 적용)

  • Park, Hong-Soo;Yang, In-Mo;Kim, Seung-Jin;Kim, Young-Geun;Jung, Choong-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.24 no.2
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    • pp.149-159
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    • 2007
  • In order to prepare high-solid coatings, acrylic resins, HSCs [poly (EA/EMA/2-HEMA/CLA)] that contain 90% solid, were synthesized by copolymerization of ethyl acrylate (EA), ethyl methacrylate (EMA), 2-hydroxyethyl methacrylate (2-HEMA) and caprolactone acrylate (CLA). The high-solid coatings named as CHSCs (HSCs/HDI-trimer) were prepared by the curing reaction between the acrylic resins containing 90% solid contents and the isocyanates (HDI-trimer) curing agent room temperature. The curing behavior and various properties were examined on the film coated with the both high-solid coatings. The glass transition temperatures $(T_g)$ of CHSCs increased proportionally with increasing the predicted $T_g$ value by Fox equation, and had nothing to do with the solid contents. The prepared film showed good properties for $60^{\circ}$ specular gloss, impact resistance, cross-hatch adhesion and heat resistance, and bad properties for pencil hardness, drying time, and pot-life. Among the film properties, the heat resistance was very excellent and could be explained by the introduction of functional monomers of CLA.

Study on the Compositions of Photosensitive Resistor Paste Using Epoxy Acrylate Oligomers and Conductive Carbonblack (에폭시 아크릴레이트 올리고머와 전도성 카본블랙을 이용한 감광성 저항 페이스트 조성 연구)

  • Park, Seong-Dae;Kang, Nam-Kee;Lim, Jin-Kyu;Kim, Dong-Kook
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.421-421
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    • 2008
  • Generally, the polymer thick-film resistors for embedded organic or hybrid substrate are patterned by screen printing so that the accuracy of resistor pattern is not good and the tolerance of resistance is too high(${\pm}$20~30%). To reform these demerits, a method using Fodel$^{(R)}$ technology, which is the patterning method using a photosensitive resin to be developable by aqueous alkali-solution as a base polymer for thick-film pastes, was recently incorporated for the patterning of thermosetting thick-film resistor paste. Alkali-solution developable photosensitive resin system has a merit that the precise patterns can be obtained by UV exposure and aqueous development, so the essential point is to get the composition similar to PSR(photo solder resist) used for PCB process. In present research, we made the photopatternable resistor pastes using 8 kinds of epoxy acrylates and a conductive carbonblack (CDX-7055 Ultra), evaluated their developing performance, and then measured the resistance after final curing. To become developable by alkali-solution, epoxy acrylate oligomers with carboxyl group were prepared. Test coupons were fabricated by patterning copper foil on FR-4 CCL board, plating Ni/Au on the patterned copper electrode, applying the resistor paste on the board, exposing the applied paste to UV through Cr mask with resistor patterns, developing the exposed paste with aqueous alkali-solution (1wt% $Na_2CO_3$), drying the patterned paste at $80^{\circ}C$ oven, and then curing it at $200^{\circ}C$ during 1 hour. As a result, some test compositions couldn't be developed according to the kind of oligomer and, in the developed compositions, the measured resistance showed different results depending on the paste compositions though they had the same amount of carbonblack.

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Evaluation on the Sulfate Attack Resistance of Cement Mortars with Different Exposure Conditions (노출조건에 따른 시멘트 모르타르의 황산염침식 저항성 평가)

  • Lee, Seung Tae
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.32 no.6A
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    • pp.427-435
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    • 2012
  • In order to evaluate the effects of exposure conditions on the resistance to sulfate attack of normal and blended cement mortars, several mechanical characteristics of the mortars such as expansion, strength and bulk density were regularly monitored for 52 cycles under sodium sulfate attack. The mortar specimens were exposed to 3 different types of exposure conditions; 1) continuous full immersion(Exposure A), continuous half-immersion(Exposure B) and cyclic wetting-drying(Exposure C). Experimental results indicated that the maximum deterioration was noted in OPC mortar specimens subjected to Exposure B, showing the wide cracks in the portions where attacking solution is adjacent to air. Additionally, the beneficial effect of ground granulated blast-furnace slag and silica fume was clearly observed showing a superior resistance against sodium sulfate attack, because of its lower permeability and densified structure. Thus, it is suggested that when concrete made with normal cement is exposed to sulfate environment, proper considerations on the exposure conditions should be taken.