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http://dx.doi.org/10.12925/jkocs.2007.24.2.6

Application of Acrylic Resins Containing Caprolactone Group and 90% Solid Contents to High-Solid Coatings  

Park, Hong-Soo (Department of Chemical Engineering, Myongji University)
Yang, In-Mo (Korea Institute of Construction Materials)
Kim, Seung-Jin (Korea Institute of Construction Materials)
Kim, Young-Geun (Korea Institute of Construction Materials)
Jung, Choong-Ho (Korea Institute of Ceramic Engineering and Technology)
Publication Information
Journal of the Korean Applied Science and Technology / v.24, no.2, 2007 , pp. 149-159 More about this Journal
Abstract
In order to prepare high-solid coatings, acrylic resins, HSCs [poly (EA/EMA/2-HEMA/CLA)] that contain 90% solid, were synthesized by copolymerization of ethyl acrylate (EA), ethyl methacrylate (EMA), 2-hydroxyethyl methacrylate (2-HEMA) and caprolactone acrylate (CLA). The high-solid coatings named as CHSCs (HSCs/HDI-trimer) were prepared by the curing reaction between the acrylic resins containing 90% solid contents and the isocyanates (HDI-trimer) curing agent room temperature. The curing behavior and various properties were examined on the film coated with the both high-solid coatings. The glass transition temperatures $(T_g)$ of CHSCs increased proportionally with increasing the predicted $T_g$ value by Fox equation, and had nothing to do with the solid contents. The prepared film showed good properties for $60^{\circ}$ specular gloss, impact resistance, cross-hatch adhesion and heat resistance, and bad properties for pencil hardness, drying time, and pot-life. Among the film properties, the heat resistance was very excellent and could be explained by the introduction of functional monomers of CLA.
Keywords
90% solid contents; caprolactone group; acrylic resin; high-solid coatings;
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