• Bulletin of the Korean Chemical Society
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• v.30 no.1
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• pp.214-218
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• 2009

Second-order rate constants ($k_N$) have been measured for nucleophilic substitution reactions of S-4-nitrophenyl thiobenzoate with a series of alicyclic secondary amines in $H_2O$ containing 20 mol % DMSO at 25.0 ${\pm}$ 0.1 ${^{\circ}C}$. The Br$\phi$nsted-type plot exhibits a downward curvature, i.e., $\beta_{nuc}$ decreases from 0.94 to 0.34 as the amine basicity increases. The reactions in the aqueous DMSO have also been suggested to proceed through a zwitterionic tetrahedral intermediate (T${\pm}$) with change in the RDS on the basis of the curved Br$\phi$nsted-type plot. The reactions in the aqueous DMSO exhibit larger $k_N$ values than those in the aqueous EtOH. The macroscopic rate constants ($k_N$) for the reactions in the two solvent systems have been dissected into the microscopic rate constants ($k_1\;and\;k_2/k_{-1}$ ratio) to investigate effect of medium on reactivity in the microscopic level. It has been found that the $k_2/k_{-1}$ ratios are similar for the reactions in the two solvent systems, while $k_1$ values are larger for the reactions in 20 mol % DMSO than for those in 44 wt % EtOH, indicating that the larger $k_1$ is mainly responsible for the larger $k_N$. It has been suggested that the transition state is more stabilized in 20 mol % DMSO through mutual polarizability interaction than in 44 wt % EtOH through H-bonding interaction.

• Journal of the Korea Institute of Building Construction
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• v.4 no.3
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• pp.109-116
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• 2004

Normally easy task of plat in urban architecture is that using underground full of activities for increase building site efficiency. Especially for using underground space for the parking lot. Also utilize underground is more increase for fulfill requirement in modern society considered with environmental friendly architecture. The primary objective of this study is to apply analyzed formal foundation type for selecting the optimum type of parking lots considered with structural stability, economical efficiency, construction efficiency, construction duration. This study aim to on criteria decided through the questionaries for the selection considered with in the scale of second stories parking lots underground, parking volume is 80 and reinforced concrete structure. The bearing capacity is 6～8m and downward from surface, healthy ground bearing capacity is 40 t/m2. This study comparative analysis and discuss economical efficiency, construction efficiency, construction duration based constructivist stability which applied Single foundation, Mat foundation, Drop Mat foundation. The result of this study is as follows: First, the result of economical efficiency is that on the basis of single foundation, Drop Mat foundation is 1.88, Mat foundation 2.04 as a comparative analysis on the basis of total construction cost included material cost, labor coast and machinery cost. Second, the result of construction efficiency order is single foundation, Drop Mat foundation, Mat foundation as a comparative analysis on the based connected characteristics. Third, the result of construction duration is that on the basis of Mat Foundation, Drop Mat foundation is 1.33, single foundation is 1.87 as a comparative analysis Critical Path. Forth, Each foundational type characteristics order through the matrix method is that overall each formal type of foundation contraries at economical efficiency and construction efficiency, construction duration. Also expect contradiction between engineers and owners due to engineer pursuit construction duration and ewer to begin with economical efficiency. Fifth, The selection of suitable foundation formal type needs that based consider project characteristic and field condition as according to above result of a comparative analysis. As a result, a comparative analysis economical efficiency, construction efficiency, construction duration of Mat foundation, Drop Mat foundation, single foundation with 3Bay reinforced structure underground parking lots on the healthy ground.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.10 no.1
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• pp.18-31
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• 2000

A stack must be designed to 1) reduce or eliminate rainfall or snowfall into a industrial exhaust system, 2) minimize a resistance to flow, 3) maximize the vertical dispersion of the contaminated air and 4) minimize maintenance. The weather cone stacks and the elbow-type stacks are very popular in Korea. But they add some resistance to the exhaust system resulting in reduction of air flow rate, but also deflect the noxious contaminants downward in undiluted form. To solve these problems, ACGIH (American Conference of Governmental Industrial Hygienists) suggested the vertical discharge stack with concentric space between the upper stack with larger diameter and the lower stack with smaller diameter. The preliminary test showed that the vertical discharge stacks did not have the good rainfall protection. The reversed cone were newly devised to satisfy the requirements for the good stack. Subsequently, the amount of rain being penetrated through the stacks was measured while the stacks were simultaneously and naturally exposed to rain in the same area outside. Test results indicate that none of the stacks tested completely exclude rain. The efficiency of rainfall protection and the pressure loss coefficient were compared. The temporary conclusion was reached to the point that the reversed cone stack is the best one. Further research is underway.

• Journal of Satellite, Information and Communications
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• v.12 no.1
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• pp.72-75
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• 2017

In this paper, we design the circular slits in the parch antenna for size reduction and high gain working at 900 MHz. Modifying the rectangular type patch, we decrease the antenna real-estate, leading to antenna miniaturization with added circular slits in itself. The antenna is tuned for under -30 dB return loss by adjusting the number of circular slits and their radii, and its design is performed for the maxim bean pattern of 4 dBi gain. Compared with the antenna without circular slits, the designed antenna shows 20 MHz downward shift of frequency, proving that the size reduction is achieved with this antenna design.

• Journal of the Society of Naval Architects of Korea
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• v.36 no.3
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• pp.8-14
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• 1999

The flor characteristics around the KRISO 3600TEU container ship model have been experimentally investigated in a subsonic wind tunnel. The mean velocity and turbulence characteristics in the stern and wake regions were measured using an x-type hot-wire probe. The flow characteristics in the stern and near wake regions revealed a complicated three-dimensional flow pattern. The measured results showed clearly the formation of longitudinal vortices and their effect on the flow pattern in the wake region. The shear layer developed along the ship model expands showly to the downward direction. The turbulence statistics measured can be used as comparative data of numerical simulations and provide insights into development of accurate turbulence models for the ship design.

• Journal of the Korean Academy of Esthetic Dentistry
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• v.10 no.1
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• pp.8-15
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• 2001

The Class III malocclusion classified in two types of Skeletal Class III and Pseudo Class III. In the case of the maxillary deficiency, the protraction H-G(facemask) with Bonded RPE can be used. For children with A-P and vertical maxillary deficiency, the preferred treatment is to move the maxilla into a more anterior and inferior position, which also increases its size as bone is added at the posterior and superior sutures. Successful forward repositioning of the maxilla can be accomplished before age 8. To resist tooth movement as much as possible, the maxillary teeth should be splinted together as a single unit. The maxillary appliance must have hooks for attachment to the facemask that are located in the canine-primary molar area above the occlusal plane. The facemask usually worn until a positive overjet of 2-5mm is achieved interincisally. Occipital chin cup is successful in those patients who can bring their incisors close to an edge-to-edge position when in centric relation. This treatment is particularly useful in patients who begin treatment with a short lower anterior facial height, as this type of treatment can lead to an increase in lower anterior facial height. If the pull of the chin cup is directed below the condyle, the force of the appliance may lead to a downward and backward rotation of the mandible.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.20 no.4
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• pp.1395-1405
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• 1996

The purpose of this experimental research is to investigate the local heat transfer characteristics in the upward free water jet impinged on a downward flat plate of uniform heat flux. The inner shape of rectangular nozzle used was sine curve type and its contraction ratio of inlet to outlet area was five. Experimental parameters considered were Reynolds number, nozzle exit-flat plate distance, and level of supplementary water. Local Nusselt number was influenced by Reynolds number, Prandtl number, supplementary water level, and distance between the nozzle exit and flat plate. Within the impingement region, the Nusselt number has a maximum value on the nozzle center axis and decreases monotonically outward from center. Outside of the impingement region, on the other hand, the Nusselt number has a secondary peak near the position where the distance from nozzle center reaches four times the nozzle width. However if nozzle exit velocity exceeds 6.2 m/s, the secondary peak appears also in the impingement region. The empirical equation for the stagnation heat transfer is a function of Prandtl, Reynolds, and axial distance from the nozzle exit. The optimum level of supplementary water to augment the heat transfer rate at stagnation point was found to be twice the nozzle width.

• The KSFM Journal of Fluid Machinery
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• v.18 no.3
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• pp.26-32
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• 2015

The authors are developing a motion of floater body type wave energy converter of the float-counterweight system. This consists of the driving pulley, wire, float and counterweight suspended from idler pulleys and rachet mechanism. Though it has succeeded in solving the major structural strength problem in which the floats would slam against adjacent structure(s) by wave load acting horizontally. In order to overcome this problem. We propose a new system in which the wire transmitting the power is wound around the pulleys and the float receiving the wave power is pulled by the wire from both its upper and lower ends to avoid the occurrence of slackening during the wave cycle. In the paper, we developed the dynamics model for the proposed system. Energy gain has been calculated for realistic wave conditions and compared with the original float-counterweight device. The important differences from the float-counterweight system are that (1) both upward and downward motions of water surface can be utilized without problem. (2) slackening of energy gain and wire tension are effectively suppressed, and (4) for the same time averaged energy gain, the maximum wire tension is fairly lowered.

• Journal of the Korean Society of Combustion
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• v.14 no.4
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• pp.7-16
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• 2009

Porous metal plates (Metal fiber, muti-hole metal plate) using mainly in surface burner are known to have a corrosion and durability problem under high temperature condition. In this study, premixed flat flame with perforated ceramic tile of more durable cordierite material was examined with respect to combustion stability and emission. The flat premixed ceramic burner consists of perforated ceramic tile and various type of baffle plates to form stable surface flame. The results show that most stable flat flame is generated using baffle plate with open ratio of 0.193. In downward flat flame mode which is widely used in condensing boiler, CO is measured below 50ppm from equivalence ratio 0.755 to 0.765 and $NO_X$ is measured below 12ppm from equivalence ratio 0.75 to 0.79. It is also found that the range of blue flame in flame stability curve becomes wider with increasing heat capacity.

• Journal of Korean Association for Spatial Structures
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• v.16 no.2
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• pp.89-96
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• 2016

Cable structures are lightweight structures of flexible type, cable members have only axial stiffness related to tension, they can carry neither bending nor compression. This study is the analysis of cable truss systems are composed of upper and low cables by connecting bracing cables, the structural principle is based on a tensegrity system by using bracing tension members, discontinuous compression members and continuous tension members. A hanging roof of cable truss system is too flexible against vertical loads, most cable members are stabilized by connecting the prestressed upper and lower cable by bracing cables. A cable truss roof system is formed by adding a set of cables with reverse curvature to the suspension cables. With the sets of cables having opposite curvature to each other, cable truss is able to carry vertical load in both upward and downward direction with equal effectiveness, and then a cable truss acts as load bearing elements by the assemble of ridge cables, valley cables and bracing cables. This paper will be shown the geometric non-linear analysis result of cable truss systems with various sag ratio for deflections and tensile forces, the analytical results are compared with the results of other researchers.