• Title/Summary/Keyword: Double-Layered

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The structure of intercalation compound between a layered double hydroxide and an ethyl orange (층상이중수산화물과 에틸오렌지의 삽입화합물의 구조)

  • Jung, Woo-Chan;Huh, Young-Duk
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.7 no.1
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    • pp.137-142
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    • 1997
  • We synthesized the intercalation compound between a layered double hydroxide and an ethyl orange. The orientation of the intercalated ethyl orange into the layered double hydroxide was investigated. The molecular plane of the ethyl orange and its N=N axis lie nearly perpendicular to the hydroxide layers with an antiparallel pattern.

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A Study on the Performance Evaluation of Double-Layered Catayst MEA (이중촉매 MEA의 성능평가에 관한 연구)

  • Kim Hong-Gun;Kang Sung-Soo;Kwac Lee-Ku;Kang Young-Woo
    • New & Renewable Energy
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    • v.2 no.2 s.6
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    • pp.50-59
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    • 2006
  • An experimental and numerical study is carried out to investigate the performance and the efficiency humidifying Membrane Electrolyte Assembly and having the double-layered catalyst in a fuel cell system which is taken into account the physical and thermal concept. Based on the principals of the problem, the equation of electronic charge conservation equation, gas-phase continuity equation, and mass balance equation are used for the numerical calculation. A unit cell for $200cm^2$ MEA is assembled and measured for finding better operational situation. After finding the optimal condition, 10 cell stacked PEMFC is fabricated. For the performance evaluation, V-I and power curves are examined in detail by changing the condition of humidity, temperature, pressure, thickness of catalyst and oxidant. It is found that the power is maximized around 500W at 80A.

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Incorporation of Antibacterial Natural Extract into Layered Double Hydroxide through Memory Effect for Antibacterial Materials (금속이중층수산화물의 메모리효과를 이용한 항균 천연소재의 담지 및 항균소재의 개발)

  • Kim, Hyeong-Jun;Jeong, Do-Gak;O, Je-Min
    • Ceramist
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    • v.22 no.3
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    • pp.301-315
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    • 2019
  • We prepared hybrids between layered double hydroxide (LDH) and natural plant extract such as Peaonia suffruticosa Andrews (PS) and Peaonia Japonica (PJ) which was confirmed anti-bacterial activity through paper disc diffusion assay. According to X-ray diffractometer, scanning electron microscope, zeta-potential measurement and quantification of extract loading amount in hybrids, we confirmed that similar amount of PS and PJ loaded on inter-particle pore of LDH with partial adsorption on surface of LDH through reconstruction process. We also evaluated the bacterial colony forming inhibition of PS extract, PJ extract, PS-LDH and PJ-LDH hybrids against Escherichia coli as gram negative bacterium and Bacillus subtilis as gram positive bacterium, suggesting that both hybrids have enhanced anti-bacterial activity compared with extract itself.

Step-wise Anion-Exchange in Layered Double Hydroxide Using Solvothermal Treatment

  • Lee, Jong-Hyeon;Rhee, Seog-Woo;Jung, Duk-Young
    • Bulletin of the Korean Chemical Society
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    • v.26 no.2
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    • pp.248-252
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    • 2005
  • Synthetic layered double hydroxides (LDHs), [$Mg_4Al_2(OH)_{12}]CO_3{\cdot}nH_2O$, were prepared in the submicron size of plate-like polycrystals. Anion-exchange reactions with various linear dicarboxylic acids were performed to produce LDH/organic hybrid materials by solvothermal treatment in toluene. X-ray powder diffraction spectra for the products indicated that the interlayer spacings of LDHs remarkably changed, up to 20 $\AA$ when 1,10-decanedicarboxylic acid anions were intercalated as an organic guest. Dicarboxylates-LDHs samples could be also re-exchanged consecutively with other dicarboxylic acids or carbonate without serious destruction of layer structure under the scanning electron microscopic observation.

The Effect of Phosphate Desorption Solution on LDH (Layered Double Hydroxide) Desorption (탈착 용액의 조성변화가 층상이중수산화물에 흡착된 인 탈착에 미치는 영향)

  • Jung, Yong-Jun
    • Journal of Korean Society on Water Environment
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    • v.24 no.6
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    • pp.670-675
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    • 2008
  • Batch type adsorption and desorption tests were performed with different types (Powder, Granule) of Layered double hydroxides (LDHs) saturated with phosphate. The adsorption isotherm was approximated as a modified Langmuir type equation. The maximum adsorption capacity was 55 mg-P/g-LDH for powder type LDH, and 46 mg-P/g-LDH for granule type LDH. The highest phosphate desorption (79.6%) was obtained with 20% NaOH solution, whereas the desorption degrees were 4.8, 22.2% and 46.7% in the solutions of acidic condition (pH 4), 30% NaCl, and 3% NaOH, respectively. It was suggested that the optimal condition for the phosphate desorption from LDH was 30% NaCl + 3~6% NaOH solutions. The desorption characteristics of LDH was little influenced by adsorbent type.

Effective Routing Schemes for Double-Layered Peer-to-Peer Systems in MANET

  • Kim, Ji-Hoon;Lee, Kwang-Jo;Kim, Taek-Hun;Yang, Sung-Bong
    • Journal of Computing Science and Engineering
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    • v.5 no.1
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    • pp.19-31
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    • 2011
  • In this paper, we propose two new routing schemes for double-layered peer-to-peer systems; a shorter-lower mobility routing scheme and a reverse path routing scheme. The shorter-lower mobility routing scheme first chooses shortest routing paths among possible routing paths and selects the path associated with the relay peer who has lower mobility to improve the reliability of the system. The reverse path routing scheme carries out unicasting (instead of multicasting) based on the reverse path information that can be obtained during the initial file search to further reduce network traffic. The experimental results showed that a double-layered peer-topeer system with the proposed hybrid scheme improved the reliability of the system about 1.5% over the hop count scheme and reduced network traffic by about 0.5% compared to the hop count scheme.

Temperature History of the Concrete for Retaining Wall Insulated with Double Layered Bubble Sheet in Winter (동절기 2중버블시트로 단열처리된 옹벽의 온도이력 특성)

  • Jung, Eun-Bong;Son, Ho-Jeong;Jang, Deok-Bae;Kyung, Yeong-Hyeok;Han, Min-Cheol;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2012.05a
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    • pp.269-270
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    • 2012
  • This study discussed the applicability of double layered bubble sheet(BS) to the concrete for retaining wall to verify the insulation effect as well as prevention of condensation. The BS was applied to the surface of retaining wall, which is contacted with ground. Temperature profile was monitored since placement of concrete. As expected, the application of BS helps the concrete keeping favorable heat insulating, preventing condensation.

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Coupled effects of electrical polarization-strain gradient on vibration behavior of double-layered flexoelectric nanoplates

  • Barati, Mohammad Reza
    • Smart Structures and Systems
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    • v.20 no.5
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    • pp.573-581
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    • 2017
  • A vibrating double-layered nanoscale piezoelectric plate is developed accounting for the flexoelectricity and surface effects. The flexoelectricity is due to the coupling between electrical polarization and strain gradient. Applying Hamilton's principle, the governing equations and related boundary conditions are derived. Assuming suitable approximate functions, the governing equations are numerically solved for simply-supported and clamped boundary conditions. Obtained results indicate that both the flexoelectricity and surface effects possess notable impact on the vibration frequencies of the system. Only flexoelectricity yields a considerable difference between the present model and previous investigations on conventional piezoelectric nanoplates. Generally, a parametric study has been performed to examine the effects of surface elasticity, flexoelectricity, applied electric voltage, interlayer stiffness, geometrical parameters and boundary conditions on vibration frequencies of piezoelectric nanoplates.

Remarkable Stability of Graphene/Ni-Al Layered Double Hydroxide Hybrid Composites for Electrochemical Capacitor Electrodes

  • Lee, Jeong Woo;In, Su-Il;Kim, Jong-Duk
    • Journal of Electrochemical Science and Technology
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    • v.4 no.1
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    • pp.19-26
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    • 2013
  • Graphene/Ni-Al layered double hydroxide (LDH) hybrid materials were synthesized by a hydrothermal reaction. Hexagonal Ni-Al LDH particles nucleated and grew on graphene sheets, thus preventing restacking of the graphene sheets and aggregation of the Ni-Al LDH nanoparticles upon drying. Electrode made from the graphene/Ni-Al LDH hybrid materials showed a substantial improvement in electrochemical capacitance relative to those made with pure Ni-Al LDH nanoparticles. In addition, the graphene/Ni-Al LDH hybrid composite materials showed remarkable stability after 4000 cycles with over 100% capacitance retention. These materials are thus very promising for use in electrochemical capacitor electrodes.

A Study of the High Sensitive Nonsilver Halide Imaging Material( II ) - Study of the aqueous coating mechanism and washing effect of the CGL in the $\varepsilon$-CuPc/PVK double-layered organic photoconductor - (고감도 비은염 화상재료 개발연구 ( II ) - Copper Phthalocyanine/PVK 전자사진감광체의 CGL의 수성 coating mechanism과 세정효과에 관한 연구 -)

  • 이상남
    • Journal of the Korean Graphic Arts Communication Society
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    • v.9 no.1
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    • pp.27-44
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    • 1991
  • In this research, double-layered photoconductor consist of the carrier generation layer(CGL) of ${\varepsilon}$ type copper phthalocyanine thin film by an aqueous coating method and the carrier transport layer(CGL) of polyvinyl carbazol(PVK) by spin coating. We inverstigated effect of the surfactant solution and cathod electrolysis to the crystal type of ${\varepsilon}$-CuPc in CGL with TEM, SEM and X-ray diffraction spectroscopy and studied the mechanism of an aqueous coating for the preparation of CGL. The effect of the washing of CGL about the electrophotographic characteristics of the ${\varepsilon}$-CUPC/PVK double-layered photoconductors is studied also.

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