• 제목/요약/키워드: Double coating

검색결과 192건 처리시간 0.027초

플라스틱용 자외선경화형 도료의 물성연구 (Physical Properties of UV curable coating on plastic)

  • 김일재;문명준
    • 한국인쇄학회지
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    • 제16권3호
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    • pp.61-80
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    • 1998
  • To investigate in influence of photosensitizer used with benzophenone(BP) in the curing rate and physical properties of UV curable hard coating on plastic, we prepared UV curable clear and pigmented coatings with DEA, DMA, NPM and TEA as photosensitizer, respectively. The curing rate calculated from the decrease of the absorbance of acrylic double bond measured by FT-IR spectroscopy increased s follows; DEA>DMA>NPM>TEA. this order could be explained by the reactivity of diethylamino group of DEA and the ease of formation of activated complex between BP and photosensitizer during the curing process. In UV curable pigmented coatings, the order of curing rate increased as follows; DEA>DMA>TEA>NPM. It was found that the curing rate of the pigmented coating can be increased by light scattering of TiO$_2$. The hardness of coating film cured by photosensitization of DEA and DMA is higher than other photosensitizers due to the crosslinking reaction of DEA and DMA radical bound to polymer backbone.

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열처리 시간에 따른 Ni-P/Cr 이중 도금 층의 계면 거동에 관한 연구 (Effect of Heat Treatment on Interface Behavior in Ni-P/Cr Double Layer)

  • 최명희;박영배;이병호;변응선;이규환
    • 한국표면공학회지
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    • 제48권6호
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    • pp.260-268
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    • 2015
  • The thermal barrier coating (TBC) for inner wall of liquid-fuel rocket combustor consists of NiCrAlY as bonding layer and $ZrO_2$ as a top layer. In most case, the plasma spray coating is used for TBC process and this process has inherent possibility of cracking due to large difference in thermal expansion coefficients among bonding layer, top layer and metal substrate. In this paper, we suggest crack-free TBC process by using a precise electrodeposition technique. Electrodeposited Ni-P/Cr double layer has similar thermal expansion coefficient to the Cu alloy substrate resulting in superior thermal barrier performance and high temperature oxidation resistance. We studied the effects of phosphorous concentrations (2.12 wt%, 6.97 wt%, and 10.53 wt%) on the annealing behavior ($750^{\circ}C$) of Ni-P samples and Cr double layered electrodeposits. Annealing temperature was simulated by combustion test condition. Also, we conducted SEM/EDS and XRD analysis for Ni-P/Cr samples. The results showed that the band layers between Ni-P and Cr are Ni and Cr, and has no formed with heat treatment. These band layers were solid solution of Cr and Ni which is formed by interdiffusion of both alloy elements. In addition, the P was not found in it. The thickness of band layer was increased with increasing annealing time. We expected that the band layer can improve the adhesion between Cr and Ni-P.

Al-MIS(p-Si) 태양전지의 AR Coating 방법 (On the AR Coating Method of Al-MIS(p-Si) Solar Cel)

  • 엄경숙;백수현
    • 대한전자공학회논문지
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    • 제21권6호
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    • pp.64-69
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    • 1984
  • Al-MIS(p-Si)태양전지의 최대 효율은 Al 박막을 0.6A/sec 이하의 속도로 증착시켜 80Å인 두께가 되었을 때임을 알았다. ZnS와 SiO로 AR coating을 했는데, 단층 피막일때는 각각 570Å과 690Å인 박막 두께에서 최대 Isc를 나타냈다. 이는 quarter-coating 조건인 n1d1=λ/4를 만족함을 알았다. 이중층 피막일 때는 한 층을 단층 피막때의 최적 두께를 유지하면서 다른 한 층을 조절했다. 이때의 최대 Isc는 단층피막일 때와 비슷한 값이었으나 넓은 범위의 두께에서 그 값이 그대로 유지되었다. 한편 dzns/ds10=1.9/2.3=570/690인 관계를 유지하면서 총 두께를 각각의 단층피막때의 최적 두께 합에 대해서 70∼90%로 얇게 했을 때 앞에서 논의한 어떤 경우보다도 20%이상의 더 높은 Isc를 얻을 수 있었다 따라서 높은 효율을 얻으면서 정밀한 두께 조절이 불필요한 새로운 AR coating방법을 얻었다.

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Optimising Ink Setting Properties on Double Coated Wood-free Papers

  • Bluvol, Guillermo;Carlsson, Roger
    • 한국펄프종이공학회:학술대회논문집
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    • 한국펄프종이공학회 2006년도 PAN PACIFIC CONFERENCE vol.2
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    • pp.215-225
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    • 2006
  • Today's requirements for print-press runnability and print quality demand an optimised absorption and adhesion of printing ink on the paper surface. Modern coating concepts for high glossing offset grades use ultra fine pigments, whereas binder level has continuously been decreased to a minimum in recent years to achieve the highest possible sheet gloss development and for economical reasons. Both the ultra fine pigments and the reduced binder levels lead in many cases to a faster ink setting rate. On the other hand, matt paper grades use relatively coarse pigments leading to a slow ink setting compared to the high glossing papers. Both too fast and too slow ink setting properties implicate drawbacks in print quality and print press runnability. The mechanisms behind the interactions between ink and coating have been presented in many previous publications. The purpose of this study was to determine and quantify how the ink setting rate is influenced by pigment system (GCC and GCC/clay blends), latex level and latex properties in the topcoat of double coated sheet fed offset paper. The roles of binder level and type in the precoat were also assessed. The effect of calendering (temperature and pressure) was studied with one formulation. The resulting ink setting characteristics were tested using three different laboratory testing instruments. The correlation amongst the different laboratory testing methods is discussed. The results show that by varying the latex properties, the pigment system and/or latex addition level, the ink tack development of ink applied to a topcoat pigment system can be significantly influenced. It can be slowed down as often desired with ultra fine pigments or speeded up in the case of coarse pigments. There was no visible effect on the ink setting rate by using different binder systems in the precoat..

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졸-겔 스핀코팅법에 의한 반사방지 및 정전기방지 복층막의 제조 및 특성 (Preparation and Characterization of Anti-reflective and Anti-static Double Layered Films by Sol-Gel Spin-Coating Method)

  • 이준종;최세영
    • 한국세라믹학회지
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    • 제34권1호
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    • pp.79-87
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    • 1997
  • 졸-겔 스핀코팅법을 이용하여 VDT 기판에 반사방지 및 정전기방지 복층막을 코팅하고 코팅졸과 겔분말의 특성 및 코팅막의 전기적, 광학적, 기계적 특성을 조사하였다. 1층막은 복층막의 간섭조건을 만족시키는 굴절율을 얻기위해 투명 전도성 재료인 ATO(Antimony doped Tin Oxide) 졸과 SiO2 졸을 몰비 68:32로 혼합한 ATO-SiO2 복합졸을, 2층막에는 저굴절율의 SiO2 졸을 사용하였다. 각 코팅막을 45$0^{\circ}C$에서 30분간 열처리하였을 때 잔류 유기물은 완전히 제거되었다. ATO막의 표면저항은 3mol%의 Sb 첨가시 약 6$\times$107$\Omega$/$\square$로 최소를 나타내었고 SiO2 졸과의 혼합시 약 30mol% 까지는 표면저항이 완만히 증가하다가 그 이후에는 급격히 증가하는 경향을 나타내었으며, 간섭조건을 만족시키는 조성인 32mol%에서는 약 3$\times$108$\Omega$/$\square$를 나타내었다. 복층막의 반사율은 550nm의 기준파장에서 약 0.64%를 나타내었으며 광투과율은 약 3.20% 증가하였다. 복층막의 미소경도는 약 471.4kg.f/mm2로 코팅하지 않은 VDT기판의 경도와 유사한 값을 나타내었다.

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단결정 실리콘 태양전지의 MgF$_2$/CeO$_2$ 반사 방지막에 환한 연구 (A Study on MgF$_2$/CeO$_2$ AR Coating of Mono-Crystalline Silicon Solar Cell)

  • 유진수;이재형;이준신
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제52권10호
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    • pp.447-450
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    • 2003
  • This paper presents a process optimization of antireflection (AR) coating on crystalline Si solar cells. Theoretical and experimental investigations were performed on a double-layer AR (DLAR) coating of MgF$_2$/CeO$_2$. We investigated CeO$_2$ films as an AR layer because they have a proper refractive index of 2.46 and demonstrate the same lattice constant as Si substrate. RF sputter grown CeO$_2$ film showed strong dependence on a deposition temperature. The CeO$_2$ deposited at 40$0^{\circ}C$ exhibited a strong (111) preferred orientation and the lowest surface roughness of 6.87 $\AA$. Refractive index of MgF$_2$ film was measured as 1.386 for the most of growth temperature. An optimized DLAR coating showed a reflectance as low as 2.04% in the wavelengths ranged from 0.4${\mu}{\textrm}{m}$ to 1.1${\mu}{\textrm}{m}$. We achieved the efficiencies of solar cells greater than 15% with 3.12% improvement with DLAR coatings. Further details on MgF$_2$, CeO$_2$ films, and cell fabrication parameters are presented in this paper.

양날개 돌출형 방수시트를 이용한 접합부 탑다운 2중 보강방식 복합방수공법의 개발 연구(Mock-Up Test) (Development of combined waterproofing method of top-down double reinforced method using two-blade protruding waterproof sheet(Mock-Up Test))

  • 최은규;송제영;이선규;박종선;김병일;오상근
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2018년도 춘계 학술논문 발표대회
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    • pp.279-280
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    • 2018
  • The waterproofing material can be roughly divided into a coating material and a sheet waterproofing material. In the case of coating waterproofing materials, sheet waterproofing materials, which are easy to use in terms of workability and quality control, have been recently used because of their incomplete use of coating thickness, long curing time and poor blending due to in situ blending. However, in the case of the sheet waterproofing material, since the sheet overlapping portion is inevitably generated, various defects (breakage due to the behavior) are frequently observed. Therefore, it is imperative to establish fundamental measures to minimize this.

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Synthesis and Dispersion Stabilization of Indium Tin Oxide Nanopowders by Coprecipitation and Sol-Gel Method for Transparent and Conductive Films

  • Cho, Young-Sang;Hong, Jeong-Jin;Kim, Young Kuk;Chung, Kook Chae;Choi, Chul Jin
    • 대한금속재료학회지
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    • 제48권9호
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    • pp.831-841
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    • 2010
  • Indium tin oxide (ITO) nanopowders were synthesized by coprecipitation and the sol-gel method to prepare a stable dispersion of ITO nano-colloid for antistatic coating of a display panel. The colloidal dispersions were prepared by attrition process with a vibratory milling apparatus using a suitable dispersant in organic solvent. The ITO coating solution was spin-coated on a glass panel followed by the deposition of partially hydrolyzed alkyl silicate as an over-coat layer. The double-layered coating films were characterized by measuring the sheet resistance and reflectance spectrum for antistatic and antireflective properties.

Design of an Antireflection Coating for High-efficiency Superconducting Nanowire Single-photon Detectors

  • Choi, Jiman;Choi, Gahyun;Lee, Sun Kyung;Park, Kibog;Song, Woon;Lee, Dong-Hoon;Chong, Yonuk
    • Current Optics and Photonics
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    • 제5권4호
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    • pp.375-383
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    • 2021
  • We present a simulation method to design antireflection coating (ARCs) for fiber-coupled superconducting nanowire single-photon detectors. Using a finite-element method, the absorptance of the nanowire is calculated for a defined unit-cell structure consisting of a fiber, ARC layer, nanowire absorber, distributed Bragg reflector (DBR) mirror, and air gap. We develop a method to evaluate the uncertainty in absorptance due to the uncontrollable parameter of air-gap distance. The validity of the simulation method is tested by comparison to an experimental realization for a case of single-layer ARC, which results in good agreement. We show finally a double-layer ARC design optimized for a system detection efficiency of higher than 95%, with a reduced uncertainty due to the air-gap distance.