• Title/Summary/Keyword: Double coating

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Improvement of Electrochemical Performance of Lithium-ion Secondary Batteries using Double-Layered Thick Cathode Electrodes

  • Phiri, Isheunesu;Kim, Jeong-Tae;Kennedy, Ssendagire;Ravi, Muchakayala;Lee, Yong Min;Ryou, Myung-Hyun
    • Journal of the Korean Electrochemical Society
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    • v.25 no.1
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    • pp.32-41
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    • 2022
  • Various steps in the electrode production process, such as slurry mixing, slurry coating, drying, and calendaring, directly affect the quality and, consequently, mechanical properties and electrochemical performance of electrodes. Herein, a new method of slurry coating is developed: Double-coated electrode. Contrary to single-coated electrode, the cathode is prepared by double coating, wherein each coat is of half the total loading mass of the single-coated electrode. Each coat is dried and calendared. It is found that the double-coated electrode possesses more uniform pore distribution and higher electrode density and allows lesser extent of particle segregation than the single-coated electrode. Consequently, the double-coated electrode exhibits higher adhesion strength (74.7 N m-1) than the single-coated electrode (57.8 N m-1). Moreover, the double-coated electrode exhibits lower electric resistance (0.152 Ω cm-2) than the single-coated electrode (0.177 Ω cm-2). Compared to the single-coated electrode, the double-coated electrode displays higher electrochemical performance by exhibiting better rate capability, especially at higher C rates, and higher long-term cycling performance. Despite its simplicity, the proposed method allows effective electrode preparation by facilitating high electrochemical performance and is applicable for the large-scale production of high-energy-density electrodes.

Study on thermal performance of vacuum window with various low-ε coating glasses (저방사 코팅이 진공창의 열성능에 미치는 영향)

  • Cho, S.H.;Tae, C.S.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.9 no.3
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    • pp.300-311
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    • 1997
  • A theoretical method was developed to analyze the effect of low-$\varepsilon$ coatings which have influence on thermal performance of vacuum windwo glazing and double pane glazing. The overall heat transfer coefficient(U) value and thermal performance were analyzed by theroretical method on various kins of windows. TRNSYS program was used to analyze total heating and cooling energy consumption on the model building which has various windows. As the result, better thermal insulation can be achieved on the vacuum window glazing than double pane glazing when low-$\varepsilon$ coating was done on the surface of glass. Total heating and cooling energy consumption was almost same on the double pane window glazing but was lessened on the vacuum window glazing when the window size of south direction increased. Therefore, low-$\varepsilon$ coating was very necessary for vacuum window glazing in order to improve thermal insulation performance and efficient energy conservation can be achieved by vacuum window glazing at the real building which has large window.

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Simulation on Reflectance from Solar Cell Surface Using Double Layered Anti-Reflective Coating (Double layer 반사방지막 구조에 대한 태양전지 표면 반사율 simulation)

  • Ra, Chang-Ho;Yang, Cheng;Yoo, Won-Jong
    • Journal of Surface Science and Engineering
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    • v.43 no.2
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    • pp.97-104
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    • 2010
  • In this paper, we conducted MATLAB simulation using the reflectance formula and the Planck's black body radiation principle, for the purpose of identifying the opimum material and thickness of anti-reflective coating from double layered structures. We found that the optimum condition was obtained when refractive index of upper layer is 1.44 and that of lower layer is 2.29. As materials close to these refractive indices, $MgF_2$ as the upper layer and $HfO_2$, ZnS, $TiO_2$ as the lower layer were suggested. The best result in an average reflectance of 2.759% was obtained from a double layered structure of $MgF_2$ 94 nm/ZnS 55 nm.

The Morphology and Adhesion of TiCN Film formed by PECVD (PECVD 에 의해 형성된 TiCN 박막의 형상 및 밀착성)

  • Huh, J.;Nam, T.W.
    • Journal of the Korean Society for Heat Treatment
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    • v.15 no.3
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    • pp.118-126
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    • 2002
  • TiCN thin films were deposited on tool steels at $510^{\circ}C$ by PECVD from a $TiCl_4+N_2+CH_4+H_2+Ar$ gaseous mixture. The microstructures and preferred orientation were investigated. The micro-scratch tests were performed using a system equipped with an acoustic emission sensor. Critical loads were determined to evaluate the adhesion of TiCN to substrate. The influences of the microstructures of substrates, double layered coatings, and coatings after nitriding(duplex coating) were investigated. The experimental results showed that the microstructures of substrates and double layered coating did not affect the critical loads considerably. By the duplex coating, critical loads were not always increased. In some cases, duplex coatings decreased critical loads significantly despite of absence of black layer. In this study, we tried to relate the results of scratch test to the residual stress analysis. Nitriding before the coating reduces the tensile residual stress in the film, which gives rise to low critical load in scratch test.

Effects of Blending Ratio of Pigments on Properties and Printability of the Double Coated Paper (안료의 배합비가 더블 도공지의 물성 및 인쇄적성에 미치는 영향)

  • Kim, Chang-Keun;Lee, Yong-Kyu
    • Journal of Forest and Environmental Science
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    • v.18 no.1
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    • pp.97-105
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    • 2001
  • The main objective of this study was to investigate effects of pigment mixed with different ratio on the double coated paper. Mineral pigments such as clay and ground calcium carbonate(GCC) as well as hollow sphere plastic pigment were used to evaluate the physical, optical properties and printabilities of double coated paper. The physical properties such as gloss and smoothness, and the printability(ink gloss) of double coated paper were measured to evaluate the effects of the bottom layer on improving the properties of top layer. The data indicated that the usage of hollow sphere plastic pigment for the bottom layer coating improved the surface properties of double coated paper, and that ink gloss was significantly influenced by the structure of bottom layer even when hollow sphere plastic pigment was used for the bottom layer coating.

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Characteristics of Crystalline Silicon Solar Cells with Double Layer Antireflection Coating by PECVD (결정질 실리콘 태양전지의 이중 반사방지막 특성에 대한 연구)

  • Kim, Jin-Kuk;Park, Je-Jun;Hong, Ji-Hwa;Kim, Nam-Soo;Kang, Gi-Hwan;Yu, Gwon-Jong;Song, Hee-Eun
    • 한국태양에너지학회:학술대회논문집
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    • 2012.03a
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    • pp.243-247
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    • 2012
  • The paper focuses on an anti-reflection (AR) coating deposited by PECVD in silicon solar cell fabrication. AR coating is effective to reduce the reflection of the light on the silicon wafer surface and then increase substantially the solar cell conversion efficiency. In this work, we carried out experiments to optimize double AR coating layer with silicon nitride and silicon oxide for the silicon solar cells. The p-type mono crystalline silicon wafers with $156{\times}156mm^2$ area, 0.5-3 ${\Omega}{\cdot}cm$ resistivity, and $200{\mu}m$ thickness were used. All wafers were textured in KOH solution, doped with $POCl_3$ and removed PSG before ARC process. The optimized thickness of each ARC layer was calculated by theoretical equation. For the double layer of AR coating, silicon nitride layer was deposited first using $SiH_4$ and $NH_3$, and then silicon oxide using $SiH_4$ and $N_2O$. As a result, reflectance of $SiO_2/SiN_x$ layer was lower than single $SiN_x$ and then it resulted in increase of short-circuit current and conversion efficiency. It indicates that the double AR coating layer is necessary to obtain the high efficiency solar cell with PECVD already used in commercial line.

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Double Hole Transport Layers Deposited by Spin-coating and Thermal-evaporating for Flexible Organic Light Emitting Diodes

  • Chen, Shin Liang;Wang, Shun Hsi;Juang, Fuh Shyang;Tsai, Yu Sheng
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08a
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    • pp.741-744
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    • 2007
  • The research applied the processes of spin-coating and thermal-evaporating in proper order to deposit the hole transport material N,N'-Bis(naphthalen-1-yl)- N,N'-bis(phenyl)-benzidine (NPB) on the ITO substrate to make flexible organic light emitting diodes (FOLED) with double hole transport layer.

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Fabrication and Pore Properties of SUS316L Membrane with Double-Layered Pore Structures by Wet Powder Spraying

  • Min-Jeong Lee;Hyeon-Ju Kim;Manho Park;Jung-Yeul Yun
    • Archives of Metallurgy and Materials
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    • v.67 no.4
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    • pp.1531-1534
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    • 2022
  • In this study, a SUS316L membrane having double layered pore structures was fabricated, and the pore characteristics were analyzed after coating with a spherical powder and a flake-shaped powder on a disk-shaped SUS316L support using a wet powder spraying process. The thickness of the coated layer was checked using an optical microscope, and air permeability was measured using a capillary flow porometer. When the coating amount was similar, the fine porous layer prepared using flake powder was thicker and showed higher porosity. In the case of a similar thickness, the case of using flake powder was half of the amount of spherical powder used. Therefore, it was confirmed that it is possible to manufacture a metal membrane having a high filter efficiency even with a small coating amount when using the flake powder.

Influence of application methods of one-step self-etching adhesives on microtensile bond strength (한 단계 자가 산부식 접착제의 적용 방식이 미세인장 결합강도에 미치는 효과)

  • Choi, Chul-Kyu;Son, Sung-Ae;Ha, Jin-Hee;Hur, Bock;Kim, Hyeon-Cheol;Kwon, Yong-Hun;Park, Jeong-Kil
    • Restorative Dentistry and Endodontics
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    • v.36 no.3
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    • pp.203-210
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    • 2011
  • Objectives: The purpose of this study was to evaluate the effect of various application methods of one-step self-etch adhesives to microtensile resin-dentin bond strength. Materials and Methods: Thirty-six extracted human molars were used. The teeth were assigned randomly to twelve groups (n = 15), according to the three different adhesive systems (Clearfil Tri-S Bond, Adper Prompt L-Pop, G-Bond) and application methods. The adhesive systems were applied on the dentin as follows: 1) The single coating, 2) The double coating, 3) Manual agitation, 4) Ultrasonic agitation. Following the adhesive application, light-cure composite resin was constructed. The restored teeth were stored in distilled water at room temperature for 24 hours, and prepared 15 specimens per groups. Then microtensile bond strength was measured and the failure mode was examined. Results: Manual agitation and ultrasonic agitation of adhesive significantly increased the microtensile bond strength than single coating and double coating did. Double coating of adhesive significantly increased the microtensile bond strength than single coating did and there was no significant difference between the manual agitation and ultrasonic agitation group. There was significant difference in microtensile bonding strength among all adhesives and Clearfil Tri-S Bond showed the highest bond strength. Conclusions: In one-step self-etching adhesives, there was significant difference according to application methods and type of adhesives. No matter of the material, the manual or ultrasonic agitation of the adhesive showed significantly higher microtensile bond strength.

Anti-Reflective Coating with Hydrophilic/Abraion-Resistant Properties using TiO2/SiOxCy Double-Layer Thin Film (TiO2/SiOxCy 이중 박막을 이용한 투명 친수성/내마모성 반사방지 코팅)

  • Lee, Sung-jun;Lee, Min-kyo;Park, Young-chun
    • Journal of Surface Science and Engineering
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    • v.50 no.5
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    • pp.345-351
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    • 2017
  • A double-layered anti-reflective coating with hydrophilic/abrasion-resistant properties was studied using anatase titanium dioxide($TiO_2$) and silicon oxycarbide($SiO_xC_y$) thin film. $TiO_2$ and $SiO_xC_y$ thin films were sequentially deposited on a glass substrate by DC sputtering and PECVD, respectively. The optical properties were measured by UV-Vis-NIR spectrophotometer. The abrasion-resistance and the hydrophilicity were observed by a taber abrasion tester and a contact angle analyzer, respectively. The $TiO_2/SiO_xC_y$ double-layer thin film had an average transmittance of 91.3%, which was improved by 10% in the visible light region (400 to 800 nm) than that of the $TiO_2$ single-layer thin film. The contact angle of $TiO_2/SiO_xC_y$ film was $6.9^{\circ}$ right after UV exposure. After 9 days from the exposure, the contact angle was $10.2^{\circ}$, which was $33^{\circ}$ lower than that of the $TiO_2$ single-layer film. By the abrasion test, $SiO_xC_y$ film showed a superior abrasion-resistance to the $TiO_2$ film. Consequently, the $TiO_2/SiO_xC_y$ double-layer film has achieved superior anti-reflection, hydrophilicity, and abrasion resistance over the $TiO_2$ or $SiO_xC_y$ single-layer film.