• Title/Summary/Keyword: Double activation

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Correlation between Trunk Stabilization Muscle Activation and Gait Parameters (몸통 안정화 근육과 보행요소의 상관관계)

  • Chae, Jung-Byung;Jung, Ju-Hyeon
    • PNF and Movement
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    • v.17 no.1
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    • pp.111-118
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    • 2019
  • Purpose: This study aimed to investigate the correlation between trunk stabilization muscle activation and the parameters of gait analysis in healthy individuals. Methods: Thirty healthy adults (15 male, 15 female) with no history of lower back pain (LBP) or current musculoskeletal and neurological injuries were studied. Trunk stabilization muscle activation (e.g., external oblique, internal oblique, transverse abdominis, erector spinae) were assessed using surface electromyography. To analyze gait, we measured temporal parameters (e.g., gait velocity, single support phase, double support phase, swing phase, and stance phase) and a spatial parameter (e.g., H-H base of support). Results: A statistically significant correlation was found between the internal oblique, transverse abdominis, and erector spinae muscle activity and gait velocity, single support phase, double support phase, swing phase, and stance phase. No statistically significant correlation was found between the external oblique muscle activity and the gait velocity, single support phase, double support phase, swing phase, and stance phase. No statistically significant correlation was found between the external oblique, internal oblique, transverse abdominis, and erector spinae muscle activity and the spatial parameter. Conclusion: This study demonstrated that a relationship exists between trunk stabilization muscle activation and temporal parameter (i.e., gait velocity, single support phase, double support phase, swing phase, and stance phase) during gait analysis. Therefore, the trunk's stabilizer muscles play an important role in the gait of healthy individuals.

Asymmetric Cyanosilylation of Aldehydes by Chiral Ti-TADDOL Complex

  • Kim, Sung-Soo;Kwak, Ju-Myung;Rajagopal, Gurusamy
    • Bulletin of the Korean Chemical Society
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    • v.27 no.10
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    • pp.1638-1640
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    • 2006
  • A variety of chiral cyanohydrins were readily prepared from aldehydes with TMSCN under the influence of chiral titanium complex formed in situ from $Ti(O^iPr)_4$/TADDOL(I) in the presence of $Ph_3PO$ as additive. The double activation method produces trimethylsilylethers in excellent yield (95%) with moderate enantiomeric excess.

Activated carbons prepared from mixtures of coal tar pitch and petroleum pitch and their electrochemical performance as electrode materials for electric double-layer capacitor

  • Lee, Eunji;Kwon, Soon Hyung;Choi, Poo Reum;Jung, Ji Chul;Kim, Myung-Soo
    • Carbon letters
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    • v.16 no.2
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    • pp.78-85
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    • 2015
  • Activated carbons (ACs) were prepared by activation of coal tar pitch (CTP) in the range of $700^{\circ}C-1000^{\circ}C$ for 1-4 h using potassium hydroxide (KOH) powder as the activation agent. The optimal activation conditions were determined to be a CTP/KOH ratio of 1:4, activation temperature of $900^{\circ}C$, and activation time of 3 h. The obtained ACs showed increased pore size distribution in the range of 1 to 2 nm and the highest specific capacitance of 122 F/g in a two-electrode system with an organic electrolyte, as measured by a charge-discharge method in the voltage range of 0-2.7 V. In order to improve the performance of the electric double-layer capacitor electrode, various mixtures of CTP and petroleum pitch (PP) were activated at the optimal activation conditions previously determined for CTP. Although the specific capacitance of AC electrodes prepared from CTP only and the mixtures of CTP and PP was not significantly different at a current density of 1 A/g, the AC electrodes from CTP and PP mixtures showed outstanding specific capacitance at higher current rates. In particular, CTP-PP61 (6:1 mixture) had the highest specific capacitance of 132 F/g, and the specific capacitance remained above 90% at a high current density of 3 A/g. It was found that the high specific capacitance could be attributed to the increased micro-pore volume of ACs with pore sizes from 1 to 2 nm, and the high power density could be attributed to the increased meso-pore volume.

Preparation and Characterization of Carbon Nanotubes-Based Composite Electrodes for Electric Double Layer Capacitors

  • Seo, Min-Kang;Park, Soo-Jin
    • Bulletin of the Korean Chemical Society
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    • v.33 no.5
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    • pp.1523-1526
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    • 2012
  • In this work, we prepared activated multi-walled carbon nanotubes/polyacrylonitrile (A-MWCNTs/C) composites by film casting and activation method. Electrochemical properties of the composites were investigated in terms of serving as MWCNTs-based electrode materials for electric double layer capacitors (EDLCs). As a result, the A-MWCNTs/C composites had much higher BET specific surface area, and pore volume, and lower volume ratio of micropores than those of pristine MWCNTs/PAN ones. Furthermore, some functional groups were added on the surface of the A-MWCNTs/C composites. The specific capacitance of the A-MWCNTs/C composites was more than 4.5 times that of the pristine ones at 0.1 V discharging voltage owing to the changes of the structure and surface characteristics of the MWCNTs by activation process.

Electrochemical Characteristics of Highly Porous Carbon Prepared by Chemical Activation Method for EDLC (화학적 활성법으로 제조된 EDLC용 고다공성 탄소전극의 전기화학 특성)

  • Eo, Soo-Mi;Kim, Han-Joo;Oh, Seung-Mo;Park, Soo-Gil
    • Proceedings of the KIEE Conference
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    • 2005.07c
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    • pp.2010-2012
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    • 2005
  • Activated carbon was activated with chemical treatment to attain high surface area with porous structure. We have been considered activated carbon is the ideal material for high voltage electric double layer capacitor due to their high specific surface area, good conductivity and chemical stability. In this study we found that increase in electrochemical capacitance due to activated carbon. Also chemically activated carbon and water treatment have resulted larger capacitance and also exhibits better electrochemical behavior, and is about 15% more than in untreated state. The structural change in activated carbon through chemical treatment activation was investigated by using SEM and XRD. In this study, the dependence of the activation behavior with KOH in the micro structure of host materials will be discussed. Furthermore, the relation to the electric double layer capacitance, especially the specific capacitance per unit area, is also discussed.

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Preparation and Characterization of high-quality activated carbon by KOH activation of pitch precursors (KOH 활성화에 의한 피치계 고품질 활성탄의 제조 및 특성)

  • Lee, Eun-Ji;Kwon, Soon-Hyung;Choi, Poo-Reum;U, Jong-Pyo;Jung, Ji-Chul;Kim, Myung-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.3
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    • pp.408-415
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    • 2014
  • In order to prepare high-quality activated carbons (ACs), coal tar pitch (CTP), and mixtures of CTP and petroleum pitch (PP) were activated with KOH. The ACs prepared by activation of CTP in the range of $700{\sim}1000^{\circ}C$ for 1~5 h had very porous textures with large specific surface areas of $2470{\sim}3081m^2/g$. The optimal activation conditions of CTP were determined as CTP/KOH ratio of 1:4, activation temperature of $900^{\circ}C$, and activation time of 3 h. The obtained AC showed the highest micro-pore volume, and pretty high specific surface area and meso-pore volume. The micro-pore volumes and specific areas of activated mixtures of CTP and PP were similar to each other but the meso-pore volume could be increased. In order to change the degree of crystallinity of precursors before KOH activation process, the CTPs were carbonized in the range of $500{\sim}900^{\circ}C$. As the carbonization temperature increased, the specific surface area and pore volume of the activated ACs with the same activation conditions for CTP decreased dramatically. It was demonstrated that the increased pore size distribution of AC electrodes in the range of 1 to 2 nm plays an important role in the performance of electric double-layer capacitor.

High-energy-density activated carbon electrode for organic electric-double-layer-capacitor using carbonized petroleum pitch

  • Choi, Poo Reum;Kim, Sang-Gil;Jung, Ji Chul;Kim, Myung-Soo
    • Carbon letters
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    • v.22
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    • pp.70-80
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    • 2017
  • Activated carbons (ACs) have been used as electrode materials of electric double-layer capacitors (EDLC) due to their high specific surface areas (SSA), stability, and ecological advantages. In order to make high-energy-density ACs for EDLC, petroleum pitch (PP) pre-carbonized at $500-1000^{\circ}C$ in $N_2$ gas for 1 h was used as the electrode material of the EDLC after KOH activation. As the pre-carbonization temperature increased, the SSA, pore volume and gravimetric capacitance tended to decrease, but the crystallinity and electrode density tended to increase, showing a maximum volumetric capacitance at a medium carbonization temperature. Therefore, it was possible to control the crystalline structure, SSA, and pore structure of AC by changing the pre-carbonization temperature. Because the electrode density increased with increasing of the pre-carbonization temperature, the highest volumetric capacitance of 28.4 F/cc was obtained from the PP pre-carbonized at $700^{\circ}C$, exhibiting a value over 150% of that of a commercial AC (MSP-20) for EDLC. Electrochemical activation was observed from the electrodes of PP as they were pre-carbonized at high temperatures above $700^{\circ}C$ and then activated by KOH. This process was found to have a significant effect on the specific capacitance and it was demonstrated that the higher charging voltage of EDLC was, the greater the electrochemical activation effect was.