• 제목/요약/키워드: Distribution rate constant

검색결과 363건 처리시간 0.025초

PA 6,6/EPM/EPM-g-MA 블렌드물의 특성과 Morphology 관계 (Relationships between Morphologies and Properties of PA 6,6/EPM/EPM-g-MA Blends)

  • 이융;이창우;장윤호;함영민
    • 공업화학
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    • 제10권5호
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    • pp.682-689
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    • 1999
  • 본 연구는 용융법에 의한 폴리아미드 6,6과 EPM 및 EPM-g-MA와 블렌딩시 탄성 중합체 함유량, 조성비(wt %), 혼합온도, 혼합속도 등의 변화에 따른 이성분 PA 6,6/EPM(or EPM-g-MA) 블렌드물과 삼성분 PA 6,6/EPM/EPM-g-MA 블렌드물을 제조하여 블렌드물 내 탄성 중합체 평균 입자 크기, 입자 형상 및 분포 등의 변화를 분석하고, 이에 따른 블렌드물의 기계적, 열적 특성에 미치는 영향을 고찰하였다. 본 연구결과, 혼합속도 250 rpm하에서 압출기 내 다섯 영역의 온도를 270, 265, 265, 255 및 $255^{\circ}C$로 변화시켜 탄성 중합체의 함유량 변화에 의하여 제조된 이성분 블렌드물중 높은 충격강도는 PA 6,6/EPM-g-MA(70/30) 블렌드물에서 확인되었으며 폴리아미드 6,6의 충격강도에 비하여 25배 증가하였다. 동일한 압출기 내 조건하에서 제조된 삼성분 블렌드물 중 PA 6,6/EPM/EPM-g-MA(70/15/15) 블렌드물 내 탄성 중합체 평균 입자크기는 $0.56{\mu}m$이면서 고른 입자분포를 나타내었으며 충격강도는 제조된 모든 블렌드물 중 가장 높았다. 이러한 블렌드물의 조성비하에서 혼합온도와 혼합속도 변화에 의하여 제조된 블렌드물의 기계적 특성과 블렌드물 내 탄성 중합체 분산정도는 감소하였다.

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사각형제트와 2차원제트의 거동해석의 비교 평가 (Comparative Evaluation of Behavior Analysis of Rectangular Jet and Two-dimensional Jet)

  • 권석재;조홍연;서일원
    • 대한토목학회논문집
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    • 제26권6B호
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    • pp.641-649
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    • 2006
  • 본 연구에서는 PIV를 이용하여 측정한 평균유속장의 실험결과에 근거하여 10의 종횡비를 갖는 3차원 순수사각형제트의 거동을 고찰하였다. 장축상의 횡분포에서 안장형 분포가 관찰되었다. 점원개념으로부터 유도된 이론적인 중심선유속의 식은 측정된 중심선유속과 잘 일치하였으며 원류핵영역, 2차원영역, 그리고 축대칭영역의 분할을 제시하였다. 이러한 이론적인 중심선유속의 감소에 의해 분할된 2차원영역의 범위가 천이영역에 비해 상대적으로 작게 관찰되었다. 작은 종횡비를 갖는 사각형제트의 거동이나 실제 해양의 깊은 수심에서 다공확산관을 통해 방류되는 하 폐수의 거동을 예측하기 위한 2차원모형의 적용은 2차원영역을 지난 천이영역과 축대칭영역에서 중대한 오차를 야기할 수 있다. 2차원영역에서 가우스 상수가 보존되는 경향을 보였으며 2차원영역의 끝 지점에서 확장률이 감소함을 알 수 있었다. 중심선유속으로 무차원화 된 중심선 난류 강도는 초기에 급격히 증가하였고 높은 레이놀즈수에서 상대적으로 높은 난류강도를 보여주었다.

태양열을 이용한 농산물건조에 관한 연구 (I)-벼의 건조에 대하여 (Drying of Crops with Solar Heated Air -Drying of Rough Rice -)

  • 이문남;금동혁;류능환
    • Journal of Biosystems Engineering
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    • 제3권2호
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    • pp.100-113
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    • 1978
  • Drying grain with conventional artificial drying methods requires great quantities of petroleum fuels. Depletion of fossil fuel increases the need of the utilization of solar energy as an alternative to petroluem fuels for drying grain , an energy intensive agricultural operation. Many techniques for the utilization of solar energy in grain drying have been developed, however, there are many problems in adopting solar energy as an energy sources for drying grain. Futhermore, very little research has been done on solar grain drying in Korea. This study was conducted to evaluate the availability of solar energy for drying of rough rice in Chuncheon, Suweon, and Jinju areas based on 50year meteorological data, and to analyze experimentally the performance of a solar air collector for dying grain, and to find the effects of solar heated air compared to unheated air on the rate of drying and energy consumption required for drying of rough rice. The results of this study was may be summarized as follows ; 1. Monthly average daily total radiation on a horizontal surface in October was 260.6 ly/day for Chuncheon, 240.3 ly/day for Suweon , and 253.4 ly/day for Jinju area, respectively. 2. the ratio of monthly average daily diffuse radiation to daily total radiation on a horizontal surface was approximately 0.41 for Chuncheon, 0.45 for Suweon, and 0.44 for Jinju area, respectively. 3. Although the statistical distribution curves of daily total radiation for the three locations were not identical , the differences among them were not large and may be neglected for many practical purposes. 4. I was estimated that the optimum tilting angle of the collector in October was approximately 46 degrees for Chuncheon and Suweon and 45 degrees for Jinju. 5. The ratio of the total radiation on a optimum tilting plane to that on a horizontal plane was estimated to be 1.36 for Chuncheon, 1.31 for Suweon, and 1.27 for Jinju , respectively. 6. The collection efficiency of the solar air collector ranged from 47. 8 to 51. 5 percent at the air flow rates of 251. 1-372.96 $m^3$/hr. High efficiency remained nearly , constant during the best sunshine hours, 10 a.m. to 2 p.m. and decreased during other hours. More energy was collected as the air flow rate incresed. 7. The average temperature rise in the drying air from the solar collector for the test period varied from $6.5^\circC$ to $21.8^\circC$ above the ambient air temperature. 8. Solar-dried rough rice averaged 13.7 percent moisture (w.b.) after 130 hours of drying with the air flow rate of 1. 64 ccm/$m^3$, and rough rice dried with natural air averaged 15.1 percent moisture (w.b.) after 325 hours of drying with the same air flow rate. 9. Energy saving of 2.4 kwh per $m^3$ percentage point of moisture removed was obtained from solar heated air drYing. The solar bin used 53.3 percent less energy per percentage point of moisture removed than the natural air bin.

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근접조사용 Ir-192 마이크로선원의 디자인과 선량 특성 (The Dose Characteristics of Designed Ir-192 Micro-source for Brachytherapy)

  • 최태진;김진희
    • 한국의학물리학회지:의학물리
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    • 제14권2호
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    • pp.81-89
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    • 2003
  • 근접조사용 선원으로 직경이 0.5 mm에 길이 3.5 mm인 Ir-192선원을 고안하고, 선량알고리즘을 개발하였다. 선원을 0.1 mm 두께로 균등분할하고 총 875개의 미소선원으로부터 조직에 도달되는 선량을 계산하고 선량분포를 조사하였다. 선원을 감싸는 캡슐용기의 두께는 0.3 mm이며, 선량기준점인 Ir선원의 Air-kerma strength(S$_{k}$ ) 는 mCi당 4.108U를 얻었으며 선원 측방의 1 cm에서 1.154 Uh$^{-1}$ (1.3167${\times}$$10^{-3}$cGy/mCi-sec)의 조직선량률을 얻었다. Air-kerma strength로부터 조직내 선량률상수(Λ)는 Ir-192에너지 스펙트럼과 실험치인 조직내 산란보정계수를 적용하여 1.154 cGy h$^{-1}$U$^{-1}$ 얻었다. 선량분포의 특성은 선원 축방향으로 56%의 상대선량률을 보였고, 케이블측의 선량감쇠는 50%를 보였다. 마이크로선원의 중심에서 반경 1 cm 주위의 선량분포와 5 cm의 선량분포를 비교한 결과 반경이 큰 경우의 측방선량에 비해 축 방향의 선량이 약 2% 감쇠함을 보았다. 선원자체의 필터효과는 점선원에 비해 88.3%의 선량률을 얻어 약 12%의 감쇠를 보였으며, 캘슐벽의 필터효과는 약 3% 정도로 미미하게 나타났으며 기준점에서 선량필터효과는 약 15.6% 감쇠되는 것으로 나타났다. Ir-192 선원과 같이 에너지가 낮은 선원을 사용하는 경우 선량분포특성에 따라 아프리케이터의 직경을 크게 하여 선원 축 방향의 선량저하를 피할 수 있음을 알 수 있었다.

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유동층 연소로에서 유.무연탄 혼합 연소법을 이용한 국내산 저질 무연탄의 활용에 관한 연구 (A Study on the Use of Low-Grade Domestic Anthracite by Anthracite - Bituminous Coal Blend Combustion in a Fluidized Bed Combustor)

  • 정종현;조상원
    • 한국환경과학회지
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    • 제6권3호
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    • pp.267-276
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    • 1997
  • It has been studded that combustion and the production of air pollution of anthracite - bituminous coal blend In a fluidized bed coal combustor, The objects of thIns study were to investigate mixing characteristics of the particles as well as the combustibility of the low grade domestic anthracite coal and Imported h19h calorific bltununous coal in the fluidized bed coal combustor. They were used as coal samples ; the domestic low grade anthracite coal with heating value of 2,010kca1/kg and the Imported high grade bituminous coal with beating value of 6,520kca1/kg. Also, the effects of air flow rate and anthracite fraction on the reaching time of steady state condition have been studied. The experimental results are presented as follows. The time of reaching to steady state was affected by the temperature variation. The steady state time was about 120 minute at 300sc1h which was the fastest. It has been found that $O^2$ and $CO^2$ concentration were reached steady state at about 100 minute. It has been found that $O^2$ concentration decreased and $CO^2$ concentration increased as the height of fluidlzed bed Increased. It was found that splash zone was mainly located from 25cm to 35cm above distributor. Also, as anthracite traction Increased, the mass of elutrlatlon particles Increased, and $CO^2$ concentration decreased. As gk flow rate Increased,$O^2$ concentration decreased and $CO^2$ concentration increased. Regardless of anthracite fraction and flow rate, the uncombustible weight percentage according to average diameter of elutriation particles were approldmately high In the case of One Particles. As anthracite traction and k now rate Increased, elutriation ratio Increased. As anthracite fraction was increased, exit combustible content over feeding combustible content was Increased. Regardless of anthracite fraction, size distribution of Ued material from discharge was almost constant. Over bed temperature 85$0^{\circ}C$ and excess air 20% , the difference of combution efficiencies were little. It is estimate that the combustion condition In anthracite-bituminous coal blend combustion is suitable at the velocity 0.3m/s, bed temperature 85$0^{\circ}C$, the excess air 20%.

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Grouting diffusion mechanism in an oblique crack in rock masses considering temporal and spatial variation of viscosity of fast-curing grouts

  • Huang, Shuling;Pei, Qitao;Ding, Xiuli;Zhang, Yuting;Liu, Dengxue;He, Jun;Bian, Kang
    • Geomechanics and Engineering
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    • 제23권2호
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    • pp.151-163
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    • 2020
  • Grouting method is an effective way of reinforcing cracked rock masses and plugging water gushing. Current grouting diffusion models are generally developed for horizontal cracks, which is contradictory to the fact that the crack generally occurs in rock masses with irregular spatial distribution characteristics in real underground environments. To solve this problem, this study selected a cement-sodium silicate slurry (C-S slurry) generally used in engineering as a fast-curing grouting material and regarded the C-S slurry as a Bingham fluid with time-varying viscosity for analysis. Based on the theory of fluid mechanics, and by simultaneously considering the deadweight of slurry and characteristics of non-uniform spatial distribution of viscosity of fast-curing grouts, a theoretical model of slurry diffusion in an oblique crack in rock masses at constant grouting rate was established. Moreover, the viscosity and pressure distribution equations in the slurry diffusion zone were deduced, thus quantifying the relationship between grouting pressure, grouting time, and slurry diffusion distance. On this basis, by using a 3-d finite element program in multi-field coupled software Comsol, the numerical simulation results were compared with theoretical calculation values, further verifying the effectiveness of the theoretical model. In addition, through the analysis of two engineering case studies, the theoretical calculations and measured slurry diffusion radius were compared, to evaluate the application effects of the model in engineering practice. Finally, by using the established theoretical model, the influence of cracking in rock masses on the diffusion characteristics of slurry was analysed. The results demonstrate that the inclination angle of the crack in rock masses and azimuth angle of slurry diffusion affect slurry diffusion characteristics. More attention should be paid to the actual grouting process. The results can provide references for determining grouting parameters of fast-curing grouts in engineering practice.

Sodium Dependent Taurine Transport into the Choroid Plexus, the Blood-Cerebrospinal Fluid Barrier

  • Chung, Suk-Jae;Ramanathan, Vikram;Brett, Claire M.;Giacomini, Kathleen M.
    • Journal of Pharmaceutical Investigation
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    • 제25권3호spc1호
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    • pp.7-20
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    • 1995
  • Taurine, a ${\beta}-amino$ acid, plays an important role as a neuromodulator and is necessary for the normal development of the brain. Since de novo synthesis of taurine in the brain is minimal and in vivo studies suggest that taurine dose not cross the blood-brain barrier, we examined whether the choroid plexus, the blood-cerebrospinal fluid (CSF) barrier, plays a role in taurine transport in the central nervous system. The uptake of $[^3H]-taurine$ into ATP depleted choroid plexus from rabbit was substantially greater in the presence of an inwardly directed $Na^+$ gradient taurine accumulation was negligible. A transient in side-negative potential gradient enhanced the $Na^+-driven$ uptake of taurine into the tissue slices, suggesting that the transport process is electrogenic, $Na^+-driven$ taurine uptake was saturable with an estimated $V_{max}$ of $111\;{\pm}\;20.2\;nmole/g/15\;min$ and a $K_M\;of\;99.8{\pm}29.9\;{\mu}M$. The estimated coupling ratio of $Na^+$ and taurine was $1.80\;{\pm}\;0.122.$ $Na^+-dependent$ taurine uptake was significantly inhibited by ${\beta}-amino$ acids, but not by ${\alpha}-amino$ acids, indicating that the transporter is selective for ${\beta}-amino$ acids. Since it is known that the physiological concentration of taurine in the CSF is lower than that in the plasma, the active transport system we characterized may face the brush border (i.e., CSF facing) side of the choroid plexus and actively transport taurine out of the CSF. Therefore, we examined in vivo elimination of taurine from the CSF in the rat to determine whether elimination kinetics of taurine from the CSF is consistent with the in vitro study. Using a stereotaxic device, cannulaes were placed into the lateral ventricle and the cisterna magna of the rat. Radio-labelled taurine and inulin (a marker of CSF flow) were injected into the lateral ventricle, and the concentrations of the labelled compounds in the CSF were monitored for upto 3 hrs in the cisterna magna. The apparent clearance of taurine from CSF was greater than the estimated CSF flow (p<0.005) indicating that there is a clearance process in addition to the CSF flow. Taurine distribution into the choroid plexus was at least 10 fold higher than that found in other brain areas (e. g., cerebellum, olfactory bulb and cortex). When unlabelled taurine was co-administered with radio-labelled taurine, the apparent clearance of taurine was reduced (p<0.0l), suggesting a saturable disposition of taurine from CSF. Distribution of taurine into the choroid plexus, cerebellum, olfactory bulb and cortex was similarly diminished, indicating that the saturable uptake of taurine into these tissues is responsible for the non-linear disposition. A pharmacokinetic model involving first order elimination and saturable distribution described these data adequately. The Michaelis-Menten rate constant estimated from in vivo elimination study is similar to that obtained in the in vitro uptake experiment. Collectively, our results demonstrate that taurine is transported in the choroid plexus via a $Na^+-dependent,saturable$ and apparently ${\beta}-amino$ acid selective mechanism. This process may be functionally relevant to taurine homeostasis in the brain.

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EQC 모델을 이용한 벤조일 퍼록사이드의 다매체 환경거동 예측 (Estimation of Multimedia Environmental Distribution for Benzoyl peroxide Using EQC Model)

  • 김미경;배희경;송상환;구현주;김현미;최광수;전성환;이문순
    • 대한환경공학회지
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    • 제27권10호
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    • pp.1090-1098
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    • 2005
  • 벤조일 퍼록사이드는 수서생물에 대해 매우 높은 독성을 나타냄에도 불구하고 환경 중 잔류 농도 및 노출영향에 대해 연구가 이루어지지 않아 OECD에서 추천하고 있는 대표적인 다매체 환경거동 모델인 EQC 모델을 이용하여 본 물질에 대한 환경중의 농도를 예측하고 위해성평가 및 화학물질의 관리를 수행하기 위한 기초자료로 활용코자 하였다. 평형, 정상상태에서 100,000 kg의 벤조일 퍼록사이드가 환경내로 유입된 상태를 나타내는 Level I과 평형, 정상상태 이류와 분해현상이 있고 일정한 속도 1,000 kg/h로 유입되었을 경우를 나타내는 Level II에서 벤조일 퍼록사이드는 주로 토양(68.3%)과 물(28.7%)로 배출되는 것으로 예측되었다. 비평형, 정상상태, 이류와 분해현상이 있고 다매체 이동을 하는 시스템에서 벤조일 퍼록사이드가 대기, 물, 토양, 침전물의 각각의 4개 매체에 연속적으로 1,000 kg/h로 유입될 경우인 Level III에서는 주로 토양(99.9%)으로 배출되었고 전체 잔류시간은 3.4년으로 예측되어 벤조일 퍼록사이드가 환경 중에 잔류성이 있는 물질로 평가되었다.

Robust Design for Showerhead Thermal Deformation

  • 공대위;김호준;이승무;원제형
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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    • pp.150.1-150.1
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    • 2014
  • Showerhead is used as a main part in the semiconductor equipment. The face plate flatness should remain constant and the cleaning performance must be gained to keep the uniformity level of etching or deposition in chemical vapor deposition process. High operating temperature or long period of thermal loading could lead the showerhead to be deformed thermally. In some case, the thermal deformation appears very sensitive to showerhead performance. This paper describes the methods for robust design using computational fluid dynamics. To reveal the influence of the post distribution on flow pattern in the showerhead cavity, numerical simulation was performed for several post distributions. The flow structure appears similar to an impinging flow near a centered baffle in showerhead cavity. We took the structure as an index to estimate diffusion path. A robust design to reduce the thermal deformation of showerhead can be achieved using post number increase without ill effect on flow. To prevent the showerhead deformation by heat loading, its face plate thickness was determined additionally using numerical simulation. The face plate has thousands of impinging holes. The design key is to keep pressure drop distribution on the showerhead face plate with the holes. This study reads the methodology to apply to a showerhead hole design. A Hagen-Poiseuille equation gives the pressure drop in a fluid flowing through such hole. The assumptions of the equation are the fluid is viscous-incompressible and the flow is laminar fully developed in a through hole. An equation can be expressed with radius R and length L related to the volume flow rate Q from the Hagen-Poiseuille equation, $Q={\pi}R4{\Delta}p/8{\mu}L$, where ${\mu}$ is the viscosity and ${\Delta}p$ is the pressure drop. In present case, each hole has steps at both the inlet and the outlet, and the fluid appears compressible. So we simplify the equation as $Q=C(R,L){\Delta}p$. A series of performance curves for a through hole with geometric parameters were obtained using two-dimensional numerical simulation. We obtained a relation between the hole diameter and hole length from the test cases to determine hole diameter at fixed hole length. A numerical simulation has been performed as a tool for enhancing showerhead robust design from flow structure. Geometric parameters for the design were post distribution and face plate thickness. The reinforced showerhead has been installed and its effective deposition profile is being shown in factory.

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동해 울릉분지 해저 경계면의 용존산소 (Dissolved Oxygen at the Bottom Boundary Layer of the Ulleung Basin, East Sea)

  • 강동진;김윤배;김경렬
    • Ocean and Polar Research
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    • 제32권4호
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    • pp.439-448
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    • 2010
  • CTD를 이용하여 용존산소의 농도에 대한 연속적인 관측이 이루어지면서 용존산소 농도 분포의 fine structure에 대한 연구가 가능해졌다. 뿐만 아니라 altimeter로부터 해저 퇴적물 표면에 최대한 가까이 까지 관측이 가능해짐에 따라 해저 경계면에서의 용존산소 농도 분포에 대한 정보를 얻을 수 있게 되었다. 지금까지 동해 울릉분지의 용존 산소 농도의 수직 분포는 동해 북부의 일본 분지와는 수심 300 m 이하에서는 수심에 따라 지속적으로 감소하는 형태를 보이는 것으로 알려져 있다. 그러나 2005년부터 2006년까지 6회에 걸쳐 수심이 1000 m보다 깊은 지역에서 해저퇴적물 상부 100 m 이내의 수심까지 용존산소를 관측한 결과, 울릉분지 내의 용존 산소 농도의 수직분포형태는 3가지로 분류된다. 첫 번째는 지금까지 알려진 바와 같이 수심에 따라 지속적으로 감소하는 형태(Type-1), 두 번째는 Type-1과 같은 형태를 보이다가 해저 경계면 근처에서 급격히 산소의 농도가 줄어드는 형태(Type-2), 세 번째는 해저 경계면 상층에 용존산소 농도의 최소층이 존재하는 형태(Type-3)이다. 울릉분지 수심 1000 m 이상되는 지역에서는 분지 전반에 걸쳐 Type-2 형태로 분포하고 Ulleung Interplane Gap을 포함하여 일본 분지와 가까운 지역에서는 Type-1, 독도 인근 해역에서는 Type-3 형태의 분포를 보인다. 표층 퇴적물에서 유기물 분해를 전제로 해저 경계면의 용존 산소 분포를 이용하여 계산된 표층 퇴적물의 산소 소모율은 $0.2{\sim}5.8\;mmol\;m^{-2}d^{-1}$로 실제 퇴적물 배양을 통해 얻은 산소 소모율 약 $1{\sim}9\;mmol\;m^{-2}d^{-1}$(정 등 2009; 이 등 2010b)와 일치하는 것으로 미루어 볼 때, 울릉분지의 전반에 걸쳐 Type-2와 같은 형태의 분포를 보이는 것은 울릉분지의 표층 퇴적물에서 높은 농도를 보이는 유기물의 분해가 일차적으로 중요한 역할을 하는 것으로 판단된다.