• 제목/요약/키워드: Distribution rate constant

검색결과 362건 처리시간 0.023초

기-고 유동층에서 Gaussian 분포 입자군의 표준편차에 따른 유출 특성 (The Characteristics of Elutriation with Gaussian Particle Size Distributions in a gas-solid fluidized bed)

  • 장현태;차왕석
    • 한국산학기술학회논문지
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    • 제10권11호
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    • pp.3274-3279
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    • 2009
  • 기-고 유동층에서 다입자경 입자의 입자분포 변화에 따른 비산유출 특성을 연구하였다. 다입자경 입자분포는 Gaussian 분포를 사용하여 실험을 수행하였다. 최소유동화속도에 대한 유속비와 Gaussian 입자분포의 표준편차에 따른 비산유출상수를 구하였으며, 이때 조업시간에 따른 압력요동의 특성치를 구하였다. 측정된 유동층의 압력요동 특성치로부터 압력요동의 표준편차, 평균압력, Power spectrum density function, 주진동수 등을 계산하였다. 입자분포군에 따라서 유출입자의 입자분포 및 압력요동 특성치는 크게 영향을 받는 것으로 나타났으며 이러한 결과로부터 압력요동 특성치로부터 유출특성의 해석이 가능함을 알 수 있었다.

혐기성 미생물부식에 의해 생성되는 철화합물 추정식 개발 (The Development of Estimation Model for Iron Compound Originated from Anaerobic Microbial Corrosion)

  • 전석준
    • 한국물환경학회지
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    • 제18권4호
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    • pp.379-386
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    • 2002
  • In this study, estimation model for iron compound originated from upflow, anaerobic fixed bed reactor, which treats sewage domestic wastewater, was developed. The estimation model was formulated by a mathematical expression which was based on the mass balance. Below the HRT of 60 minute, sulfide concentration combining with iron $FeS_2$ is the highest because the maximum sulfate consumption rate $V_{maxS}$ and half-saturation constant of sulfate $K_{mS}$ exert an important effect on the estimation model as temperature was increased. But increment of $FeS_2$ concentration is weakened above the HRT of 60 minutes and represent the lowest value at the HRT of 108 minutes. It implies that liquid phase distribution ratio of sulfide ${\alpha}r$ becomes lower as temperature was increased. While phosphorus concentration combining with iron $Fe_3(PO_4)_3$ is increased as HRT and temperature are increased, which is affected by phosphorus removal rate constant $k_p$. As the result of estimating the iron concentrations of corrosion by the model, the concentration of iron corrosion is higher than any other at the HRT of 108 minute and $20^{\circ}C$. The predicted values were compared with measured ones at different HRT(13.5, 27, 54, 108 min) and temperature(20, 25, $30^{\circ}C$). The experimental data could be fitted with the simulated curves. Therefore, the mathematical expression could be applicable to design full-scale wastewater treatment plants.

Bis-hydroxyethyl Naphthalate의 축중합 반응에 관한 속도론적 연구 (Kinetic Study on the Polycondensation Reaction of Bis-hydroxyethyl Naphthalate)

  • 이성진;정성일
    • 폴리머
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    • 제26권4호
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    • pp.422-430
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    • 2002
  • Antimony trioxide 촉매를 사용하여 241 - $260^{\circ}C$ 범위에서 bishydroxyethyl naphthalate (BHEN)의 축중합 반응에 관한 속도론적 연구를 수행하였다. 반응은 회분식 반응기에서 진행되었고 반응물의 농도는 high performance liquid chromatography (HPLC)를 사용하여 측정하였다. 분자종 모델을 적용하여 구한 반응속도상수의 정반응 및 역반응 활성화 에너지 값은 각각 19.7과 31.4 kcal/mole 이었으며, 평형상수는 1.4-2.0으로 PET 축중합 반응의 경우보다 큰 값을 가지며 온도에 따라 어느 정도 변하였다. 말단기인 hydroxyethyl기의 반응속도는 분자의 크기에 관계없이 일정함을 Flory, 모델식으로부터 확인할 수 있었다. 관능기 모델을 적용한 결과 정반응과 역반응 활성화 에너지 길기 큰 차이가 없었으며, 평형상수는 1.4정도의 값을 가졌다. 관능기 모델로부터 구한 속도상수 값은 분자종 모델로부터 구한 값의 3-4배로서 두 모델이 모두 반응계를 잘 설명하였다. 제안된 분자종 모델이 10개의 분자종을 모두 예측해야 하는 어려움에도 불구하고 실험 결과와 잘 맞음을 알 수 있었다.

입자영상유속계를 이용한 가두리 망지의 난류강도 계측 (Measurement of turbulence intensity of cage net using the particle imaging velocimetry)

  • 배재현;안희춘
    • 수산해양기술연구
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    • 제50권4호
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    • pp.595-603
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    • 2014
  • This study is aimed to analyze the hydrodynamic characteristics of the cage net in the circulating water channel. It visualized wake flows using a PIV (paricle imaging velocimetry) and analyzed the flow velocity distribution. In addition, the vorticity and turbulence intensity were analyzed from the wake flow distribution and compared changes by flow velocity. Results showed that the average turbulence intensity in the circulating water channel was very stable showing less than 1% in the range between 0.2 and 0.8 m/s. The drag coefficient affecting to the netting was estimated to be 1.35. The flow decreasing rate of the wake in the middle of the netting was 2.1% at the range of 0.2 m/s and it was constant at 6.6-6.9% over the range of 0.4 m/s irrespective of velocity increases. Finally, the change of turbulence intensity by netting and knot mesh could be confirmed. These results can be utilized as a basic information for the future research of flow characteristics by fishing nets and meshes.

열분해 특성상수를 활용한 탄소/페놀릭 복합재료의 온도분포 해석 (The Analysis of the temperature distribution in Carbon/Phenolic composite by thermal decomposition parameters)

  • 김연철;박영채
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2006년도 제26회 춘계학술대회논문집
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    • pp.45-49
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    • 2006
  • 탄소/페놀릭 복합재료가 높은 온도에서 열분해 되는 현상을 연구하기 위하여 열중량분석기(TGA)가 이용되었다. 높은 온도와 다양한 하중조건에서 운용되는 고체 추진기관의 열방호 시스템으로 적합한 재료를 분석하고 개발하는데 연구목적이 있다. 실제 연소조건과 유사한 온도 상승속도를 고려하기 위하여 열분해 특성상수 값은 1000 K/min인 경우로 예측된 값을 FEM 해석코드 자료로 활용하였다. 온도 분포는 실험 결과 값과 같은 거동을 보였으며 열분해 깊이는 ${\pm}1mm$ 이내에서 해석 결과와 잘 일치 하였다.

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Impact of fine particles on the rheological properties of uranium dioxide powders

  • Madian, A.;Leturia, M.;Ablitzer, C.;Matheron, P.;Bernard-Granger, G.;Saleh, K.
    • Nuclear Engineering and Technology
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    • 제52권8호
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    • pp.1714-1723
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    • 2020
  • This study aims at characterizing the rheological properties of uranium oxide powders for nuclear fuel pellets manufacturing. The flowability of these powders must be compatible with a reproducible filling of press molds. The particle size distribution is known to have an impact on the rheological properties and fine particles (<100 ㎛) are suspected to have a detrimental effect. In this study, the impact of the particle size distribution on the rheological properties of UO2 powders was quantified, focusing on the influence of fine particles. Two complementary approaches were used. The first approach involved characterizing the powder in a static state: density, compressibility and shear test measurements were used to understand the behavior of the powder when it is transitioned from a static to a dynamic state (i.e., incipient flow conditions). The second approach involved characterizing the behavior of the powder in a dynamic state. Two zones, corresponding to two characteristic behaviors, were demonstrated for both types of measurements. The obtained results showed the amount of fines should be kept below 10 % wt to ensure a robust mold filling operation (i.e., constant mass and production rate).

압축성을 고려한 사출성형 충전과정에 관한 연구 (Analysis of Filling in Injection Molding with Compressibility)

  • 한경희;임용택
    • 대한기계학회논문집A
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    • 제21권5호
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    • pp.735-745
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    • 1997
  • In this study, the compressibility of resin was considered in filling analysis to account for the possible packing type flow. A numerical simulation program employing a hybrid finite element/finite difference scheme was developed to solve Hele-Shaw flow of the compressible viscous fluid at non-isothermal conditions. To advance the melt front, a control volume approach was adopted. Thin complex 3-D shapes of cavities, runners, and sprues were discretized by employing triangular, cylindrical and/or rectangular strip elements. Mass conservation was applied to each control volume to solve for the pressure distribution. Directly applying a constant mass flow rate at the inlet removes calculation of the apparent pressure boundary conditions, resulting in better simulation condition. The Cross model was used to model viscosity and the Tait equation was employed to represent density as a function of temperature and pressure. The validity of the developed program was verified through comparisons with available data in the literature and the effect of compressibility on the pressure distribution was discussed. To reduce computation time, 1-D and 2-D elements were used instead of applying triangular elements and the numerical results were compared to each other.

Turbulent Flow Field Structure of Initially Asymmetric Jets

  • Kim, Kyung-Hoon;Kim, Bong-Whan;Kim, Suk-Woo
    • Journal of Mechanical Science and Technology
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    • 제14권12호
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    • pp.1386-1395
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    • 2000
  • The mear field structure of round turbulent jets with initially asymmetric velocity distributions is investigated experimentally. Experiments are carried out using a constant temperature hot-wire anemometry system to measure streamwise velocity in the jets. The measurements are undertaken across the jet at various streamwise stations in a range starting from the jet exit plane and up to a downstream location of twelve diameters. The experimental results include the distributions of mean and instantaneous velocities, vorticity field, turbulence intensity, and the Reynolds shear stresses. The asymmetry of the jet exit plane was obtained by using circular cross-section pipes with a bend upstream of the exit. There pipes used here include a straight pipe, and 90 and 160 degree-bend pipes. Therefore, at the upstream of the upstream of the pipe exit, secondary flow through the bend mean streamwise velocity distribution could be controlled by changing the curvature of pipes. The jets into the atmosphere have two levels of initial velocity skewness in addition to an axisymmetric jet from a straight pipe. In case of the curved pipe, a six diameter-long straight pipe section follows the bend upstream of the exit. The Reynolds number based on the exit bulk velocity is 13,400. The results indicate that the near field structure is considerably modified by the skewness of an initial mean velocity distribution. As the skewness increases, the decay rate of mean velocity at the centerline also increases.

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구형 유전체비드를 가지는 단층절연방전관의 수(水)오존농도측정 및 전계분포 시뮬레이션 (The measurement of Ozone Concentration and Simulation of Electric Field Distribution at Dielectric Tube of one Layer with Globular Dielectric in Water)

  • 이동훈;박재윤;박홍재;고희석;이현수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 제5회 영호남 학술대회 논문집
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    • pp.44-47
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    • 2003
  • In this paper, the electric field distribution in dielectric tube with one layer and spherical dielectric($ZrO_2$) in water was simulated. The reactor was made up of the spherical dielectric that is diameter : 3.0[mm], $ZrO_2(\varepsilon_r:10)$ and one glass plate of thickness(2[mm]), $\varepsilon_r$(10) as electrode. The discharge gap was 8[mm]. To get more strong electric field, the dielectric constant should be higher comparatively. Using the spherical dielectric for water discharge in dielectric tube, the location of equipotential line was shifting from the interior to the exterior. At real water discharge experimental, ozone was measured higher dissolved ozone in water at condition of water rate(l[l/min]) and injector than condition of non-injector or 2~3[l/min].

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구형 유전체비드를 가지는 단층절연방전관의 $H_2O_2$ 농도 측정 및 전계분포시뮬레이션 (The measurement of $H_2O_2$ Concentration and Simulation of Electric Field Distribution at Dielectric Tube of one Layer with Globular Dielectric in Water)

  • 박홍재;박재윤;이동훈;고희석;이현수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 제5회 영호남 학술대회 논문집
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    • pp.40-43
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    • 2003
  • In this paper, the electric field distribution in dielectric tube with one layer and spherical dielectric(glass) in water was simulated. The reactor was made up of the spherical dielectric that is diameter : 3.0[mm], glass(${\varepsilon}_r$:5) and one glass plate of thickness(2[mm]), ${\varepsilon}_r$(5) as electrode. The discharge gap was 8[mm). Toget more strong electric field, the dielectric constant should be higher comparatively. Using the spherical dielectric for water discharge in dielectric tube, the location of equipotential line was shifting from the interior to the exterior. At real water discharge experimental, $H_2O_2$ was measured higher generated $H_2O_2$ in water at condition of water rate(1[l/min]) and injector than condition of non-injector or 2-3[l/min])

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