• Title/Summary/Keyword: Distribution rate constant

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The Characteristics of Elutriation with Gaussian Particle Size Distributions in a gas-solid fluidized bed (기-고 유동층에서 Gaussian 분포 입자군의 표준편차에 따른 유출 특성)

  • Jang, Hyun-Tae;Cha, Wang-Seog
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.10 no.11
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    • pp.3274-3279
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    • 2009
  • The elutriation characteristics of particle size distribution were investigated in a gas-solid fluidized bed. Experiments were carried out with the mulit-sized particles of Gaussian distributions. The elutriation rate constant obtained from the experiment was correlated with the standard deviation of particle size and the dimensionless group of the velocity ratio. The standard deviation of pressure fluctuation, mean pressure, major frequency and power spectrum density function were calculated by pressure fluctuation properties. Size distribution of elutriated particles and pressure fluctuations were measured for the particle size distribution of particle system depended largrly on the size distribution. Characteristics of fluidization and elutriation were greatly influenced by the particle size distribution and these characteristics could be interpreted with pressure fluctuation properties.

The Development of Estimation Model for Iron Compound Originated from Anaerobic Microbial Corrosion (혐기성 미생물부식에 의해 생성되는 철화합물 추정식 개발)

  • Jeon, Seok-Jun
    • Journal of Korean Society on Water Environment
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    • v.18 no.4
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    • pp.379-386
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    • 2002
  • In this study, estimation model for iron compound originated from upflow, anaerobic fixed bed reactor, which treats sewage domestic wastewater, was developed. The estimation model was formulated by a mathematical expression which was based on the mass balance. Below the HRT of 60 minute, sulfide concentration combining with iron $FeS_2$ is the highest because the maximum sulfate consumption rate $V_{maxS}$ and half-saturation constant of sulfate $K_{mS}$ exert an important effect on the estimation model as temperature was increased. But increment of $FeS_2$ concentration is weakened above the HRT of 60 minutes and represent the lowest value at the HRT of 108 minutes. It implies that liquid phase distribution ratio of sulfide ${\alpha}r$ becomes lower as temperature was increased. While phosphorus concentration combining with iron $Fe_3(PO_4)_3$ is increased as HRT and temperature are increased, which is affected by phosphorus removal rate constant $k_p$. As the result of estimating the iron concentrations of corrosion by the model, the concentration of iron corrosion is higher than any other at the HRT of 108 minute and $20^{\circ}C$. The predicted values were compared with measured ones at different HRT(13.5, 27, 54, 108 min) and temperature(20, 25, $30^{\circ}C$). The experimental data could be fitted with the simulated curves. Therefore, the mathematical expression could be applicable to design full-scale wastewater treatment plants.

Kinetic Study on the Polycondensation Reaction of Bis-hydroxyethyl Naphthalate (Bis-hydroxyethyl Naphthalate의 축중합 반응에 관한 속도론적 연구)

  • 이성진;정성일
    • Polymer(Korea)
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    • v.26 no.4
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    • pp.422-430
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    • 2002
  • The kinetics of polycondensation of bishydroxyethyl naphthalate has been studied in the range of 241 -$260^{\circ}C$ using antimony trioxide catalyst. The reaction was performed in a batch reactor and the concentration of reaction mixture was measured with HPLC. The activation energy values of forward and reverse reaction determined from molecular species model were found to be 19.7 and 31.4 kcal/mole, respectively, and the equilibrium constants were in the range of 1.4-2.0, which were larger than that of polycondensation of PET and varied to some degree with temperature. It was confirmed by applying the Flory's distribution function that the reaction rate of the hyroxyethyl group does not depend on the molecular size. By applying functional group model, we observed that there was few difference between the activation energy of the forward reaction and that of reverse reaction, therefore the equilibrium constant has almost constant value of 1.4. The rate constants obtained from functional group model was about 3-4 times larger than that from molecular species model, which showed that both model explains the reaction system well. Although the molecular species model should predict the concentration of as many as ten molecules, it fits for the experimental results well.

Measurement of turbulence intensity of cage net using the particle imaging velocimetry (입자영상유속계를 이용한 가두리 망지의 난류강도 계측)

  • Bae, Jae-Hyun;An, Heui-Chun
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.50 no.4
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    • pp.595-603
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    • 2014
  • This study is aimed to analyze the hydrodynamic characteristics of the cage net in the circulating water channel. It visualized wake flows using a PIV (paricle imaging velocimetry) and analyzed the flow velocity distribution. In addition, the vorticity and turbulence intensity were analyzed from the wake flow distribution and compared changes by flow velocity. Results showed that the average turbulence intensity in the circulating water channel was very stable showing less than 1% in the range between 0.2 and 0.8 m/s. The drag coefficient affecting to the netting was estimated to be 1.35. The flow decreasing rate of the wake in the middle of the netting was 2.1% at the range of 0.2 m/s and it was constant at 6.6-6.9% over the range of 0.4 m/s irrespective of velocity increases. Finally, the change of turbulence intensity by netting and knot mesh could be confirmed. These results can be utilized as a basic information for the future research of flow characteristics by fishing nets and meshes.

The Analysis of the temperature distribution in Carbon/Phenolic composite by thermal decomposition parameters (열분해 특성상수를 활용한 탄소/페놀릭 복합재료의 온도분포 해석)

  • Kim Yun-Chul;Park Young-Che
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2006.05a
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    • pp.45-49
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    • 2006
  • The thermal degradation of carbon fiber reinforced phenolic composites have been studied at high temperature by using thermogravimetry analysis (TGA). The aim is that ultimately it can be used to predict the service temperature during solid rocket firing for any level and type of mechanical loading and to recommend protection systems required. To simulate the high heating rate in firing condition, the modified thermal decomposition constant (1000 K/min) was used for FEM analysis. The temperature distribution and the thickness of thermal decomposition were estimated well and we could predict the thickness of thermal decomposition within ${\pm}1mm$.

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Impact of fine particles on the rheological properties of uranium dioxide powders

  • Madian, A.;Leturia, M.;Ablitzer, C.;Matheron, P.;Bernard-Granger, G.;Saleh, K.
    • Nuclear Engineering and Technology
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    • v.52 no.8
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    • pp.1714-1723
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    • 2020
  • This study aims at characterizing the rheological properties of uranium oxide powders for nuclear fuel pellets manufacturing. The flowability of these powders must be compatible with a reproducible filling of press molds. The particle size distribution is known to have an impact on the rheological properties and fine particles (<100 ㎛) are suspected to have a detrimental effect. In this study, the impact of the particle size distribution on the rheological properties of UO2 powders was quantified, focusing on the influence of fine particles. Two complementary approaches were used. The first approach involved characterizing the powder in a static state: density, compressibility and shear test measurements were used to understand the behavior of the powder when it is transitioned from a static to a dynamic state (i.e., incipient flow conditions). The second approach involved characterizing the behavior of the powder in a dynamic state. Two zones, corresponding to two characteristic behaviors, were demonstrated for both types of measurements. The obtained results showed the amount of fines should be kept below 10 % wt to ensure a robust mold filling operation (i.e., constant mass and production rate).

Analysis of Filling in Injection Molding with Compressibility (압축성을 고려한 사출성형 충전과정에 관한 연구)

  • Han, Kyeong-Hee;Im, Yong-Taek
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.21 no.5
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    • pp.735-745
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    • 1997
  • In this study, the compressibility of resin was considered in filling analysis to account for the possible packing type flow. A numerical simulation program employing a hybrid finite element/finite difference scheme was developed to solve Hele-Shaw flow of the compressible viscous fluid at non-isothermal conditions. To advance the melt front, a control volume approach was adopted. Thin complex 3-D shapes of cavities, runners, and sprues were discretized by employing triangular, cylindrical and/or rectangular strip elements. Mass conservation was applied to each control volume to solve for the pressure distribution. Directly applying a constant mass flow rate at the inlet removes calculation of the apparent pressure boundary conditions, resulting in better simulation condition. The Cross model was used to model viscosity and the Tait equation was employed to represent density as a function of temperature and pressure. The validity of the developed program was verified through comparisons with available data in the literature and the effect of compressibility on the pressure distribution was discussed. To reduce computation time, 1-D and 2-D elements were used instead of applying triangular elements and the numerical results were compared to each other.

Turbulent Flow Field Structure of Initially Asymmetric Jets

  • Kim, Kyung-Hoon;Kim, Bong-Whan;Kim, Suk-Woo
    • Journal of Mechanical Science and Technology
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    • v.14 no.12
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    • pp.1386-1395
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    • 2000
  • The mear field structure of round turbulent jets with initially asymmetric velocity distributions is investigated experimentally. Experiments are carried out using a constant temperature hot-wire anemometry system to measure streamwise velocity in the jets. The measurements are undertaken across the jet at various streamwise stations in a range starting from the jet exit plane and up to a downstream location of twelve diameters. The experimental results include the distributions of mean and instantaneous velocities, vorticity field, turbulence intensity, and the Reynolds shear stresses. The asymmetry of the jet exit plane was obtained by using circular cross-section pipes with a bend upstream of the exit. There pipes used here include a straight pipe, and 90 and 160 degree-bend pipes. Therefore, at the upstream of the upstream of the pipe exit, secondary flow through the bend mean streamwise velocity distribution could be controlled by changing the curvature of pipes. The jets into the atmosphere have two levels of initial velocity skewness in addition to an axisymmetric jet from a straight pipe. In case of the curved pipe, a six diameter-long straight pipe section follows the bend upstream of the exit. The Reynolds number based on the exit bulk velocity is 13,400. The results indicate that the near field structure is considerably modified by the skewness of an initial mean velocity distribution. As the skewness increases, the decay rate of mean velocity at the centerline also increases.

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The measurement of Ozone Concentration and Simulation of Electric Field Distribution at Dielectric Tube of one Layer with Globular Dielectric in Water (구형 유전체비드를 가지는 단층절연방전관의 수(水)오존농도측정 및 전계분포 시뮬레이션)

  • Lee, Dong-Hoon;Park, Jae-Youn;Park, Hong-Jae;Koh, Hee-Seog;Lee, Hyun-Su
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.08a
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    • pp.44-47
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    • 2003
  • In this paper, the electric field distribution in dielectric tube with one layer and spherical dielectric($ZrO_2$) in water was simulated. The reactor was made up of the spherical dielectric that is diameter : 3.0[mm], $ZrO_2(\varepsilon_r:10)$ and one glass plate of thickness(2[mm]), $\varepsilon_r$(10) as electrode. The discharge gap was 8[mm]. To get more strong electric field, the dielectric constant should be higher comparatively. Using the spherical dielectric for water discharge in dielectric tube, the location of equipotential line was shifting from the interior to the exterior. At real water discharge experimental, ozone was measured higher dissolved ozone in water at condition of water rate(l[l/min]) and injector than condition of non-injector or 2~3[l/min].

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The measurement of $H_2O_2$ Concentration and Simulation of Electric Field Distribution at Dielectric Tube of one Layer with Globular Dielectric in Water (구형 유전체비드를 가지는 단층절연방전관의 $H_2O_2$ 농도 측정 및 전계분포시뮬레이션)

  • Park, Hong-Jae;Park, Jae-Youn;Lee, Dong-Hoon;Koh, Hee-Seog;Lee, Hyun-Su
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.08a
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    • pp.40-43
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    • 2003
  • In this paper, the electric field distribution in dielectric tube with one layer and spherical dielectric(glass) in water was simulated. The reactor was made up of the spherical dielectric that is diameter : 3.0[mm], glass(${\varepsilon}_r$:5) and one glass plate of thickness(2[mm]), ${\varepsilon}_r$(5) as electrode. The discharge gap was 8[mm). Toget more strong electric field, the dielectric constant should be higher comparatively. Using the spherical dielectric for water discharge in dielectric tube, the location of equipotential line was shifting from the interior to the exterior. At real water discharge experimental, $H_2O_2$ was measured higher generated $H_2O_2$ in water at condition of water rate(1[l/min]) and injector than condition of non-injector or 2-3[l/min])

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