• Journal of Powder Materials
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• v.30 no.5
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• pp.394-401
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• 2023

Li_1.5Al_0.5Ti_1.5(PO₄)₃ (LATP) is considered to be one of the promising solid-state electrolytes owing to its excellent chemical and thermal stability, wide potential range (~5.0 V), and high ionic conductivity (~10^-4 S/cm). LATP powders are typically prepared via the sol-gel method by adding and mixing nitrate or alkoxide precursors with chelating agents. Here, the thermal properties, crystallinity, density, particle size, and distribution of LATP powders based on chelating agents (citric acid, acetylacetone, EDTA) are compared to find the optimal conditions for densely sintered LATP with high purity. In addition, the three types of LATP powders are utilized to prepare sintered solid electrolytes and observe the microstructure changes during the sintering process. The pyrolysis onset temperature and crystallization temperature of the powder samples are in the order AC-LATP > CA-LATP > ED-LATP, and the LATP powder utilizing citric acid exhibits the highest purity, as no secondary phase other than LiTi₂PO₄ phase is observed. LATP with citric acid and acetylacetone has a value close to the theoretical density (2.8 g/cm³) after sintering. In comparison, LATP with EDTA has a low sintered density (2.2 g/cm³) because of the generation of many pores after sintering.

• Journal of Korean Society of Water and Wastewater
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• v.19 no.4
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• pp.421-428
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• 2005

Dissolved air flotation (OAF) is a solid-liquid separation system that uses fine bubbles rising from bottom to remove particles in water. In this study, we investigated the effect of L/W (L; Length, W; Width) on the hydro-dynamic behavior in DAF system using CFD (Computational Fluid Dynamics) and ADV (Acoustic Doppler Velocimetry) technique. The factual full-scale DAF system, L/W ratio of 1:1, was selected and various L/W ratio (2:1, 3:1, 4:1 and 5:1) conditions were simulated with CFD. For modelling, 2-phase (gas-liquid) flow equations for the conservation of mass, momentum and turbulence quantities were solved using an Eulerian-Eulerian approach based on the assumption that very small particle is applied in the DAF system. Also, for verification of CFD simulation results, we measured the factual velocity at some points in the full-scale DAF system with ADV technique. Both the simulation and the measurement results were in good accordance with each other. As the results of this study, we concluded that L/W ratio and outlet geometry play important role for flow pattern and fine bubble distribution in the flotation zone. In the ratio of 1:1, the dead zone is less than those in other cases. On the other hands, in the ration of 3:1, the fine bubbles were more evenly distributed.

• Journal of Ocean Engineering and Technology
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• v.23 no.2
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• pp.47-52
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• 2009

A Lagrangian particle tracking model coupled with the Princeton Ocean Model were used to estimate the average residence time of coastal water in Masan Bay, Korea. Our interest in quantifying the transport time scales in Masan Bay was stimulated by the search for a mechanistic understanding of this spatial variability, which is consistent with the concept of spatially variable transport time scales. Tidal simulation was calibrated through a comparison with the results of semi-diurnal current and water elevation measured at the tidal stations of Masan, Gadeokdo. In the model simulations, particles were released in eight cases, including slack before ebb, peak ebb, slack before flood, and peak flood, during both spring and neap tides. The averaged values obtained from the particle release simulations were used for the average residence times of the coastal water in Masan Bay. The average residence times for the southeastern parts of Somodo and the Samho River, Masan Bay were estimated to be about 20~50days and 70~80days, respectively. The spatial difference for the average residence time was controlled by the tidal currents and distance from the mouth of the bay. Our results might provide useful for understanding the transport and behavior of coastal water in a bay and might be used to estimate the dissimilative capacity for environmental assessment.

• Carbon letters
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• v.5 no.4
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• pp.180-185
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• 2004

Thermolysis of $Cu(NO_3)_2{\cdot}3H_2O$ impregnated activated carbon fiber (ACF) was studied by means of XRD analysis to obtain Cu-impregnated ACF. $Cu(NO_3)_2{\cdot}3H_2O$ was converted into $Cu_2O$ around $230^{\circ}C$. The $Cu_2O$ was reduced to Cu at $400^{\circ}C$, resulting in ACF-C(Cu). Some Cu particles have a tendency to aggregate through the heat treatment, resulting in the ununiform distribution in ACF. Catalytic decomposition of NO gas has been performed by Cu-impregnated ACF in a column reactor at $400^{\circ}C$. Initial NO concentration was 1300 ppm diluted in helium gas. NO gas was effectively decomposed by 5~10 wt% Cu-impregnated ACF at $400^{\circ}C$. The concentration of NO was maintained less than 200 ppm for 6 hours in this system. The ACF-C(Cu) deoxidized NO to $N_2$ and was reduced to ACF-$C(Cu_2O)$ in the initial stage. The ACF-$C(Cu_2O)$ also deoxidized NO to $N_2$ and reduced to ACF-C(CuO). This ACF-C(CuO) was converted again into ACF-C(Cu) by heating. There was no consumption of ACF in mass during thermolysis and catalytic decomposition of NO to $N_2$ by copper. The catalytic decomposition was accelerated with increase of the reaction temperature.

• Proceedings of KOSOMES biannual meeting
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• 2007.11a
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• pp.23-28
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• 2007

This study estimated the behavior(movement) characteristics of floating marine debris flowing in the Nakdong River Estuary using a simple numerical particle-tracking model. This numerical experiment considered the maximum water discharge outflow from the Nakdong River barrage during the passage of typhoon Maemi in 2003. The simulation showed that the particle distribution and movement of floating marine debris in the Nakdong River Estuary reached a stable state at 72 hours after the typhoon had passed, during the flαxl period of river discharge. The quantity of floating particles distributed on the east coast of Gadeok and Jinu Islands increased by 40% at 33 hours after starting the model, while the change in other sea areas was $20{\sim}40%$.

• Journal of the Korea Organic Resources Recycling Association
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• v.26 no.3
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• pp.33-37
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• 2018

In order to recycle sewage dredging soil, we analyzed particle size distribution and organic content of dredged sewage sediments. Based on this, it was determined that particles with relatively low organic content of 1.0 mm or more could be recycled as fine aggregate. Although it was inorganic at the size of 5 mm or more, it contained a number of foreign substances other than fine aggregate, which were needed to be removed with a sieve. Since there are volatile suspended solids between 1.0 and 5.0 mm size, they were removed by means of flotation. Fine aggregate was obtained from dredging soil by screening followed with flotation method, and the proportion of fine aggregate obtained in this study was around 38 %.

• Korean Journal of Food Science and Technology
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• v.42 no.1
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• pp.115-118
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• 2010

The physicochemical properties such as blue value, iodine affinity, degree of polymerization (DP), $\alpha$-amylase digestibility, particle size, RVA pasting, and gel hardness of 4 different millet starches (foxtail, waxy foxtail, proso, and waxy proso) were investigated. The iodine affinity value of the four samples were 4.22, 0.49, 1.07, and 0.21%, and the DP values were 1830, 3880, 4660, and 4130, respectively. The levels of $\alpha$-amylase digestibility of the raw starches were 20.1, 30.7, 18.2 and 35.6%, respectively. The mean size of the proso millet starch was the smallest, $8.25\;{\mu}m$, and the size distribution of the particles was the narrowest among all the samples. Foxtail starch showed the largest peak viscosity and setback viscosity in RVA pasting.

• Transactions on Electrical and Electronic Materials
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• v.5 no.5
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• pp.199-203
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• 2004

Superconducting B $i_2$S $r_2$C $a_{n-l}$C $u_{n}$ $O_{x}$(n=2～4) thin films were prepared by single target DC-magnetron sputtering. And, that was compared with the B $i_2$S $r_2$C $a_{n-l}$C $u_{n}$ $O_{x}$(n=1～3) thin film fabricated by using the ion beam sputtering. Phase intergrowth among n=2-3, 3-4 and 4-5 phases was observed. The molar fraction of each phase in the mixed crystal of the deposited films was determined by x-ray diffraction analyses and investigated as a function of $O_2$ gas pressure during sputtering. We investigated the changes of the superconducting properties by molar fraction of each phase. Also, the thin film surface observation was carried out by atomic force microscope. The images show the average particle size decreases, and the distribution density of particles on the film surface was to increase with lower gas pressures. The fabrication conditions for selective growth of the single n=2, 3 and 4 phases in BiSrC $a_{n-l}$C $u_{n}$ $O_{x}$(n=2～4) thin film are discussed.e discussed.ussed.

• Journal of the Korean Ceramic Society
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• v.36 no.7
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• pp.742-750
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• 1999

Nanosized TiO2 powders were synthesized using the chemical vapor conduensation (CVC) process with various precursor feeding rates (0.37 and 0.752 ml/min) and oxygen flow rates(1-2slm) conditions and powder characteristics were investigated in terms of formation of nanosized powder varying with the above processing conditions. For this study the main thermodynamic and fluid dynamic factors -supersaturation ratio collision frequency and residence time-were theoretically established and compared to the characteristics of formed TiO2 powder. The loosely combined anatase phase powders (including less than 3%of rutile phase) having 20-30nm crystallite size were obtained at overall conditions. The particle size and th degree of agglomeration for a precursor flow rate of 0.376 ml/min turn out to be smaller than for a flow rate of 0.742ml/min. And the decreasing of particles size and particle size distribution were observed with increasing oxygen flow rate as the residence time and collision frequency were reduced by increasing oxygen flow rate,. It appears that further scrutiny is needed to elucidate the influence of the individual thermodynamic and kinetic parameters mdependently.

• Clean Technology
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• v.13 no.3
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• pp.208-214
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• 2007

Environmentally-friendly acrylic resin particles having the diameter between $0.1\;and\;1\;{\mu}m$ were prepared using non-aqueous dispersion (NAD) polymerization technique. The first step is to prepare the stabilizer and the next step is the NAD polymerization by dropping an acrylic monomer to stabilizer dispersed in organic media. To obtain a NAD resin with proper level of viscosity, it fumed out that stabilizers having sufficient viscosity such as 1000 cP need to be used, for which the stepwise feeding of monomer and initiator was necessary. It was necessary to put proper amount of stabilizer, but no more increase in viscosity was observed when more than that amount of stabilizer was added. Choice of proper monomers considering solubility parameter was essential to avoid the bimodal particle size distribution in the NAD resin product.