• Title/Summary/Keyword: Distribution of particles

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Modification of isotropic coal-tar pitch by acid treatments for carbon fiber melt-spinning

  • Yoo, Mi Jung;Ko, Hyo Jun;Lim, Yun-Soo;Kim, Myung-Soo
    • Carbon letters
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    • v.15 no.4
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    • pp.247-254
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    • 2014
  • In this work, thermal treatment accompanied with different acid treatments was applied to a commercial coal tar pitch (CTP) to obtain a spinnable precursor pitch for carbon fiber. In the case of thermal treatment only, a relatively high reaction temperature of between $380^{\circ}C$ and $400^{\circ}C$ was required to obtain a softening point (SP) range of $220^{\circ}C-260^{\circ}C$ and many meso-phase particles were created during the application of high reaction temperature. When nitric acid or sulfuric acid treatment was conducted before the thermal treatment, the precursor pitch with a proper SP range could be obtained at reaction temperatures of $280^{\circ}C-300^{\circ}C$, which were about $100^{\circ}C$ lower than those for the case of thermal treatment only. With the acid treatments, the yield and SP of the precursor pitch increased dramatically and the formation of meso-phase was suppressed due to the lower reaction temperatures. Since the precursor pitches with acid and thermal treatment were not spinnable due to the inhomogeneity of properties such as molecular weight distribution and viscosity, the CTP was mixed with ethanol before the consecutive nitric acid and thermal treatments. The precursor pitches with ethanol, nitric acid, and thermal treatments were easily spinnable, and their spinning and carbon fiber properties were compared to those of air blowing and thermal treated CTP.

Ratio of Bedload to Total Sediment Load in Gravel-bed Rivers (자갈하천 총유사량에 대한 소류사의 비율)

  • Park, Sang Doeg
    • Journal of The Geomorphological Association of Korea
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    • v.25 no.2
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    • pp.15-29
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    • 2018
  • The sediment transport process in a river reflects the process of geomorphological change in the watershed, influencesthe river bed variation and the river channel migration, and is a parametric phenomenon that exhibits a dynamic self-adjusting process. Sediment load is divided into bedload and suspended load depending on the dominant mechanism. Quantitative sediment load is important information for solving river problems. Because it is difficult and time consuming to measure bedload, compared to that ofsuspended load, data on the sediment transport load and the research required for the gravel-bed rivers are insufficient. This study is to analyze the ratio of the bedload to the total sediment load in gravel-bed rivers. The sediment load ratio in gravel-bed rivers increases with the flow rate per unit width, and the rate of the bedload varies more rapidly than the suspended load. The sediment transport efficiency coefficient has been affected by the ratio of the flow depth to the mean diameter of particles and has been dependent on the shear velocity Reynolds number. So $A^{\ast}$ and $B^{\ast}$ are introduced to compensate for the uncertainties such as bed materials, sediment transport, and flow velocity distribution, and the coefficient of bedload ratio has been presented. For the sediment load data in experimental channels and rivers, A* was 3.1. The dominant variables of $B^{\ast}$ were $u_*d_m/{\nu}$ in the gravel-bed and h/dm in the sand-bed. When $B^{\ast}$ the is the same, in the experimental channels the coefficient of bedload ratio was affected by the bed forms, but in the rivers it was of little difference between the gravel-bed and sand-bed.

High Resolution Fine Dust Mass Concentration Calculation Using Two-wavelength Scanning Lidar System (두파장 스캐닝 라이다 시스템을 이용한 고해상도 미세먼지 질량 농도 산출)

  • Noh, Youngmin;Kim, Dukhyun;Choi, Sungchul;Choi, Changgi;Kim, TaeGyeong;Kim, Gahyeong;Shin, Dongho
    • Korean Journal of Remote Sensing
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    • v.36 no.6_3
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    • pp.1681-1690
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    • 2020
  • A scanning lidar system has been developed. The system has two wavelength observation channels of 532 and 1064 nm and is capable of 360-degree horizontal scanning observation. In addition, an analysis method that can classify the measured particle as an indicator of coarse-mode particle (PM2.5-10) and an indicator of fine-mode particles (PM2.5) and calculate the mass concentration of each has been developed by using the backscatter coefficient at two wavelengths. It was applied to the data calculated by observation. The mass concentrations of PM10 and PM2.5, which showed a distribution of 22-110 ㎍/㎥ and 7-78 ㎍/㎥, respectively, were successfully calculated in the Ulsan Onsan Industrial Complex using the developed scanning lidar system. The analyzed results showed similar values to the mass concentrations measured on the ground around the lidar observation area, and it was confirmed that high concentrations of 80-110 ㎍/㎥ and 60-78 ㎍/㎥ were measured at points discharged from factories, respectively.

Aerosol Sampling with Two Stage Filter Sampler and Seasonal Variation of Metal Components in the Atmosphere (이단 필터 샘플러에 의한 대기 부유분진의 포집 및 금속 성분의 계절별 거동에 관한 연구)

  • Lee, Yong-Keun;Kim, Nam-Hoon;Myung, No-Seung;Whang, Kyu-Ja
    • Journal of Korean Society for Atmospheric Environment
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    • v.4 no.2
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    • pp.20-27
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    • 1988
  • A simple two stage aerosol filter sampler which allows simultaneous and fractional collection of two different-size particles, coarse and fine, was constructed and applied to the collection of Seoul atmospheric particulate for inorganic analysis. The sampler consist of two 47-mm diameter filter holder, a pneumatic pump, and a flowmeter. Filtering rate normally runs around 20$\ell$/min for 8 hrs. Using the sampler, a series of seasonal aerosol samples were collected from June 1986 to March 1988 at Yonsei University campus, Seoul and subsequently analysed for ten environmentally important metals using an atomic absorption spectrometer and an inductively coupled plasma emission spectrometer. The analysed metals are Al, Cd, Cr, Cu, Fe, Mn, Ni, Pb, V, and Zn. The analytical results showed the following order of metal abundance; Al > Fe > Zn > Pb > Mn > Cu > V > Ni > Cr > Cd. Based upon their size distribution pattern, the analyzed matals could be clasified into two groups, those present primarily in coarse particle and those in fine particle. Fe, Al, Mn, V, and Cr belong to the former group while the rest to the latter. Most metal concentration were highest in spring or winter, and lowest in autumn. Statistical analysis showed strong correlations between Al and Fe, Pb and Zn, and Cu and Mn.

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Effects of Extrusion Ratio and Extrusion Temperature on Microstructure and Tensile Properties of SEN6 Magnesium Alloy (SEN6 마그네슘합금의 미세조직과 인장 특성에 미치는 압출비와 압출 온도의 영향)

  • H. J. Kim;J. Y. Lee;S. C. Jin;S. H. Park
    • Transactions of Materials Processing
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    • v.33 no.3
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    • pp.178-184
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    • 2024
  • In this study, we investigated the effects of extrusion ratio and extrusion temperature on the microstructure and tensile properties of extruded Mg-6Al-0.3Mn-0.3Ca-0.2Y (SEN6) alloy. As the extrusion ratio and temperature increase, dynamic recrystallization during extrusion is promoted, leading to the formation of a fully recrystallized microstructure with increased grain size. Additionally, the increases in extrusion ratio and temperature lead to texture strengthening, exhibiting a higher maximum texture intensity. The extruded materials contain three types of secondary phases, i.e., Al8Mn4Y, Al2Y, and Al2Ca, with irregular or polygonal shapes. The quantity, size, distribution, and area fraction of the second-phase particles are nearly identical between the two materials. Despite its larger grain size, the tensile yield strength of the material extruded at 450 ℃ and an extrusion ratio of 25 (450-25) is higher than that of the material extruded at 325 ℃ and an extrusion ratio of 10 (325-10), which is mainly attributed to the stronger texture hardening effect of the former. The ultimate tensile strength is similar in the two materials, owing to the higher work hardening rate in the 325-10 extrudate. Despite differences in grain size and recrystallization fraction, numerous twins are formed throughout the specimen during tensile deformation in both materials; consequently, the two materials exhibit nearly the same tensile elongation.

Optimization of Rod-shaped γ-LiAlO2 Particle Reinforced MCFC Matrices by Aqueous Tape Casting (수계 테이프 케스팅 법에 의한 봉상 γ-LiAlO2 입자 강화 MCFC 매트릭스 제조 공정의 최적화)

  • Choi, Hyun-Jong;Shin, Mi-Young;Hyun, Sang-Hoon;Lim, Hee-Chun
    • Journal of the Korean Ceramic Society
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    • v.46 no.3
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    • pp.282-287
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    • 2009
  • Rod-shaped particle reinforced $LiAlO_2$ matrices for MCFC were fabricated by an aqueous tape-casting technique. The hydrolysis reaction and agglomeration of $\gamma-LiAlO_2$ particles in aqueous slurries were inhibited by additions of $LiOH{\cdot}H_2O$ and glycerin to the aqueous $\gamma-LiAlO_2$ slurry. The tape-casting, performed using the aqueous slurry containing protein albumin, was fast and led to an effective drying at casting temperature range of $60{\sim}65^{\circ}C$. The strength of the particle reinforced matrix was improved about 4 times compared to that of matrix without reinforcement. Pore size distribution ($0.1{\sim}0.4{\mu}m$) and porosity ($50{\sim}60%$) of the reinforced matrices were determined to be appropriate for the MCFC matrix. The aqueous tape casting process is not only environmental-friendly but also efficient for fabricating MCFC matrices compared to non-aqueous tape casting.

Development of Organic Compound Fertilizer Based on Treated Human Waste (분뇨잔사(糞尿殘渣)를 이용(利用)한 유기종합비료(有機綜合肥料) 개발(開發))

  • Shin, Jae-Sung;Seong, Ki-Seog;Lim, Dong-Kyu
    • Korean Journal of Soil Science and Fertilizer
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    • v.17 no.1
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    • pp.55-59
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    • 1984
  • An organic compound fertilizer was manufactured using wet oxidation human waste as principal source of phosphorus and organic matter. The waste was treated with sulfuric and glutamic acids to increase the available and water-soluble $P_2O_5$ contents. The treatment of 0.1 N sulfuric acid with 24 hours curing was best way in recovering the maximum percentage of $P_2O_5$ originally in the waste. The particle size distribution of trial product varied considerably in the amount of glutamic acid used for granulation. The number of relatively large fertilizer particles was increased as the amount of glutamic acid was increased. The granule crushing strength was generally high in large granules in which 12.5 weight percent of glutamic acid were used for granulation. The trial product showed high moisture absorption due to its porous structure and chemical makeup.

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Prediction of the Mechanical Erosion Rate Decrement for Carbon-Composite Nozzle by using the Nano-Size Additive Aluminum Particle (나노 알루미늄 입자 첨가 추진제에 의한 탄소복합재 노즐의 기계적 삭마 감소 특성 예측)

  • Tarey, Prashant;Kim, Jaiho;Levitas, Valeny I.;Ha, Dongsung;Park, Jae Hyun;Yang, Heesung
    • Journal of the Korean Society of Propulsion Engineers
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    • v.19 no.6
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    • pp.42-53
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    • 2015
  • In this study, the influence of Al particle size, as an additive for solid propellant, on the mechanical erosion of the carbon-composite nozzle was evaluated. A new model which can predict the size and distribution of the agglomerated reaction product($Al(l)/Al_2O_3(l)$) was established, and the size of agglomerate were calculated according to the various initial size of Al in the solid propellant. With predicted results of the model, subsequently, the characteristics of mechanical erosion on the carbon-composite nozzle was estimated using a commercial CFD software, STAR CCM+. The result shows that the smaller the initial Al particles are, in the solid propellant, the lower is the mechanical erosion rate of the composite nozzle wall, especially for the nano-size Al particle.

Effects of Secondary Forming Process on Mechanical Properties of $SiC_p$/Al Composites Fabricated by Squeeze Casting (용탕단조법에 의하여 제조한 $SiC_p$/Al 복합재료의 2차 성형공정이 기계적 성질에 미치는 영향)

  • Seo, Y.H;Kang, C.G
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.20 no.11
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    • pp.3474-3490
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    • 1996
  • A metal matrix composites(MMCs) for A16061 reinforced with silicon carbide particles is fabricated by melt-stirring method. The primary products of MMCs billets are prepared by volume fractions 5 vol% to 20 vol% and particle size $13\mu m$ to $22\mu m$.This paper will be made to examine the microstructure and mechanical properties of fabricated $SiC_p$/Al 6061 composite by melt-stirring and squeeze casting method. The MMC billets is extruded at $500^{\circ}C$ under the constant extrusion velocity $V_e$=2mm/min using curved shape die. Extrusion force, particle rearrangement, micro structure and mechanical properties of extruded composites will be investigated. The mechanical properties of primary billets manufactured by melt-stirring and squeeze casting method will be compared with extrusion specimen. The effect of volume fraction and size of the reinforcements will be studied. The increase in uniformity of particle dispersion is the major reason for an improvement in reliability due to hot extrusion with optimal shape die. Experimental Young's modulus and 0.2% offset yield strength for the extruded MMCs will be compared with theretical values calculated by the Eshelby method. A method will be proposed for the prediction of Young's modulus and yield strength in $SiC_p$ reinforced MMCs.

A new thermal conductivity estimation model for weathered granite soils in Korea

  • Go, Gyu-Hyun;Lee, Seung-Rae;Kim, Young-Sang;Park, Hyun-Ku;Yoon, Seok
    • Geomechanics and Engineering
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    • v.6 no.4
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    • pp.359-376
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    • 2014
  • Thermal conductivity of ground has a great influence on the performance of Ground Heat Exchangers (GHEs). In general, the ground thermal conductivity significantly depends on the density (or porosity) and the moisture content since they are decisive factors that determine the interface area between soil particles which is available for heat transfer. In this study, a large number of thermal conductivity experiments were conducted for soils of varying porosity and moisture content, and a database of thermal properties for the weathered granite soils was set up. Based on the database, a 3D Curved Surface Model and an Artificial Neural Network Model (ANNM) were proposed for estimating the thermal conductivity. The new models were validated by comparing predictions by the models with new thermal conductivity data, which had not been used in developing the models. As for the 3D CSM, the normalized average values of training and test data were 1.079 and 1.061 with variations of 0.158 and 0.148, respectively. The predictions became somewhat unreliable in a low range of thermal conductivity values in considering the distribution pattern. As for the ANNM, the 'Logsig-Tansig' transfer function combination with nine neurons gave the most accurate estimates. The normalized average values of training data and test data were 1.006 and 0.954 with variations of 0.026 and 0.098, respectively. It can be concluded that the ANNM gives much better results than the 3D CSM.