• Title/Summary/Keyword: Dissolved organic matters

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A report on the mass summer mortalities of the farmed Pacific oysters, Crassostrea gigas and Bay scallops Argopecten irradians in the local waters of Goseong Bay, Korea

  • Han, Jong Cheol;Jo, Qtae;Park, Young Cheol;Park, Tae Gyu;Lee, Deok Chan;Cho, Kee-Chae
    • The Korean Journal of Malacology
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    • v.29 no.3
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    • pp.239-244
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    • 2013
  • Mass mortalities of farmed shellfish, mostly in summer season, thus named mass summer mortalities, have been a global issue in shellfish aquaculture. The 2013 mass summer mortalities in the confined waters of Goseong Bay, Goseong, Korea were quite a unique and intensive for two farmed species, the Pacific oysters, Crassostrea gigas, and bay scallops, Argopecten irradians. The mortalities were progressive from the bottom of the suspended oysters and caged scallops in the waters, reaching up to 80% for the oyster and 95% for the scallop in about 20 days after the first occurrence, early August, 2013. We monitored a wide range of environmental factors, including water temperature, dissolved oxygen (DO), salinity, turbidity, acidity (pH), organic and inorganic matters, chemical oxygen demand (COD), suspected pathogenic agent, and phytoplankton composition throughout the water column where the two species were suspended or caged. Our survey concluded that the hypoxia or anoxia might be a major cause of the mortalities. Here, we detailed the mortalities and ways to arrive at the conclusion.

Roles of polypropylene beads and pH in hybrid water treatment of carbon fiber membrane and PP beads with water back-flushing

  • Song, Sungwon;Park, Yungsik;Park, Jin Yong
    • Membrane and Water Treatment
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    • v.10 no.2
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    • pp.155-163
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    • 2019
  • The roles of polypropylene (PP) beads and pH on membrane fouling and treatment efficiency were investigated in a hybrid advanced water treatment process of tubular carbon fiber membranes (ultrafiltration (UF) or microfiltration (MF)) and PP beads. The synthetic feed including humic acid and kaolin flowed inside the membrane, and the permeated contacted the PP beads fluidized in the space between the membrane and the module with UV irradiation and periodic water back-flushing. In the hybrid process of UF ($0.05{\mu}m$) and PP beads, final resistance of membrane fouling ($R_f$) after 180 min increased as PP beads increased. The turbidity treatment efficiency was the maximum at 30 g/L; however, that of dissolved organic matters (DOM) showed the highest at PP beads 50 g/L. The $R_f$ strengthened as pH of feed increased. It means that the membrane fouling could be inhibited at low alkali condition. The treatment efficiency of turbidity was almost constant independent of pH; however, that of DOM showed the maximum at pH 5. For MF ($0.1{\mu}m$), the final $R_f$ was the minimum at PP beads 40 g/L. The treatment efficiencies of turbidity and DOM were the maximum at PP beads 10 g/L.

Comparison of Ocean Optical Properties Between the Micronesia and the Korean Peninsula (남태평양 마이크로네시아와 한반도 주변 해역의 해수 광학특성 비교)

  • Moon, Jeong-Eon;Choi, Jong-Kuk
    • Korean Journal of Remote Sensing
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    • v.37 no.5_1
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    • pp.1125-1133
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    • 2021
  • This study attempted to understand seawater characteristics like chlorophyll concentration (CHL), total suspended matter concentration (TSM), absorption characteristics, and remote sensing reflectance around Weno Island, Micronesia, located in the South Pacific Ocean near the equator. 50 in-situ measurement from May to June 2013 were analyzed and compared with data from around Korean peninsula. CHL around Weno Island was 0.11-0.49 mg/m3 (average 0.26 mg/m3), and TSM was 0.03-0.31 g/m3, (average 0.16 g/m3), showing typical clear water characteristics. Absorption coefficient of total suspended matters at 443 nm showed over 0.5 times less than that from East Sea and the slope of absorption coefficient spectrum of dissolved organic matter showed much larger than that of Korean peninsula, indicating the concentration of organic matter is very low and dissolved organic matter of marine origin is considered to be the main component in the study area. As a result of comparing the remote sensing reflectance spectrum with that of coastal waters around the Korean peninsula, coastal waters around Weno Island showed typical CASE-1 water properties. It was possible to understand the marine optical characteristics of coral reef habitats in tropical waters, and it can be used to develop seawater algorithms specialized in the study area.

Influencing Factors on NOM Removal using Blended Coagulants (혼합응집제에 의한 자연유기물질 제거에 미치는 영향 인자)

  • 명복태;우달식;최종헌;문철훈;이윤진;조영태;조관형;남상호
    • Journal of environmental and Sanitary engineering
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    • v.16 no.3
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    • pp.96-103
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    • 2001
  • This study was carried out to investigate the major factors for the removal of NOMs (Natural Organic Matters) by alum ferric chloride and blended coagulants that consisted of alum and ferric chloride. Investigated factors were pH, the dosage of coagulant, alkalinity, hardness and bloc strength. The particle size contained in the test water came from the Han River was also measured. DOC(Dissolved Organic Carbon) removal at pH 6 was two to three times higher than at pH 8.5. The blended coagulant showed 9 to 10 percent higher DOC removal efficiency and 2 to 4 percent higher turbidity under the same condition. Alkalinity consumption of alum, ferric chloride and blended coagulant was 81%, 90% and 86% of theoretical value, respectively. The limit concentration of alkalinity to avoid pin floe was 10 mg $CaCO_3/L$ when alum was used. Hardness had no apparent effect on coagulation. The residual turbidity and $UV_{254}$ showed a tendency of increasing with floc strength($sec^{-1}$) increase. The order of floe strength was the following; alum >blended coagulant > ferric chloride. The particle counter test showed 89 percent of the small particle size(SPS, $1~5{\;}{\mu}textrm{m}$) and 11 percent of the medium to large particle size(M.LPS, $5~125{\;}{\mu}textrm{m}$). At PH7.85, the particle removal efficiencies of SPS($1~5{\;}{\mu}textrm{m}$) and M.LPS($5~125{\;}{\mu}textrm{m}$) in the coagulation process were 81% and 95%, respectively.

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Removal of Algogenic Organic Matter in Drinking Water Treatment Process (정수처리공정에서 조류유래 유기물질의 제거)

  • Park, Se-Jin;Cha, Il-Kwon;Yoon, Tai-Il
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.4
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    • pp.377-384
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    • 2005
  • Algae causes not only the eutrophication of lake, but also the deterioration of drinking water process. Especially, algogenic organic matters(AOM) are assumed as disinfection by-products(DBPs) precursors like humic and fulvic acids. In this study, it was investigated the characteristics changes of algogenic organic matter(AOM) by prechlorination and coagulation treatment. Evaluation of enhanced coagulation and applicability of UV oxidation process were also evaluated as the drinking water treatment system for the eutrophicated water source. prechlorination was effective process for algae removal but caused releasing of dissolved organic matter(DOC) into water due to the destruction of algae's cell. In coagulation treatment with Fe(III) coagulant, reaction pH is an important factor for the removal of AOM and triholomathanes(THMs). At pH 5, removal efficiency of DOC and THMs were dramatically improved by 50% and 28%, respectively, in comparison with the conventional coagulation treatment at about pH 7. Photo-Fenton($UV/H_2O_2/Fe^{3+}$) process among the UV oxidations is the most effective system to remove AOM, but its removal efficiency was lower than that of enhanced coagulation treatment at pH 5.

A Study on the Appropriateness as Organic Matters Indicator and the Distribution of Chemical Oxygen Demand and Total Organic Carbon in Masan Bay, Korea (마산만 해수 중 화학적산소요구량과 총유기탄소 분포 특성 및 유기물 지표로서의 적절성 검토)

  • PARK, MI-OK;LEE, YONG-WOO;CHO, SEONG-AH;KIM, HYE-MI;PARK, JUN-KUN;KIM, SUNG-GIL;KIM, SEONG-SOO;LEE, SUK MO
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.26 no.2
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    • pp.82-95
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    • 2021
  • We investigated the temporal and spatial distribution characteristics of chemical oxygen demand (COD) and total organic carbon (TOC) in all 13 locations of Masan Bay from February to November in 2015. The COD and TOC contents were high during the June-August period when the pollution load increased. In particular, the concentrations of COD and TOC were about twice as high in the surface water as in the bottom water. In spatial distribution, the COD and TOC concentrations at the inner bay were about twice as high as those of the outer bay in Masan Bay. As a result of estimating the oxidation efficiency of COD from the surface layer of Masan Bay in 2015 based on the theoretical oxygen demand (TOD), it was at the level of about 23%. Due to the low oxidation efficiency of COD, there is a risk that the organic matter in Masan Bay will be somewhat underestimated. Therefore, for quantitative analysis of organic matter, COD and TOC analyses need to be combined.

Assessment for Production of Organic Matter in the Wando Costal Area. (완도해역에서 유기물의 생산량 평가)

  • Kim Woo-Hang
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.12 no.3 s.26
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    • pp.165-170
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    • 2006
  • In this study, organic matters production was calculated with long term data in Wando costal area where was selected for non influent of fresh water. The objective of this study was to evaluate relationship between nutrients and phytoplankton and, between phytoplankton and organic matter. The result of DIN was the highest with 0.138 mg/L in winter season and the lowest with 0.052 mg/L in summer season. Similarly, DIP was shown to be 0. 017 mg/L in winter and 0.011 mg/L in summer. Limiting nutrient was revealed with nitrogen in Wando costal area. Specially in summer season, nitrogen limitation was the greatest with 10.5 of N/P ratio. Chl. -a was increased 80%, 108% in spring and summer compare with winter. COD was the lowest with 0.84 mg/L in winter and the highest with 1.10 mg/L in summer. The interrelation between nutrients and Chl. -a was high. Relationship $coefficient(r^2)$ were 0.93(P<0.05), 0.89(P <0.05) between DIN and Chi. -a, DIP and Chl. -a. This results suggest dissolved nutrients might be utilized at the production of phytoplankton. Also Relationship $coefficient(r^2)$ was 0.77(P<0.05) between Chl. -a and COD. COD production rate was calculated with regression equation. The COD production rate was 17% in winter and 36% in summer. It was revealed nutrients were decreased according to temperature increasing and then Phytoplankton and organic matter were increased. The Relationship of Nutrients, Chl. -a and COD was very high.

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Application of Lime Stone, Sand, and Zeolite as Reactive Capping Materials for Marine Sediments Contaminated with Organic Matters and Nutrients (유기물 및 영양염류로 오염된 해양퇴적물 정화를 위한 석회석, 모래, 제올라이트의 반응성 피복 소재로서 적용성 평가)

  • Kang, Ku;Park, Seong-Jik
    • Journal of Korean Society of Environmental Engineers
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    • v.39 no.8
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    • pp.470-477
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    • 2017
  • In this study, the applicability of calcite, sand, and zeolite for the remediation of sediments contaminated with organics and nutrients were investigated. Sediments and seawater for water tank experiments were sampled from Pyeongtaek harbor, and 1 cm or 3 cm of calcite, sand, and zeolite were capped on the sampled sediments. pH, electric conductivity (EC), dissolved oxygen (DO), chemical oxygen demand (COD), total nitrogen (TN), and total phosphorus (TP) were monitored for 63 days. The sampled sediments were highly contaminated with organic matter and total nitrogen. DO in uncapped condition was exhausted within 10 days but DO in capping condition except 3 cm of zeolite capping was prolonged above 2 mg/L. Capping efficiency for interrupting COD release from sediments was in the following order: zeolite 1 cm > calcite 1 cm > calcite 3 cm > sand 3 cm ${\cong}$ zeolite 3 cm ${\cong}$ sand 1 cm. Zeolite was found to be effective for interrupting nitrogen release. T-P was not observed in both uncapped and capped sediment, i.e., all experimental conditions. It can be concluded that zeolite can be effectively used for the remediation of sediments highly contaminated with organic matter and nitrogen.

Role of Water Current in the CROM Operation for the Water Quality Improvement of Eutrophic Reservoir (부영양 저수지의 수질개선을 위한 CROM 운영 및 유속의 영향)

  • Lee, Ju-Hwan;Hwang, Soon-Jin;Kim, Baik-Ho
    • Journal of Korean Society on Water Environment
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    • v.26 no.3
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    • pp.518-524
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    • 2010
  • Continuous removal of organic matters (CROM) using freshwater bivalve Anodonta woodiana was operated to evaluate the effect of water current on the water quality improvement (clearance) of eutrophic lake. The CROM system comprised three treatment steps such as flow control, treatment and analysis, and operated at the two different currents ($24L\;h^{-1}$ and $48L\;h^{-1}$) with mussels at density of $312.5indiv.\;m^{-2}$ for 12 consecutive days. Water quality including suspended solids (SS) and chlorophyll-a (Chl-a) was daily measured at the same time. Results indicate that although both the system strongly decreased the concentration of SS and chl-a, a slow CROM system was more effective to diminish the SS contents than a fast CROM system; 82% and 66%, respectively (ANOVA, P<0.0001). Clearance rates, based on chl-a, were also significantly higher in a slow system than a fast system (ANOVA, P<0.0001), although the mussel mortality was conversely. In both systems, there showed a remarkable excretion of dissolved inorganic nutrients (i.e. $NH_3-N$ and $PO_4-P$), while a slow CROM system was higher than a fast system, significantly (ANOVA, P<0.0001). Therefore, it may suggest that a slow current CROM system is more suitable to maximize the efficacy of water quality improvement, but further study is needed to diminish the mortality of mussel and to reuse the nutrient released during the operation.

Co-precipitation of Turbidity and Dissolved Organic Matters by Coagulation (응집(凝集)에 의한 탁도물질(濁度物質) 및 용존(溶存) 유기물질(有機物質)의 동시제거(同時除去)에 대한 연구(硏究))

  • Jeong, Sang-Gi;Jun, Hang-Bae;Kim, Hag-Seong
    • Journal of Korean Society of Water and Wastewater
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    • v.9 no.3
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    • pp.99-107
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    • 1995
  • Various humic substances are widely distributed in natural water body, such as rivers and lakes and cause the yellowish or brownish color to water. The evidence that humic substances are precursors of THMs formation in chlorinated drinking water has been reported m the Jiteratures. For the reason of public health as well as aesthetics, needs for humic substances removal have been increased in the conventional water treatment processes. In this research, the characteristics of aluminium coagulation of humic acids and humic acids were investigated. The optimum pH and coagulants dosage to remove these materials simultaneously by coagulation were alto studied. The results are as followed; 1. UV-254 absorptiometry for measuring the concentration of aquatic humic acids showed good applicability and stable results. 2. The optimal pH range for humic acids removal by aluminium coagulation was 5 to 5.5, however, an increase in aluminium coagulant dosage could enhance the removal rate of humic acids in the wide pH range. 3. Coprecipitation of humic acids in the typical pH range of 6.5 to 8 in water treatment processes may require the sweep coagulation mechanism with the excess aluminium coagulant dosage. 4. Using PAC(poly aluminium chloride) or PASS(poly aluminium silica sulfate) as coagulants was able to expand the operating range for removing humic acids. 5. From the coagulation of humic substances(UV-254) and turbidity at pH range of 5.5 - 6.0 and alum dose of 86 ppm, the removal efficiency of turbidity from the reservoir water was above 90% and that of UV-254 was above 70%. 6. By using the reservoir water, the optimum condition of rapid mixing for simultaneous removal of turbidity and UV-254 absorbance was pH of 5.8 and LAS dose of 86 ppm, in this study.

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