• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.9 no.4
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• pp.179-195
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• 2004

The trophic state of the coastal waters of the southern part of Korea was assessed using biogeochemical data obtained from the National Marine Environmental Monitoring Program conducted by the National Fisheries Research and Development Institute for six years. The trophic state of different areas, analyzed by non-metric multi-dimensional scaling (MDS) analysis, could divide the areas into three groups. Masan Bay, with suboxic water masses and/or the highest concentrations of dissolved inorganic nitrogen and phosphorus occurred, was assessed as being in a hypertrophic state. Ulsan Bay, Onsan Bay, Busan and Jinhae Bay, located near strong point sources, were in a eutrophic state. Other areas, including Tongyong, Yosu, Mokpo and Jeju island, were evaluated as being in a mesotrophic state. During 1997 to 2002, the average values of excess nitrogen, which is the difference between the measured dissolved inorganic nitrogen (DIN) and the corrected DIN using the Redfield ratio, were positive at Ulsan, Onsan, and Busan, where there were inflows from polluted rivers. In contrast, those were negative values in Haengam Bay, Gwangyang Bay and nearby Yosu. This suggests that the limiting element for phytoplankton growth differed among sites. The time series data of excess nitrogen showed gradual decrease over time in the hypertrophic waters, but the opposite trend in the mesotrophic waters. This indicated that the ratio of nitrogen to phosphate varied according to the trophic state of the coastal waters. The enrichment of organic matter in sediment in eutrophic waters would disturb the normal pattern of biogeochemical cycling of nitrogen and phosphate. In order to assess the condition of the coastal environment, the benthic boundary layer should be considered.

• Economic and Environmental Geology
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• v.54 no.1
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• pp.151-160
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• 2021

2:1 clay minerals such as smectite incorporating ammonium were extracted to investigate the ammonium behavior and nitrogen isotope characteristics for two different sediment cores which were collected from shimmering sites on seafloor of the Wakamiko crater, southwestern Japan. Inorganic nitrogen contents in clay fraction were estimated by calibration curve based on consistently decreasing carbon and nitrogen ratio during the treatment to decompose organic materials, after removing inorganic carbon. The results show that the proportions of inorganic nitrogen for total nitrogen in clay fraction of SWS site(Core#1094MR: av. 18.2%) are higher than those in SES site(Core#1093MG: av. 11.5%). Relatively good crystallinity of the former suggests that exchangeable ammonium was transformed to non-exchangeable ammonium during more evolving diagenetic process. Nitrogen isotope variance of clay fraction(SES site: Core#1093MG: -4.4 ~ +0.2 ‰, av. -2.4 ‰; SWS site: Core#1094MR: -0.7 ~ +3.0 ‰, av. +1.5 ‰) during sequential decomposition of exchangeable ammonium suggests that heat flow derived from deep magma led to nitrogen isotope fractionation between dissolved ammonium and ammonia in the fluids involved in the formation of 2:1 clay mineral incorporating ammonium with local temperature variation.

• Environmental Engineering Research
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• v.24 no.1
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• pp.107-116
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• 2019

Nitrogen removal, nitrous oxide ($N_2O$) emission and microbial community in sequencing batch and continuous-flow intermittent aeration processes were investigated. Two sequencing batch reactors (SBRs) and two continuous-flow multiple anoxic and aerobic reactors (CMRs) were operated under high dissolved oxygen (DO) (SBR-H and CMR-H) and low DO (SBR-L and CMR-L) concentrations, respectively. Nitrogen removal was enhanced under CMR and low DO conditions (CMR-L). The highest total inorganic nitrogen removal efficiency of 91.5% was achieved. Higher nitrifying and denitrifying activities in SBRs were observed. CMRs possessed higher $N_2O$ emission factors during nitrification in the presence of organics, with the highest $N_2O$ emission factor of 60.7% in CMR-L. SBR and low DO conditions promoted $N_2O$ emission during denitrification. CMR systems had higher microbial diversity. Candidatus Accumulibacter, Nitrosomonadaceae and putative denitrifiers ($N_2O$ reducers and producers) were responsible for $N_2O$ emission.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.31 no.2
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• pp.176-185
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• 1998

For the sustainable production of cultured arkshell Scapharca broughtonii and pre-estimation of the harvest of it, we investigated the relationship between the habitat environmental factors and the physiological conditions of the arkshell in the two experiment sites near the Chinhae Bay, Korea. For the analysis of habitat environmental factors such as temperature, salinity, dissolved oxygen, DIP (dissolved inorganic phosphate), DIN (dissolved inorganic nitrogen), suspended solids and chlorophyll a of bottom water and T-S (total sulfide) and COD (chemical oxygen demand) of surface sediment were measured, To determine physiolosical condition of cultured arkshell, shell length, fatness, glycogen, hemoglobin content and gametogenesis were examined. Water temperature were higher in Woongchon than in Songdo in 1992, and were Higher in Songdo in 1993. Salinity were higher in Songdo than in Woongchon except from January to May in 1992. COD, suspended solids and chlorophyll a content were higher in Songdo than in Woongchon, while the contents of sediment sulfide, DO, DIP and DIN were higher in Woongchon. Based on the environmental assessment, significant factors affecting the growth and physiological condition of arkshell were quantity of food and total sulfide content in the bottom sediment.

• Journal of the Korean Society for Marine Environment & Energy
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• v.18 no.2
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• pp.74-80
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• 2015

To assess environmental characteristics of the aquaculture area in Tongyeong, pH, dissolved oxygen (DO), dissolved inorganic nitrogen (DIN), dissolved inorganic phosphorous (DIP) and chemical oxygen demand (COD), and acid volatile sulfur (AVS) were measured in seawater and sediment samples collected from 10 locations of Tongyeong coastal area from July to December in 2013. The quality of the seawater may be affected by seasonal variation rather than the distance from fish farm. However, sediment was contrary to seawater; the distance from fish farm may be a main factor to affect COD and AVS in sediment than season and other parameters. It is expected that contaminated organic sediments of fishery located in semi-closed bay are rapidly dispersed into surrounding waters due to fast current.

• Journal of Environmental Science International
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• v.21 no.10
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• pp.1171-1179
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• 2012

Headwaters initiate material export to downstream environments. A nested headwater study examined the flux of dissolved constituents and water from a perennial stream and four ephemeral/intermittent streams in the Upper Gulf Coastal Plain of Mississippi. Water was collected during storm and baseflow conditions. Multiple linear regression was used to model constituent concentration and calculate flux. Event was the major source of water discharged from the ephemeral and intermittent streams however, baseflow was the major source for water discharged by the perennial stream during events. The perennial stream had an area weighted average yields of 10.1, 0.01, 1.03, 0.65 kg/ha/yr of DON (dissolved organic nitrogen), $NO_3^-$-N, $NH_4^+$-N and $PO_4^{-3}$, respectively while large variabilities existed between the ephemeral and intermittent streams. These findings highlight the importance of headwaters in protecting the low order drainage basins as a key to water quality within perennial streams.

• Journal of Sensor Science and Technology
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• v.32 no.2
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• pp.67-74
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• 2023

A microfluidic paper-based analytical device (µPAD) is proposed for the selective detection of ammonia in water by using the modified Berthelot reagent and a fluidic channel consisting of hollow paper. The modified Berthelot reagents were uniformly dispersed in cyclohexane and then immobilized in a detection zone of the µPAD. The loading position of the reagents and the type of a sample flow channel were optimized to achieve a sensitive ammonia detection within a short analytical time. The NH₃ µPAD exhibits a linear colorimetric response to the concentration of ammonia dissolved in water in the range of 1-100 mg L^-1, and its limit-of-detection is 1.75 mg L^-1. In addition, the colorimetric response was not influenced by the addition of 100 mg L^-1 nitrogen containing compounds (sodium nitrate, sodium nitrite, uric acid, hydroxylamine, butylamine, diethylamine) or inorganic salts (NaCl, Na₂HPO₄), presenting the enough selectivity in the detection of water-dissolved ammonia against possible interferents.

• Korean Journal of Ecology and Environment
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• v.33 no.4 s.92
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• pp.350-357
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• 2000

This paper evaluated the influence of point source and flow events on inorganic nitrogen fractions at 17 sites of Taechung Reservoir during 1993${\sim}$1994. Total nitrogen (TN) averaged 1.53 mg/L during the study and ranged between 0.70 and 2.56 mg/L. Dissolved inorganic nitrogen(DIN) accounted for >90% of TN regardless of season and location, indicating a nitrogen-rich system showing eutrophic${\sim}$hypereutrophic conditions. Some 67${\sim}$94% of DIN was NO$_{3}$-N, whereas mean level of NH$_{4}$-N was less than 5% of DIN. During monsoon 1993, dilution of NO$_{3}$-N was evident in the headwaters as a result of mixing of lake water with rain water, while NH$_{4}$-N increased>100% compared to the premonsoon. Values of NH$_{4}$-N had a positive correlation with rainfall (r=0.85; p<0.001) and negative correlations with theoretical water residence time(r=-0.90; p<0.001) and conductivity(r=-0.78, p<0.001), respectively. These outcomes suggest that NH$_{4}$-N came from external input from the watershed during the monsoon. In both years, mean TN was greater in the mid-lake sites than any other sites. A great amount of TN in the mid-lake was most pronounced in monsoon 1994 because of an accumulated influence of the point sources during low inflow. Overall data suggest that concentrations of TN in this system did not show large differences along the longitudinal gradients and its distributions is likely determined by point-sources rather than inflow regime.

• Journal of the Korean Society for Marine Environment & Energy
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• v.7 no.1
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• pp.13-21
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• 2004

Temporal changes of Chl-α, physical and chemical factors were investigated by diurnal observation at 2-hour interval at three fixed stations in the western Chinhae Bay from 12 Aug. to 13 Aug. 1999. Difference of dissolved oxygen between surface and bottom layer was maximum when the thermocline were strong. Organic distribution such as COD was affected by the growth of phytoplankton. Limitting factor was nitrogen, that is, inorganic nitrogen plays a significant role on regulating the algal growth. Surface distribution of dissolved inorganic nitrogen was very low compared to bottom layer by uptake of organisms. Maximum value of Chl-α at station C2 and C11 were observed from subsurface layer, ranges of which exceeded possibility concentration of red tide outbreak, 10 mg/㎥. On the other hand, that of C15 exist at surface layer. In this area, DIN and DIP concentrations increased by input sources such as rainfall and benthic flux before the bloom of phytoplankton. Accumulation of phytoplankton occurred at subsurface layer by the rapid uptake of DIN, especially nitrate ion, when strong thermocline existed as approach to the afternoon, which led to the increase of organics in water column and oxygen deficiency water mass at bottom layer until late at evening. Since then, DIN increases gradually as water temperature decrease to minimum. The quantitative understanding of nitrogen of fluxed to and from the various sources is necessary for environmental management.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.11 no.4
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• pp.165-171
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• 2006

This is the research to prepare a purification program for relatively less polluted stream by using phytoremediation. We calculated a treatment amount of nutrients followed by growth of Helianthus annuus (a kind of sunflower), setting up the plant reactor in the hothouse. Moreover, to investigate a field applicability, we could find increased contents of nitrogen, carbon and hydrogen in plants by setting up a H. annuus planted artificial floating island in an irrigation canal. When we changed the dissolved inorganic nitrogen(DIN) concentration of the influent from 28.5 to 199.2 mg/l and the dissolved inorganic phosphorus(DIP) concentration of the influent from 13.3 to 25.4 mg/l, growth disorder has not appeared though it is much higher than the criterion of water for irrigation. In this case, the removal rate of DIN was $81.7\sim98.6%$, and that of DIP was $81.9\sim98.4%$ in 3 days stay on average. It has appeared that the efficient hydraulic retention time(HRT) was 48 hours. The following contents of nitrogen, carbon and hydrogen of H. annuus appeared in the artificial floating island: nitrogen was $3.2\sim7.8%$ in the trunk and $3.0\sim6.3%$ in the root. Carbon was $40.1\sim57.7%$ in the trunk and $43.4\sim53.8%$ in the root.