• Journal of Korean Society of Water and Wastewater
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• v.34 no.6
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• pp.463-471
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• 2020

A 1,000 ㎥/d DAF(dissolved air flotation) pilot plant was installed to evaluate the performance of the floating process using the Nakdong River. Efficiency of various DAF operations under different conditions, such as hydraulic loading rate, coagulant concentration was evaluated in the current research. The operation conditions were evaluated, based on the removal or turbidity, TOC(total organic carbon), THMFP(trihalomethane formation potential), Mn(manganese), and Al(aluminum). Also, particle size analysis of treated water by DAF was performed to examine the characteristics of particles existing in the treated water. The turbidity removal was higher than 90%, and it could be operated at 0.5 NTU or less, which is suitable for the drinking water quality standard. Turbidity, TOC, and THMFP resulted in stable water quality when replacing the coagulant from alum to PAC(poly aluminum chloride). A 100% removal of Chl-a was recorded during the summer period of the DAF operations. Mn removal was not as effective as where the removal did not satisfy the water quality standards for the majority of the operation period. Hydraulic loading of 10 m/h, and coagulant concentrations of 40 mg/L was determined to be the optimal operating conditions for turbidity and TOC removal. When the coagulant concentration increases, the Al concentration of the DAF treated water also increases, so coagulant injection control is required according to the raw water quality. Particle size distribution results indicated that particles larger than 25 ㎛ showed higher removal rates than smaller particles. The total particel count in the treated water was 2,214.7 counts/ml under the operation conditions of 10 m/h of hydraulic loading rate and coagulant concentrations of 60 mg/L.

• Journal of Industrial and Engineering Chemistry
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• v.67
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• pp.301-311
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• 2018

In this study, the ion-gelation method was applied to fabricate novel Fe-carbon-bentonite-alginate beads ($Fe^0$/C-BABs). $Fe^0$/C-BABs could effectively control Fe release during persulfate (PS) activation in N-acetyl-p-aminophenol (APAP) oxidation. A novel two-stage approach that combined $Fe^0$/C-BABs and an oyster-shell-filled bed (OSFB) column was developed to address the low pH and high Fe concentration of the effluent of the traditional PS process. The application of the $Fe^0$/C-BABs and OSFB column regulated pH levels and Fe release during the advanced oxidation of APAP. The characteristics of $Fe^0$/C-BABs were also investigated through scanning electron microscopy, energy dispersive spectrometry, and Fourier transform infrared spectroscopy. The long-term operation performance of $Fe^0$/C-BABs in a continuous fixed-bed reactor under simultaneous PS and APAP feeding was also evaluated. The effects of initial PS concentration, pH, fixed-bed weight, in-flow rate, and dissolved oxygen (DO) were investigated. Under selected conditions, 86.3% efficiency was achieved during the first stage of APAP degradation (effluent pH of 3.05, Fe contents: $106.25mgL^{-1}$). Water quality improved after the effluent was passed through the OSFB column (effluent pH of 6.32, Fe contents: $21.43mgL^{-1}$). Moreover, this study analyzed the free radicals and intermediates produced during APAP degradation to identify the possible routes of APAP degradation.

• Journal of Korean Society on Water Environment
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• v.37 no.6
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• pp.531-538
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• 2021

In this study, the TOC in six estuarine reservoirs in the West Sea (Ganwol, Namyang, Daeho, Bunam, Sapkyo, and Asan) was estimated using optically-active water quality factors by the water environment monitoring network. First, specification data and land use maps of each estuarine reservoir were collected. Subsequently, water quality data from 2013 to 2020 were collected. The data comprised of 11 parameters: pH, dissolved oxygen, BOD, COD, suspended solids (SS), total nitrogen, total phosphorus, water temperature, electrical conductivity, total coliforms, and chlorophyll-a (Chl-a). The TOC in the estuarine reservoirs was 4.9~7.0 mg/L, with the highest TOC of 7.0 mg/L observed at the Namyang reservoir, which has a low shape coefficient and high drainage density. The correlation of TOC with water quality factors was also analyzed, and the correlation coefficients of Chl-a and SS were 0.28 and 0.19, respectively, while the correlation coefficients of these factors in the Namyang reservoir were 0.42 and 0.27, respectively. To improve the estimation of TOC using Chl-a and SS, the TOC was averaged in 5 mg/L units, and Chl-a and SS were averaged. Correlation analysis was then performed and the R² of Chl-a-TOC was 0.73. The R² of SS-TOC was 0.73 with a non-linear relationship. TOC had a significant non-linear relationship with Chl-a and SS. However, the relationship should be assessed in terms of the spatial and temporal variations to construct a reliable remote sensing system.

• Journal of Microbiology and Biotechnology
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• v.32 no.10
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• pp.1292-1298
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• 2022

Soil autotrophic bacterial communities play a significant role in the soil carbon (C) cycle in paddy fields, but little is known about how rhizosphere soil microorganisms respond to different long-term (35 years) fertilization practices under double rice cropping ecosystems in southern China. Here, we investigated the variation characteristics of rhizosphere soil RubisCO gene cbbL in the double rice ecosystems of in southern China where such fertilization practices are used. For this experiment we set up the following fertilizer regime: without any fertilizer input as a control (CK), inorganic fertilizer (MF), straw returning (RF), and organic and inorganic fertilizer (OM). We found that abundances of cbbL, 16S rRNA genes and RubisCO activity in rhizosphere soil with OM, RF and MF treatments were significantly higher than that of CK treatment. The abundances of cbbL and 16S rRNA genes in rhizosphere soil with OM treatment were 5.46 and 3.64 times higher than that of CK treatment, respectively. Rhizosphere soil RubisCO activity with OM and RF treatments increased by 50.56 and 45.22%, compared to CK treatment. Shannon and Chao1 indices for rhizosphere soil cbbL libraries with RF and OM treatments increased by 44.28, 28.56, 29.60, and 23.13% compared to CK treatment. Rhizosphere soil cbbL sequences with MF, RF and OM treatments mainly belonged to Variovorax paradoxus, uncultured proteobacterium, Ralstonia pickettii, Thermononospora curvata, and Azoarcus sp.KH33C. Meanwhile, cbbL-carrying bacterial composition was obviously influenced by soil bulk density, rhizosphere soil dissolved organic C, soil organic C, and microbial biomass C contents. Fertilizer practices were the principal factor influencing rhizosphere soil cbbL-carrying bacterial communities. These results showed that rhizosphere soil autotrophic bacterial communities were significantly changed under conditions of different long-term fertilization practices Therefore, increasing rhizosphere soil autotrophic bacteria community with crop residue and organic manure practices was found to be beneficial for management of double rice ecosystems in southern China.

• Journal of Microbiology and Biotechnology
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• v.32 no.9
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• pp.1178-1185
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• 2022

Steroids are a class of compounds with cyclopentane polyhydrophenanthrene as the parent nucleus, and they usually have unique biological and pharmacological activities. Most of the biosynthesis of steroids is completed by a series of enzymatic reactions starting from cholesterol. Synthetic biology can be used to synthesize cholesterol in engineered microorganisms, but the production of cholesterol is too low to further produce other high-value steroids from cholesterol as the raw material and precursor. In this work, combinational strategies were established to increase the production of cholesterol in engineered Saccharomyces cerevisiae RH6829. The basic medium for high cholesterol production was selected by screening 8 kinds of culture media. Single-factor optimization of the carbon and nitrogen sources of the culture medium, and the addition of calcium ions, zinc ions and citric acid, further increased the cholesterol production to 192.53 mg/l. In the 5-L bioreactor, through the establishment of strategies for glucose and citric acid feeding and dissolved oxygen regulation, the cholesterol production was further increased to 339.87 mg/l, which was 734% higher than that in the original medium. This is the highest titer of cholesterol produced by microorganisms currently reported. The fermentation program has also been conducted in a 50-L bioreactor to prove its stability and feasibility.

• KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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• v.28 no.1
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• pp.9-14
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• 2022

Packages of different atmospheres (air (control), 100% CO₂, vacuum, and vacuum + O₂ absorber) were prepared for 0.4 kg rice cake (ddukgukdduk) using gas-barrier plastic film and stored at 10℃ for 11 days. The stored products were evaluated in their packages atmosphere, total aerobic bacteria, yeast and molds, texture and sensory quality during storage period. In the air package, the O₂ concentration decreased from initial 21% to 16% on storage 4 days and the CO₂ concentration increased to 23% on storage of 11 days, which resulted from the growth of microorganisms. CO₂ concentration decreased from initial 98% to 36% on storage 11 days in the 100% CO₂ package. It is reasoned that CO₂ was dissolved into the product reducing the volume of the package. Vacuum and vacuum +O₂ absorber package maintained shrunk vacuum condition until 11 days of storage. Total aerobic bacteria count increased significantly in the control package (6.41 log (cfu/g) after 11 days) compared to the 100% CO₂ package (4.96 log (cfu/g) after 11 days). Yeast and molds were 6.66 in control package, 3.43 in 100% CO₂ package, 4.66 in vacuum package, and 3.78 in vacuum + O₂ absorber package after 11 days. There was no significant difference between control and the other treatments for the texture of the stored products. Sensory quality was the worst in control package on the storage of 8 days. All treatment groups except control improved the quality preservation, but vacuum and vacuum + O₂ absorber packages suffered from cracking of the product. Thus 100% CO₂ flushing is suggested as a desired packaging condition.

• Journal of Korean Society on Water Environment
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• v.39 no.2
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• pp.153-161
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• 2023

The reservoir tank in an apartment is crucial for maintaining the quality of drinking water after it has undergone treatment. Investigating the water quality and potential contaminants in the reservoir tank is essential to ensure the safety of the drinking water. This study examined the water quality and precipitated suspended solids that accumulate at the bottom of the reservoir tanks in four apartments located in Gyeonggi province. As a result of the water quality investigation, turbidity increased proportionally to the distance from the water treatment plant (WTP) to the household. Heavy metals were also detected in the reservoir tank inlet but not in the water supplied from the WTP. The precipitated suspended solids (SS) in the reservoir tank contain high levels of heavy metals and total organic carbon (TOC). The precipitated SS mainly consists of Al, Mn, and Fe, which are expected to be a combination with turbidity-inducing substances. The X-ray diffraction (XRD) analysis revealed the presence of γ-FeO(OH), MnO₂, and β-Fe₂O₃ in the SS. Additionally, F-EEM analysis indicates that the dissolved organic matter in the SS is mainly derived from a natural water source and microorganism activities, including metal-oxidizing bacteria and biofilms that can absorb metal ions. Based on these findings, several countermeasures can be taken to prevent the inflow of SS into the household, including regularly cleaning the reservoir tank, replacing or cleaning old pipes in the water supply system, and implementing monitoring and filtering systems to manage the SS.

• Proceedings of the Korea Water Resources Association Conference
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• 2021.06a
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• pp.85-85
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• 2021

CDOM(Colored or Chromophoric Dissolved Organic Matter)은 바다, 호수 및 강에서 담수, 오수, 퇴적물 등으로부터 공급된 유기물질의 일종으로 가시광선에서 빛을 흡수하는 성질을 가지며, 2016년부터 환경부에서 선정한 하천, 호수 등 방류수의 수질오염 표준인 TOC(Total Organic Carbon)를 간접 추정할 수 있는 매개변수가 될 수 있다. 따라서, 본 연구에서는 백제보 상류 23 km 구간을 대상으로 2개년(2016~2017) 중 7일의 초분광영상 자료를 활용하여 내륙지역의 CDOM에 대한 적정 반사도 밴드값(R_rs)과 CDOM을 추정하는 알고리즘을 개발하고자 한다. CDOM은 흡수계수(α_CDOM)를 통해 간접 추정되며, 흡수계수의 기준 파장값(λ)은 연구별로 350 nm, 375 nm, 400 nm, 412 nm 및 440 nm 등 다르게 나타난다. 초분광영상은 AsaFENIX 초분광 센서에서 관측된 380~970 nm까지 4 nm 간격, 127개 대역의 분광해상도와 2 m의 공간해상도를 가진 영상을 활용하였으며, 자료의 연속성을 위해 smoothing 기법을 활용하여 가공하였다. 추정 알고리즘은 Random forest를 활용하였으며, 70%의 trainning과 30%의 test로 구분하여 적용하였다. 산출된 CDOM은 결정계수(R²), Nash-Sutcliffe efficiency(NSE)를 이용하여 실측 CDOM과 비교하였다. 흡수계수별 CDOM의 산정 결과 α_CDOM(350 nm)의 trainning, test에서 각각 R²가 0.71, 0.74, NSE가 0.25, 0.49로 가장 높았으며, 적정 반사도 밴드값은 R_rs(466), R_rs(493), R_rs(548), R_rs(641)를 사용하였을 때 trainning, test에서 각각 R²가 0.93, 0.90, NSE가 0.85, 0.69로 가장 높게 나타났다.

• Korean Journal of Environmental Agriculture
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• v.42 no.2
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• pp.83-92
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• 2023

Excess N and P from the livestock manure applied to farmlands, have entered the water systems and poses a serious threat to the natural environment. Consequently, there has been recent awareness towards the management of livestock manure and its related fields. In this study, piggery wastewater was collected from a piggery in Pohang city, Korea. At 800℃, thermal decomposition of a natural stone, magnesite (MgCO₃), yielded powered MgO with particle sizes ranging between 10 to 100 ㎛. Furthermore, NH₄⁺-N and PO₄^3--P were recovered as struvite precipitates from the piggery wastewater, by adjusting the pH with MgO and H₃PO₄. At pH 10, the recovery efficiencies of NH₄⁺-N and PO₄^3--P were found to be 86.1% and 94.1%, respectively. Using an X-ray Diffractometer (XRD), the struvite in the precipitate was confirmed to be consistent with standard pure struvite. Further, the purity of the struvite precipitate was analyzed using an energy dispersive X-ray (EDX) and thermal gravimetry-differential thermal analysis (TG-DTA), and found to be between 79.2% and 93.0%. Additionally, struvite-containing piggery wastewater and sawdust were mixed in a weight ratio of 2.5:1 and processed into a mature compost. The newly manufactured compost passed all quality standards required for first-class graded livestock composts. Moreover, this compost was sprayed directly onto the soil at the test site, and various parameters of the soil's effluent, such as total organic carbon (TOC), total nitrogen (T-N), total phosphorus (T-P), and dissolved oxygen (DO), were analyzed and measured. Based on these results, it is determined that the newly manufactured compost can more significantly reduce water pollution than commercial compost.

• Journal of the Korean Society for Heat Treatment
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• v.36 no.1
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• pp.22-32
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• 2023

In general, when scrap is dissolved in an electric arc furnace, the amount of electric furnace steel dust (EAFD) generated is about 1.5% of the scrap charge amount, and the electric furnace steel dust collected by the bag filter is charged into the Rotary Kiln or Rotary Hearth Furnace (RHF), and the zinc component is recovered as crude zinc oxide, at which time a clinker of Fe-Base is generated. In this research, first, for the efficient resource conversion of electric furnace steel dust, a reduction and roasting experiment was conducted and the reaction kinetics was examined. As a result of the experiment, it was observed that the reduction and roasting reaction was actively conducted in the range of 1100~1150℃, and melting occurred in the range of 1250℃. In the past, this clinker was widely used as a roadbed material for road construction and an Fe-Source for cement production, but in recent years, it has been mainly reclaimed due to strengthening environmental standards. However, landfill treatment is by no means a desirable treatment method due to environmental pollution caused by leachate, expensive landfill costs, and waste of Fe resources. Therefore, in order to more actively recycle the Fe component in the clinker, first of all the clinker was pulverized into an optimal particle size, and anthracite and binder (starch) were added to the magnetic material obtained by specific gravity and magnetic separation for briquet. As a experimental results, it was possible to efficiently separate clinker as Fe component and other slag component by specific gravity and magnetic force. As a results of loading and dissolving the manufactured briquet clinker in an electric arc furnace, it was observed that the unit of power and production yield were clearly improved and the carbon addition effect in molten metal was also somewhat.