• Title/Summary/Keyword: Dispersion of Cu

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Effects of Upset Pressure on Weldability in the Friction Welding of Cu to Cu-W Sintered Alloy (동-텅스텐 소결합금(Cu-W)과 동(Cu)의 마찰용접 특성에 미치는 업셋압력의 영향에 관한 연구)

  • 강성보;민택기
    • Journal of Welding and Joining
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    • v.17 no.5
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    • pp.69-76
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    • 1999
  • A copper-tungsten sintered alloy(Cu-W) has been friction welded to a tough pitch copper in order to investigate the effect of upset pressure on friction weldability. Under the condition of friction time 0.8sec, upset pressure 150MPa, the tensile strength and Charpy impact value of the friction welded joint were 336MPa, $400KJ/m^2$ respectively. And highest temperature of the weld measured was below $800^{circ}K$ which is very lower than melting point of Cu($1356^{circ}K$). Under the same conditions, W grains picked up in Cu matrix from Cu-W profitably affected on these mechanical fracture, and were dispersed in Cu by plastic flow during brake time.

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Etching and Polishing Behavior of Cu thin film according to the additive chemicals

  • Ryu, Ju-Suk;Eom, Dae-Hong;Hong, Yi-Koan;Park, Jum-Yong;Park, Jin-Goo
    • Proceedings of the International Microelectronics And Packaging Society Conference
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    • 2002.05a
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    • pp.274-278
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    • 2002
  • The purpose of this study was to characterize the reaction of Cu surface with Cu slurry and CMP performance as a function of additives in CMP slurry. The polish rate of Cu was dependent on the kind of organic acids added in slurry. It was considered that polish rate of Cu was dependent on the concentration of carboxylates and mean particle size. When the etchant and oxidant were added in slurry, the highest removal rate and lower etch rate were measured at neutral pH. The addition of etchant, oxidant and pH adjustor played key roles of CMP ability in slurry. As the pH increased, polish rate of Cu was increased by the enhanced the mechanical effects due to effective dispersion of slurry particles. Alumina abrasives was more desirable for 1st step slurry because of high removal rate of Cu and high selectivity ratio among TaN and Cu.

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THE EFFECT OF Cu SUBSTITUTION ON THE PROPERTIES OF NiZn FERRITE

  • Nam, J.H.;Jung, H.H.;Shin, J.Y.;Oh, J.H.
    • Journal of the Korean Magnetics Society
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    • v.5 no.5
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    • pp.548-551
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    • 1995
  • The effect of Cu substitution on the properties of NiZn ferrites sintered at low temperature with composition is investigated. The densification of NiCuZn ferrite in dependent upon Cu content in the composition of (N/sub 0.5-x/Cu/sub x/ Zn/sub 0.5/O)(Fe/sub 2/O/sub 3/)/sub 0.98/. Electrical resistivity is maximum at x=0.2. Dispersion characteristics of complex permeability of (Ni/sub 0.5-x/ Cu/sub x/Zn/sub 0.5/O)(Fe/sub 2/O/sub 3)/sub 0.98/ is observed above x=0.3 and relaxation frequency increases with higher temperature. The magnetic loss of NiCuZn ferrite is occurred above the Cu content x=0.3 at a low frequency.

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Synthesis of Cu/Al2O3 Nanostructured Composite Powders for Electrode Application by Thermochemical Process (열화학적 방법에 의한 전극용 나노 Cu/Al2O3 복합분말 합성)

  • 이동원;배정현;김병기
    • Journal of Powder Materials
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    • v.10 no.5
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    • pp.337-343
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    • 2003
  • Nanostructured Cu-$Al_2O_3$ composite powders were synthesized by thermochemical process. The synthesis procedures are 1) preparation of precursor powder by spray drying of solution made from water-soluble copper and aluminum nitrates, 2) air heat treatments to evaporate volatile components in the precursor powder and synthesis of nano-structured CuO + $Al_2O_3$, and 3) CuO reduction by hydrogen into pure Cu. The suggested procedures stimulated the formation of the gamma-$Al_2O_3$, and different alumina formation behaviors appeared with various heat treating temperatures. The mean particle size of the final Cu/$Al_2O_3$ composite powders produced was 20 nm, and the electrical conductivity and hardness in the hot-extruded bulk were competitive with Cu/$Al_2O_3$ composite by the conventional internal oxidation process.

Experimental Study on Dispersion and Thermal Properties of Nanofluids based on POE Oil (POE 오일 나노유체의 열물성과 분산성 평가를 위한 실험적 연구)

  • Lee, K.S.;Lee, K.A.;Lee, J.S.;Lee, H.Y.;Park, S.J.;Lee, Y.S.;Kim, S.;Jang, S.P.;Kim, Jeong-Bae
    • Journal of the Korean Solar Energy Society
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    • v.32 no.3
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    • pp.170-177
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    • 2012
  • To apply the nanofluids into the general vapor compression cycle, basically have to know the thermal properties including thermal conductivity and dynamic viscosity. And needs to show the dispersion characteristics for various nanofluids and concentrations. So, firstly this study showed experimentally the thermal properties for various concentration (0.1%~0.7%, as mass balance) and temperature($20^{\circ}C{\sim}40^{\circ}C$) on $Al_2O_3$, $TiO_2$, and CuO nanofluids using base fluid as POE oil that has used in the scroll compressor for various refrigeration system. From the results, the dynamic viscosity of nanofluids was considerably changed from the base POE oil. And, the dispersion characteristics of various nanofluids using the simple methods like as analyzing the RGB value or measuring the sinking height of nanofluids were showed experimentally. Through the results, the dispersion characteristics of $Al_2O_3$ nanofluid was better than those of $TiO_2$, and CuO nanofluids not considering the real refrigeration cycle rurming conditions.

Dispersion and Migration of Potentially Toxic Elements in the Rock-Soil-Plant System from the Boeun Area Underlain by Black Shales, Korea (보은지역 흑색셰일 분포지역에서의 암석-토양-식물계내 잠재적 독성원소들의 분산과 이동)

  • Lee, Jin-Soo;Chon, Hyo-Taek;Kim, Kyoung-Woong
    • Economic and Environmental Geology
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    • v.30 no.6
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    • pp.587-601
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    • 1997
  • This study had three purposes: (1) to investigate the enrichment levels and dispersion patterns of potentially toxic elements in the rock-soil-plant system; (2) to evaluate the uptake ratios of heavy metals from soils into plants and (3) to assess the chemical speciation of heavy metals in soils. Rock, surface soil and plant samples were collected in the Boeun area underlain by black shales of the Okchon Zone. These samples were analyzed for multi-elements using INAA, ICP-AES and AAS. The maximum abundance of U in black shales is 16 mg/kg and radioactivity counts up to 300 cpm. In particular, Mo, V, Ba, Cd, Pb and U are enriched in black shales. Most of soils derived from black shales show high concentrations of U, As, Mo, Ba, Cu, Cd, Pb, Zn and mean concentrations of As and Mo in soils (20 mg/kg of As and 6.6 mg/kg of Mo) are higher than the permissible level suggested by Kloke (1979). Enrichment index values of soils are calculated and higher than 1.0 in the black shale area with the highest value of 6.4. Mean concentration of Cd in plants is higher than those of Cu, Pb and Zn. The concentration of Cd in plant species decreases in the order of Chinese cabbage > red pepper > soybean=sesame > rice stalk > com > rice grain. The biological absorption coefficients (BAC) in plants are in the order of Cd > Zn=Cu > Pb, which suggests that Cd is more bioavailable to plants than Cu, Pb and Zn. From the results of sequential extraction analysis of soils, relatively high proportion of Cu, Pb and Zn are present as residual fractions whereas that of Cd as non-residual fractions. Cadmuim occurs predominantly as exchangeable/water-acid soluble phase in soils, and Cd is more mobile and bioavailable than Cu, Pb and Zn.

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Dispersion of Heavy Metals in the Geochemical Environment around the Geumwang Gold-Silver Mine (금왕 금·은광산 주변 지구화학적 환경에서의 중금속 원소들의 분산)

  • Park, Jong-Jin;Kim, Myeong-Kyun;Chon, Hyo-Taek
    • Economic and Environmental Geology
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    • v.30 no.5
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    • pp.407-416
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    • 1997
  • Soil, tailings, stream sediment and surface water samples collected in the vicinity of the Geumwang Au-Ag mine were analyzed in order to investigate the pollution level of heavy metals and to determine the dispersion patterns. Although the maximum concentrations of soils collected at the flotation plant and tailings dam were 9,270 ppm As, 17 ppm Cd, 1,480 ppm Cu, 10,080 ppm Pb and 18,400 ppm Zn, dispersion of heavy metals were limited in the vicinity of the flotation plant and tailings dam. This may be due to high pH values (> 8.0) of the soils by flotation solution for mineral processing. The pH values of water samples near the flotation plant and tailings dam were over 8.0 and Cd, Cu and Zn concentrations were not detected. The waters in the vicinity of Geumwang mine generally belong to a $Ca^{2+}-SO_{4}{^{2-}}$ $(HCO_3{^-})$ type.

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Microstructural properties of Pt-doped $YBa_{2}Cu_{3}O_{7-x}$ high $T_c$ superconductor prepared by melting method.

  • Song, Jin-Tae
    • Proceedings of the Materials Research Society of Korea Conference
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    • 1992.05a
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    • pp.16-16
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    • 1992
  • We have studied the effect of platinum addition on the supercon ducting properties of YB $a_2$C $u_3$$O_{7-x}$ (123) compound and elucidated the mechanism of fine dispersion of $Y_2$BaCu $O_{5}$(211) particles in YB $a_2$C $u_3$$O_{7-x}$ superconductor prepared by melting method from the metallurgical point of view. In this study, BaCu $O_2$ and CuO-rich phase unreacted during the peritecitc reaction markedly decreased by the 211 powder addition. The 211 particle of Pt-fee sintered samples exhibited 8~10$\mu$m in size, but in 1wt%Pt-added sample, 211 particles were finely dispersed in 123 matrix and the size of 211 particle was about 1~2$\mu$m. And, the critical temperature( $T_{c. zero}$) of Pt doped samples was 91.5K and the transport critical current density ( $J_{c}$) of Pt-doped samples was much more than 10$^4$A/$\textrm{cm}^2$. The high $J_{c}$ and fine dispersion of 211 particles of Pt doped YB $a_2$C $u_3$$O_{7-x}$ superconductor are attributed to $Ba_4$CuP $t_2$ $O_{8}$ compounds formed during the partial melting, which were considered als nucleation sites of 211 particles, rather than Pt inself.han Pt inself.

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Enhanced Catalytic Activity of Cu/Zn Catalyst by Ce Addition for Low Temperature Water Gas Shift Reaction (Ce 첨가에 따른 저온수성가스전이반응용 Cu/Zn 촉매의 활성 연구)

  • Byun, Chang Ki;Im, Hyo Bin;Park, Jihye;Baek, Jeonghun;Jeong, Jeongmin;Yoon, Wang Ria;Yi, Kwang Bok
    • Clean Technology
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    • v.21 no.3
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    • pp.200-206
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    • 2015
  • In order to investigate the effect of cerium oxide addition, Cu-ZnO-CeO2 catalysts were prepared using co-precipitation method for water gas shift (WGS) reaction. A series of Cu-ZnO-CeO2 catalyst with fixed Cu Content (50 wt%, calculated as CuO) and a given ceria content (e.g., 0, 5, 10, 20, 30, 40 wt%, calculated as CeO2) were tested for catalytic activity at a GHSV of 95,541 h-1, and a temperature range of 200 to 400 ℃. Cu-ZnO-CeO2 catalysts were characterized by using BET, SEM, XRD, H2-TPR, and XPS analysis. Varying composition of Cu-ZnO-CeO2 catlysts led the difference characteristics such as Cu dispersion, and binding energy. The optimum 10 wt% doping of cerium facilitated catalyst reduction at lower temperature and improved the catalyst performance greatly in terms of CO conversion. Cerium oxide added catalyst showed enhanced activities at higher temperature when it compared with the catalyst without cerium oxide. Consequently, ceria addition of optimal composition leads to enhanced catalytic activity which is attributed to enhanced Cu dispersion, lower binding energy, and hindered Cu metal agglomeration.