• Title/Summary/Keyword: Dispersion media

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Biocompatible Individual Dispersion of Single-walled Carbon Nanotubes

  • Najeeb, C.K.;Kim, Duck-Jong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.529-529
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    • 2012
  • Dispersion of carbon nanotubes in biocompatible media are of particular interest for diverse biomedical and nanomedicine applications. Various biomolecules and biopolymers such as DNA, proteins, poly L-lysine, starch, gelatin, steroid biosurfactants, and chitosan have shown capability for the effective dispersion of carbon nanotubes in water. Chitosan has demonstrated capacity for effective dispersion of single-walled carbon nanotubes (SWCNTs) in acidic medium and it also showed tendency to preferentially disperse smaller diameter nanotubes. Chemical functionalizations of chitosan enable its solubility in neutral pH water by reducing the intra and inter molecular hydrogen bonding. Herein, we present a neutral pH water soluble chitosan derivative, chitosan-hydroxyphenyl acetamide (CHPA), obtained by functionalizing the amino groups of chitosan with 4-hydroxyphenyl acetic acid, as an efficient biocompatible dispersant for debundling and solubilization of SWNTs in neutral aqueous solutions. Various process conditions for individual dispersion of SWCNTs are analyzed based on optical absorption and Raman spectroscopy.

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The Quantitative Characterization of the Dispersion State of Single-Walled Carbon Nanotubes (단일벽 탄소나노튜브의 분산도 정량적 평가)

  • Yoon, Do-Kyung;Choi, Jae-Boong;Kim, Young-Jin;Baik, Seung-Hyun
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.31 no.4
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    • pp.483-489
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    • 2007
  • We have investigated quantitative measurement techniques of the degree of dispersion of single-walled carbon nanotubes (SWNTs). SWNTs were suspended in aqueous media using a sodium dodecyl sulfate (SDS) surfactant. SWNTs with different dispersion states were prepared by controlling the intensity and time of sonication and centrifugation. The laser spectroscopic techniques were employed to characterize the dispersion state; i.e., raman fluorescence and absorption spectroscopic techniques. Raman spectroscopy has been used to probe the dispersion and aggregation state of SWNTs in solution. Individually suspended SWNTs show increased fluorescence peaks and decreased roping peaks at a raman shift 267 $cm^{-1}$ compared with the samples containing bundles of SWNTs. The ultraviolet-visible-near infrared (UV-vis-NIR) absorption spectrum of decanted supernatant samples show sharp van Hove singularity peaks

Application of VSI-EBG Structure to High-Speed Differential Signals for Wideband Suppression of Common-Mode Noise

  • Kim, Myunghoi;Kim, Sukjin;Bae, Bumhee;Cho, Jonghyun;Kim, Joungho;Kim, Jaehoon;Ahn, Do Seob
    • ETRI Journal
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    • v.35 no.5
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    • pp.827-837
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    • 2013
  • In this paper, we present wideband common-mode (CM) noise suppression using a vertical stepped impedance electromagnetic bandgap (VSI-EBG) structure for high-speed differential signals in multilayer printed circuit boards. This technique is an original design that enables us to apply the VSI-EBG structure to differential signals without sacrificing the differential characteristics. In addition, the analytical dispersion equations for the bandgap prediction of the CM propagation in the VSIEBG structure are extracted, and the closed-form expressions for the bandgap cutoff frequencies are derived. Based on the dispersion equations, the effects of the impedance ratio, the EBG patch length, and via inductances on the bandgap of the VSI-EBG structure for differential signals are thoroughly examined. The proposed dispersion equations are verified through agreement with the full-wave simulation results. It is experimentally demonstrated that the proposed VSI-EBG structure for differential signaling suppresses the CM noise in the wideband frequency range without degrading the differential characteristics.

Spatial moment analysis of multispecies contaminant transport in porous media

  • Natarajan, N.;Kumar, G. Suresh
    • Environmental Engineering Research
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    • v.23 no.1
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    • pp.76-83
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    • 2018
  • Spatial moment analysis has been performed on the concentration of the first species in a multispecies solute transport in porous media. Finite difference numerical technique was used in obtaining the solute concentration. A constant continuous source of contaminant was injected at the inlet of the domain. Results suggest that the decaying of solute mass increases as the magnitude of mean fluid velocity increases. The dispersion coefficient is highly time dependent under decaying of solutes with a complex behavior of mixing of solutes. The solute mobility and mixing varies non-linearly with time during its initial period, while the same ceases with higher decay rates of the first species much faster.

A Study on Heat and Mass Transfer in Porous Media (다공질 물질 속에서의 열 및 물질 전달에 대한 연구)

  • Chung, Mo
    • Solar Energy
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    • v.15 no.1
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    • pp.39-51
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    • 1995
  • A numerical scheme based on a coordinate transform into stream function-velocity potential is proposed to solve heat and momentum transfer in porous media with phase change. A significant simplification of both computational domain and governing equations can be achieved by the transform. The dispersion term in the flow through porous media, which is important at the phase change interface, can be successfully incorporated into the numerical scheme without introducing any further computational complications.

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Underlayer effects on crystallographic and magnetic characteristics of Co-Cr(-Ta) layer (Co-Cr(-Ta) 층의 결정성 및 자기적 특성에 미치는 하지층 효과)

  • 금민종;공석현;가출현;손인환;김경환
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.208-211
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    • 2000
  • We prepared Co-Cr-Ta and Co-Cr-Ta/Ti thin film for perpendicular magnetic recording media by facing targets sputtering system (FTS system). Ti underlayer effects on crystallographic and magnetic characteristics of Co-Cr-Ta perpendicular magnetic recording media have been investigated. Crystallgraphic and magnetic characteristic of prepared thin films were evaluated by x-ray diffractometry(XRD), vibrating sample magnetometer(VSM) and kerr hysteresis loop measurement. The coercivity and anisotropy field increase by introduced Ti underlayer when substrate temperature is higher than 150$^{\circ}C$. The c-axis dispersion angle and grain size of Co-Cr-Ta/Ti thin film is decrease than Co-Cr-Ta when substrate temperature is higher than 100$^{\circ}C$. Consequently, the use of a Ti underlayer highly orientated can be improved crystallographic and magnetic characteristics of Co-Cr -Ta perpendicular media layer.

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Preparation and Dispersion Characteristics of Oil-based Magnetic Fluids with Synthesized Magnetite (합성마그네타이트를 이용한 유상자성유체의 제조 및 분산특성)

  • Cho, Myeong-Ho;Kim, Mahn;Min, Dong-Joon;Oh, Jae-Hyun
    • Journal of the Korean Ceramic Society
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    • v.33 no.8
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    • pp.901-908
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    • 1996
  • The oil-based magnetic fluids were prepared with synthesized ultrafine magnette by allowing surfactactants such as sodium oleate and aliquat 336 to adsorb on the surface of magnetite particles. The dispersion ratio of oil-based magnetic fluids was higher than 90% when the amount of sodium oleate and aliqua 336 were more than 2.63$\times$10-2 mol and 6.56$\times$10-3 mol for 20g of magnetite respectively. The dispersion ratio of oil-based magnetic fluids with the amount of secondary surfactant addition was higher than 90% when oil-based magnetic fluids were prepared with aliquat 336 of cationic type. However oil-based magnetic fluids prepared with surfactants of anionic and nonionic type showed lower dispersion than whose with cationic surfac-tants.

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An experimental study on the correlation of hydraulic mean radius and hydrodispersive parameters in rockfill porous media (자갈 다공성매질에서 수리평균반경과 수리분산 매개변수의 상관성에 관한 실험적 연구)

  • Han, Ilyeong;Lee, Jaejoung;Kim, Gyoo Bum
    • Journal of Korea Water Resources Association
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    • v.54 no.11
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    • pp.863-873
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    • 2021
  • The mechanical dispersion which dominates solute transport in porous media is caused by the difference in flow velocity within pores. Longitudinal dispersion coefficient and longitudinal dispersivity that are hydro-dispersive parameters of advection-dispersion equation can only be obtained by experiment. Hydraulic mean radius that represents the amount and intensity of flowing water within pores can be obtained by the formula using the factors for physical properties. A slug injection test was conducted and a power type empirical formula for obtaining a longitudinal dispersivity using a hydraulic mean radius in rockfill porous media was derived. It is possible to obtain the longitudinal dispersivity depending on transport distance because it contains a formula for a scale constant, and expected to be applicable to waterways filled with homogeneous gravel and small flow rate.

Enhancement of Nitrendipine Bioavailability in Rats by its Solid Dispersion with $Hydroxypropyl-{\beta}-Cyclodextrin$ after Oral Administration (흰쥐에 경구 투여시 히드록시프로필-베타-시클로덱스트린과 니트렌디핀 고체분산에 의한 생체이용률 증가)

  • Yong, Chul-Soon
    • Journal of Pharmaceutical Investigation
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    • v.27 no.4
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    • pp.295-301
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    • 1997
  • Nitrendipine, a slightly soluble calcium channel blocking agent forms a solid dispersion system with $hydroxypropyl-{\beta}-cyclodextrin$, which exhibits better dissolution characteristics than the uncomplexed drug. The dissolution rate of nitrendipine was markedly increased in solid dispersion system in pharmacopeial disintegration media at pH 1.2 and pH 6.8. Four different dosage forms of nitrendipine were administered to rats: (a) nitrendipine in the solution of PEG 400; (b) nitrendipine solid dispersion system with $hydroxypropyl-{\beta}-cyclodextrin$ in a molar ratio of 1:2 by solvent evaporation method and administered in capsule form; (c) physical mixture of nitrendipine with $hydroxypropyl-{\beta}-cyclodextrin$ in a molar ratio of 1:2 and administered in capsule form; (d) nitrendipine alone administered in capsule form. Relative bioavailability after the oral administration of various dosage forms to rats with a dose of 10 mg/kg equivalent to nitrendipine was compared with that of nitrendipine in the solution of PEG 400. The AUC of solid dispersion was significantly bigger than that of nitrendipine powder. $T_{max}$ of solid dispersion was significantly shorter and $C_{max}$ was higher than that of nitrendipine powder. These results indicate that the bioavailability of nitrendipine could be improved markedly by inclusion complexation. An interesting correlation also appears to exist between the in vitro dissolution data and the area under the plasma concentration-time curves.

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