• Carbon letters
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• v.20
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• pp.53-61
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• 2016

The reportedly synergistic effects of carbon nanotubes (CNTs) and graphene hybrids have prompted strong demand for an efficient modifier to enhance their dispersion. Here, we investigated the ability of poly(acrylonitrile) (PAN) to overcome the van der Waals interaction of multi-walled CNTs (MWCNTs) and graphene by employing a simple wrapping process involving ultrasonication and subsequent centrifugation of PAN/MWCNT/graphene solutions. The physical wrapping of MWCNTs and graphene with PAN was investigated for various PAN concentrations, in an attempt to simplify and improve the polymer-wrapping process. Transmission electron microscopy analysis confirmed the wrapping of the MWCNTs and graphene with PAN layers. The interaction between the graphitic structure and the PAN molecules was examined using proton nuclear magnetic resonance, ultraviolet-visible spectroscopy, Fourier transform infrared spectroscopy, thermogravimetric analysis, and Raman spectroscopy. The obtained results revealed that the cyano groups of the PAN molecules facilitated adhesion of the PAN molecules to the MWCNTs and graphene for polymer wrapping. The resulting enhanced dispersion of MWCNTs and graphene was verified from zeta potential and shelf-life measurements.

• Bulletin of the Korean Chemical Society
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• v.32 no.12
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• pp.4195-4198
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• 2011

Intramolecular ${\pi}-{\pi}$ and ${\sigma}-{\pi}$ interactions are omnipresent for numerous energetic and structural phenomena in nature, and the exact description of these nonbonding interactions plays an important role in the accurate prediction of the three-dimensional structures for numerous interesting molecular systems such as protein folding and polymer shaping. We have selected two prototype molecular systems for benchmarking calculations of intramolecular ${\pi}-{\pi}$ and ${\sigma}-{\pi}$ interactions. Accurately describing conformational energy of such systems requires highly elaborate but very expensive ab initio methods such as coupled cluster singles, doubles, and (triples) (CCSD(T)). Our calculations reveal a double hybrid density functional incorporating dispersion correction (B2PLYP-D) that agrees excellently with the CCSD(T) results, indicating that B2PLYP-D can serve as a practical method of choice.

• Journal of the Optical Society of Korea
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• v.18 no.3
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• pp.207-216
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• 2014

In this work, we report detailed numerical analysis of the near-elliptic core index-guiding triangular-lattice and square-lattice photonic crystal fiber (PCFs); where we numerically characterize the birefringence, single mode, cut-off behavior and group velocity dispersion and effective area properties. By varying geometry and examining the modal field profile we find that for the same relative values of $d/{\Lambda}$, triangular-lattice PCFs show higher birefringence whereas the square-lattice PCFs show a wider range of single-mode operation. Square-lattice PCF was found to be endlessly single-mode for higher air-filling fraction ($d/{\Lambda}$). Dispersion comparison between the two structures reveal that we need smaller lengths of triangular-lattice PCF for dispersion compensation whereas PCFs with square-lattice with nearer relative dispersion slope (RDS) can better compensate the broadband dispersion. Square-lattice PCFs show zero dispersion wavelength (ZDW) red-shifted, making it preferable for mid-IR supercontinuum generation (SCG) with highly non-linear chalcogenide material. Square-lattice PCFs show higher dispersion slope that leads to compression of the broadband, thus accumulating more power in the pulse. On the other hand, triangular-lattice PCF with flat dispersion profile can generate broader SCG. Square-lattice PCF with low Group Velocity Dispersion (GVD) at the anomalous dispersion corresponds to higher dispersion length ($L_D$) and higher degree of solitonic interaction. The effective area of square-lattice PCF is always greater than its triangular-lattice counterpart making it better suited for high power applications. We have also performed a comparison of the dispersion properties of between the symmetric-core and asymmetric-core triangular-lattice PCF. While we need smaller length of symmetric-core PCF for dispersion compensation, broadband dispersion compensation can be performed with asymmetric-core PCF. Mid-Infrared (IR) SCG can be better performed with asymmetric core PCF with compressed and high power pulse, while wider range of SCG can be performed with symmetric core PCF. Thus, this study will be extremely useful for designing/realizing fiber towards a custom application around these characteristics.

• Korean Journal of Cognitive Science
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• v.23 no.1
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• pp.73-95
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• 2012

Two experiments were conducted to verify how the factors of attentional dispersion, reason for waiting, and cue of time flow affect the perceived waiting time. In experiment 1, based on the characteristics of waiting experience that Maister(1985) suggested, levels of attentional dispersion and whether or not offering a reason for waiting were manipulated. Participants estimated elapsed time(the objective time was 10 minutes) using either prospective or retrospective estimation method. Overall results were that they overestimated the elapsed time regardless of the experimental conditions. However, both main effects of the attentional dispersion and the reason for waiting were statistically significant. That is, when attention was more dispersed and when the reason was given, overestimation of elapsed time was reduced. No difference was found between the two estimation methods, and none of the interaction was significant. Experiment 2 was a replication of Experiment 1 except that a cue of time flow was added by using scroll bar on a computer screen. Because it has been suggested that the cue can help us to manage the waiting time and result in differences between the two time estimation methods. The results showed that main effects of the attentional dispersion and the reason for waiting were significant as those in Experiment 1. In addition, main effect of time estimation method and the three-way interaction were also significant. None of two-way interaction was significant. That is, the perceived waiting time is much shorter in the retrospective method, and the effects of the attentional dispersion and the reason of waiting were dependent upon the estimation methods. Both experiments showed that offering a clear reason for waiting is more important than the attentional dispersion in reducing the perceived waiting time. Some implications of these results for the service industry and the future direction of research were discussed in the final section.

• Journal of Advanced Navigation Technology
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• v.16 no.3
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• pp.440-448
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• 2012

Optimal net residual dispersion (NRD) and effective launching power range of optical transmission links with optical phase conjugator (OPC) and dispersion management (DM) for compensating the distorted wavelength division multiplexing (WDM) signals due to interaction of group velocity dispersion (GVD) and optical nonlinear effects. WDM systems considered in this research have optical links with the random distribution of residual dispersion per span (RDPS) in each single mode fiber (SMF) spans of only one half transmission section for designing the adaptive optical transmission system configurations. It is confirmed that optimal NRD is 10 ps/nm and effective launching power range is obtained to be -8~1 dBm under NRD = 10 ps/nm in optical links with total dispersion controlled by precompensation. And, it is also confirmed that optimal NRD is -10 ps/nm and effective launching power range is obtained to be -7.5~1 dBm under NRD = -10 ps/nm in optical links with total dispersion controlled by postcompensation.

• Journal of Advanced Navigation Technology
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• v.16 no.5
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• pp.801-809
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• 2012

Dispersion management (DM) is the typical technique compensating for the distorted signals due to interaction of group velocity dispersion (GVD) and optical nonlinear effects for transmitting wavelength division multiplexed (WDM) channel with the excellent performance. Optimal net residual dispersion (NRD) and effective launching power range of optical transmission links with random distribution and artificial distribution of single mode fiber (SMF) length and residual dispersion per span (RDPS) required to flexibly design of optical links in DM. It is confirmed that optimal net residual dispersion (NRD) are +10 ps/nm and -10 ps/nm controlled by precompensation and postcompensation, respectively, in both of the considered distribution patterns of SMF length and RDPS. And, in optimal NRD, system performance in optical links with the descending distribution of SMF length and the ascending distribution of RDPS among the artificial distribution patterns are more improved, consequently, effective launching power range is expanded by almost 2 dB than those in optical links with the uniform distribution.

• Journal of the Korea Institute of Military Science and Technology
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• v.18 no.5
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• pp.582-593
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• 2015

For military training and course-of-action analysis, OneSAF Int'l version being used in ROK Army has a limited capability to simulate NBC(nuclear, biological, and chemical) damages. For high-fidelity NBC combat simulation, it is required to visualize NBC contamination dispersion in consideration of weather conditions and terrain characteristics. However, OneSAF itself handling interaction among thousands of combat entities cannot carry out a simulation of NBC contamination dispersion because it brings about an excess burden. To resolve this problem, this research aims to design simulation federation for analysis on NBC operational effects. After examining design consideration to connect OneSAF and a NBC contamination dispersion model, we design a federation architecture that facilitates the interaction between OneSAF and a NBC contamination dispersion model. Afterwards, we implement a federation interface to share simulation data by publish-subscribe pattern and to translate them into the proprietary format for each model. We prove the possibility of federation between both models, as showing that dispersion of NBC contaminated cloud and changes in concentration are reflected in OneSAF-based engagement simulation.

• Proceedings of the Korean Institute of Navigation and Port Research Conference
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• 2014.06a
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• pp.258-259
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• 2014

It is needed the introduction of a new wave dispersion relationship considering the condition of seabed to examine closely the interaction between wave and seabed. In this study, a wave dispersion relationship is newly developed considering the condition of seabed such as permeability and displacement. Wave damping rates are compared and analysed according to the various soil parameters such as seabed soil thickness, elastic modulus, saturation, permeability, and porosity.

• Korea-Australia Rheology Journal
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• v.19 no.2
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• pp.81-88
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• 2007

Blends of collagen dispersion (COL) with poly(vinyl alcohol) (PVA) in different weight ratios were investigated by oscillatory rheometry, Fourier transform-infrared spectroscopy and scanning electron microscopy. It was found that even with 80% of PVA, the COL/PVA blends behaved more like collagen dispersion than pure PVA solution in the dynamic thermal and frequency processing, for instance, a dominant elastic appearance (G'>G"), a similar shear thinning behavior and the thermal denaturation below $40^{\circ}C$. However, influence on the blend behaviour by PVA was noticeable, for instance, an increase of dynamic denaturation temperature, the decreasing intensity of amide I, II and III bands as well as the diminishing irregular pores on the surface of blends. The interaction between collagen and PVA could be observed, especially at the regions with low content or high content of PVA.

• Journal of the Optical Society of Korea
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• v.16 no.2
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• pp.95-100
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• 2012

We show that the minimum EOP (eye-opening penalty) obtained by tunable dispersion compensation is a function of a figure of merit for a nonlinear process, $I_0L_{eff}$, where $I_0$ is the optical intensity and $L_{eff}$ is the effective length of the interaction region. Using this rule, we do not need to conduct nonlinear simulations in all the cases of signal power and transmission length to obtain the signal distortion in dispersion-managed optical transmission. Instead, we need to conduct a simulation in only one case of a signal power and find the functional relation, and then we can obtain the values of the signal distortion in other cases using the discovered functional relation. This technique can reduce the number of nonlinear simulations to less than 10%.