• Title/Summary/Keyword: Dispersion forces

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INTERPARTICLE POTENTIAL OF 10 NANOMETER TITANIUM NANOPARTICLES IN LIQUID SODIUM: THEORETICAL APPROACH

  • KIM, SOO JAE;PARK, GUNYEOP;PARK, HYUN SUN;KIM, MOO HWAN;BAEK, JEHYUN
    • Nuclear Engineering and Technology
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    • v.47 no.6
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    • pp.662-668
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    • 2015
  • A suspension of titanium nanoparticles (Ti NPs) in liquid sodium (Na) has been proposed as a method to mitigate the violent sodium-water reaction (SWR). The interparticle potential between Ti NPs in liquid Na may play a significant role in the agglomeration of NPs on the reaction surface and in the bulk liquid Na, since the potential contributes to a reduction in the long-term dispersion stability. For the effective control of the SWR with NPs, a physical understanding of the molecular dynamics of NPs in liquid Na is key. Therefore in this study, the nonretarded Van der Waals model and the solvation potential model are employed to analyze the interparticle potential. The ab initio calculation reveals that a strong repulsive force driven by the solvation potential exceeds the interparticle attraction and predicts the agglomeration energy required for two 10-nm Ti NPs to be $4{\times}10^{-17}J$. The collision theory suggests that Ti NPs can be effective suppressors of the SWR due to the high energy barrier that prevents significant agglomeration of Ti NPs in quiescent liquid Na.

Structural Analysis of a Cable Anchor System for a Cable-Stayed Bridge over the Sea (해상 사장교의 Pipe형 케이블 정착구에 관한 구조해석)

  • KONG BYUNG-SEUNC;HONG NAMSEEG
    • Journal of Ocean Engineering and Technology
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    • v.19 no.5 s.66
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    • pp.34-42
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    • 2005
  • The cable connection zone of the cable-stayed bridge transfers deal-load, live-load, and second-load to the cables on the structural joint zone of the cables and the main girders are the most critical parts in which big cable tensile forces are generated by those loads. Therefore, it is necessary to thoroughly check the main girder, structurally to secure the required stability. Because of the heavy tensile force of cables linked in the connection zone of the cable-stayed bridge, locally concentrated stress, as well as the dispersion of stress, occurs in the structurally contacted point of cable and main girder thus, we need to make a thorough investigation through a detailed structural analysis. Directly delivering the tensile force to the connection zone of the cable, the consequently big effect in the tensile force fluctuation caused by the live-load will make it necessary to review the fatigue strength. As the connection zone of the cable is designed to resist the tensile force of the cable, which is applied to a connecting section as a concentrated force, thick plates are used. These plates are frequently made of welded structure, thus, the investigation of the welding workability is inevitable.

The Characteristic of Wave Propagation in the Irregular Wave-current field (불규칙파.흐름 공존장에서 파랑변동특성)

  • Lee, Chang-Ho;Kim, Heon-Tae;Ryu, Cheong-Ro;Lee, In-Cheol
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2003.05a
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    • pp.128-134
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    • 2003
  • Numerical study on interactions of waves and currents has considerable practical interests in coastal and ocean engineering. And wave-current interactions strongly influence wave characteristics, current profiles, and forces on offshore structures. Presence of currents affects wave properties such as wave height and wave profiles. Furthermore, in case of the irregular waves, it is more complicated problem. The propose of present study, using the one-dimensional wave-current numerical model is based on the extended Boussinesq equation(Madsen, 1991) and an alternative form of wave-current dispersion relation(Mohiuddin, 1999, 2000) including wave action concept, is to simulate wave propagation in a current field including the irregular waves and discuss applicability of the model in a wave-current field.

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A semi-analytical study on the nonlinear pull-in instability of FGM nanoactuators

  • Attia, Mohamed A.;Abo-Bakr, Rasha M.
    • Structural Engineering and Mechanics
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    • v.76 no.4
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    • pp.451-463
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    • 2020
  • In this paper, a new semi-analytical solution for estimating the pull-in parameters of electrically actuated functionally graded (FG) nanobeams is proposed. All the bulk and surface material properties of the FG nanoactuator vary continuously in thickness direction according to power law distribution. Here, the modified couple stress theory (MCST) and Gurtin-Murdoch surface elasticity theory (SET) are jointly employed to capture the size effects of the nanoscale beam in the context of Euler-Bernoulli beam theory. According to the MCST and SET and accounting for the mid-plane stretching, axial residual stress, electrostatic actuation, fringing field, and dispersion (Casimir or/and van der Waals) forces, the nonlinear nonclassical equation of motion and boundary conditions are obtained derived using Hamilton principle. The proposed semi-analytical solution is derived by employing Galerkin method in conjunction with the Particle Swarm Optimization (PSO) method. The proposed solution approach is validated with the available literature. The freestanding behavior of nanoactuators is also investigated. A parametric study is conducted to illustrate the effects of different material and geometrical parameters on the pull-in response of cantilever and doubly-clamped FG nanoactuators. This model and proposed solution are helpful especially in mechanical design of micro/nanoactuators made of FGMs.

Development of specific organ-targeting drug delivery system 1

  • Kim, Chong-Kook;Jeong, Eun-Ju;Yang, Ji-Sun;Kim, Seung-Hwan;Kim, Yang-Bae
    • Archives of Pharmacal Research
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    • v.8 no.3
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    • pp.159-168
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    • 1985
  • In attempt to develop a drug delivery system using serum albumin microspheres, bovine serum albumin microspheres containing antitumor agent, cytarabine, were prepared. The shape, surface characteristics, size distribution, behavior of in vitro distribution, drug release behaior, and degradation of albumin microspheres in animal liver tissue homogenate and proteolytic enzyme were investigated. The shape of albumin microspheres was spherical and the surface was smooth and compact. The size distribution of the albumin microspheres was affected by dispersion forces during emulsification and albumin concentration. Distribution of albumin mirospheres after intravenous administration in rabbit was achieved immediately. In vitro, albumin microsphere matrix was so hard that it retained most of cytarabine except initial burst during the first 10 minutes, and the level of drug release during the initial burst was affected by heating temperature, drug/albumin concentration ratio and size distribution. After drug release test, the morphology of albumin micropheres was not changed. Albumin microsphere matrix was degraded by the rabbit liver tissue homogenate and proteolytic enzyme. The degree of degradation was affected by heating temperature.

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Electrochemical Catalysts Test for Nano Pt Particles on Carbon Support Synthesized by a Polyol Process Parameter Control (폴리올 공정 제어에 의한 탄소기반 나노 Pt 촉매 담지 특성 평가)

  • Chae Lin Moon;Jin Woo Bae;Soon Mok Choi
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.36 no.2
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    • pp.164-169
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    • 2023
  • Nano Pt particles were dispersed on carbon-based supports by a polyol process for a catalyst application in a polymer electrolyte fuel cell. We tried to optimize the effect of pH on the electrostatic forces between the support and the Pt colloids. We investigated the relationship among the surface charges on the carbon support, the solution pH, and the concentration of a glycolate, and the Pt particle size. The produced catalyst with nano Pt particles on the support was evaluated by the long-term cyclic voltammetry (CV) performance test and compared with the results from a commercial catalyst. Our experimental results reveal that the pH-control can modify the particle size distribution and the dispersion of the nano Pt particles. This resulted in a cost-effective method for the synthesis of highly Pt loaded Pt/C catalysts for fuel cells better than a commercial catalyst system.

A refined vibrational analysis of the FGM porous type beams resting on the silica aerogel substrate

  • Mohammad Khorasani;Luca Lampani;Abdelouahed Tounsi
    • Steel and Composite Structures
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    • v.47 no.5
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    • pp.633-644
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    • 2023
  • Taking a look at the previously published papers, it is revealed that there is a porosity index limitation (around 0.35) for the mechanical behavior analysis of the functionally graded porous (FGP) structures. Over mentioned magnitude of the porosity index, the elastic modulus falls below zero for some parts of the structure thickness. Therefore, the current paper is presented to analyze the vibrational behavior of the FGP Timoshenko beams (FGPTBs) using a novel refined formulation regardless of the porosity index magnitude. The silica aerogel foundation and various hydrothermal loadings are assumed as the source of external forces. To obtain the FGPTB's properties, the power law is hired, and employing Hamilton's principle in conjunction with Navier's solution method, the governing equations are extracted and solved. In the end, the impact of the various variables as different beam materials, elastic foundation parameters, and porosity index is captured and displayed. It is revealed that changing hygrothermal loading from non-linear toward uniform configuration results in non-dimensional frequency and stiffness pushing up. Also, Al - Al2O3 as the material composition of the beam and the porosity presence with the O pattern, provide more rigidity in comparison with using other materials and other types of porosity dispersion. The presented computational model in this paper hopes to help add more accuracy to the structures' analysis in high-tech industries.

Analysis of the factors of the failure of the North Korean Army's Great Bypass Maneuver to Honam during the Korea War from an indirect approach strategy: Focusing on the Naval and Marine Corps' Tongyeong Amphibious Operation to Stop the "Dislocation" (간접접근전략으로 본 6·25전쟁기 북한군의 호남 방면 대우회기동 실패 요인 분석 -'교란'을 저지한 해군·해병대의 통영상륙작전을 중심으로-)

  • Choi, Ho-jae
    • Maritime Security
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    • v.6 no.1
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    • pp.109-135
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    • 2023
  • The North Korean military's maneuver toward Honam was the fastest maneuver the North Korean army had demonstrated during the Korean War, and it was a threatening attack that forced the Korean and Allied forces to fully adjust the defenses of the Nakdong River. However, when this study analyzed the North Korean military's maneuver toward Honam in terms of indirect approach strategy, there were a number of factors that inevitably led to its failure. In terms of implementing the indirect approach strategy, the North Korean military cited a number of failure factors, including the dispersion of combat forces, the inflexibility of changing the line of operation, the maneuvering of ground forces, and the lack of psychological distaction. However, the North Koreans were preparing for a final "surprise attack," in which the 7th Division, which was following the North Korean 6th Division, took another diversion and attempted to attack in the direction of Tongyeong. With this, the North Koreans intended to break through the Nakdong River defenses and head for Pusan. However, the North Korean attack was ultimately thwarted by the Korean Navy and Marine Corps' Tongyeong Amphibious Operation. With a swift maneuver using the sea as a maneuvering space, the Navy and Marine Corps occupied key points first, creating an advantageous situation and fending off an attack by the North Korean 7th Division. The Navy and Marine Corps' Tongyeong Amphibious Operation finally thwarted the North Korean military's maneuver toward Honam, thus maintaining the Nakdong River defenses.

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Surface-modified Nanoparticle Additives for Wear Resistant Water-based Coatings for Galvanized Steel Plates

  • Becker-Willinger, Carsten;Heppe, Gisela;Opsoelder, Michael;Veith, H.C. Michael;Cho, Jae-Dong;Lee, Jae-Ryung
    • Corrosion Science and Technology
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    • v.9 no.4
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    • pp.147-152
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    • 2010
  • Conventional paints for conversion coating applications in steel production derived mainly from water-based polymer dispersions containing several additives actually show good general performance, but suffer from poor scratch and abrasion resistance during use. The reason for this is because the relatively soft organic binder matrix dominates the mechanical surface properties. In order to maintain the high quality and decorative function of coated steel sheets, the mechanical performance of the surface needs to be improved significantly. In fact the wear resistance should be enhanced without affecting the optical appearance of the coatings by using appropriate nanoparticulate additives. In this direction, nanocomposite coating compositions (Nanomer$^{(R)}$) have been derived from water-based polymer dispersions with an increasing amount of surface-modified nanoparticles in aqueous dispersion in order to monitor the effect of degree of filling with rigid nanoparticles. The surface of nanoparticles has been modified for optimum compatibility with the polymer matrix in order to achieve homogeneous nanoparticle dispersion over the matrix. This approach has been extended in such a way that a more expanded hybrid network has been condensed on the nanoparticle surface by a hydrolytic condensation reaction in addition to the quasi-monolayer type small molecular surface modification. It was expected that this additional modification will lead to more intensive cross-linking in coating systems resulting in further improved scratch-resistance compared to simple addition of nanoparticles with quasi-monolayer surface modification. The resulting compositions have been coated on zinc-galvanized steel and cured. The wear resistance and the corrosion protection of the modified coating systems have been tested in dependence on the compositional change, the type of surface modification as well as the mixing conditions with different shear forces. It has been found out that for loading levels up to 50 wt.-% nanoparticles, the mechanical wear resistance remains almost unaffected compared to the unmodified resin. In addition, the corrosion resistance remained unaffected even after $180^{\circ}$ bending test showing that the flexibility of coating was not decreased by nanoparticle addition. Electron microscopy showed that the inorganic nanoparticles do not penetrate into the organic resin droplets during the mixing process but rather formed agglomerates outside the polymer droplet phase resulting in quite moderate cross linking while curing, because of viscosity. The proposed mechanisms of composite formation and cross linking could explain the poor effect regarding improvement of mechanical wear resistance and help to set up new synthesis strategies for improved nanocomposite morphologies, which should provide increased wear resistance.

Consideration of the entropic effect in protein-ligand docking using colony energy (콜로니 에너지를 이용한 단백질-리간드 결합 문제에서의 엔트로피 효과 계산)

  • Lee, Ju-Yong;Seok, Cha-Ok
    • Bioinformatics and Biosystems
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    • v.1 no.2
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    • pp.103-108
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    • 2006
  • Computational prediction of protein-ligand binding has been widely used as a tool to discover lead compounds fur new drugs. Prediction accuracy is determined in part by the scoring function used in docking calculations. Diverse scoring functions are available, and these can be classified into force-field based, empirical, and knowledge-based functions depending upon the basic assumptions made in development. Among these, force-field based functions consider physical interactions the most in detail. However, the force-field based functions have the drawback of not including the entropic effect while considering only the energy contribution such as dispersion or electrostatic forces. In this article, a method to take into account of the entropic effect using the colony energy is suggested when force-field based scoring functions is used by extracting conformational information obtained from the pre-existing docking program. An improved result for decoy discrimination is illustrated when the method is applied to the DOCK scoring function, and this implies that more accurate docking calculation is possible.

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